CN205326823U - Mellow wine hydrogen power generating equipment and storage device thereof - Google Patents
Mellow wine hydrogen power generating equipment and storage device thereof Download PDFInfo
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- CN205326823U CN205326823U CN201520872773.9U CN201520872773U CN205326823U CN 205326823 U CN205326823 U CN 205326823U CN 201520872773 U CN201520872773 U CN 201520872773U CN 205326823 U CN205326823 U CN 205326823U
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Abstract
The utility model discloses a mellow wine hydrogen power generating equipment and storage device thereof, storage device includes: storage container, the isolation mechanism regulating unit who sets up partition mechanism in the container, is connected with partition mechanism, isolation mechanism divide into two at least regions with storage container, and isolation mechanism regulating unit adjusts the position of isolation mechanism in storage container, adjusts each regional size. Isolation mechanism regulating unit includes control module, actuating mechanism, and control module and actuating mechanism are connected, control module controls partition mechanism's position through control actuating mechanism, liquid reduction or carbon dioxide in the liquid storage container increase when reaching the settlement condition, the action of actuating mechanism drive partition mechanism. The utility model discloses can collect the carbon dioxide of power generating equipment release, reduce carbon dioxide's emission, be favorable to the environmental protection, simultaneously, the carbon dioxide of collection can cyclic utilization.
Description
Technical field
This utility model belongs to electric vehicle engineering field, relates to a kind of electric automobile, particularly relates to the storage device of a kind of alcohol hydrogen generating equipment。
Background technology
In numerous new forms of energy, Hydrogen Energy will become the 21 century optimal energy。This is because, when burning the coal of identical weight, gasoline and hydrogen, the energy that hydrogen produces is maximum, and the product of its burning is water, it does not have lime-ash and waste gas, does not pollute the environment；And coal and oil combustion generate is carbon dioxide and sulfur dioxide, greenhouse effect and acid rain can be produced respectively。Coal and reserves are limited, and hydrogen is mainly stored in water, and after burning, unique product is also water, can produce hydrogen continuously, be finished never。
Hydrogen is a kind of colourless gas。One gram of Hydrogen Energy of burning discharges your heat of 142 kilojoules, is 3 times of gasoline caloric value。The weight of hydrogen is particularly lightweight, and it is all light more than gasoline, natural gas, kerosene, thus carries, transports conveniently, is the most suitable fuel of the high-speed flight vehicles such as space flight, aviation。Hydrogen can burn in oxygen, and the temperature of hydrogen flame may be up to 2500 DEG C, thus the conventional hydrogen cutting of people or welding ferrous materials。
In the Nature, the distribution of hydrogen is very extensive。Water is exactly big " warehouse " of hydrogen, wherein contains the hydrogen of 11%。There is the hydrogen of 1.5% earth Rio；All contain hydrogen in oil, coal, natural gas, animal and plant body etc.。The main body of hydrogen is to exist with the form of compound water, and earth surface about 70% is covered by water, and moisture storage capacity is very big, accordingly, it can be said that hydrogen is the energy of " inexhaustible, nexhaustible "。If can with suitable method preparing hydrogen from water, then hydrogen also will be the comparatively inexpensive energy of a kind of price。
Having many uses of hydrogen, the suitability is strong。It can not only be used as fuel, and metal hydride has the function that chemical energy, heat energy and mechanical energy are changed mutually。Such as, hydrogen storage metal has inhales hydrogen heat release and the ability putting hydrogen of absorbing heat, and can be got up by heat storage, use as heating in room and air-conditioning。
Hydrogen, as gaseous fuel, is first used on automobile。In May, 1976, the U.S. develops a kind of automobile making fuel with hydrogen；Later, Japan also succeeded in developing a kind of automobile being fuel with liquified hydrogen；In the latter stage seventies, hydrogen has been tested by the Mercedes of front Germany, and they have only used five kg of hydrogen, just makes running car 110 kilometers。
With hydrogen as motor vehicle fuel, not only totally, easily start at low temperatures, and the corrosiveness of electromotor is little, the service life of electromotor can be extended。Due to hydrogen and air can Homogeneous phase mixing, carburator used on general automobile can be saved completely, thus the structure of existing automobile can be simplified。More interestingly, if in the oil add 4% hydrogen。Use it as automobile engine fuel, so that it may fuel-economizing 40%, and without petrol engine being done great improvement。
Hydrogen easily becomes liquid under certain pressure and temperature, thus it is all very convenient with iron flask car, on-highway tractor or ship transportation。The hydrogen of liquid both can be used as the fuel of automobile, aircraft, it is possible to as the fuel of rocket, guided missile。The U.S. is flown to the Apollo Personnel investigation Program of the moon " Long March carrier rocket that number spacecraft and China launch a man-made satellite., all make fuel with liquified hydrogen。
It addition, use hydrogen hydrogen fuel cell Hydrogen Energy can also be directly translated into electric energy, make utilizing of Hydrogen Energy more convenient。At present, this fuel cell is used in spacecraft and submarine, and effect is pretty good。Certainly, due to relatively costly, also it is difficult to commonly use for the moment。
Now the annual production of hydrogen is about 36,000,000 tons in the world, is wherein mostly and produces from oil, coal and natural gas, and this must consume fossil fuel natively very in short supply；The hydrogen separately having 4% is to produce by the method for electrolysis water, but the electric energy consumed is too many, does not calculate very much, and therefore, people are trying to explore research hydrogen manufacturing new method。And the energy consumption in Chemical Manufacture can be reduced with methanol, water reformation hydrogen production and reduce cost, it is expected to substitute the technique of " water electrolysis hydrogen production " that be referred to as electricity-eating tiger, utilizes advanced methanol vapor to reform--pressure swing adsorption making pure hydrogen and rich in CO2Mixing gas, through further post processing, hydrogen and carbon dioxide gas can be obtained simultaneously。
By catalyst, under the effect of catalyst, there is the transformationreation of methanol decomposition reaction and carbon monoxide, generate hydrogen and carbon dioxide in methanol and steam, this is the gas solid catalytic reaction system of component more than, many reactions under certain temperature, pressure condition。Reactional equation is as follows:
CH3OH→CO+2H2(1)
H2O+CO→CO2+H2(2)
CH3OH+H2O→CO2+3H2(3)
The H that reforming reaction generates2And CO2, then through palladium membrance separation by H2And CO2Separate, obtain high-purity hydrogen。The power consumption of pressure swing adsorption method is high, equipment is big, and is not suitable for small-scale hydrogen and prepares。
Existing hydrogen gas generating system, it is common that utilize the hydrogen gas generation prepared, namely prepare hydrogen and separate with hydrogen gas generation。Prepare hydrogen first with hydrogen producer, hydrogen is positioned in hydrogen gas buffer, then by the hydrogen gas generation in hydrogen gas buffer。The volume of hydrogen gas buffer is comparatively huge, not Portable belt, and mobility is poor, thus constraining the portability of hydrogen preparation and generating equipment。
In order to improve the portability of hydrogen producer, the applicant proposed mobile hydrogen making electricity generation system in 2013, and volume is little, it is simple to carry。Although mobile hydrogen making electricity generation system not discharge of noxious gases, but carbon dioxide can be discharged, too much carbon dioxide can cause greenhouse effect, is unfavorable for environmental conservation。
In view of this, nowadays in the urgent need to designing a kind of new hydrogen gas generating system, in order to overcome the drawbacks described above of existing hydrogen gas generating system。
Utility model content
Technical problem to be solved in the utility model is: provide the storage device of a kind of alcohol hydrogen generating equipment, can collect the carbon dioxide of generating equipment release, reduces the discharge of carbon dioxide, is conducive to protection environment；Meanwhile, the carbon dioxide of collection can recycle。
Additionally, this utility model also provides for a kind of alcohol hydrogen generating equipment, the carbon dioxide of generating equipment release can be collected, reduce the discharge of carbon dioxide, be conducive to protection environment；Meanwhile, the carbon dioxide of collection can recycle。
For solving above-mentioned technical problem, this utility model adopts the following technical scheme that
The storage device of a kind of alcohol hydrogen generating equipment, described storage device includes: driving mechanism that container, the space mechanism being arranged in container are connected with space mechanism, control module, induction module；
Container is at least divided into two spaces by described space mechanism；In two spaces, a placing response liquid, opposite side arranges the carbon dioxide of hydrogen gas generating system release, the liquid then compressed or solid-state；Control module and connect driving mechanism, induction module respectively；
Described driving mechanism includes motor, and induction module includes pressure transducer or/and liquid level sensor；Induction module link control module；Described control module connects driving mechanism, controls the driving mechanism action to space mechanism；
Described storage device also includes liquefying plant or/and solidification equipment, by the co 2 liquefaction collected or/and solidify。
The storage device of a kind of alcohol hydrogen generating equipment, described storage device includes: the interrupter regulon that storage container, the space mechanism being arranged in container are connected with space mechanism；
Storage container is divided at least two region by described interrupter, and interrupter regulon regulates interrupter position in storage container, regulates the size of regional。
As a kind of preferred version of the present utility model, described interrupter regulon includes controlling module, driving mechanism, controls module and is connected with driving mechanism；
In some regions that storage container is isolated by described space mechanism, have at least placing response liquid in a region, have at least in a region to arrange the carbon dioxide of hydrogen gas generating system release, the liquid then compressed or solid-state；
Described control module comes the position of control interval mechanism by controlling driving mechanism；When liquid in liquid storage container reduces or carbon dioxide increases up to impose a condition, driving mechanism drives space mechanism action。
As a kind of preferred version of the present utility model, described interrupter regulon also includes induction module, in order to sense the amount of reaction liquid in container, or/and sense the amount of carbon dioxide of hydrogen gas generating system release, the liquid then compressed or solid-state；And sensed data is sent to controlling module；
The Data Control driving mechanism that described control module senses according to the induction module action to space mechanism；When liquid in liquid storage container reduces or carbon dioxide increases up to impose a condition, driving mechanism drives space mechanism action。
As a kind of preferred version of the present utility model, when liquid in liquid storage container reduces or carbon dioxide increases up to impose a condition, described control module controls driving mechanism and drives space mechanism action, reduces the volume of reaction liquid, increases the volume of carbon dioxide。
As a kind of preferred version of the present utility model, described storage device also includes liquefying plant or/and solidification equipment, by the co 2 liquefaction collected or/and solidify。
A kind of alcohol hydrogen generating equipment, including hydrogen production by methanol system, hydrogen gas generating system, hydrogen production by methanol system is connected with hydrogen gas generating system；
Described hydrogen production by methanol system includes hydrogen manufacturing subsystem, air pressure adjustment subsystem, Collection utilization subsystem, and hydrogen manufacturing subsystem, air pressure adjustment subsystem, hydrogen gas generating system, Collection utilization subsystem are sequentially connected with；
Described hydrogen manufacturing subsystem utilizes methanol-water to prepare hydrogen, and described hydrogen manufacturing subsystem includes solid hydrogen storage container, storage container, raw material conveying device, device for rapidly starting, hydrogen producer, membrane separation device；
The middle part of described storage container is provided with dividing plate, and the side of dividing plate arranges reaction liquid, and opposite side arranges the carbon dioxide of hydrogen gas generating system release, the liquid then compressed or solid-state；Dividing plate is connected to pushing mechanism, and when the liquid in storage container reduces or carbon dioxide increases up to impose a condition, pushing mechanism drives dividing plate action, reduces the volume of storage reaction liquid regions, increases the volume in storage carbon dioxide region；
Described hydrogen producer includes heat exchanger, vaporizer, reformer chamber；Membrane separation device is arranged in separation chamber, and separation chamber is arranged at the inside of reformer chamber；Described solid hydrogen storage container, storage container are connected with hydrogen producer respectively；In storage container, storage has the first alcohol and water of liquid；
Described device for rapidly starting provides for hydrogen producer and starts the energy；Described device for rapidly starting includes the first startup device, the second startup device；Described first starts device includes the first heating arrangements, the first gasification pipe, and the internal diameter of the first gasification pipe is 1～2mm, and the first gasification pipe is closely wound on the first heating arrangements；One end of described first gasification pipe connects storage container, is sent in the first gasification pipe by methanol by raw material conveying device；The other end of the first gasification pipe exports vaporized methanol, then by ignition mechanism ignition；Or, the other end of the first gasification pipe exports vaporized methanol, and the methanol temperature of output reaches self-ignition point, and methanol is direct spontaneous combustion after exporting from the first gasification pipe；Described second starts device includes the second gasification pipe, the main body of the second gasification pipe is arranged at described reformer chamber, first gasification pipe is or/and the methanol of the second gasification pipe output heats the second gasification pipe while being reformer chamber heating, by the methanol gasifying in the second gasification pipe；Described reformer chamber inwall is provided with and adds pipe line, adds and is placed with catalyst in pipe line；Described device for rapidly starting by heat described in add pipe line attach most importance to whole room heating；After described hydrogen generating system starts, hydrogen generating system is provided by the hydrogen that hydrogen producer prepares and runs the required energy；
The initial start energy of described device for rapidly starting is that some solar energys start module, and solar energy starts solar panel that module includes being sequentially connected with, solar energy-electric energy change-over circuit, solaode；Solar energy starts module provides electric energy for the first heating arrangements；Or, the initial start energy of described device for rapidly starting is manual generator, and the electric energy sent is stored in battery by manual generator；
Described catalyst includes the oxide of Pt, the oxide of Pd, the oxide of Cu, the oxide of Fe, the oxide of Zn, rare-earth oxide, transition metal oxide；Wherein, precious metals pt content accounts for the 0.6%～1.8% of catalyst gross mass, Pd content accounts for the 1.1%～4% of catalyst gross mass, the oxide of Cu accounts for the 6%～12% of catalyst gross mass, the oxide of Fe accounts for the 3%～8% of catalyst gross mass, the oxide of Zn accounts for the 8%～20% of catalyst gross mass, and rare-earth oxide accounts for the 6%～40% of catalyst gross mass, and all the other are transition metal oxide；
Or, described catalyst is copper-based catalysts, including material and mass fraction thereof is: the Al of ZrO, 55-80 part of ZnO, 0.5-3 part of CuO, 3-18 part of 3-17 part2O3, the CeO of 1-3 part2, the La of 1-3 part2O3；
Storing solid hydrogen in described solid hydrogen storage container, when hydrogen generating system starts, by gasifying, solid hydrogen is converted to gaseous hydrogen by module, and gaseous hydrogen passes through combustion heat release, provides for hydrogen producer and starts heat energy, as the startup energy of hydrogen producer；
First alcohol and water in described storage container is delivered to heat exchanger heat exchange by raw material conveying device, enters vaporizer gasification after heat exchange；Methanol vapor and steam after gasification enter reformer chamber, and it is 300 DEG C～420 DEG C that reformer chamber is provided with catalyst, reformer chamber bottom and middle portion temperature；The temperature on described reformer chamber top is 400 DEG C～570 DEG C；Reformer chamber is connected by connecting line with separation chamber, all or part of top being arranged at reformer chamber of connecting line, and the high temperature that can pass through reformer chamber top continues the heating gas from reformer chamber output；Described connecting line is as the buffering between reformer chamber and separation chamber so that identical or close with the temperature of separation chamber from the temperature of the gas of reformer chamber output；Temperature in described separation chamber is set as 350 DEG C～570 DEG C；It is provided with membrane separator in separation chamber, obtains hydrogen from the aerogenesis end of membrane separator；
Described raw material conveying device provides power, by the feedstock transportation in storage container to hydrogen producer；Described raw material conveying device provides the pressure of 0.15～5MPa to raw material so that the hydrogen that hydrogen producer prepares has enough pressure；
After described hydrogen producer starts hydrogen manufacturing, the hydrogen partial that hydrogen producer prepares is or/and residual air is run by the maintenance hydrogen producer that burns；
The hydrogen that described hydrogen producer prepares is delivered to membrane separation device and is easily separated, for the difference of inside and outside pressure of membrane separation device of separating hydrogen gas be more than or equal to 0.7MPa；Described membrane separation device is the membrane separation device at porous ceramic surface Vacuum Deposition palladium-silver, and film plating layer is palladium-silver, and the mass percent palladium of palladium-silver accounts for 75%～78%, and silver accounts for 22%～25%；
Described hydrogen manufacturing subsystem by prepared hydrogen by transfer conduit real-time Transmission to hydrogen gas generating system；Described transfer conduit is provided with air pressure adjustment subsystem, for adjusting the air pressure in transfer conduit；Described hydrogen gas generating system utilizes the hydrogen gas generation that hydrogen manufacturing subsystem prepares；
Described air pressure adjustment subsystem includes microprocessor, gas pressure sensor, valve positioner, air outlet valve, outlet pipe；Described gas pressure sensor is arranged in transfer conduit, in order to sense the barometric information in transfer conduit, and sends the barometric information of sensing to microprocessor；This barometric information received from gas pressure sensor is compared by described microprocessor with setting threshold interval；When the pressure data received is higher than the maximum setting threshold interval, microprocessor controls valve positioner and opens the air outlet valve setting time, air pressure in transfer conduit is made to be in set point, one end of outlet pipe connects air outlet valve simultaneously, the other end connects described hydrogen manufacturing subsystem, is that the firing equipment that needs of hydrogen manufacturing subsystem is heated by burning；When the pressure data received is lower than the minima setting threshold interval, microprocessor controls described hydrogen manufacturing subsystem and accelerates the transporting velocity of raw material；
Described Collection utilization subsystem connects the Vent passageway of hydrogen gas generating system, hydrogen, oxygen gas and water is collected respectively from expellant gas, utilize the hydrogen collected, oxygen for hydrogen manufacturing subsystem or/and hydrogen gas generating system, the water collected is as the raw material of hydrogen manufacturing subsystem, thus recycling；
Described Collection utilization subsystem includes hydrogen/oxygen separator, hydrogen water separator, hydrogen check-valves, oxygen water separator, oxygen check valve, by hydrogen and oxygen separation, is then separated from water by hydrogen respectively, oxygen is separated from water；
Described hydrogen producer also includes electric energy estimation block, hydrogen prepares detection module, electric energy memory module；The electric energy that when whether the electric energy that described electric energy estimation block sends in real time in order to estimate hydrogen gas generation device can meet reformation, separation, needs consume；If it is satisfied, then closedown device for rapidly starting；
Whether hydrogen prepares the hydrogen that detection module prepared in real time for detecting hydrogen producer stable；If hydrogen prepared by hydrogen producer is unstable, then controls device for rapidly starting and be again started up, and the electric energy obtained is partially stored in electric energy memory module, use when electric energy is not enough to the consumption providing hydrogen producer；
Described hydrogen gas generation device is fuel cell system, and fuel cell system includes: gas supply device, pile；Described gas supply device utilizes the gas of compression as power, and automatic transport is to pile；
Described fuel cell system also includes air intake conduit, outlet pipe；The gas of described compression is mainly oxygen；Air enters pile with oxygen after mixing container mixing；
Described fuel cell system also includes gas regulating system；Described gas regulating system includes valve regulated and controls device, and oxygen content sensor is or/and compress gas compression ratio sensor；
Described oxygen content sensor is in order to sense the air of mixing and the content of oxygen in oxygen in mixing container, and the data sensed is sent to valve regulated control device；
Described compression gas compression ratio sensor is in order to sense the compression ratio of compressed oxygen, and the data sensed is sent to valve regulated control device；
Described valve regulated controls device according to oxygen content sensor or/and the sensing result of compression gas compression ratio sensor regulates oxygen delivery valve door, air entrainment valve door, controls the conveying ratio of compressed oxygen, air；Mixing gas is pushed to pile reaction by the power that compressed oxygen produces after entering mixing container；
Described fuel cell system also includes humidification system, and humidification system includes humidity exchanging container, humidity exchange pipeline, and humidity exchange pipeline is a part for air intake conduit；After described reaction, gas outlet pipe is delivered to humidity exchanging container,
The material of described humidity exchange pipeline is only permeable airtight so that after reaction, gas and natural air carry out humidity exchange, and cannot circulate between gas。
A kind of alcohol hydrogen generating equipment, including hydrogen generating system, hydrogen gas generating system, hydrogen generating system is connected with hydrogen gas generating system；
Described hydrogen production by methanol system includes hydrogen manufacturing subsystem, and described hydrogen manufacturing subsystem includes hydrogen producer, membrane separation device；Described hydrogen producer includes heat exchanger, vaporizer, reformer chamber；Membrane separation device is arranged in separation chamber；
Described hydrogen generating system includes storage container, and storage container includes carbon dioxide collection region, collects the carbon dioxide of release in hydrogen gas generating system。
Described hydrogen generating system utilizes preparing hydrogen by reforming methanol-water steam, and hydrogen obtains highly purified hydrogen by being coated with the membrane separation device of palladium-silver, and the hydrogen of acquisition is generated electricity by hydrogen gas generating system, and the electric energy sent is for genemotor work。
As a kind of preferred version of the present utility model, described storage device includes: the interrupter regulon that storage container, the space mechanism being arranged in container are connected with space mechanism；
Storage container is divided at least two region by described interrupter, and interrupter regulon regulates interrupter position in storage container, regulates the size of regional。
As a kind of preferred version of the present utility model, described interrupter regulon includes controlling module, driving mechanism, controls module and is connected with driving mechanism；
In some regions that storage container is isolated by described space mechanism, have at least placing response liquid in a region, have at least in a region to arrange the carbon dioxide of hydrogen gas generating system release, the liquid then compressed or solid-state；
Described control module comes the position of control interval mechanism by controlling driving mechanism；When liquid in liquid storage container reduces or carbon dioxide increases up to impose a condition, driving mechanism drives space mechanism action。
The beneficial effects of the utility model are in that: the alcohol hydrogen generating equipment that the utility model proposes and storage device thereof, the storage device of alcohol hydrogen generating equipment, can collect the carbon dioxide of generating equipment release, reduce the discharge of carbon dioxide, are conducive to protection environment；Meanwhile, the carbon dioxide of collection can recycle。
This utility model device for producing hydrogen volume is little, utilizes distinctive catalyst formulation and palladium film to purify, and the hydrogen of preparation is quickly, stable, purity is high, it is possible to provide stable input energy sources for automobile。
Accompanying drawing explanation
Fig. 1 is the composition schematic diagram of this utility model water hydrogen car。
Fig. 2 is the composition schematic diagram of this utility model hydrogen generating system, electricity generation system。
Fig. 3 is the operating diagram of Collection utilization subsystem。
Fig. 4 is another composition schematic diagram of this utility model hydrogen generating system, electricity generation system。
Fig. 5 is the composition schematic diagram of hydrogen manufacturing subsystem。
Fig. 6 is another composition schematic diagram of hydrogen manufacturing subsystem。
Fig. 7 is the structural representation of the first startup device。
Fig. 8 is the structural representation storing container。
Fig. 9 is the composition schematic diagram of fuel cell system in this utility model system。
Detailed description of the invention
Preferred embodiment of the present utility model is described in detail below in conjunction with accompanying drawing。
Embodiment one
Refer to Fig. 8, this utility model discloses the storage device of a kind of alcohol hydrogen generating equipment, the middle part of storage device is provided with dividing plate 101, and the side of dividing plate 101 arranges reaction liquid, and opposite side arranges the carbon dioxide of hydrogen gas generating system release, the liquid then compressed or solid-state。The two ends of dividing plate 101 are arranged in chute 102, can slide along chute 102。
Interrupter regulon includes the driving mechanism being connected with dividing plate 101, and controls module, induction module；Control module and connect driving mechanism, induction module respectively。Described driving mechanism can include motor, and induction module can include pressure transducer (be used for sense gas pressure intensity) or/and liquid level sensor (being used for sensing liquid level position)。
Described induction module, in order to sense the amount of reaction liquid in container, senses the amount of the carbon dioxide of hydrogen gas generating system release, the liquid then compressed or solid-state simultaneously；And sensed data is sent to controlling module。
The Data Control driving mechanism that described control module senses according to the induction module action to dividing plate 101；When liquid in liquid storage container reduces or carbon dioxide increases up to impose a condition, driving mechanism drives dividing plate 101 action, reduces the volume of reaction liquid, increases the volume of carbon dioxide。
Described storage device also includes liquefying plant or/and solidification equipment, by the co 2 liquefaction collected or/and solidify。
So can while preparing hydrogen, collect the carbon dioxide of release, reducing the discharge of carbon dioxide, the carbon dioxide of collection is also used as the raw material of subsequent handling (as utilized carbon dioxide to prepare methanol, for the hydrogen that preparation generating needs)。
Embodiment two
Refer to Fig. 1, this utility model discloses a kind of water hydrogen car (a kind of application of this utility model alcohol hydrogen generating equipment), described power vehicle includes: vehicle body, hydrogen production by methanol system, hydrogen gas generating system, genemotor, and hydrogen production by methanol system, hydrogen gas generating system, genemotor are arranged in vehicle body；Hydrogen production by methanol system, hydrogen gas generating system, genemotor are sequentially connected with。Described hydrogen production by methanol system utilizes preparing hydrogen by reforming methanol-water steam, and hydrogen obtains highly purified hydrogen by being coated with the membrane separation device of palladium-silver, and the hydrogen of acquisition is generated electricity by hydrogen gas generating system, and the electric energy sent is for genemotor work。This utility model alcohol hydrogen generating equipment includes hydrogen production by methanol system therein, hydrogen gas generating system。
Refer to Fig. 2 to Fig. 4, described hydrogen production by methanol system includes hydrogen manufacturing subsystem 100, air pressure adjustment subsystem 200, Collection utilization subsystem 400, and hydrogen manufacturing subsystem 100, air pressure adjustment subsystem 200, hydrogen gas generating system 300, Collection utilization subsystem 400 are sequentially connected with。
Described hydrogen manufacturing subsystem 100 utilizes methanol-water to prepare hydrogen, is used for generating electricity to hydrogen gas generating system 300 by transfer conduit real-time Transmission by prepared hydrogen；Described Collection utilization subsystem 400 connects the Vent passageway of hydrogen gas generating system 300, collects hydrogen from expellant gas, or utilizes the hydrogen collected for hydrogen manufacturing subsystem 100 or/and hydrogen gas generating system 300。
Referring to Fig. 5, described solid hydrogen storage container 80, storage container 10 are connected with hydrogen producer 20 respectively；Storage container 10 stores the first alcohol and water of liquid, described solid hydrogen storage container 80 stores solid hydrogen。
Referring to Fig. 8, described storage container is arranged at the rear portion of vehicle body；The middle part of storage container is provided with dividing plate 101, and the side of dividing plate 101 arranges reaction liquid, and opposite side arranges the carbon dioxide of hydrogen gas generating system release, the liquid then compressed or solid-state。Dividing plate 101 is connected to pushing mechanism, and when the liquid in storage container reduces or carbon dioxide increases up to impose a condition, pushing mechanism drives dividing plate action, reduces the volume of storage reaction liquid regions, increases the volume in storage carbon dioxide region。So while preparing hydrogen, can collecting the carbon dioxide of release, reduce the discharge of carbon dioxide, the carbon dioxide of collection is also used as the raw material of subsequent handling。The two ends of dividing plate 101 are arranged in chute 102, can slide along chute 102。
When hydrogen generating system starts, by gasifying, the solid hydrogen in solid hydrogen storage container 80 is converted to gaseous hydrogen by module, and gaseous hydrogen passes through combustion heat release, provides for hydrogen producer 20 and starts heat energy, as the startup energy of hydrogen producer 20。Certainly, solid hydrogen storage container 80 is not necessaries of the present utility model, it is possible to start hydrogen producer 20 by other energy。
Described raw material conveying device 50 provides power, by the feedstock transportation in storage container 10 to hydrogen producer 20；Described raw material conveying device 50 provides the pressure of 0.15～5MPa (as provided the pressure of 0.2MPa or 1.1MPa or 1.2MPa or 1.5MPa or 5MPa) to raw material so that the hydrogen that hydrogen producer 20 prepares has enough pressure。After described hydrogen producer 20 starts hydrogen manufacturing, the hydrogen partial that hydrogen producer 20 prepares runs (certainly, the operation of hydrogen producer 20 can also pass through other energy) or/and residual air maintains hydrogen producer 20 by burning。
Referring to Fig. 6, described device for rapidly starting provides for hydrogen producer and starts the energy；Described device for rapidly starting includes the first startup device 40, second and starts device 60。
As it is shown in fig. 7, described first startup device 40 includes housing the 41, first heating arrangements the 42, first gasification pipe 43, the internal diameter of the first gasification pipe 43 is 1～2mm, and the first gasification pipe 43 is closely wound on the first heating arrangements 42；First heating arrangements 42 can be electrically heated rod, utilizes alternating current or accumulator, aneroid battery。
One end of described first gasification pipe 43 connects storage container 10, and methanol is admitted in the first gasification pipe 43；The other end of the first gasification pipe 43 exports vaporized methanol, then by ignition mechanism ignition；Or, the other end of the first gasification pipe 43 exports vaporized methanol, and the methanol temperature of output reaches self-ignition point, and methanol is direct spontaneous combustion after exporting from the first gasification pipe 43。
Described second starts device 60 includes the second gasification pipe, and the main body of the second gasification pipe is arranged at described reformer chamber, and the second gasification pipe is reformer chamber heating (can also be the heating of other unit of hydrogen generating system)。First gasification pipe 43 is or/and the methanol of the second gasification pipe output heats the second gasification pipe while being reformer chamber heating, by the methanol gasifying in the second gasification pipe。
First, the methanol needing the first gasification pipe 43 output heats the second gasification pipe, the setting time after the methanol producing to gasify can be continued, it is possible to select to close the first startup device 40, and be that the second gasification pipe heats by the methanol of the second gasification pipe output until the second gasification pipe；So can reduce the dependence to extra power further。
In order to improve the firing rate of hydrogen producer, the reformer chamber inwall at described hydrogen producer 20 is provided with and adds pipe line, adds and is placed with catalyst (as can by heating and temperature control at 380 DEG C～480 DEG C) in pipe line；Described device for rapidly starting 40 is attached most importance to the heating of whole room by adding pipe line described in heating, it is possible to improve the efficiency of heating surface。After described hydrogen generating system starts, hydrogen generating system is provided by the hydrogen that hydrogen producer prepares and runs the required energy；At this point it is possible to closedown device for rapidly starting。
In addition, in order to start automobile when there is no other energy, the initial start energy of described device for rapidly starting is that some solar energys start module, and solar energy starts solar panel that module includes being sequentially connected with, solar energy-electric energy change-over circuit, solaode；Solar energy starts module provides electric energy for the first heating arrangements；Or, the initial start energy of described device for rapidly starting is manual generator, and the electric energy sent is stored in battery by manual generator。
First alcohol and water in described storage container is delivered to heat exchanger heat exchange by raw material conveying device, enters vaporizer gasification after heat exchange；Methanol vapor and steam after gasification enter reformer chamber, and it is 320 DEG C～430 DEG C that reformer chamber is provided with catalyst, reformer chamber bottom and middle portion temperature；The temperature on described reformer chamber top is 440 DEG C～560 DEG C；Reformer chamber is connected by connecting line with separation chamber, all or part of top being arranged at reformer chamber of connecting line, and the high temperature that can pass through reformer chamber top continues the heating gas from reformer chamber output；Described connecting line is as the buffering between reformer chamber and separation chamber so that identical or close with the temperature of separation chamber from the temperature of the gas of reformer chamber output；Temperature in described separation chamber is set as 360 DEG C～560 DEG C；It is provided with membrane separator in separation chamber, obtains hydrogen from the aerogenesis end of membrane separator。
Described reformer chamber is provided with catalyst, and catalyst includes the oxide of Pt, the oxide of Pd, the oxide of Cu, the oxide of Fe, the oxide of Zn, rare-earth oxide, transition metal oxide。Wherein precious metals pt content accounts for the 0.5%～2% of catalyst gross mass, Pd content accounts for the 1%～5% of catalyst gross mass, the oxide of Cu accounts for the 5%～15% of catalyst gross mass, the oxide of Fe accounts for the 2%～10% of catalyst gross mass, the oxide of Zn accounts for the 10%～25% of catalyst gross mass, rare-earth oxide accounts for the 5%～45% of catalyst gross mass, and all the other are transition metal oxide。
Or, described catalyst is copper-based catalysts, including material and mass fraction thereof is: the Al of ZrO, 55-80 part of ZnO, 0.5-3 part of CuO, 3-18 part of 3-17 part2O3, the CeO of 1-3 part2, the La of 1-3 part2O3。As, copper-based catalysts includes material and mass fraction is: the CuO of 10 parts, the ZnO of 10 parts, the ZrO of 2 parts, the Al of 60 parts2O3, the CeO of 2 parts2, the La of 2 parts2O3。
Described raw material conveying device provides power, by the feedstock transportation in storage container to hydrogen producer；Described raw material conveying device provides the pressure of 0.15～5MPa to raw material so that the hydrogen that hydrogen producer prepares has enough pressure；After described hydrogen producer starts hydrogen manufacturing, the hydrogen partial that hydrogen producer prepares is or/and residual air is run by the maintenance hydrogen producer that burns。
The hydrogen that described hydrogen producer 20 prepares is delivered to membrane separation device 30 and is easily separated, for the difference of inside and outside pressure of membrane separation device 30 of separating hydrogen gas be more than or equal to 0.7MPa (the inside and outside pressure such as membrane separation device 30 is 0.7MPa or 1.1MPa or 1.2MPa or 1.5MPa or 5MPa)。In the present embodiment, described membrane separation device 30 is the membrane separation device at porous ceramic surface Vacuum Deposition palladium-silver, and film plating layer is palladium-silver, and the mass percent palladium of palladium-silver accounts for 75%～78%, and silver accounts for 22%～25%。
Described hydrogen manufacturing subsystem by prepared hydrogen by transfer conduit real-time Transmission to hydrogen gas generating system；Described transfer conduit is provided with air pressure adjustment subsystem, for adjusting the air pressure in transfer conduit；Described hydrogen gas generating system utilizes the hydrogen gas generation that hydrogen manufacturing subsystem prepares。
As shown in Figure 4, described air pressure adjustment subsystem 200 includes microprocessor 21, gas pressure sensor 22, valve positioner 23, air outlet valve 24, outlet pipe 25。Described gas pressure sensor 22 is arranged in transfer conduit, in order to sense the barometric information in transfer conduit, and sends the barometric information of sensing to microprocessor 21；This barometric information received from gas pressure sensor 22 is compared by described microprocessor 21 with setting threshold interval, and controls the switch of air outlet valve 24 with this。When the pressure data received is higher than the maximum setting threshold interval, microprocessor 21 controls valve positioner 23 and opens the air outlet valve setting time, air pressure in transfer conduit is made to be in set point. preferably, one end of outlet pipe 25 connects air outlet valve 24, the other end connects described hydrogen manufacturing subsystem 100, is that the firing equipment (such as reformer chamber) that needs of hydrogen manufacturing subsystem 100 is heated by burning；When the pressure data received is lower than the minima setting threshold interval, microprocessor 21 controls described hydrogen manufacturing subsystem 100 and accelerates the transporting velocity of raw material, thus improving hydrogen manufacturing speed。
As shown in Figure 3, described Collection utilization subsystem 400 includes hydrogen water separator 401, hydrogen check-valves 402, the Vent passageway of hydrogen gas generating system 300 connects the entrance of hydrogen water separator 401, is provided with hydrogen check-valves 402, it is prevented that hydrogen pours in down a chimney in the pipeline that hydrogen water separator 401 exit connects；Described hydrogen water separator 401 is for separating hydrogen gas and water。Additionally, described Collection utilization subsystem also includes hydrogen/oxygen separator, for separating hydrogen gas and oxygen；Hydrogen/oxygen separator is arranged between described hydrogen gas generating system Vent passageway and hydrogen water separator。
In the present embodiment, described Collection utilization subsystem 400 also includes oxygen water separator 411, oxygen check valve 412, is used for collecting oxygen。The hydrogen that described Collection utilization subsystem 400 is collected and oxygen are for hydrogen manufacturing subsystem 100, it is also possible to for hydrogen gas generating system 300。Additionally, the oxygen collected can be deposited in setting container, for people's oxygen uptake；The water collected can be drunk for people。
Owing to described Collection utilization subsystem includes moisture trap (such as above-mentioned hydrogen water separator, oxygen water separator), therefore water (the ratio also many several times of the moisture in raw material can be collected, because methanol also contains hydrogen atom, water is obtained with oxygen reaction) after preparing hydrogen, water is delivered to hydrogen manufacturing subsystem 100, raw water can recycle, it is not necessary to additionally adds。
Therefore, this utility model system can collect the utility such as hydrogen, oxygen gas and water from the residual air of hydrogen gas generating system, it is possible to improves the generating efficiency of system, simultaneously conservation (water)。
Described hydrogen manufacturing subsystem utilizes methanol-water to prepare hydrogen, and described hydrogen manufacturing subsystem includes solid hydrogen storage container, storage container, raw material conveying device, device for rapidly starting, hydrogen producer, membrane separation device；
Described hydrogen gas generating system includes fuel cell, and fuel cell includes some sub-fuel cell modules, and each sub-fuel cell module includes at least one super capacitor；So can export electric energy efficiently, without jumbo lithium battery。
Additionally, described automobile can also include the second genemotor, energy storage units, kinetic energy converting unit, kinetic energy converting unit, energy storage units, the second genemotor are sequentially connected with；The energy of automobile brake is converted to electric energy and is stored in energy storage units by described kinetic energy converting unit, provides electric energy for the second genemotor。Described second genemotor is also connected with hydrogen gas generating system, hydrogen gas generating system provide the energy for the second genemotor。So the energy of skidding consumption can be stored as electric energy, thus the effectively save energy。
Meanwhile, described automobile also includes road environment induction module, allocation database, hydrogen distribution module；Hydrogen distribution module is connected with road environment induction module, allocation database respectively, according to the hydrogen that the data in the data of road environment induction module sensing and allocation database are each genemotor distribution correspondence。
Described road environment induction module is in order to sense road congestion information, ground flat degree information；Road congestion information is according to automobile real-time speed, acceleration, deceleration frequency, and determines down time；Ground flat degree information is determined according to the obliquity sensor arranged on automobile chassis。
Described allocation database stores some tables of data, tables of data records the data (these data according to environmental information power that two genemotors distribution is different, can improve efficiency) for genemotor, the second genemotor distribution hydrogen that each road congestion information, ground flat degree information are corresponding；In genemotor, the second genemotor, one is used for driving trailing wheel or/and front-wheel (such as trailing wheel), and another is used for driving front-wheel or/and trailing wheel (such as front-wheel and trailing wheel)。So, it is possible to more efficiently distribute kinetic energy to automobile, improve efficiency, save the energy。
Referring to Fig. 9, in the present embodiment, described hydrogen gas generating system is fuel cell system, and fuel cell system includes: gas supply device, pile 201；Described gas supply device utilizes the gas of compression as power, and automatic transport is to pile 201。
In the present embodiment, gas supply device is compressed gas body feeding 202, and described compression gas enters pile 201 after being delivered to a mixing container 203, one end of mixing container 203 connects air；Natural air is reacted by the power that compression gas produces after entering mixing container 203 in setting ratio inspiration pile, regulates oxygen content。
Described fuel cell system also includes air intake conduit, outlet pipe, and air intake conduit, outlet pipe are all through humidification system 204。The gas of described compression is mainly oxygen (can also be air)；Natural air enters pile 201 with compressed oxygen after mixing container mixing。
Described fuel cell system also includes gas regulating system, and gas regulating system is arranged in mixing container 203；Described gas regulating system includes valve regulated and controls device, and oxygen content sensor is or/and compress gas compression ratio sensor。
Described oxygen content sensor is in order to sense the air of mixing and the content of oxygen in oxygen in mixing container, and the data sensed is sent to valve regulated control device。
Described compression gas compression ratio sensor is in order to sense the compression ratio of compressed oxygen, and the data sensed is sent to valve regulated control device。
Described valve regulated controls device according to oxygen content sensor or/and the sensing result of compression gas compression ratio sensor regulates oxygen delivery valve door, air entrainment valve door, controls the conveying ratio (if natural air ratio can be 0-70%) of compressed oxygen, natural air；Mixing gas is pushed to pile reaction by the power that compressed oxygen produces after entering mixing container, utilizes natural air to do dilution decompression。
Described humidification system 204 includes humidity exchanging container, humidity exchange pipeline, and humidity exchange pipeline is a part for air intake conduit；After described reaction, gas outlet pipe is delivered to humidity exchanging container。
The material of described humidity exchange pipeline is only permeable airtight so that after reaction, gas and natural air carry out humidity exchange, and cannot circulate between gas。Humidity exchange pipeline spiral in humidity exchanging container is arranged, it is possible to sufficiently conducted humidity exchanges。
Embodiment three
The present embodiment discloses the storage device of a kind of alcohol hydrogen generating equipment, and described storage device includes: the interrupter regulon that storage container, the space mechanism being arranged in container are connected with space mechanism。Storage container is divided at least two region by described interrupter, and interrupter regulon regulates interrupter position in storage container, regulates the size of regional。
The present embodiment also discloses a kind of alcohol hydrogen generating equipment, and including hydrogen generating system, hydrogen gas generating system, hydrogen generating system is connected with hydrogen gas generating system。Described hydrogen generating system utilizes preparing hydrogen by reforming methanol-water steam, and hydrogen obtains highly purified hydrogen by being coated with the membrane separation device of palladium-silver, and the hydrogen of acquisition is generated electricity by hydrogen gas generating system, and the electric energy sent is for genemotor work。Described hydrogen generating system includes storage container, and storage container includes carbon dioxide collection region, collects the carbon dioxide of release in hydrogen gas generating system。
In sum, the alcohol hydrogen generating equipment that the utility model proposes and storage device, the storage device of alcohol hydrogen generating equipment, the carbon dioxide of generating equipment release can be collected, reduce the discharge of carbon dioxide, be conducive to protection environment；Meanwhile, the carbon dioxide of collection can recycle, as the follow-up raw material preparing methanol。
Here description of the present utility model and application is illustrative, is not wishing to limit in the above-described embodiments scope of the present utility model。The deformation of embodiments disclosed herein and change are possible, for those skilled in the art embodiment replace and the various parts of equivalence are known。It should be appreciated by the person skilled in the art that when without departing from spirit of the present utility model or substitutive characteristics, this utility model can in other forms, structure, layout, ratio, and realize with other assembly, material and parts。When without departing from this utility model scope and spirit, it is possible to embodiments disclosed herein is carried out other deformation and changes。
Claims (9)
1. the storage device of an alcohol hydrogen generating equipment, it is characterised in that described storage device includes: driving mechanism that container, the space mechanism being arranged in container are connected with space mechanism, control module, induction module；
Container is at least divided into two spaces by described space mechanism；In two spaces, a placing response liquid, opposite side arranges the carbon dioxide of hydrogen gas generating system release, the liquid then compressed or solid-state；Control module and connect driving mechanism, induction module respectively；
Described driving mechanism includes motor, and induction module includes pressure transducer or/and liquid level sensor；Induction module link control module；Described control module connects driving mechanism, controls the driving mechanism action to space mechanism；
Described storage device also includes liquefying plant or/and solidification equipment, by the co 2 liquefaction collected or/and solidify。
2. the storage device of an alcohol hydrogen generating equipment, it is characterised in that described storage device includes: the interrupter regulon that storage container, the space mechanism being arranged in container are connected with space mechanism；
Storage container is divided at least two region by described interrupter, and interrupter regulon regulates interrupter position in storage container, regulates the size of regional。
3. the storage device of alcohol hydrogen generating equipment according to claim 2, it is characterised in that:
Described interrupter regulon includes controlling module, driving mechanism, controls module and is connected with driving mechanism；
In some regions that storage container is isolated by described space mechanism, have at least placing response liquid in a region, have at least in a region to arrange the carbon dioxide of hydrogen gas generating system release, the liquid then compressed or solid-state；Described control module comes the position of control interval mechanism by controlling driving mechanism。
4. the storage device of alcohol hydrogen generating equipment according to claim 2, it is characterised in that:
Described interrupter regulon also includes induction module, in order to sense the amount of reaction liquid in container, or/and sense the amount of carbon dioxide of hydrogen gas generating system release, the liquid then compressed or solid-state；And sensed data is sent to controlling module；Described control module connects driving mechanism, controls the driving mechanism action to space mechanism。
5. the storage device of alcohol hydrogen generating equipment according to claim 2, it is characterised in that:
Described storage device also includes liquefying plant or/and solidification equipment, by the co 2 liquefaction collected or/and solidify。
6. an alcohol hydrogen generating equipment, it is characterised in that: including hydrogen production by methanol system, hydrogen gas generating system, hydrogen production by methanol system is connected with hydrogen gas generating system；
Described hydrogen production by methanol system includes hydrogen manufacturing subsystem, air pressure adjustment subsystem, Collection utilization subsystem, and hydrogen manufacturing subsystem, air pressure adjustment subsystem, hydrogen gas generating system, Collection utilization subsystem are sequentially connected with；
Described hydrogen manufacturing subsystem utilizes methanol-water to prepare hydrogen, and described hydrogen manufacturing subsystem includes solid hydrogen storage container, storage container, raw material conveying device, device for rapidly starting, hydrogen producer, membrane separation device；
The middle part of described storage container is provided with dividing plate, and the side of dividing plate arranges reaction liquid, and opposite side arranges the carbon dioxide of hydrogen gas generating system release, the liquid then compressed or solid-state；Dividing plate is connected to driving mechanism, and driving mechanism regulates the position of dividing plate；
Described hydrogen producer includes heat exchanger, vaporizer, reformer chamber；Membrane separation device is arranged in separation chamber, and separation chamber is arranged at the inside of reformer chamber；Described solid hydrogen storage container, storage container are connected with hydrogen producer respectively；In storage container, storage has the first alcohol and water of liquid；
Described device for rapidly starting provides for hydrogen producer and starts the energy；Described device for rapidly starting includes the first startup device, the second startup device；Described first starts device includes the first heating arrangements, the first gasification pipe, and the internal diameter of the first gasification pipe is 1～2mm, and the first gasification pipe is closely wound on the first heating arrangements；One end of described first gasification pipe connects liquid container, is sent in the first gasification pipe by methanol by raw material conveying device；The other end of the first gasification pipe exports vaporized methanol, then by ignition mechanism ignition；Described second starts device includes the second gasification pipe, the main body of the second gasification pipe is arranged at described reformer chamber, first gasification pipe is or/and the methanol of the second gasification pipe output heats the second gasification pipe while being reformer chamber heating, by the methanol gasifying in the second gasification pipe；Described reformer chamber inwall is provided with and adds pipe line, adds and is placed with catalyst in pipe line；Described device for rapidly starting by heat described in add pipe line attach most importance to whole room heating；
The initial start energy of described device for rapidly starting is that some solar energys start module, and solar energy starts solar panel that module includes being sequentially connected with, solar energy-electric energy change-over circuit, solaode；Solar energy starts module provides electric energy for the first heating arrangements；Or, the initial start energy of described device for rapidly starting is manual generator, and the electric energy sent is stored in battery by manual generator；
Described solid hydrogen stores and stores solid hydrogen in container；First alcohol and water in described liquid container is delivered to heat exchanger heat exchange by raw material conveying device, enters vaporizer gasification after heat exchange；Vaporizer is connected with reformer chamber, and reformer chamber is provided with catalyst；It is provided with membrane separation device in separation chamber, obtains hydrogen from the aerogenesis end of membrane separation device；Described membrane separation device is the membrane separation device at porous ceramic surface Vacuum Deposition palladium-silver；
Described hydrogen manufacturing subsystem by prepared hydrogen by transfer conduit real-time Transmission to hydrogen gas generating system；Described transfer conduit is provided with air pressure adjustment subsystem, for adjusting the air pressure in transfer conduit；Described hydrogen gas generating system utilizes the hydrogen gas generation that hydrogen manufacturing subsystem prepares；
Described air pressure adjustment subsystem includes microprocessor, gas pressure sensor, valve positioner, air outlet valve, outlet pipe；Described gas pressure sensor is arranged in transfer conduit, in order to sense the barometric information in transfer conduit, and sends the barometric information of sensing to microprocessor；
Described Collection utilization subsystem connects the Vent passageway of hydrogen gas generating system, collects hydrogen, oxygen gas and water from expellant gas respectively；
Described Collection utilization subsystem includes hydrogen/oxygen separator, hydrogen water separator, hydrogen check-valves, oxygen water separator, oxygen check valve；
Described hydrogen gas generating system is fuel cell system, and fuel cell system includes: gas supply device, pile；Described gas supply device utilizes the gas of compression as power, and automatic transport is to pile；Described pile includes some sub-fuel cell modules, and each sub-fuel cell module includes at least one super capacitor；
Described fuel cell system also includes air intake conduit, outlet pipe；The gas of described compression is mainly oxygen；Air enters pile with oxygen after mixing container mixing；
Described fuel cell system also includes gas regulating system；Described gas regulating system includes valve regulated and controls device, and oxygen content sensor is or/and compress gas compression ratio sensor；
Described oxygen content sensor is in order to sense the air of mixing and the content of oxygen in oxygen in mixing container, and the data sensed is sent to valve regulated control device；
Described compression gas compression ratio sensor is in order to sense the compression ratio of compressed oxygen, and the data sensed is sent to valve regulated control device；
Described fuel cell system also includes humidification system, and humidification system includes humidity exchanging container, humidity exchange pipeline, and humidity exchange pipeline is a part for air intake conduit；After described reaction, gas outlet pipe is delivered to humidity exchanging container,
The material of described humidity exchange pipeline is only permeable airtight so that after reaction, gas and natural air carry out humidity exchange, and cannot circulate between gas。
7. an alcohol hydrogen generating equipment, it is characterised in that: including hydrogen generating system, hydrogen gas generating system, hydrogen generating system is connected with hydrogen gas generating system；
Described hydrogen generating system includes hydrogen manufacturing subsystem, and described hydrogen manufacturing subsystem includes hydrogen producer, membrane separation device；Described hydrogen producer includes heat exchanger, vaporizer, reformer chamber；Membrane separation device is arranged in separation chamber；
Described hydrogen generating system includes storage device, and storage device includes carbon dioxide collection region, collects the carbon dioxide of release in hydrogen gas generating system。
8. alcohol hydrogen generating equipment according to claim 7, it is characterised in that:
Described storage device includes: the interrupter regulon that storage container, the space mechanism being arranged in container are connected with space mechanism；
Storage container is divided at least two region by described interrupter, and interrupter regulon regulates interrupter position in storage container, regulates the size of regional。
9. alcohol hydrogen generating equipment according to claim 8, it is characterised in that:
Described interrupter regulon includes controlling module, driving mechanism, controls module and is connected with driving mechanism；
In some regions that storage container is isolated by described space mechanism, have at least placing response liquid in a region, have at least in a region to arrange the carbon dioxide of hydrogen gas generating system release, the liquid then compressed or solid-state；Described control module connects driving mechanism, controls driving mechanism and comes the position of control interval mechanism。
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| CN105390719A (en) * | 2015-11-03 | 2016-03-09 | 上海合既得动氢机器有限公司 | Alcohol hydrogen power generation device and storage apparatus thereof |
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