CN205050709U - Two high pressure are inorganic to be ultracapacitor system - Google Patents

Two high pressure are inorganic to be ultracapacitor system Download PDF

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Publication number
CN205050709U
CN205050709U CN201520825232.0U CN201520825232U CN205050709U CN 205050709 U CN205050709 U CN 205050709U CN 201520825232 U CN201520825232 U CN 201520825232U CN 205050709 U CN205050709 U CN 205050709U
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China
Prior art keywords
high pressure
flow collection
collection sheet
capacitor
pole plate
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Expired - Fee Related
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CN201520825232.0U
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Chinese (zh)
Inventor
陈辉
陈楠
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Hubei Sheng Rong Science And Technology Ltd
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Hubei Sheng Rong Science And Technology Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/13Energy storage using capacitors

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Abstract

The utility model relates to a two high pressure are inorganic to be ultracapacitor system, including the encapsulation casing, stacking together in the internal order of getting plate electrode, epoxy strip according to epoxy strip, the plate electrode of officiallying enroll, capacitor unit, burden of encapsulating shell, the suppression forms, wherein just, be equipped with 30 slice at least and above capacitor unit between the negative plate, capacitor unit establishes ties the equipment and forms, through unfamiliar interval between per two capacitor unit. The problem of the monolithic uniformity is not good in the current condenser production, leads to the internal resistance too high, and pressure endurance is poor to and environment endurance is poor in using is solved, making can not contact and the short circuit between diaphragm and the mass flow body between the two adjacent chip capacitor monomers, welding after using different external pressures with the compaction of multiunit electric capacity monomer, epoxy resin sealing reuses, and adjustment pressure remains the internal resistance of electric capacity product throughout unanimously in the manufacturing process, gluing agent and dispersing agent need be do not not added, the stability of product has been improved.

Description

Two high pressure inorganic system ultracapacitor
Technical field
The utility model relates to a kind of two high pressure inorganic systems ultracapacitor, especially relates to a kind of to the isostructural improvement of high-voltage super capacitor.
Background technology
Ultracapacitor, be again double electric layer capacitor ultracapacitor, after on applied voltage to two pole plates, ion in electrolyte can be adsorbed on pole plate and complete polarization, the charge and discharge process of ultracapacitor is physical process all the time, there is no chemical reaction, therefore ultracapacitor can repeated charge hundreds thousand of time.Ultracapacitor is a kind of Novel energy storage apparatus between traditional capacitor and storage battery, the advantages such as it has, and power density is large, capacity is large, long service life, non-maintaining, economic environmental protection.
Traditional inorganic system ultracapacitor, monomer voltage is generally no more than 1V, once reach window voltage, brine electrolysis reaction will occur pole piece, produces oxygen and hydrogen, and this situation makes ultracapacitor be restricted in the application in more high voltage field.A large amount of gas generation simultaneously can cause electric capacity to break, and cannot continue to use, be different from the rich solution electric capacity of organic series, the electric capacity electrolyte comparision contents of inorganic series is low, if the perforate design adopting lead acid accumulator similar, water inside electric capacity monomer can evaporate very soon and cause integral capacitor internal resistance huge, can not use.Although inorganic series has the problems referred to above, but compare the high voltage of organic series, high energy storage, the environmental protection more of inorganic series, safer, can not blast, and inorganic series also has the use of its uniqueness, the application such as in automobile starting, diesel locomotive startup, hybrid vehicle startup.Therefore, improve the frame mode of current inorganic series super capacitor, the monomer voltage and the raising force resistance that improve ultracapacitor are extremely urgent.
Summary of the invention
The utility model technical issues that need to address are to provide the inorganic series super capacitor of high pressure of a kind of safety more and pressure tolerance, it mainly solves existing mineral condenser, and the bad internal resistance caused of monolithic consistency is too high in process of production, the force resistance of the gas produced after reaching window voltage is poor, and the technical problem of environmental resistance ability in using.
The technical solution of the utility model is for this reason: two high pressure inorganic system ultracapacitor, comprise encapsulating housing, it is characterized in that: form according to the compacting that is stacked together of the order of epoxy resin bar, battery lead plate of officiallying enroll, capacitor monomer, negative power taking pole plate, epoxy resin bar in encapsulating housing; Wherein be provided with at least 30 and above capacitor monomer between positive and negative pole plate, capacitor is monomer series-connected to be assembled, by barrier film interval between every two capacitor monomers.
Further improvement is: described positive and negative power taking pole plate is stainless steel or the alloy pole plate of conduction, and two pieces of power taking pole plates stretch out a lug respectively as external power supply.
Further improvement is: described capacitor monomer is plaster contg. active ingredients, plaster contg. active ingredients is made up of flow collection sheet and the activated carbon powder being coated on flow collection sheet both sides, the surrounding of flow collection sheet reserves 3-5mm frame and insulation frame coordinates, and flow collection sheet material is stainless steel band or nickel strap.
Further improvement is: described plaster contg. active ingredients is super-activated carbon, alkaline electrolyte is mixed and be coated on flow collection sheet, is cut into sheet after drying.
Further improvement is: the area of barrier film is consistent with active material size; The area of barrier film is less than the area of flow collection sheet, makes barrier film just in time can cover plaster contg. active ingredients completely.
Further improvement is: described pressing pressure size is at 5-13T.
Beneficial effect:
Adopt epoxy resin bar instead of epoxy resin board in the utility model, when building like this, encapsulating epoxy resin can flow between power taking pole plate and housing, plays better insulation effect and sealing effectiveness.Due to the heat insulation anti-shock performance that the epoxy resin with firm shell and the inside filling is good, this kind of electric capacity can be used under the condition of the scope of high low temperature and strenuous vibration, simultaneously due to pressurization assembling and excellent sealing, short time overvoltage charging also can not cause electric capacity crack damage, overvoltage is adjusted to rated voltage electric capacity and can continue to use.
Positive and negative power taking pole plate is that stainless steel or alloy pole plate two pieces of pole plates can tolerate the pressure of some strength and indeformable.
The carbon dust of plaster contg. active ingredients surrounding 3-5mm is before the use scraped, and then pad insulate frame, can not out when such carbon dust is extruded, and barrier film also can intercept completely; The length of barrier film is consistent with width and active material size; And barrier film is the super inorganic series capacitors dedicated diaphragm paper with suitable aperture in addition; The area of diaphragm paper is smaller than the area of flow collection sheet, namely just in time can cover active material completely at diaphragm paper; Flow collection sheet like this when pressurization assembling between adjacent two panels and barrier film all can not contact and cause short circuit.
Plaster contg. active ingredients is coated on flow collection sheet after being stirred by super-activated carbon, alkaline electrolyte, is cut into sheet and forms after drying.Adhesive or dispersant all can be used to improve the bonding of carbon dust and collector in the processing of general battery, adhesive and dispersant can cause the increase of internal resistance, owing to finally using huge pressure compaction electric capacity monomer in the utility model, carbon dust can not arbitrarily flow and come off, therefore do not need in active material to add adhesive and dispersant, increase the capacity of electric capacity like this and reduce internal resistance; Have employed the scheme that adjustment pressure obtains consistent internal resistance simultaneously, improve the stability of product.
Diaphragm size be arranged on pressurization assembling time adjacent two panels between flow collection sheet and barrier film all can not contact and cause short circuit.
The pressure of 5-13T is used to ensure that the consistency of electric capacity.
Accompanying drawing explanation
Fig. 1 is structural representation of the present utility model.
Fig. 2 is the utility model capacitor monomer schematic diagram.
Fig. 3 stacks the structural representation press-fiting order.
Description of symbols in figure: 1 is battery lead plate of officiallying enroll; 2 is negative power taking pole plates; 3 is lugs; 4 is plaster contg. active ingredients; 4-1 is flow collection sheet, and 5 is barrier films; 6 is encapsulating housings; 7 is encapsulating epoxy resins; 8 is activated carbon powders; 9 is insulation frames; 10 is epoxy resin bars.
Embodiment
Below by embodiment, and by reference to the accompanying drawings, the technical solution of the utility model is described in further detail.
Two high pressure inorganic system ultracapacitor, comprises encapsulating housing 6, forms in encapsulating housing according to the compacting that is stacked together of the order of epoxy resin bar 10, battery lead plate of officiallying enroll 1, capacitor monomer, negative power taking pole plate 2, epoxy resin bar 10; Wherein be provided with at least 30 and above capacitor monomer between positive and negative pole plate 1,2, capacitor is monomer series-connected to be assembled, by barrier film 5 interval between every two capacitor monomers.
Positive and negative power taking pole plate 1,2 is stainless steel or the alloy pole plate of conduction, and two pieces of power taking pole plates stretch out a lug respectively as external power supply.
Capacitor monomer is plaster contg. active ingredients 4, and plaster contg. active ingredients 4 is made up of flow collection sheet 4-1 and the activated carbon powder 8 being coated on flow collection sheet both sides, and the surrounding of flow collection sheet 4-1 reserves 3-5mm frame and insulation frame 9 coordinates, and flow collection sheet 4-1 material is stainless steel band or nickel strap.
Plaster contg. active ingredients 4 is super-activated carbon, alkaline electrolyte is mixed and is coated on flow collection sheet 4-1, is cut into sheet after drying.
The area of barrier film 5 is consistent with active material 4 size; The area of barrier film 5 is less than the area of flow collection sheet 4-1, makes barrier film 5 just in time can cover plaster contg. active ingredients 4 completely.
Pressing pressure size is at 5-13T.The series resistance of housing is measured in the process of pressure, all the time pressure size is adjusted, make the internal resistance of all electric capacity all identical, then under packing state, use the technology such as electric welding or laser welding iron covering and housing to be coupled together, and then build encapsulating epoxy resin from that side that lug stretches out and seal completely, housing is iron, and alloy or fiberglass etc. can tolerate the material of some strength pressure.
Show by experiment when pressure is more than 13T time, the internal resistance decline degree of electric capacity is also not obvious, general under the pressure condition of 10-15T, electric capacity internal resistance does not change substantially, when pressure continues to increase again time, internal resistance can increase on the contrary, and reason is that excessive pressure causes the electrolyte in the middle of active material to ooze out, and carbon dust electric conductivity declines.
Embodiment 1: two high pressure inorganic system ultracapacitor of this example, there are two pieces of power taking pole plates to be respectively to officially enroll battery lead plate 1 and negative power taking pole plate 2, two pieces of power taking pole plates respectively stretch out a lug 3 for external power supply, at least 30 and above capacitor monomer is provided with between two pieces of power taking pole plates, namely plaster contg. active ingredients 4, plaster contg. active ingredients 4 is made up of flow collection sheet 4-1 and the superincumbent activated carbon powder 8 of coating, plaster contg. active ingredients 4 scraping pads insulation frame 9 later, separate with barrier film 5 between neighboring capacitors monomer, then the capacitor monomer of series connection closed assembly is put into the encapsulating housing 6 of consistent size, stack order according to epoxy resin bar 10, to officially enroll battery lead plate 1, electric capacity monomer, negative power taking pole plate 2, the order of epoxy resin bar 10, the pressure of 5-13T is used lid to be compressed into encapsulating housing 6 and welds, make the electric capacity internal resistance that draws consistent, then seal completely by building encapsulating epoxy resin just above.Be the high pressure inorganic system ultracapacitor of 24V, 40m Ω, 15F after assembling, above the startup being mainly used in passenger vehicle, it is 28V that the short time overcharges ceiling voltage, can stablize discharge and recharge under-30 DEG C and 70 DEG C of ambient temperatures.
Embodiment 2: two high pressure inorganic system ultracapacitor of this example, plaster contg. active ingredients 4 is 90, power taking pole plate is 4, and stacking order is power taking pole plate A, 30 plaster contg. active ingredients, power taking pole plate B, 30 plaster contg. active ingredients, power taking pole plate C, 30 plaster contg. active ingredients, power taking pole plate D, all the other operations are with embodiment 1.
When external power supply, the lug of power taking pole plate A forms new positive electrode together with the tab welding of power taking pole plate C, and the lug of power taking pole plate D forms new negative electrode together with the tab welding of power taking pole plate B.Be the high-voltage super capacitor of 24V, 18m Ω, 45F after assembling, above the startup being mainly used in heavy truck, it is 28V that the short time overcharges ceiling voltage, can stablize discharge and recharge under-30 DEG C and 70 DEG C of ambient temperatures.
These embodiments are only not limited to preferred embodiment above-mentioned for illustration of the utility model.

Claims (6)

1. pair high pressure inorganic system ultracapacitor, comprises encapsulating housing, it is characterized in that: form according to the compacting that is stacked together of the order of epoxy resin bar, battery lead plate of officiallying enroll, capacitor monomer, negative power taking pole plate, epoxy resin bar in encapsulating housing; Wherein be provided with at least 30 and above capacitor monomer between positive and negative pole plate, capacitor is monomer series-connected to be assembled, by barrier film interval between every two capacitor monomers.
2. according to claim 1 pair of high pressure inorganic system ultracapacitor, is characterized in that: described positive and negative power taking pole plate is stainless steel or the alloy pole plate of conduction, and two pieces of power taking pole plates stretch out a lug respectively as external power supply.
3. according to claim 1 pair of high pressure inorganic system ultracapacitor, it is characterized in that: described capacitor monomer is plaster contg. active ingredients, plaster contg. active ingredients is made up of flow collection sheet and the activated carbon powder being coated on flow collection sheet both sides, the surrounding of flow collection sheet reserves 3-5mm frame and insulation frame coordinates, and flow collection sheet material is stainless steel band or nickel strap.
4. according to claim 3 pair of high pressure inorganic system ultracapacitor, is characterized in that: described plaster contg. active ingredients is super-activated carbon, alkaline electrolyte is mixed and be coated on flow collection sheet, is cut into sheet after drying.
5. according to claim 4 pair of high pressure inorganic system ultracapacitor, is characterized in that: the area of barrier film is consistent with active material size; The area of barrier film is less than the area of flow collection sheet, makes barrier film just in time can cover plaster contg. active ingredients completely.
6. according to claim 1 pair of high pressure inorganic system ultracapacitor, is characterized in that: described pressing pressure size is at 5-13T.
CN201520825232.0U 2015-10-24 2015-10-24 Two high pressure are inorganic to be ultracapacitor system Expired - Fee Related CN205050709U (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106611654A (en) * 2015-10-24 2017-05-03 湖北圣融科技有限公司 Double-high-voltage inorganic super capacitor

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106611654A (en) * 2015-10-24 2017-05-03 湖北圣融科技有限公司 Double-high-voltage inorganic super capacitor

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Granted publication date: 20160224

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