CN204982006U - Draw continuous ion exchange system of copper ion in follow ore waste water - Google Patents

Draw continuous ion exchange system of copper ion in follow ore waste water Download PDF

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Publication number
CN204982006U
CN204982006U CN201520655471.6U CN201520655471U CN204982006U CN 204982006 U CN204982006 U CN 204982006U CN 201520655471 U CN201520655471 U CN 201520655471U CN 204982006 U CN204982006 U CN 204982006U
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China
Prior art keywords
resin
resin columns
waste water
exchange system
columns
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CN201520655471.6U
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Chinese (zh)
Inventor
许云鹏
曾绍洪
沈沉
吴晓斌
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Huasheng Fluid Separation Technology (Xiamen) Co., Ltd.
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Huasheng Fluid Separation Technology (xiamen) Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

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  • Treatment Of Water By Ion Exchange (AREA)

Abstract

The utility model provides a draw continuous ion exchange system of copper ion in follow ore waste water, relates to a continuous ion exchange system, including 1-No. 24 resin post, feeding house steward, ejection of compact house steward, with the feeding branch pipe of feeding house steward intercommunication, with the ejection of compact branch pipe of ejection of compact house steward intercommunication 1 in-No. 24 resin posts, 1-No. 12 resin post is the adsorption zone, and 13-No. 24 the resin post is distinguished for analytic, in the adsorption zone, adopt the series system to connect between 1-No. 5 resin post, adopt parallel to connect between 6-No. 12 resin posts, in the analytic district, adopt 2 parallelly connected resin posts to establish ties in addition 2 parallelly connected resin posts between 14-No. 19 resin posts and establish ties the mode of 2 remaining parallelly connected resin posts again and connect, 20 all adopt parallel to connect with no. 21 resin posts, 22 and no. 23 resin posts.

Description

A kind of continuous ionic exchange system extracting cupric ion from ore waste water
Technical field
The utility model relates to a kind of continuous ionic exchange system, is specifically related to a kind of continuous ionic exchange system extracting cupric ion from ore waste water.
Background technology
At metallurgy industry, hydrometallurgy is traditional metallurgical method.The process of hydrometallurgy to be exactly metalliferous mineral raw material at the aqueous solution of acidic medium or alkaline medium carry out chemical treatment or organic solvent extraction, separating impurity, extraction metal and compound thereof.But common metal mineral have other metal associated minerals a lot, therefore, also can by these dissolving metals in acid, alkaline medium.After major metal is extracted, the integral part that remaining metal ion then becomes waste water is discharged.This not only increases the intractability of waste water, also result in the waste of resource simultaneously.
Except containing except major metal in ore waste water, generally also containing a small amount of cupric ion, have a lot from the method for waste water extraction copper at present, conventional method has: extraction process, ion exchange method.When adopting the method for extraction to draw cupric ion, but the method is difficult to realize the qualified discharge of waste water and can causes secondary pollution to the process of extraction agent; Adopt the cupric ion in traditional organic backbone ion-exchanger absorption waste water, due to the restriction by ion-exchanger kind and performance, running cost is higher.
Summary of the invention
In order to overcome the above-mentioned defect of prior art, the utility model by the following technical solutions:
A kind of continuous ionic exchange system extracting cupric ion from ore waste water, comprise 1 ~ No. 24 resin column, charging house steward, discharge header pipe, with charging house steward be communicated with feed-inputing branched pipe, with discharge header pipe be communicated with discharging arm, in described 1 ~ No. 24 resin column, 1 ~ No. 12 resin column is adsorption zone, and 13 ~ No. 24 resin columns are for resolving district; In described adsorption zone, between 1 ~ No. 5 resin column, adopt series system to connect, between 6 ~ No. 12 resin columns, adopt parallel way to connect; In described parsing district, the mode of 2 that adopt another 2 resin columns in parallel of 2 in parallel resin columns series connection to connect remaining again between 14 ~ No. 19 resin columns resin columns in parallel connects; 20 adopt parallel way to be connected with No. 21 resin columns, 22 with No. 23 resin columns respectively.
Wherein, described No. 1 resin column connection water tank suitable for reading, No. 5 resin column end openings connect material transfer tank, mine wastewater enters 6 ~ No. 8 resin columns by the charging house steward of 6 ~ No. 8 resin columns respectively by diverting valve, the discharge header pipe access material transfer tank of 6 ~ No. 8 resin columns, material transfer tank is connected with the upper endfeed house steward of 9 ~ No. 12 resin columns by feed back pipeline;
Wherein, described No. 13 resin columns connection air line suitable for reading, described No. 13 resin column end openings access water tank, water tank is connected with endfeed house steward on No. 15 resin columns with 14 by reflux line;
Wherein, described 18 are connected with material transfer tank by feed back pipeline with No. 19 total condominium of resin column lower end discharging;
Wherein, sulfuric acid oppositely enters 20 and No. 21 resin columns from 20 and No. 21 resin column lower ends, 20 and No. 21 resin column upper end discharge header pipe access material transfer tanks; 22 and No. 23 resin column lower end discharge header pipe are by reflux line access material transfer tank, and upper end pan feeding arm connects copper sulfate conduit;
Wherein, described No. 24 resin columns access air line suitable for reading, end opening is by reuse water pipeline access water tank;
Wherein, filling male ion-exchange resin in described resin column.
The utility model beneficial effect:
The utility model adopts continuous ionic switching technology to extract cupric ion from ore waste water, and waste water is turned waste into wealth, and realizes environmental protection and produces.
The utility model, by optimizing the mode of connection between resin column, effectively saves water consumption, improves product yield, discharge of wastewater is few; Running cost is low.
Accompanying drawing explanation
Fig. 1 is the structural representation that the utility model embodiment extracts the continuous ionic exchange system of cupric ion from ore waste water.
Drawing reference numeral illustrates: water tank 1, reuse water pipeline 2, diverting valve 3, material transfer tank 4, feed back pipeline 5, air line 6, water tank 7, reflux line 8, feed back pipeline 9, material transfer tank 10, reflux line 11, copper sulfate conduit 12, air line 13.
Embodiment
As shown in Figure 1, a kind of continuous ionic exchange system extracting cupric ion from ore waste water, comprise 1 ~ No. 24 resin column, charging house steward, discharge header pipe, with charging house steward be communicated with feed-inputing branched pipe, with discharge header pipe be communicated with discharging arm, in described 1 ~ No. 24 resin column, 1 ~ No. 12 resin column is adsorption zone, and 13 ~ No. 24 resin columns are for resolving district; In described adsorption zone, between 1 ~ No. 5 resin column, adopt series system to connect, between 6 ~ No. 12 resin columns, adopt parallel way to connect; In described parsing district, the mode of 2 that adopt another 2 resin columns in parallel of 2 in parallel resin columns series connection to connect remaining again between 14 ~ No. 19 resin columns resin columns in parallel connects; 20 adopt parallel way to be connected with No. 21 resin columns, 22 with No. 23 resin columns respectively.
Wherein, described No. 1 resin column connection water tank 1 suitable for reading, No. 5 resin column end openings connect material transfer tank 4, mine wastewater enters 6 ~ No. 8 resin columns by the charging house steward of 6 ~ No. 8 resin columns respectively by diverting valve 3, the discharge header pipe access material transfer tank 4 of 6 ~ No. 8 resin columns, material transfer tank 4 is connected with the upper endfeed house steward of 9 ~ No. 12 resin columns by feed back pipeline 5;
Wherein, described No. 13 resin columns connection air line 6 suitable for reading, described No. 13 resin column end openings access water tank 7, water tank 7 is connected with endfeed house steward on No. 15 resin columns with 14 by reflux line 8;
Wherein, described 18 are connected with material transfer tank 10 by feed back pipeline 9 with No. 19 total condominium of resin column lower end discharging;
Wherein, sulfuric acid oppositely enters 20 and No. 21 resin columns from 20 and No. 21 resin column lower ends, upper end discharge header pipe access material transfer tank 10; 22 and No. 23 resin column lower end discharge header pipe access material transfer tank 10 by reflux line 11, and upper end pan feeding arm connects copper sulfate conduit 12;
Wherein, described No. 24 resin columns access air line 13 suitable for reading, end opening accesses water tank 1 by reuse water pipeline 2;
Wherein, filling male ion-exchange resin in described resin column.
The foregoing is only the preferred embodiments of the present invention, be not limited to the present invention, for a person skilled in the art, the present invention can have various modifications and variations.Within the spirit and principles in the present invention all, any amendment done, equivalent replacement, improvement etc., all should be included within protection scope of the present invention.

Claims (5)

1. one kind is extracted the continuous ionic exchange system of cupric ion from ore waste water, comprise 1 ~ No. 24 resin column, charging house steward, discharge header pipe, with charging house steward be communicated with feed-inputing branched pipe, with discharge header pipe be communicated with discharging arm, it is characterized in that: in described 1 ~ No. 24 resin column, 1 ~ No. 12 resin column is adsorption zone, and 13 ~ No. 24 resin columns are for resolving district; In described adsorption zone, between 1 ~ No. 5 resin column, adopt series system to connect, between 6 ~ No. 12 resin columns, adopt parallel way to connect; In described parsing district, the mode of 2 that adopt another 2 resin columns in parallel of 2 in parallel resin columns series connection to connect remaining again between 14 ~ No. 19 resin columns resin columns in parallel connects; 20 all adopt parallel way to be connected with No. 21 resin columns, 22 with No. 23 resin columns.
2. a kind of continuous ionic exchange system extracting cupric ion from ore waste water as claimed in claim 1, it is characterized in that: described No. 1 resin column connection water tank suitable for reading, No. 5 resin column end openings connect material transfer tank, mine wastewater enters 6 ~ No. 8 resin columns by the charging house steward of 6 ~ No. 8 resin columns respectively by diverting valve, the discharge header pipe access material transfer tank of 6 ~ No. 8 resin columns, material transfer tank is connected with the upper endfeed house steward of 9 ~ No. 12 resin columns by feed back pipeline.
3. a kind of continuous ionic exchange system extracting cupric ion from ore waste water as claimed in claim 1, is characterized in that: described 18 are connected with material transfer tank by feed back pipeline with No. 19 total condominium of resin column lower end discharging.
4. a kind of continuous ionic exchange system extracting cupric ion from ore waste water as claimed in claim 1, is characterized in that: described 20 and No. 21 resin column upper end discharge header pipe access material transfer tanks; 22 and No. 23 resin column lower end discharge header pipe are by reflux line access material transfer tank, and upper end feed-inputing branched pipe connects copper sulfate conduit.
5. a kind of continuous ionic exchange system extracting cupric ion from ore waste water as claimed in claim 1, is characterized in that: described No. 24 resin columns access air line suitable for reading, and end opening is by reuse water pipeline access water tank.
CN201520655471.6U 2015-08-28 2015-08-28 Draw continuous ion exchange system of copper ion in follow ore waste water Active CN204982006U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201520655471.6U CN204982006U (en) 2015-08-28 2015-08-28 Draw continuous ion exchange system of copper ion in follow ore waste water

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Application Number Priority Date Filing Date Title
CN201520655471.6U CN204982006U (en) 2015-08-28 2015-08-28 Draw continuous ion exchange system of copper ion in follow ore waste water

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CN204982006U true CN204982006U (en) 2016-01-20

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CN201520655471.6U Active CN204982006U (en) 2015-08-28 2015-08-28 Draw continuous ion exchange system of copper ion in follow ore waste water

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110372127A (en) * 2019-07-31 2019-10-25 赛普特环保技术(厦门)有限公司 The extraction element and technique of a kind of complete-dihydrogen orthophosphate of inositol six

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110372127A (en) * 2019-07-31 2019-10-25 赛普特环保技术(厦门)有限公司 The extraction element and technique of a kind of complete-dihydrogen orthophosphate of inositol six

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GR01 Patent grant
CP03 Change of name, title or address

Address after: Room 802, No. 30, Jiayuanli, Huli District, Xiamen City, Fujian Province

Patentee after: Huasheng Fluid Separation Technology (Xiamen) Co., Ltd.

Address before: Room 802, No. 30, Jiayuanli, Huli District, Xiamen City, Fujian Province

Patentee before: Huasheng fluid separation technology (Xiamen) Co., Ltd.

CP03 Change of name, title or address