CN205042248U - Complex function filter material is knitted to fine machine of superfine glass of denitration and dioxin - Google Patents

Complex function filter material is knitted to fine machine of superfine glass of denitration and dioxin Download PDF

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Publication number
CN205042248U
CN205042248U CN201520480998.XU CN201520480998U CN205042248U CN 205042248 U CN205042248 U CN 205042248U CN 201520480998 U CN201520480998 U CN 201520480998U CN 205042248 U CN205042248 U CN 205042248U
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catalyst
superfine glass
ptfe
layer
denitration
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宋朋泽
鞠东升
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Liaoning Xin Hongyuan environmental protection material Co. Ltd.
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Yingkou Hongyuan Fiberglass Technology Co Ltd
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Abstract

The utility model provides a complex function filter material is knitted to fine machine of superfine glass of denitration and dioxin is in proper order including containing the PTFE micropore thin layer of catalyst, first catalyst hybrid processing liquid flooding layer, superfine glass fibre and catalysis PTFE fiber blending machine fabric layer and second catalyst hybrid processing liquid flooding layer, superfine glass fibre is the blending cloth that adopts quick -witted mode of knitting to make with catalysis PTFE fiber blending machine fabric layer, contain to cover through hot pressing between PTFE micropore thin layer and the first catalyst hybrid processing liquid flooding layer of catalyst and close. The utility model discloses can show the efficiency that improves filter fineness and denitration and reach the dioxin.

Description

A kind of denitration is with the woven complex function filtrate of the superfine glass fiber of bioxin
Technical field
The present invention relates to Environmental-protecting dust-removing filed of flue gas purification, particularly relate to and a kind ofly there is denitration with the woven composite filtering material of the superfine glass fiber of bioxin effect.
Background technology
At present, along with the fast development of economy, the discharge of industrial waste gas sharply increases.The pollution of China's atmospheric environment is on the rise, and progressively pollutes transformation by coal-smoke pollution to mixed type, and flue dust, SOx, NOx, Hg total emission volumn rank first in the world.Wherein nitrogen oxide, bioxin is one of major pollutants in air, and discharge capacity exceedes the self-purification ability of enviroment, endangers huge, and environmental aspect situation is very severe.Nitrogen oxide, bioxin is the topmost gaseous contaminant affecting air quality, is the important symbol whether measurement air is polluted.
Coal-burning power plant and garbage burning factory are the rich anies influential family of SOx and NOx emission, and the pollutant produced in flue gas comprises oxysulfide, nitrogen oxide, dust, the pellet (harmful substance such as IP), dioxin (PCDD/Fs), heavy metal.At present, nitrogen oxide becomes first pollutant acid gas gradually, the water of nitrogen oxide in air is combined and finally can changes into nitric acid and nitrate, nitric acid is one of origin cause of formation of acid rain, it and other pollutants can produce photochemical pollution under certain condition, and serious environment pollution also jeopardizes health.Bioxin is that a class source is wide, strong toxicity, the organic pollution that stability is high.It is the general designation of Duo chlorodiphenyl Bing bioxin and polychlorinated dibenzo, and the former is 75 kinds, the latter 135 kinds, totally 210 homologs.These compounds main have strongly carcinogenic, teratogenesis, mutagenic feature.Due to bioxin stability and be soluble in the characteristic of grease, be just difficult to discharge once enter human body, long term accumulation, will permanent destruction human body immune system and upset the hormone secretion of human body, great bodily injury is formed to human body.
The environmental problem that the harmful substances such as nitrogen oxide, bioxin cause and huge to the harm of health.Although, research and develop various denitrating flue gas both at home and abroad, removed the techniques such as bioxin, had their own characteristics each, and achieve certain achievement, but the common removal efficiency problem that there is a harmful substance, the harmful substances such as the nitrogen oxide, bioxin in flue gas have certain escape phenomenon.
Environmental benefit and economic benefit consider the Developing mainstream by becoming the harmful substance Prevention Technique such as nitrogen oxide, bioxin from now on.In order to improve the removal efficiency of harmful substance further, by R & D design new type functional Environmental-protecting dust-removing filtering material, active catalyst is implanted in filtrate, realize carrying out dedusting simultaneously at high-temperature flue gas, the poisonous and harmful substances such as the nitrogen oxide, bioxin contained in high-temperature flue gas are carried out to the object of catalytic decomposition.Therefore, in original Environmental-protecting dust-removing system, without the need to changing existing process equipment and working condition, the catalytic decomposition of the harmful substances such as residual nitrogen oxide, bioxin can be completed.
Summary of the invention
The object of the invention is to solve the subproblem existed in the filtrate technology of existing denitrifying oxide, bioxin, provide a kind of denitration with the woven complex function filtrate of the superfine glass fiber of bioxin.
The object of the invention is to be achieved through the following technical solutions:
Denitration, with the woven complex function filtrate of the superfine glass fiber of bioxin, comprises the PTFE microporous film layer containing catalyst, the first catalyst mix treatment fluid impregnate layer, superfine glass fiber and catalysis PTFE fiber blend machine-woven fabric layer and the second catalyst mix treatment fluid impregnate layer successively.
Preferably, described superfine glass fiber and catalysis PTFE fiber blend machine-woven fabric layer are the blended cloths adopting woven mode to make.
Preferably, described containing between the PTFE microporous film layer of catalyst and the first catalyst mix treatment fluid impregnate layer passes through hot pressing cladding.
Beneficial effect of the present invention:
(1) of the present invention there is denitration He the woven composite filtering material of the superfine glass fiber of bioxin effect to have applicable working condition scope wide, without the need to changing original process equipment and working condition, the catalytic decomposition of the harmful substances such as residual nitrogen oxide, bioxin can be completed; System cloud gray model safety and steady, the notable features such as high-efficiency low-resistance long-life, energy resource consumption and operation and maintenance cost lower 30%;
(2) of the present invention have denitration with the woven composite filtering material of the superfine glass fiber of bioxin effect has effect of surface filtration simultaneously, dust is trapped in the surface of filtrate, can realizes Dust Capacity and be less than 5mg/Nm 3near-zero release;
(3) of the present invention have denitration with the woven composite filtering material of the superfine glass fiber of bioxin effect is while filtrating smoke dust, due to the introducing of multi-level catalyst distribution layer, promote the contact area of waste gas and catalyst at double, significantly improve the catalytic decomposition efficiency to harmful substances such as nitrogen oxide, bioxin; Give full play to the function that filtrate removes harmful substance;
(4) adopt superfine glass fiber and catalysis PTFE fiber to make base material, ensure that filtrate entirety has higher hot strength, there is the catalytic decomposition function of the harmful substances such as nitrogen oxide, bioxin simultaneously;
(5) of the present invention have denitration with the superfine glass fiber of bioxin effect woven composite filtering material heat resistance is outstanding.Glass and PTFE fiber continuous operation temperature 260 DEG C, heatproof can reach 280 DEG C instantaneously, meets the temperature conditions of harmful substance and the double requirements of life of bag filter such as catalyst decomposes nitrogen oxide, bioxin.
Accompanying drawing explanation
Fig. 1 is the structural representation of filtrate of the present invention.
Detailed description of the invention
In order to better the present invention is described, below in conjunction with the accompanying drawing in the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described.
Denitration, with the woven complex function filtrate of the superfine glass fiber of bioxin, comprises the PTFE microporous film layer containing catalyst, the first catalyst mix treatment fluid impregnate layer, superfine glass fiber and catalysis PTFE fiber blend machine-woven fabric layer and the second catalyst mix treatment fluid impregnate layer successively; Described superfine glass fiber and catalysis PTFE fiber blend machine-woven fabric layer are the blended cloths adopting woven mode to make; Described containing between the PTFE microporous film layer of catalyst and the first catalyst mix treatment fluid impregnate layer passes through hot pressing cladding.
Prepare above-mentioned denitration with the method for the woven complex function filtrate of the superfine glass fiber of bioxin, comprise the following steps: (1), by after the mixing of active metal catalyst powder and PTFE mixed with resin, makes the PTFE fiber containing catalyst and the PTFE microporous membrane containing catalyst respectively; (2) the PTFE fiber containing catalyst and superfine glass fiber blending are made complex yarn, adopt woven mode to weave and make superfine glass fiber and catalysis PTFE fiber blend machine-woven fabric layer; (3) active metal catalyst emulsion and PTFE emulsion are mixed and made into catalyst mix treatment fluid, mass-impregnation process are carried out to superfine glass fiber and catalysis PTFE fiber blend machine-woven fabric layer, sinters at 300-350 DEG C afterwards; (4) superfine glass fiber after sintering and catalysis PTFE fiber blend machine-woven fabric layer are introduced in hot laminating machine with the PTFE microporous membrane containing catalyst simultaneously, carry out the processing of surface heat laminated film-covered.Active metal catalyst in described step (1) is selected from V 2o 5, WO 3, MoO 3/ TiO 2in one or more; The mass ratio of active metal catalyst powder, PTFE toner is 1 ~ 10:99 ~ 90.Be 1-5:5-1 containing the PTFE fiber of catalyst and the mass ratio of superfine glass fiber in described step (2).In described step (3), the mass ratio of the active ingredient of active metal catalyst emulsion and PTFE emulsion is 1-99:99-1.The solid content of described PTFE emulsion is 30 ~ 50%.The active ingredient of described active metal catalyst emulsion is V 2o 5, WO 3, MoO 3/ TiO 2in one or more.The solid content of described active metal catalyst emulsion is 40 ~ 60%.
Embodiment 1
By active catalyst V 2o 5, MoO 3/ TiO 2micro mist and PTFE resin mix uniformly by the mass ratio of 5:95, make the PTFE fiber containing catalyst and the PTFE microporous membrane containing catalyst respectively; Wherein, the kind of auxiliary agent and quality can be selected arbitrarily as required.PTFE fiber containing catalyst is mainly used in making Woven filter cloth, and the PTFE microporous membrane containing catalyst is the laminating surface at filtrate finally.By implanting the mode of active catalyst in filtrate, reach the effect removing the harmful substances such as nitrogen oxides in effluent, bioxin while filtering smoke.Concrete steps are as follows:
One is that the PTFE fiber containing catalyst is made complex yarn by the quality of 1:1 than blending with superfine glass fiber, adopts woven mode to weave composite filtering cloth, and this filter cloth is superfine glass fiber and catalysis PTFE fiber blend machine-woven fabric layer 3;
Two be by solid content be 50% active metal catalyst emulsion and solid content be 40% PTFE emulsion be that 20:80 makes catalyst mix treatment fluid by the mass ratio of active ingredient, mass-impregnation process is carried out to composite filtering cloth, at 300 DEG C, carry out high temperature sintering afterwards, form the first catalyst mix treatment fluid impregnate layer 2 and the second catalyst mix treatment fluid impregnate layer 4 in the upper and lower surface of superfine glass fiber and catalysis PTFE fiber blend machine-woven fabric layer.
Three is introduce in hot laminating machine with the PTFE microporous membrane 1 containing active catalyst after the process of filtrate mass-impregnation simultaneously, carry out the processing of surface heat laminated film-covered, film and base material are firmly combined, finally make denitration with the superfine glass fiber of bioxin woven complex function filtrate material.
Denitration is with the superfine glass fiber of bioxin woven complex function filtrate material entirety is divided into four levels: to be followed successively by PTFE microporous film layer 1, first catalyst mix treatment fluid impregnate layer 2, superfine glass fiber and catalysis PTFE fiber blend machine-woven fabric layer 3 containing catalyst and the second catalyst mix treatment fluid impregnate layer 4 to pure qi (oxygen) face by dust-collecting face.
Denitration is with the superfine glass fiber of bioxin woven complex function filtrate material, significantly improve the filtering accuracy of filtrate, filtrate from outside to inside (dust-collecting face is to pure qi (oxygen) face) forms multi-level active catalyst distribution layer, and when high-temperature flue gas is through out-of-date, dust is blocked on the surface of filtrate; When gas containing harmful substance passes through, the harmful substances such as nitrogen oxide, bioxin and active catalyst react, and oxious component is broken down into harmless material and dust is collected in the lump, thus realize flue gas ash removal and the double effects removing harmful substance.
Denitration is with the parameter of the woven complex function filtrate of the superfine glass fiber of bioxin
Embodiment 2
By active catalyst V 2o 5, WO 3, TiO 2micro mist and PTFE resin mix uniformly by the mass ratio of 6:94, make the PTFE fiber containing catalyst and the PTFE microporous membrane containing catalyst respectively; Wherein, the kind of auxiliary agent and quality can be selected arbitrarily as required.PTFE fiber containing catalyst is mainly used in making Woven filter cloth, and the PTFE microporous membrane containing catalyst is the laminating surface at filtrate finally.By implanting the mode of active catalyst in filtrate, reach the effect removing the harmful substances such as nitrogen oxides in effluent, bioxin while filtering smoke.Concrete steps are as follows:
One is that the PTFE fiber containing catalyst is made complex yarn by the quality of 2:2 than blending with superfine glass fiber, adopts woven mode to weave composite filtering cloth, and this filter cloth is superfine glass fiber and catalysis PTFE fiber blend machine-woven fabric layer 3;
Two be by solid content be 45% active metal catalyst emulsion and solid content be 45% PTFE emulsion be that 40:60 makes catalyst mix treatment fluid by the mass ratio of active ingredient, mass-impregnation process is carried out to composite filtering cloth, at 320 DEG C, carry out high temperature sintering afterwards, form the first catalyst mix treatment fluid impregnate layer 2 and the second catalyst mix treatment fluid impregnate layer 4 in the upper and lower surface of superfine glass fiber and catalysis PTFE fiber blend machine-woven fabric layer.
Three is introduce in hot laminating machine with the PTFE microporous membrane 1 containing active catalyst after the process of filtrate mass-impregnation simultaneously, carry out the processing of surface heat laminated film-covered, film and base material are firmly combined, finally make denitration with the superfine glass fiber of bioxin woven complex function filtrate material.
Denitration is with the superfine glass fiber of bioxin woven complex function filtrate material entirety is divided into four levels: to be followed successively by PTFE microporous film layer 1, first catalyst mix treatment fluid impregnate layer 2, superfine glass fiber and catalysis PTFE fiber blend machine-woven fabric layer 3 containing catalyst and the second catalyst mix treatment fluid impregnate layer 4 to pure qi (oxygen) face by dust-collecting face.
There is denitration with the woven composite filtering material of the superfine glass fiber of bioxin effect, significantly improve the filtering accuracy of filtrate, filtrate from outside to inside (dust-collecting face is to pure qi (oxygen) face) forms multi-level active catalyst distribution layer, and when high-temperature flue gas is through out-of-date, dust is blocked on the surface of filtrate; When gas containing harmful substance passes through, the harmful substances such as nitrogen oxide, bioxin and active catalyst react, and oxious component is broken down into harmless material and dust is collected in the lump, thus realize flue gas ash removal and the double effects removing harmful substance.
There is denitration with the woven composite filtering material of the superfine glass fiber of bioxin effect
The above; be only the present invention's preferably detailed description of the invention, but protection scope of the present invention is not limited thereto, is anyly familiar with those skilled in the art in the technical scope that the present invention discloses; the change that can expect easily or replacement, all should be encompassed within protection scope of the present invention.Therefore, protection scope of the present invention should be as the criterion with the protection domain of claims.

Claims (3)

1. the woven complex function filtrate of the superfine glass fiber of a denitration and bioxin, it is characterized in that, comprise the PTFE microporous film layer containing catalyst, the first catalyst mix treatment fluid impregnate layer, superfine glass fiber and catalysis PTFE fiber blend machine-woven fabric layer and the second catalyst mix treatment fluid impregnate layer successively.
2. denitration according to claim 1 is with the woven complex function filtrate of the superfine glass fiber of bioxin, it is characterized in that, described superfine glass fiber and catalysis PTFE fiber blend machine-woven fabric layer are the blended cloths adopting woven mode to make.
3. denitration according to claim 1 is with the woven complex function filtrate of the superfine glass fiber of bioxin, it is characterized in that, described containing between the PTFE microporous film layer of catalyst and the first catalyst mix treatment fluid impregnate layer passes through hot pressing cladding.
CN201520480998.XU 2015-07-02 2015-07-02 Complex function filter material is knitted to fine machine of superfine glass of denitration and dioxin Active CN205042248U (en)

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Effective date of registration: 20180102

Address after: 115004 Liaoning Province, Yingkou City West District No. 101 West Street wise

Patentee after: Liaoning Xin Hongyuan environmental protection material Co. Ltd.

Address before: Liaoning province Yingkou City West District No. 101 West Street wise

Patentee before: Yingkou Hongyuan Fiberglass Technology Co., Ltd.