CN205199238U - Dimethyl diallyl ammonium chloride production tail gas recovery plant - Google Patents

Dimethyl diallyl ammonium chloride production tail gas recovery plant Download PDF

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Publication number
CN205199238U
CN205199238U CN201521045409.1U CN201521045409U CN205199238U CN 205199238 U CN205199238 U CN 205199238U CN 201521045409 U CN201521045409 U CN 201521045409U CN 205199238 U CN205199238 U CN 205199238U
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China
Prior art keywords
tail gas
ammonium chloride
diallyl ammonium
dimethyl diallyl
gas recovery
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Expired - Fee Related
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CN201521045409.1U
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Chinese (zh)
Inventor
俞益平
周铁林
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Zhejiang Dachuan New Material Co Ltd
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Zhejiang Dachuan New Material Co Ltd
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Abstract

The utility model discloses a dimethyl diallyl ammonium chloride production tail gas recovery plant. Be equipped with heating coil and agitator among the reation kettle, the material stirs reaction back in reation kettle, and dimethyl diallyl ammonium chloride tail gas is taken out from reation kettle by the vacuum degassing machine earlier, get into in proper order the condenser, lower storage reservoir, deodorization equipment, spray among the deodorization equipment mouthful and the suction pump, forms a hydrologic cycle, deodorization equipment links has activated carbon adsorption tank, later tail gas is taken out by an air exhauster again, through the chimney atmospheric dilution. Utility model's advantage lies in: this equipment utilization condenser can be cooled down to tail gas, makes its quick cold, improves recovery efficiency, and deodorization equipment utilizes ultraviolet lamp light to shine tail gas, and catalysis photooxidation reaction makes remaining dimethyl diallyl ammonium chloride thoroughly decompose, and activated carbon adsorption tank can adsorb particulate matter and high molecular compound in the tail gas, and messenger's harm that tail gas caused is far below original equipment.

Description

Dimethyl diallyl ammonium chloride produces tail gas recovery device
Technical field
Utility model relates to chemical field, refers to that a kind of tail gas recycle is equipped, and especially a kind of dimethyl diallyl ammonium chloride produces the reclaimer of tail gas.
Background technology
Dimethyl diallyl ammonium chloride is a kind of colourless transparent liquid, soluble in water, ethanol, isobutanol, is insoluble to ester, ketone and other carbohydrate.Dimethyl diallyl ammonium chloride can be made under various PH condition has excellent anti-salt, the compound of alkali resistance, can be used for radical initiator (as peroxide, azo-compound) etc. to be polymerized, can with other vinyl monomer homopolymerization or copolymerization, introduce quaternary ammonium group group to polymer, thus there is extremely strong polarity and the affinity to anionic property material.Dimethyl diallyl ammonium chloride (DMDAAC) and copolymer thereof, as a kind of water-soluble cationic polymer, have that positive charge density is high, good water solubility, molecular weight are easy to control, high effect nontoxic, the advantage such as cheap, therefore be widely used in the fields such as oil exploitation, papermaking, mining, textile printing and dyeing, daily-use chemical industry and water treatment, become a large study hotspot of contemporary region of chemistry.China starts late to its research, Related product performance and range of application and also there is a certain distance abroad.In the production process of dimethyl diallyl ammonium chloride, tail gas can process with burning process by the tail gas of generation, and then is discharged in air.The more method of current employing is burnt by the tail gas mixed diesel of dimethyl diallyl ammonium chloride, and organic matter is all burnt into water and carbon dioxide.The residual gas in most of tail gas although this method can burnout, but still the tail gas that can remain 3% to 5% is not burnedly just discharged into air, still can produce pungent smell, cause environmental pollution.
Utility model content
The object of utility model is for the problems referred to above, provides a kind of dimethyl diallyl ammonium chloride and produces tail gas recovery device.
For achieving the above object, utility model have employed following technical proposal: a kind of dimethyl diallyl ammonium chloride produces tail gas recovery device, it is characterized in that, it comprises a reactor, dimethyl diallyl ammonium chloride is prepared in a kettle., heat(ing) coil and agitator is had in described reactor, described heat(ing) coil is fixed on reactor inwall, described agitator is driven by motor axis of rotation, after material carries out stirring reaction in a kettle., the production tail gas of dimethyl diallyl ammonium chloride is first extracted out from reactor by vacuum degassing machine, enter condenser, spray equipment and filter course is had in described condenser, dimethyl diallyl ammonium chloride gas in condenser is cooled into liquid and reclaims, residual gas after filtration is extracted out by an air exhauster again, send into underground pond, water is filled in described underground pond, deodorizing device is entered again by the gas after filtering in described underground pond, some quartz burners are had in described deodorizing device, sprinkling equipment and suction pump, water in cistern below deodorizing device can be extracted into top by described suction pump, form a water circulation, tail gas enters charcoal absorption case again after deodorizing device, some drawer type active carbon layers are had in described charcoal absorption case, tail gas is extracted out by another air exhauster again, air is entered by chimney.
Produce in tail gas recovery device at above-mentioned dimethyl diallyl ammonium chloride, described reactor is automatic agitating type reactor.
Produce in tail gas recovery device at above-mentioned dimethyl diallyl ammonium chloride, described heat(ing) coil is that the coiling of helix stainless steel tube forms, and is fixed on reactor inwall.
Produce in tail gas recovery device at above-mentioned dimethyl diallyl ammonium chloride, described vacuum degassing machine vacuum is 680 ~ 800 millimetress of mercury.
Produce in tail gas recovery device at above-mentioned dimethyl diallyl ammonium chloride, described condenser is Water spray condenser.
Produce in tail gas recovery device at above-mentioned dimethyl diallyl ammonium chloride, described air exhauster one and air exhauster two are centrifugal exhaust fan, discharge capacity 2000m 3/ h.
Produce in tail gas recovery device at above-mentioned dimethyl diallyl ammonium chloride, described deodorizing device is photooxidation deodorizing device, inside establishes some quartz burners.
Produce in tail gas recovery device at above-mentioned dimethyl diallyl ammonium chloride, described suction pump lift is 5m, and water is extracted in the spray catch basin of top the sprinkling equipment that supplies water by pipeline and recycles by suction pump.
Produce in tail gas recovery device at above-mentioned dimethyl diallyl ammonium chloride, described charcoal absorption case is tubular, inner horizontal multiple drawer type active carbon layer.
Compared with prior art, the advantage of utility model is: utilize this whole set of dimethyl diallyl ammonium chloride to produce tail gas recovery device to process the production tail gas of dimethyl diallyl ammonium chloride, utilize condenser can lower the temperature to tail gas, it is made to be cooled to liquid fast, accomplish that waste gas recovery utilizes, improve organic efficiency, tail gas passes through underground pond, residual gas fraction wherein can be dissolved in pond, deodorizing device utilizes ultraviolet light to irradiate tail gas, the photooxidation reaction of catalysis dimethyl diallyl ammonium chloride, the dimethyl diallyl ammonium chloride remained is made to decompose more thorough, charcoal absorption case can particle in absorption tail gas and macromolecular compound, tail gas can be entered high-altitude by chimney stack, the harm that tail gas is caused is far below original equipment.A whole set of dimethyl diallyl ammonium chloride is produced tail gas recovery device and can be played waste gas recovery utilization, protection of the environment, the effect of decreasing pollution.
Accompanying drawing explanation
In order to be illustrated more clearly in utility model embodiment or technical scheme of the prior art, be briefly described to the accompanying drawing used required in embodiment or description of the prior art below, apparently, accompanying drawing in the following describes is only some embodiments of utility model, for those of ordinary skill in the art, under the prerequisite not paying creative work, other accompanying drawing can also be obtained according to these accompanying drawings.
Fig. 1 is the structural representation of utility model;
Fig. 2 is the reactor structural representation of utility model;
Fig. 3 is the deodorizing device structural representation of utility model.
Detailed description of the invention
Below in conjunction with the accompanying drawing in utility model embodiment, be clearly and completely described the technical scheme in utility model embodiment, obviously, described embodiment is only utility model part embodiment, instead of whole embodiments.Based on the embodiment in utility model, those of ordinary skill in the art, not making the every other embodiment obtained under creative work prerequisite, belong to the scope of utility model protection.
As Fig. 1, Fig. 2, shown in Fig. 3, dimethyl diallyl ammonium chloride stirs generation chemical reaction by the stirring of the heating of heat(ing) coil 2 and agitator 3 in automatic stirring reactor 1, hot water circuit is constantly had to flow through in heat(ing) coil 2, the temperature in reactor 1 can be ensured, the tail gas that reaction produces is extracted out by vacuum degassing machine 4, vacuum degassing machine 4 vacuum is 680 millimetress of mercury, degassing performance is strong, dimethyl diallyl ammonium chloride in reactor 1 can be produced tail gas 1 extraction from reactor, import to condenser 5, condenser 5 is spraying condenser, the filter course 6 of tail gas first in condenser, filter course 6 is active carbon layer, can particle in absorption tail gas and macromolecular compound, filter course 6 can be dismantled, be convenient for changing active carbon wherein, Water spray condenser 7 again in condenser, the water smoke of spray is utilized to lower the temperature to tail gas, dimethyl diallyl ammonium chloride residual in tail gas is made to be condensed into liquid, and be collected recovery.Tail gas is extracted out by air exhauster 8 afterwards, enter underground pond 9, underground pond 9 can dissolve most of soluble gas, secondary filter is carried out to gas, tail gas out enters deodorizing device 10 afterwards from underground pond 9, deodorizing device 10 is the photooxidation deodorizing device formed with quartz burner 11, inside there are 40 quartz burners, utilize Ultraviolet radiation catalysis light reaction, pernicious gas residual in tail gas is decomposed, also spray system is had in deodorizing device 10, can cleaning of off-gas again, tail gas through deodorizing device is extracted into charcoal absorption case 13 by another air exhauster 18 again, charcoal absorption case 13 is horizontal tubular casing, there is drawer type active carbon the inside, particle in tail gas and macromolecular compound can be done last all over filtering, the gas filtered is discharged to the outside air by the chimney 14 that 8m is high, effectively can reduce dimethyl diallyl ammonium chloride and produce tail gas to the pollution of environment, protection of the environment economize energy.For using water wisely, condenser 7, in can with water pump 12, water pump 12 lift 5m, can realize water resource in condenser 7 inside and recycle, reach water-saving object.
The foregoing is only the preferred embodiment of utility model, not in order to limit utility model, within all spirit in utility model and principle, any amendment done, equivalent replacement, improvement etc., within the protection domain that all should be included in utility model.

Claims (9)

1. a dimethyl diallyl ammonium chloride produces tail gas recovery device, comprise reactor (1), dimethyl diallyl ammonium chloride is preparation in reactor (1), heat(ing) coil (2) and agitator (3) is had in described reactor (1), described heat(ing) coil (2) is fixed on reactor (1) inwall, the rotating shaft (15) of driven by motor is provided with in described agitator (3), reactor (1) connects vacuum degassing machine (4), the production tail gas of dimethyl diallyl ammonium chloride is extracted out from reactor (1) by vacuum degassing machine (4), described vacuum degassing machine (4) is connected with condenser (5), spray equipment (7) and filter course (6) is provided with in described condenser (5), described condenser (5) is connected with an air exhauster one (8), air exhauster one (8) is connected with underground pond (9), described underground pond fills water in (9), it is characterized in that, gas after filtering in described underground pond (9) enters deodorizing device (10) again, quartz burner (11) is provided with in described deodorizing device (10), spray equipment (7), suction pump (12), water in deodorizing device (10) below cistern (16) can be extracted into top by described suction pump (12), form a water circulation, tail gas enters charcoal absorption case (13) again after deodorizing device (10), described charcoal absorption case (13) is connected with an air exhauster two (18), air exhauster two (18) is connected with the chimney (14) leading to air.
2. dimethyl diallyl ammonium chloride according to claim 1 produces tail gas recovery device, and it is characterized in that, described reactor (1) is automatic agitating type reactor.
3. dimethyl diallyl ammonium chloride according to claim 1 produces tail gas recovery device, and it is characterized in that, described heat(ing) coil (2) forms for the coiling of helix stainless steel tube, is fixed on reactor (1) inwall.
4. dimethyl diallyl ammonium chloride according to claim 1 produces tail gas recovery device, and it is characterized in that, described vacuum degassing machine (4) vacuum is 680 ~ 800 millimetress of mercury.
5. dimethyl diallyl ammonium chloride according to claim 1 produces tail gas recovery device, and it is characterized in that, described condenser (5) is Water spray condenser.
6. dimethyl diallyl ammonium chloride according to claim 1 produces tail gas recovery device, and it is characterized in that, described air exhauster one (8) and air exhauster two (18) are centrifugal exhaust fan, discharge capacity 2000m 3/ h.
7. dimethyl diallyl ammonium chloride according to claim 1 produces tail gas recovery device, and it is characterized in that, described deodorizing device is photooxidation deodorizing device (10), inside establishes some quartz burners.
8. dimethyl diallyl ammonium chloride according to claim 1 produces tail gas recovery device, it is characterized in that, described suction pump (12) lift is 5m, and water is extracted in the spray catch basin of top the sprinkling equipment that supplies water by pipeline and recycles by suction pump (12).
9. dimethyl diallyl ammonium chloride according to claim 1 produces tail gas recovery device, and it is characterized in that, described charcoal absorption case (13) is tubular, inner horizontal multiple drawer type active carbon layer.
CN201521045409.1U 2015-12-16 2015-12-16 Dimethyl diallyl ammonium chloride production tail gas recovery plant Expired - Fee Related CN205199238U (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108043170A (en) * 2017-12-16 2018-05-18 浙江省新昌县华佳国财塑胶有限公司 A kind of plastic cement processing waste gas treatment equipment
CN108610259A (en) * 2018-06-06 2018-10-02 江苏富淼科技股份有限公司 A kind of circulation producing method of dimethyl diallyl ammonium chloride
CN108636066A (en) * 2018-07-10 2018-10-12 江苏富淼科技股份有限公司 A kind of exhaust treatment system
CN108889079A (en) * 2018-09-15 2018-11-27 江苏瑞源加热设备科技有限公司 A kind of environment-friendly type vacuum calcining furnace

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108043170A (en) * 2017-12-16 2018-05-18 浙江省新昌县华佳国财塑胶有限公司 A kind of plastic cement processing waste gas treatment equipment
CN108610259A (en) * 2018-06-06 2018-10-02 江苏富淼科技股份有限公司 A kind of circulation producing method of dimethyl diallyl ammonium chloride
CN108636066A (en) * 2018-07-10 2018-10-12 江苏富淼科技股份有限公司 A kind of exhaust treatment system
CN108889079A (en) * 2018-09-15 2018-11-27 江苏瑞源加热设备科技有限公司 A kind of environment-friendly type vacuum calcining furnace

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CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20160504

Termination date: 20211216

CF01 Termination of patent right due to non-payment of annual fee