CN205055792U - Volatility organic gas's absorption purifier - Google Patents
Volatility organic gas's absorption purifier Download PDFInfo
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- CN205055792U CN205055792U CN201520786134.0U CN201520786134U CN205055792U CN 205055792 U CN205055792 U CN 205055792U CN 201520786134 U CN201520786134 U CN 201520786134U CN 205055792 U CN205055792 U CN 205055792U
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- tower body
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- 238000010521 absorption reaction Methods 0.000 title claims abstract description 17
- 238000012856 packing Methods 0.000 claims abstract description 33
- 239000007788 liquid Substances 0.000 claims abstract description 22
- 239000007789 gas Substances 0.000 claims abstract description 19
- 239000010453 quartz Substances 0.000 claims abstract description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 12
- 238000000746 purification Methods 0.000 claims description 6
- 238000012546 transfer Methods 0.000 abstract description 6
- 238000000034 method Methods 0.000 description 10
- 230000003647 oxidation Effects 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 239000007800 oxidant agent Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 2
- 239000002912 waste gas Substances 0.000 description 2
- 239000012028 Fenton's reagent Substances 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 239000005708 Sodium hypochlorite Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000000809 air pollutant Substances 0.000 description 1
- 231100001243 air pollutant Toxicity 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000010170 biological method Methods 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- KYKAJFCTULSVSH-UHFFFAOYSA-N chloro(fluoro)methane Chemical compound F[C]Cl KYKAJFCTULSVSH-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- MGZTXXNFBIUONY-UHFFFAOYSA-N hydrogen peroxide;iron(2+);sulfuric acid Chemical compound [Fe+2].OO.OS(O)(=O)=O MGZTXXNFBIUONY-UHFFFAOYSA-N 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000010815 organic waste Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000003348 petrochemical agent Substances 0.000 description 1
- 238000007539 photo-oxidation reaction Methods 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
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- Treating Waste Gases (AREA)
Abstract
本实用新型涉及一种挥发性有机气体的吸收净化装置,包括塔体,设置在塔体内部带孔栅板、设置在带孔栅板上的填料层,设置在填料层内部的紫外灯,设置在塔体内且位于填料层上方的喷头,设置在塔体底部的循环液池,塔体底部的进气口和顶部的出气口;所述喷头与循环液池之间以管道连通,管道上设置压力泵;所述紫外灯设置在石英管内,所述石英管横向贯穿填料层且两端开口于塔体侧壁。本实用新型具有操作简单,传质效率高,吸收液使用效率高,去除效率高,应用范围广等优点。
The utility model relates to an absorbing and purifying device for volatile organic gases, which comprises a tower body, a grid plate with holes arranged inside the tower body, a packing layer arranged on the grid plate with holes, an ultraviolet lamp arranged inside the packing layer, and The nozzle in the tower body and above the packing layer, the circulating liquid pool at the bottom of the tower body, the air inlet at the bottom of the tower body and the gas outlet at the top; the nozzle and the circulating liquid pool are connected by pipelines, and the pressure is set on the pipelines. pump; the ultraviolet lamp is arranged in a quartz tube, and the quartz tube traverses through the packing layer and opens at the side wall of the tower body at both ends. The utility model has the advantages of simple operation, high mass transfer efficiency, high absorption liquid use efficiency, high removal efficiency, wide application range and the like.
Description
技术领域 technical field
本实用新型属于大气治理设备领域,具体涉及一种挥发性有机气体的吸收净化装置。 The utility model belongs to the field of atmospheric treatment equipment, in particular to an absorption and purification device for volatile organic gases.
背景技术 Background technique
挥发性有机气体(VOCs)是常见的大气污染物。VOCs来源广泛,工业源主要来源于石化、制药、印刷、喷漆、钢铁等重点行业。该类有机物大多具有毒性,且挥发到大气中不仅会危害人体健康,部分有机废气还会形成光化学烟雾,从而导致雾霾天气,氟氯烃(CFC)类化合物还具有破坏臭氧层的作用。因此,对VOCs控制方法的研究一直是国内外研究热点问题之一。 Volatile organic gases (VOCs) are common air pollutants. VOCs have a wide range of sources, and industrial sources mainly come from key industries such as petrochemicals, pharmaceuticals, printing, painting, and steel. Most of these organic substances are toxic, and volatilization into the atmosphere will not only endanger human health, but some organic waste gases will also form photochemical smog, resulting in haze weather, and chlorofluorocarbon (CFC) compounds also have the effect of destroying the ozone layer. Therefore, the research on VOCs control methods has always been one of the hot research issues at home and abroad.
目前VOCs废气的治理技术主要有:吸收法、氧化法、吸附法、生物法、膜处理法等,其中吸收法净化气态污染物,是利用适当的吸收剂,从废气中选择性地去除气态污染物以消除污染,针对VOCs气体而言,主要利用VOCs溶解度的不同来实现分离净化。该方法设备简单、一次性投资费用低,广泛应用于可溶性气态污染控制中。填料吸收塔是以塔内的填料作为气液两相间接触构件的传质设备。填料塔的设计直接影响到整个填料塔的操作运行和填料性能的发挥。填料的性质、气液接触面积、传质效率等因素一直是人们的研究方向。 At present, the treatment technologies of VOCs waste gas mainly include: absorption method, oxidation method, adsorption method, biological method, membrane treatment method, etc. Among them, the absorption method to purify gaseous pollutants is to use appropriate absorbents to selectively remove gaseous pollution from waste gas In order to eliminate pollution, for VOCs gas, the difference in solubility of VOCs is mainly used to achieve separation and purification. The method has simple equipment and low one-time investment cost, and is widely used in the control of soluble gaseous pollution. The packed absorption tower is a mass transfer device in which the packing in the tower is used as a contact member between the gas and liquid phases. The design of the packed tower directly affects the operation of the entire packed tower and the performance of the packing. The nature of packing, gas-liquid contact area, mass transfer efficiency and other factors have always been the research direction of people.
紫外光与氧化剂联用的高级氧化技术,无论是UV/NaClO、UV/Fenton、UV/H2O2等,均能产生协同作用,其本质都是生成氧化性更强的羟基自由基。因此,将传统的填料吸收塔与先进的光氧化技术相联合,不仅可有效改善填料塔的传质效率,而且增强了化学吸收氧化剂对VOCs的降解性能,具有广阔的应用前景。 The advanced oxidation technology combined with ultraviolet light and oxidant, whether it is UV/NaClO, UV/Fenton, UV/ H2O2 , etc., can produce synergistic effects, and its essence is to generate more oxidative hydroxyl radicals. Therefore, combining the traditional packed absorption tower with advanced photooxidation technology can not only effectively improve the mass transfer efficiency of the packed tower, but also enhance the degradation performance of chemical absorption oxidants on VOCs, which has broad application prospects.
实用新型内容 Utility model content
本实用新型所要解决的技术问题是,提供一种操作简单、去除效率高、便于吸收液使用回收的用于紫外光联合化学吸收净化挥发性有机气体的装置。 The technical problem to be solved by the utility model is to provide a device for purifying volatile organic gases with ultraviolet light combined with chemical absorption, which is simple in operation, high in removal efficiency, and easy to use and recycle the absorption liquid.
本实用新型解决其技术问题采用的技术方案是, The technical scheme that the utility model solves its technical problem adopts is,
一种挥发性有机气体的吸收净化装置,包括塔体,设置在塔体内部带孔栅板、设置在带孔栅板上的填料层,设置在填料层内部的紫外灯,设置在塔体内且位于填料层上方的喷头,设置在塔体底部的循环液池,塔体底部的进气口和顶部的出气口;所述喷头与循环液池之间以管道连通,管道上设置压力泵;所述紫外灯设置在石英管内,所述石英管横向贯穿填料层且两端开口于塔体侧壁。 A device for absorbing and purifying volatile organic gases, comprising a tower body, a grid plate with holes arranged inside the tower body, a packing layer arranged on the grid plate with holes, an ultraviolet lamp arranged inside the packing layer, arranged in the tower body and The spray head located above the packing layer, the circulating liquid pool arranged at the bottom of the tower body, the air inlet at the bottom of the tower body and the gas outlet at the top; the spray head and the circulating liquid pool are connected by pipelines, and a pressure pump is arranged on the pipelines; The ultraviolet lamp is arranged in the quartz tube, and the quartz tube traverses through the packing layer, and the two ends of the quartz tube are opened on the side wall of the tower body.
进一步的,所述带孔栅板的形状与塔体的截面匹配。 Further, the shape of the grid plate with holes matches the cross section of the tower body.
进一步的,所述塔体底部、循环液池上方在塔体内壁设置斜向的导流板。 Further, oblique deflectors are arranged on the inner wall of the tower at the bottom of the tower body and above the circulating liquid pool.
进一步的,所述塔体截面为方形或圆形。 Further, the cross-section of the tower body is square or circular.
进一步的,所述填料层为两个以上,每个填料层的上方均对应设置喷头。 Further, there are more than two packing layers, and a sprinkler head is correspondingly arranged above each packing layer.
进一步的,所述紫外灯安装在防水插座上。 Further, the ultraviolet lamp is installed on a waterproof socket.
本实用新型的有益效果在于: The beneficial effects of the utility model are:
(1)循环液池将塔体、填料层和喷头连接在一起,构成循环系统,实现循环液的持续喷淋和循环利用,提高喷淋效率,便于溶液回收,具有更为稳定的去除效率,同时体系的原料消耗量小; (1) The circulating liquid pool connects the tower body, the packing layer and the nozzle together to form a circulating system, which realizes the continuous spraying and recycling of the circulating liquid, improves the spraying efficiency, facilitates the solution recovery, and has a more stable removal efficiency. At the same time, the raw material consumption of the system is small;
(2)填料层与塔体截面平行,挥发性有机气体与吸收液充分接触,反应彻底; (2) The packing layer is parallel to the cross-section of the tower body, and the volatile organic gas is in full contact with the absorption liquid, and the reaction is thorough;
(3)紫外灯安装在石英管内,能够保护紫外灯不受外界环境腐蚀损坏,且石英管两端开口于塔体侧壁,方便紫外灯的拆卸操作; (3) The ultraviolet lamp is installed in the quartz tube, which can protect the ultraviolet lamp from the corrosion and damage of the external environment, and the two ends of the quartz tube are opened on the side wall of the tower body, which is convenient for the disassembly operation of the ultraviolet lamp;
(4)紫外灯贯穿填料层,紫外光照均匀、强度高,有效提高吸收液的氧化效率; (4) The ultraviolet light penetrates the filler layer, and the ultraviolet light is uniform and high-intensity, which effectively improves the oxidation efficiency of the absorption liquid;
(5)填料层设置两个以上,采用多层喷淋,充分湿润填料,提高传质效率。 (5) There are more than two packing layers, and multi-layer spraying is used to fully wet the packing and improve the mass transfer efficiency.
本实用新型结构简单,操作方便,具有传质效率高,吸收液使用效率高,去除效率高,应用范围广等优点。 The utility model has the advantages of simple structure, convenient operation, high mass transfer efficiency, high absorption liquid use efficiency, high removal efficiency and wide application range.
附图说明 Description of drawings
图1为本实用新型的结构示意图; Fig. 1 is the structural representation of the utility model;
图2为本实用新型填料层的结构示意图; Fig. 2 is the structural representation of the utility model packing layer;
附图中,1、进气口;2、填料层;3、塔体;4、喷头;5、出气口;6、紫外灯;7、带孔栅板;8、循环液池;9、压力泵;10、导流板;11石英管。 In the attached drawings, 1. Air inlet; 2. Packing layer; 3. Tower body; 4. Nozzle; 5. Air outlet; 6. Ultraviolet lamp; 7. Grid with holes; Pump; 10, deflector; 11 quartz tube.
具体实施方式 detailed description
为使本实用新型的上述目的、特征和优点能够更加明显易懂,下面将结合本实用新型实施例中的附图和具体实施方式,对本实用新型实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本实用新型一部分实施例,而不是全部的实施例。基于本实用新型中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本实用新型保护的范围。 In order to make the above-mentioned purposes, features and advantages of the utility model more obvious and easy to understand, the technical solutions in the utility model embodiments will be clearly and completely described below in conjunction with the drawings and specific implementation methods in the utility model embodiments Obviously, the described embodiments are only a part of the embodiments of the present utility model, rather than all the embodiments. Based on the embodiments of the present utility model, all other embodiments obtained by persons of ordinary skill in the art without making creative efforts belong to the scope of protection of the present utility model.
如图1和2所示,本实施例包括塔体3,设置在塔体3内部带孔栅板7、设置在带孔栅板7上的填料层2,设置在填料层2内部的紫外灯6,设置在塔体3内且位于填料层上方的喷头4,设置在塔体3底部的循环液池8,塔体3底部的进气口1和顶部的出气口5;所述喷头4与循环液池8之间以管道连通,管道上设置压力泵9;所述紫外灯6设置在石英管11内,所述石英管11横向贯穿填料层2且两端开口于塔体3侧壁;所述填料层2设置两个,每个填料层2的上方均对应设置喷头4。 As shown in Figures 1 and 2, this embodiment includes a tower body 3, a perforated grating 7 arranged inside the tower body 3, a packing layer 2 arranged on the perforated grating 7, and an ultraviolet lamp arranged inside the packing layer 2 6. The nozzle 4 arranged in the tower body 3 and above the packing layer, the circulating liquid pool 8 arranged at the bottom of the tower body 3, the air inlet 1 at the bottom of the tower body 3 and the gas outlet 5 at the top; the nozzle 4 and the The circulating liquid pools 8 are communicated with pipelines, and a pressure pump 9 is arranged on the pipelines; the ultraviolet lamp 6 is arranged in a quartz tube 11, and the quartz tube 11 runs through the packing layer 2 transversely and opens at the side wall of the tower body 3 at both ends; Two packing layers 2 are provided, and a nozzle 4 is correspondingly arranged above each packing layer 2 .
所述塔体3底部、循环液池8上方在塔体3内壁设置斜向的导流板10。 The bottom of the tower body 3 and the top of the circulating liquid pool 8 are provided with oblique deflectors 10 on the inner wall of the tower body 3 .
所述塔体3截面为圆形。 The cross-section of the tower body 3 is circular.
所述紫外灯6安装在防水插座上。 Described ultraviolet lamp 6 is installed on the waterproof socket.
本实用新型的工作过程为:挥发性有机气体从塔体底部的进气口进入,经过填料层,喷头喷出循环液,具体为次氯酸钠、双氧水和芬顿试剂等常用循环液,在紫外灯的照射下进行化学氧化,挥发性有机气体经两层填料层后由塔体上部的出气口排出;喷淋出的循环液落入循环液池,由压力泵供给给喷头,循环使用。 The working process of the utility model is: the volatile organic gas enters from the air inlet at the bottom of the tower body, passes through the packing layer, and the nozzle sprays out circulating liquid, specifically sodium hypochlorite, hydrogen peroxide and Fenton’s reagent and other commonly used circulating liquids. Chemical oxidation is carried out under irradiation, and the volatile organic gas is discharged from the gas outlet on the upper part of the tower body after passing through two layers of packing layers; the circulating liquid sprayed out falls into the circulating liquid pool, and is supplied to the nozzle by the pressure pump for recycling.
Claims (4)
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
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CN105964136A (en) * | 2016-06-08 | 2016-09-28 | 浙江奇彩环境科技股份有限公司 | Organic exhaust gas degradation method and device |
CN107243230A (en) * | 2017-07-21 | 2017-10-13 | 商志民 | A kind of processing unit of organic exhaust gas |
CN108310948A (en) * | 2018-03-14 | 2018-07-24 | 常州大学 | The absorption plant and absorption process of acetone contained by a kind of exhaust gas |
CN109046018A (en) * | 2018-09-30 | 2018-12-21 | 广东键盟环保科技有限公司 | A kind of VOC exhaust gas liquid phase photocatalysis treatment system and VOC waste gas processing method |
CN110721565A (en) * | 2019-10-26 | 2020-01-24 | 厦门蓝清环保科技有限公司 | Spray tower with good silt discharging effect |
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2015
- 2015-10-12 CN CN201520786134.0U patent/CN205055792U/en active Active
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105964136A (en) * | 2016-06-08 | 2016-09-28 | 浙江奇彩环境科技股份有限公司 | Organic exhaust gas degradation method and device |
CN107243230A (en) * | 2017-07-21 | 2017-10-13 | 商志民 | A kind of processing unit of organic exhaust gas |
CN108310948A (en) * | 2018-03-14 | 2018-07-24 | 常州大学 | The absorption plant and absorption process of acetone contained by a kind of exhaust gas |
CN109046018A (en) * | 2018-09-30 | 2018-12-21 | 广东键盟环保科技有限公司 | A kind of VOC exhaust gas liquid phase photocatalysis treatment system and VOC waste gas processing method |
CN110721565A (en) * | 2019-10-26 | 2020-01-24 | 厦门蓝清环保科技有限公司 | Spray tower with good silt discharging effect |
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Effective date of registration: 20180126 Address after: Hebei province Shijiazhuang City Kok Street 050000 No. 168 Patentee after: Environmental Science and Technology Co., Ltd. Hebei is run Address before: 050000 Shijiazhuang, Yu Yu Street, Hebei, No. 26 Patentee before: Hebei University of Science and Technology |