CN205276734U - Laminated body - Google Patents

Abstract

The utility model provides a through third dimension etc. And have the laminated body of aesthetic property. The utility model discloses laminated body's characterized in that has the pattern layer on the substrate, the pattern layer is scattered discontinuous concave part and is formed in painted pattern region, painted pattern region is formed by the connector of granular inorganic particle the constrictor that has granular organogel in the concave part.

Description

Laminate

Technical field

This utility model relates to a kind of novel laminate. Laminate of the present utility model is applicable to the surface-coated of building and civil structure thing etc., is specifically applicable to the pattern decorative etc. of building wall.

Background technology

From the viewpoint of view, building wall etc. is pursued aesthetic property by people. In recent years, from this point of view, for instance the pattern decorative etc. of natural stone style receives publicity.

As such pattern decorative, for instance Patent Document 1 discloses a kind of bottom film that arranges on base material the method that pressing pattern duplicate duplicates pattern in the above. The pattern decorative obtained by this patent documentation 1 is the point-like film formed by splash. Additionally, describe a kind of after being coated on face to carry out background color application in patent documentation 2, by the method that splash sprays many painting gobs.

Prior art literature

Patent documentation

Patent documentation 1: Japanese Unexamined Patent Publication 11-290769 publication

Patent documentation 2: Japanese Unexamined Patent Publication 2005-238138 publication

Utility model content

[utility model problem to be solved]

When the splash as described in above-mentioned patent documentation 1 and patent documentation 2, because the coloured material of multiple different colours can be used, so multicolor patterns can be formed. But, the multicolor patterns formed is plane, lacks change and is difficult to show third dimension etc.

This utility model completes to solve the problems referred to above, its object is to provide a kind of laminate by third dimension etc. with aesthetic property.

[means for solving the above]

The present utility model people contemplates after having carried out diligent research and arranges specific pattern pattern layer on base material, thus completing this utility model.

That is, laminate of the present utility model has following characteristics.

1, a kind of laminate, it is characterised in that there is patterned layer on base material,

Above-mentioned patterned layer spreads discontinuous recess in colored pattern region and is formed,

Above-mentioned colored pattern region is formed by the connector of particulate inorganic granule,

Above-mentioned recess exists the constrictor of granular organogel.

2, according to the laminate described in 1, it is characterised in that above-mentioned granular organogel is coloured granular organogel, above-mentioned recess and above-mentioned colored pattern region are heterochromatic.

3, the laminate according to 1 or 2, it is characterised in that above-mentioned recess is bigger than above-mentioned particulate inorganic granule.

4, the laminate according to any one of 1��3, it is characterised in that as above-mentioned recess, is mixed with the recess that two or more size, shape, the degree of depth and/or tone are different.

5, the laminate according to any one of 1��4, it is characterised in that above-mentioned recess is the contraction of the granular organogel by being embedded in above-mentioned connector and is formed.

Utility model effect

Above-mentioned 1��5 utility model related to is obtained the laminate by third dimension etc. with aesthetic property. According to this utility model, it is possible to show shade sense, depth feelings and thick and heavy sense etc., it is possible to make it have the aesthetic property as natural stone. It addition, also obtain following effect in above-mentioned 2��4 utility models related to.

In above-mentioned 2 utility models related to, above-mentioned recess and above-mentioned colored pattern region are heterochromatic, are consequently formed multicolor patterns. This laminate can improve design effect of the present utility model.

In above-mentioned 3 utility models related to, by arranging relatively large recess, thus enable that the big-pattern pattern formed by recess is more obvious.

In above-mentioned 4 utility models related to, as recess, it is mixed with the recess that two or more size, shape, the degree of depth and/or tone are different, it is possible to highlight visible change, improve design effect of the present utility model.

Accompanying drawing explanation

Fig. 1 is the profile schema diagram of the example illustrating this utility model laminate.

Fig. 2 is the plane model figure of the example illustrating this utility model laminate.

The explanation of symbol

1 ... patterned layer

2 ... base material

3 ... colored pattern region

4 ... recess

5 ... the connector of particulate inorganic granule

6 ... the constrictor of granular organogel

Detailed description of the invention

Hereinafter, to being used for implementing embodiment of the present utility model illustrating.

Fig. 1 is the profile schema diagram of the example illustrating this utility model laminate. In FIG, on base material (2), patterned layer (1) it is laminated with.

As base material (2), it is possible to list the material such as constituting the surface such as building and civil structure thing. As this base material, it is possible to list such as: concrete, mortar, Side fascia, extrusion molding plate, plasterboard, pearlite slab, plywood, brick, plastic plate, metallic plate, glass, ceramic tile etc. These base materials can be formed with the base material of coating (existing coating, primary coat coating etc.) in its surface or be pasted with the base material etc. of wallpaper.

Fig. 2 is the plane model figure of the example illustrating this utility model laminate, it is shown that the state of this utility model laminate in terms of side, surface. In fig. 2, colored pattern region (3) are scattered with multiple discontinuous recess (4).

Colored pattern region (3) is formed by the connector (5) of particulate inorganic granule. The pattern in colored pattern region (3) is preferably made up of two or more colors. This multicolor patterns can by using the different two or more particulate inorganic granule of color to be formed.

Connector (5) can be formed by the compositions such as containing particulate inorganic granule and resinous principle. By using this compositions, particulate inorganic granule can be obtained by the securing layer of resin.

The tone of particulate inorganic granule contributes to the pattern of colored pattern region (3). Particulate inorganic granule makes have micro concavo-convex (concavo-convex less than recess (4) degree of depth) on the surface of colored pattern region (3), it is also possible to contribute to showing the three-dimensional design with shade sense. Adjusted design can also be carried out by the combination etc. of multiple particulate inorganic granule in colored pattern region (3).

As particulate inorganic granule preferred in this utility model, as long as its basic material is inanimate matter, it is no matter natural product or artifact all can use. As this particulate inorganic granule, it is preferable that at least contain the form of particulate colored inorganic particle. As this particulate colored inorganic particle, it is particularly preferred to the light transmission opaque particulate colored inorganic particle less than 3%, more preferably it is preferably the particulate colored inorganic particle of light transmission less than 2%. As this (A) composition, specifically can list such as: marble, imperial shadow granite, serpentinite, granite, sandstone, slate (slate), basalt, gabbro, diabase, andesite, limestone and their ground product, porcelain ground product, ceramics mince, clipped wire etc. In addition it is also possible to use for meeting above-mentioned condition, fluorite, Mirabilitum crystallina, Anhydrite, Silicon stone, quartz sand and their ground product, glass dust are minced, bead etc. painted after material.

Described light transmission is the full light transmittance measured by transmissometer. In this mensuration, particulate inorganic granule test portion is filled in clear glass container thick in 5mm, then fills water gradually, utilize vibration to remove the bubble in container afterwards. Wherein, as test portion, selecting to use particle diameter is the test portion of 0.5mm��1.0mm.

Connector (5) can also be the form containing granular transparency inorganic particle on the basis of above-mentioned particulate colored inorganic particle. If using this granular transparency inorganic particle, it becomes possible to further improve the attractive in appearance and depth feelings as natural stone. As granular transparency inorganic particle, it is preferable that light transmission be more than the 3% granular transparency inorganic particle of (be more preferably preferably 3��50%, more preferably 10��30%). As granular transparency inorganic particle, can enumerate out such as: silicon dioxide, Mirabilitum crystallina, Anhydrite, Silicon stone etc. and their ground product, glass dust mince, bead etc., as long as meet the granular transparency inorganic particle of above-mentioned light transmission, it is possible to use any type of colorless or colored.

The mean diameter of particulate inorganic granule is preferably 0.01mm��5mm, is more preferably preferably 0.02mm��2mm, more preferably 0.03mm��0.8mm. The particulate inorganic granule different by combining various particle diameter, it is also possible to extension scope of design. It should be noted that the mean diameter of particulate inorganic granule is to use the wire-mesh screen of regulation in JISZ8801-1:2000 to sieve, and calculate its distribution of weight meansigma methods, the value obtained therefrom.

Resinous principle in connector (5), undertakes the effect of fixing above-mentioned particulate inorganic granule. As this resinous principle, it is possible to use various resinous principles. As resinous principle, it is possible to enumerate out such as: solvent-soluble resin, non-aqueous dispersion type resin, no-solvent type resin, water-dispersion type resin, water-soluble resin etc. As resin types, preferred organic resin, it is possible to enumerate out such as: acrylic resin, polyurethane resin, epoxy resin, vinyl chloride resin, vinyl acetate resin, acrylic silicon resin, fluororesin, polyvinyl alcohol (polyvinylalcohol), cellulose derivative etc. or their complex etc. This resinous principle can also be the resinous principle with the character that can produce cross-linking reaction.

Converted by solid content, total amount relative to 100 weight portion particulate inorganic granules, the ratio of resinous principle is preferably below more than 3 weight portions 50 weight portion, more preferably preferably below more than 4 weight portions 30 weight portions, it is preferred that 5 weight portions are less than 20 weight portions, it is most preferred that more than 6 weight portions below 19 weight portions. As long as this ratio, just can give flexible utilization, because of the connection of particulate inorganic granule, there is design attractive in appearance.

As the composition constituting connector (5), as long as not appreciable impact effect of the present utility model, the composition beyond mentioned component can be used as required. This composition can list such as: plasticizer, algaecide, antibacterial, deodorizer, adsorbent, fire retardant, coloring pigment, filler pigment, bright pigment, phosphorescent pigment, fluorescent pigment, aggregate, fiber, UV absorbent, antioxidant, catalyst etc.

Colored pattern region (3) as long as thickness suitably set according to purpose, but be preferably 0.5mm��10mm, more preferably be preferably 1mm��8mm.

The constrictor of granular organogel is there is in this utility model laminate in above-mentioned recess (4). That is, above-mentioned recess (4) is formed by the contraction of the granular organogel being embedded in above-mentioned connector (5). In this utility model, the contraction of this granular organogel is utilized to form recess (4), thus having played above-mentioned design effect.

In this utility model, connector (5) before it is dried is embedded with perisystolic granular organogel. At this, connector (5) is formed by the particulate inorganic granule not shunk as described above. To this, granular organogel shrinks while dry. Therefore, in connector (5) before it is dried, the part occupied by perisystolic granular organogel becomes space along with the contraction of granular organogel, thus forming recess (4).

The size (major diameter in plane graph) of recess (4) or be shaped as size corresponding with the size of granular organogel or shape or shape. The degree of depth of recess (4) suitably can set according to the size of granular organogel or solid content.

Recess (4) be preferably sized to 1mm��30mm, more preferably 2mm��20mm.

The degree of depth of recess (4) is preferably 0.3mm��10mm, more preferably 0.5mm��5mm.

The size (major diameter) of granular organogel is preferably 1mm��30mm, more preferably 2mm��20mm. Expect the mean diameter being sized larger than above-mentioned particulate inorganic granule of granular organogel. The big-pattern pattern formed by recess can be made in this situation more obvious.

As long as the solid content of granular organogel is set in the scope forming recess (4). The solid content of granular organogel is preferably 1��50 weight %, more preferably 2��40 weight %.

The shape of granular organogel is not particularly limited, it is possible to enumerate out such as: spherical, football shaped, egg-shaped, cylindric, discoid, prism-shaped, dumpling shape, thread, raindrop shape etc.

In this utility model, by the different various granular organogels such as size, solid content and shape are combined, it is possible to form the different various recesses such as size, shape and the degree of depth. This laminate highlights visible change, it is also possible to extension scope of design.

In this utility model, as granular organogel, it is possible to use transparent with machine gel, painted granular organogel etc. Wherein, preferably painted in this utility model (namely, coloured granular organogel) granular organogel. The tone of recess (4) suitably can set according to the tone of granular organogel. In this utility model, multiple recesses (4) both can be unified into same tone, it is also possible to the recess (4) of the different tone of mixing.

Granular organogel such as can by making coloured material gelatine containing organic resin and pigment be formed. As the organic resin in coloured material, it is possible to use the organic resin same with above-mentioned connector (5).

As the pigment in above-mentioned coloured material, it is possible to use coloring pigment. Specifically, as coloring pigment, it is possible to enumerate out such as: inorganic colored pigments such as titanium dioxide, zinc oxide, aluminium oxide, carbon black, iron sesquioxide (red oxide paint), yellow iron oxide, black iron oxide, ultramarine, cobalt greens; The organic coloring pigments such as azo system, naphthols system, pyrazolone system, anthraquinone system, perylene system, quinacridone, bisazo system, isoindolinone system, benzimidazole system, phthalocyanine system, quinophthalone system; Pearlescent pigment; Aluminum pigment; Bright pigment; Phosphorescent pigment; Fluorescent pigment etc. By combining one or more kinds of this coloring pigment, it is possible to granular organogel is modulated into desired tone. In coloured material, it is also possible to use filler pigment on the basis of above-mentioned coloring pigment.

The gelatine of coloured material can adopt known gelatine method, for instance gel formation material and gellant can be used to carry out.

As gel formation material, can list such as: polyvinyl alcohol, polymethylacrylic acid, poly(ethylene oxide), soluble polyurethane, biogum, galactomannan derivant, alginic acid or its derivant, cellulose derivative, gelatin, casein, albumin etc., or these water-soluble high-molecular compounds are passed through oxidation reaction, methylation reaction, carboxymethylation reaction, ethoxyl etherification, hydroxypropylation reacts, sulfating reaction, phosphorus oxidation reacts, cationoid reaction etc. and the material etc. of chemical modification, the one of above-mentioned substance can be adopted or two or more.

As gellant, it is possible to list such as: the sulfate of the metals such as magnesium, calcium, barium, aluminum, sodium, potassium, zinc, ferrum, zirconium, acetate, acylate, silicate, borate etc., it is possible to adopt this one therein or two or more.

Patterned layer of the present utility model (1) can by obtaining being dried by the coating that such as following (I) or (II) method obtains.

(I) application contains the compositions of granular organogel, particulate inorganic granule and resinous principle.

(II) application contains the compositions of particulate inorganic granule and resinous principle, and before the coating formed by said composition dries, utilizes spraying etc. to make granular organogel be embedded in this coating.

In this utility model, it is possible to formation varnish (clear) layer on patterned layer (1). By arranging this layer of varnish (3), the texture of colored pattern region (3) and recess (4) is homogenized, improves the decorative effect of entirety. Additionally it is capable of the protection of patterned layer (1).

In this utility model, it is possible to the upper lamination patterned layer (1) of base material (2) at existing structure. Additionally, by the upper lamination patterned layer (1) of base material (2 ') in tabular, film like etc., it is also possible to obtain the laminate of tablet. Jointing material etc. can be used to be pasted onto on the base material (2) of existing structure by this tablet laminate.

Base material (2 ') as above-mentioned tabular, film like etc., it is possible to enumerate out such as: weave cotton cloth, non-woven fabrics, ceramic paper, synthetic paper, net, fabric, plasterboard, plywood, slate plate, metallic plate etc. This base material can also be made up of two or more above-mentioned materials.

(embodiment)

Embodiment described below, further feature clearly of the present utility model.

Utilize common method, by the 40 particulate colored inorganic particle of weight portion 1 (painted silica sands, dark brown, mean diameter 170 ��m, light transmission is less than 1%), the 40 particulate colored inorganic particle of weight portion 2 (painted silica sands, faint yellow, mean diameter 100 ��m, light transmission is less than 1%), 20 weight portions granular the transparency inorganic particle (Mirabilitum crystallina, mean diameter 200 ��m, light transmission 16%), 30 parts by weight resin compositions (Acrylic Resin Emulsion, solid content 50 weight %, glass transition temperature 0 DEG C) it is mixed and stirred for, thus produce compositions 1.

On the other hand, produce compositions 2, said composition 2 is containing 30 weight portion coloured granular organogel 1 (black egg-shaped gel particles, with Acrylic Resin Emulsion, the granular substance of black iron oxide and coloured material that water is main component, particle diameter 3��6mm), 30 weight portion coloured granular organogel 2 (the spherical gel particles of Lycoperdon polymorphum Vitt, with Acrylic Resin Emulsion, black iron oxide, the granular substance of titanium dioxide and coloured material that water is main component, particle diameter 7��9mm), 40 weight portion aqueous mediums (aqueous medium being main component with Acrylic Resin Emulsion and water).

By according to weight ratio 85:15 mixing above-mentioned composition 1 and above-mentioned composition 2, thus obtaining compositions 3.

After the upper coating prime lacquer of base material (slate plate), with spray gun spraying above-mentioned composition 3, and make it dry after pressing lightly on this painting face with roller, thus obtain laminate. The laminate obtained is studded with black recess and Lycoperdon polymorphum Vitt recess in the colored pattern region being keynote with Sandy, each recess respectively sized by, the different state such as shape, the degree of depth, this laminate has the aesthetic properties such as third dimension, shade sense and depth feelings.

Claims (5)

1. a laminate, it is characterised in that there is patterned layer on base material,

Described patterned layer spreads discontinuous recess in colored pattern region and is formed,

Described colored pattern region is formed by the connector of particulate inorganic granule,

Described recess exists the constrictor of granular organogel.

2. laminate according to claim 1, it is characterised in that described granular organogel is coloured granular organogel, described recess and described colored pattern region are heterochromatic.

3. laminate according to claim 1 and 2, it is characterised in that described recess is bigger than described particulate inorganic granule.

4. the laminate according to any one of claims 1 to 3, it is characterised in that described recess is mixed with the recess that two or more size, shape, the degree of depth and/or tone are different.

5. the laminate according to any one of Claims 1 to 4, it is characterised in that described recess is the contraction of the granular organogel by being embedded in described connector and is formed.