CN204958680U - Industrial waste water's processing apparatus - Google Patents

Industrial waste water's processing apparatus Download PDF

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Publication number
CN204958680U
CN204958680U CN201520687894.6U CN201520687894U CN204958680U CN 204958680 U CN204958680 U CN 204958680U CN 201520687894 U CN201520687894 U CN 201520687894U CN 204958680 U CN204958680 U CN 204958680U
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China
Prior art keywords
reactor
waste water
bio
line mixer
treatment unit
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Withdrawn - After Issue
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CN201520687894.6U
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Chinese (zh)
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邓万军
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DALIAN BISHUILANTIAN ENVIRONMENTAL PROTECTION TECHNOLOGY ENGINEERING Co Ltd
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Individual
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Abstract

The utility model relates to an industrial waste water's processing apparatus. This processing apparatus include ozone generator, waste water intake jar, waste water pump, line mixer, ozone catalytic oxidation reactor, produce water pitcher and bioreactor, ozone generator and line mixer are connected, the output that waste water was intake jar passes through the waste water pump to be connected with line mixer, line mixer's the output and the entry linkage of ozone catalytic oxidation reactor, and the delivery port and the input of producing the water pitcher of ozone catalytic oxidation reactor are connected, and the output of product water pitcher passes through the waste water pump to be connected with bioreactor, bioreactor's the delivery port and the entry linkage of product water pitcher. Adopt the utility model discloses a processing apparatus realizes high -efficiency biological denitrogenation performance, the utility model discloses an effluent treatment plant realizes ozone catalytic oxidation and biochemical integration and handles, reduces the running cost, effectively realizes the reaction of waste water catalytic oxidation and go on in step with the waste water membrane separation that output water quality of water is good, the stability of the device reliability of operation with is improved.

Description

The treatment unit of trade effluent
Technical field
The utility model belongs to technical field of sewage, is specifically related to a kind for the treatment of unit of trade effluent.
Background technology
Trade effluent is industrial association product, and the generation of trade effluent is comparatively large, and containing a large amount of all kinds of organic pollutant and solubility salt impurity, direct discharge can cause serious harm to water body and surrounding environment, must carry out process and could discharge or reuse.Biochemical process is the most frequently used method of process all types of industries waste water, can effective all kinds of organic pollutant of degrading waste water, and processing cost is cheap.Along with industrial technology development and the raising day by day of environmental requirement, more and more higher to the requirement of all types of industries wastewater treatment standard and reuse, though current many trade effluents still cannot meet the demands after biochemical treatment, meanwhile, the trade effluent of various difficult biochemical treatment is also had still to face the high difficult problem of processing cost.
Utility model content
The utility model is low for solving trade effluent combined treatment process ozone utilising efficiency in prior art, biochemical effects is undesirable, the problem of the deficiency that processing cost is high, by catalytic ozonation reactor and bio-reactor coupling, provide the treatment unit of the trade effluent of a kind of catalytic ozonation and biochemistry integration, the problem of the difficult biochemical treatment of effective solution trade effluent, especially has unique effect in advanced treatment of industrial waste water and reuse.
The utility model is achieved in that the treatment unit of trade effluent, and comprise ozonizer, influent waste water tank, waste water pump, line mixer, catalytic ozonation reactor, produce water pot and bio-reactor, ozonizer is connected with line mixer; The output terminal of influent waste water tank is connected with line mixer by waste water pump, the output terminal of line mixer is connected with the entrance of catalytic ozonation reactor, the outlet of catalytic ozonation reactor is connected with the input terminus producing water pot, the output terminal producing water pot is connected with bio-reactor by waste water pump, and the water outlet of bio-reactor is connected with the entrance producing water pot.
Further, described catalytic ozonation reactor comprises reactor body, film pipe, central tube, waterwater entrance, water outlet and drain; Reactor body upper end is provided with drain, and the side of reactor body is provided with water outlet; Be provided with central tube in reactor body, be provided with waterwater entrance bottom described central tube, the two ends of central tube are fixed by tube sheet; Described film pipe two ends are fixed by tube sheet and seal, and film circumference of cannon bone is around central tube circumferentially shape arrangement, and intercommunication between each film pipe, central tube is communicated with film pipe.
Further, the film pipe of described catalytic ozonation reactor is ceramic-film tube or titanium alloy bar or titanium alloy tube, and this film pipe is the pipe of 5 ~ 10 microns, aperture, diameter 20 ~ 40 millimeters, length 1 ~ 1.5 meter.
Further, described central tube to be diameter be vitrified pipe or the stainless steel tube of 100 ~ 300 millimeters.
Further, described bio-reactor comprises reactor body, boiling ball reaction bed, waterwater entrance, air intlet, hand hole, water outlet and drain, described reactor body inside is provided with boiling ball reaction bed, boiling ball reaction bed there is at least one boiling ball, described boiling ball is the acrylic sphere of diameter 30-70 millimeter, this boiling ball there is aperture 2-5 millimeter mesh, boiling ball inside is divided into central core and skin, central core fills iron-carbon filling material and polypropylene hollow ball, outer filling volcanics and leca, composition proportion is the boiling ball of 0.8-1.5, the lower end of reactor body is provided with waterwater entrance and air intlet, and the upper end of reactor body is provided with drain, and the side of reactor body is provided with hand hole, and opposite side is provided with water outlet.
Further, described bio-reactor inside is also provided with volcanics filtering layer.
Further, this treatment unit also comprises vacuum pump, air cleaning unit, air compressor machine and product water pump.
Further, described vacuum pump with produce the venting port of water pot and be connected, described air cleaning unit and air compressor machine and bio-reactor are connected in series; Described product water pump is connected with the output terminal producing water pot.
The utility model, by catalytic ozonation reactor and bio-reactor coupling, forms catalytic ozonation of new generation and biochemical integrated treatment unit.By controlling select the type of powder catalytic and add concentration, and the add-on of ozone and hydraulic detention time, control the degree of depth and the efficiency of catalytic ozonation, thus realize the B/CB ratio improving difficult biochemical waste water, effectively can improve synchronous digestion and denitrification usefulness; The trade effluent chemical oxygen demand (COD) of the multiple difficult degradations such as significant depth process oil refining, chemical industry and papermaking; Especially be applicable to process vinyl cyanide waste water, meet new environmental protection and reuse requirement.Catalytic ozonation catalyst reactor is Fe 2o 3, several composite reactive components in CoO, CuO, MnO, NiO, PtO, ZnO, VO and CeO, the granularity of powder is 50-100 micron (150-300 order), adds the 0.1%-5% that concentration is water in reactor.
Compared with traditional wastewater treatment equipment, the beneficial effects of the utility model are:
Adopt treatment unit of the present utility model, the utilising efficiency of ozone can improve more than 30%; Biological denitrificaion efficiency improves more than 20%; Chemical oxygen demand (COD) degradation efficiency can improve 20-30%; Realize high-efficiency biological denitrification performance; Wastewater treatment equipment of the present utility model realizes catalytic ozonation and biochemistry is close-coupled processing, reduces running cost, and effectively realize waste water catalytic oxidation and wastewater membrane and be separated and synchronously carry out, production water water quality is good; Improve the reliability and stability of plant running.
Accompanying drawing explanation
Fig. 1 is the utility model device schematic diagram;
Fig. 2 is the utility model catalytic ozonation structure of reactor schematic diagram;
Fig. 3 is the utility model catalytic ozonation reactor sectional view;
Fig. 4 is the utility model bioreactor construction schematic diagram;
Fig. 5 is the utility model boiling spherical structure schematic diagram.
Wherein, 1, ozonizer, 2, influent waste water tank, 3, waste water pump, 4, catalytic ozonation reactor, 41, central tube, 42, film pipe, 43, waterwater entrance, 44, water outlet, 45, drain, 5, produce water pot, 6, bio-reactor, 61, outer, 62, boiling ball reaction bed, 63, waterwater entrance, 64, air intlet, 65, hand hole, 66, water outlet, 67, drain, 68, volcanics filtering layer, 69, boiling ball, 610, central core, 7, air cleaning unit, 8, air compressor machine, 9, line mixer, 10, vacuum pump, 11, produce water pump.
Embodiment
Below by embodiment, the utility model is described further.
Embodiment 1
As shown in Fig. 1 ~ 5, a kind of industrial waste water disposal device, comprise ozonizer 1, influent waste water tank 2, waste water pump 3, line mixer 9, catalytic ozonation reactor 4, produce water pot 5 and bio-reactor 6, ozonizer 1 is connected with line mixer 9; The output terminal of influent waste water tank 2 is connected with line mixer 9 by waste water pump 3, the output terminal of line mixer 9 is connected with the entrance of catalytic ozonation reactor 4, the outlet of catalytic ozonation reactor 4 is connected with the input terminus producing water pot 5, the output terminal producing water pot 5 is connected with bio-reactor 6 by waste water pump 3, and the water outlet of bio-reactor 6 is connected with the entrance producing water pot 5.
Catalytic ozonation reactor 4 comprises reactor body, film pipe 42, central tube 41, waterwater entrance 43, water outlet 44 and drain 45; Reactor body upper end is provided with drain 45, and the side of reactor body is provided with water outlet 44; Be provided with central tube 41 in reactor body, the bottom of described central tube 41 is provided with waterwater entrance 43, and the two ends of central tube 41 are fixed by tube sheet; Described film pipe 42 two ends are fixed by tube sheet and seal, and film pipe 42 is around central tube 41 circumferentially shape arrangement, and the inner intercommunication of each film pipe 42, central tube 41 is communicated with film pipe 42.Described film pipe 42 is ceramic-film tube, and this film pipe 42 is the pipe of 5 ~ 10 microns, aperture, diameter 20 ~ 40 millimeters, length 1 ~ 1.5 meter.Central tube 41 for diameter be vitrified pipe or the stainless steel tube of 100 ~ 300 millimeters.
Bio-reactor 6 comprises reactor body, boiling ball reaction bed 62, waterwater entrance 63, air intlet 64, hand hole 65, water outlet 66 and drain 67, described reactor body inside is provided with boiling ball reaction bed 62, boiling ball reaction bed 62 there is at least one boiling ball 69, described boiling ball 69 is the acrylic sphere of diameter 30-70 millimeter, this boiling ball 69 there is aperture 2-5 millimeter mesh, boiling ball 69 inside is divided into central core 610 and outer 61, central core 610 fills iron-carbon filling material and polypropylene hollow ball, outer 61 filling volcanics and leca composition proportion are the boiling ball 69 of 0.8-1.5, the lower end of reactor body is provided with waterwater entrance 63 and air intlet 64, and the upper end of reactor body is provided with drain 67, and the side of reactor body is provided with hand hole 65, and opposite side is provided with water outlet 66.
During use, trade effluent is flowed into influent waste water tank 2, mix through line mixer 9 with the gas ozoniferous that ozonizer 1 produces through waste water pump 3 pressurization, enter the catalytic ozonation reactor 4 containing fine catalyst together, gas is discharged by the drain 45 of catalytic ozonation reactor 4 tower top, and the water after process is drawn into through ceramic membrane separation and produces water pot 5; Then entered bio-reactor 6 by waste water pump 3 pressurization, blast air aeration simultaneously in bio-reactor 6, the qualified waste water after process is pumped to and produces water pot 5; Reuse or discharge after desalting treatment.
Embodiment 2
As shown in Fig. 1 ~ 5, a kind of industrial waste water disposal device, comprise ozonizer 1, influent waste water tank 2, waste water pump 3, line mixer 9, catalytic ozonation reactor 4, produce water pot 5, bio-reactor 6, vacuum pump 10, air cleaning unit 7, air compressor machine 8 and produce water pump 11, ozonizer 1 is connected with line mixer 9; The output terminal of influent waste water tank 2 is connected with line mixer 9 by waste water pump 3, the output terminal of line mixer 9 is connected with the entrance of catalytic ozonation reactor 4, the outlet of catalytic ozonation reactor 4 is connected with the input terminus producing water pot 5, vacuum pump 10 is connected with the venting port producing water pot 5, the output terminal producing water pot 5 is connected with bio-reactor 6 by waste water pump 3, and described air cleaning unit 7 and air compressor machine 8 are connected in series with the air intlet 64 of bio-reactor 6; Described product water pump 11 is connected with the output terminal producing water pot 5, and the water outlet of bio-reactor 6 is connected with the entrance producing water pot 5.
Bio-reactor 6 comprises reactor body, boiling ball reaction bed 62, volcanics filtering layer 68, waterwater entrance 63, air intlet 64, hand hole 65, water outlet 66 and drain 67, described reactor body inside is provided with boiling ball reaction bed 62, boiling ball reaction bed 62 there is at least one boiling ball 69, described boiling ball 69 is the acrylic sphere of diameter 30-70 millimeter, this boiling ball 69 there is aperture 2-5 millimeter mesh, boiling ball 69 inside is divided into central core 610 and outer 61, central core 610 fills iron-carbon filling material and polypropylene hollow ball, outer 61 filling volcanics and leca composition proportion are the boiling ball 69 of 0.8-1.5, be provided with volcanics filtering layer 68 below boiling ball reaction bed 62, volcanics filtering layer 68 fills volcanics, the lower end of reactor body is provided with waterwater entrance 63 and air intlet 64, and the upper end of reactor body is provided with drain 67, and the side of reactor body is provided with hand hole 65, and opposite side is provided with water outlet 66.
During use, trade effluent is flowed into influent waste water tank 2, mix through line mixer 9 with the gas ozoniferous that ozonizer 1 produces through waste water pump 3 pressurization, enter the catalytic ozonation reactor 4 containing fine catalyst together, gas is discharged by the drain 45 of catalytic ozonation reactor 4 tower top, and the water after process is drawn into through ceramic membrane separation and produces water pot 5; Gas enters vacuum pump 10, then bio-reactor 6 is entered by waste water pump 3 pressurization, air is blasted bio-reactor 6 air aeration by air cleaning unit 7 and air compressor machine 8, after the boiling ball reaction bed 62 of waste water through containing in bio-reactor 6 and volcanics filtering layer 68 process, qualified waste water is pumped to and produces water pot 5; Reuse or discharge after desalting treatment.
Catalytic ozonation catalyst in reactor main component is Fe 2o 3, several composite reactive components in CoO, CuO, MnO, NiO, PtO, ZnO, VO and CeO, the granularity of powder is 50-100 micron (150-300 order), and adding concentration is 0.1%-5%.
Test example
The trade effluent of Dalian petro-chemical corporation vinyl cyanide comprehensive discharge, through traditional aerobic/anaerobic technique and the process of Jian Xie aeration system, water outlet chemical oxygen demand (COD) (COD) is 150-350mg/L, and ammonia nitrogen is 100-200mg/L, is difficult to satisfied new emission standard requirement.Adopt the utility model device and integrated processing technique, with Fe 2o 3, CoO, CuO, MnO and CeO powder composite reactive component is catalyzer.After process, water outlet COD is less than 60mg/L, and ammonium nitrogen is less than 5mg/L; The utilising efficiency of ozone can improve more than 30%; Biological denitrificaion efficiency improves more than 20%; Chemical oxygen demand (COD) degradation efficiency can improve 20-30% and meet new standard-required, and is this type of waste water recycling creation prerequisite, solves a difficult problem for acrylic nitrile waste water process.
The above; be only the utility model preferably embodiment; but protection domain of the present utility model is not limited thereto; anyly be familiar with those skilled in the art in the technical scope that the utility model discloses; be equal to according to the technical solution of the utility model and utility model design thereof and replace or change, all should be encompassed within protection domain of the present utility model.

Claims (8)

1. the treatment unit of a trade effluent, it is characterized in that, comprise ozonizer (1), influent waste water tank (2), waste water pump (3), line mixer (9), catalytic ozonation reactor (4), produce water pot (5) and bio-reactor (6), ozonizer (1) is connected with line mixer (9); The output terminal of influent waste water tank (2) is connected with line mixer (9) by waste water pump (3), the output terminal of line mixer (9) is connected with the entrance of catalytic ozonation reactor (4), the outlet of catalytic ozonation reactor (4) is connected with the input terminus producing water pot (5), the output terminal producing water pot (5) is connected with bio-reactor (6) by waste water pump (3), and the water outlet of bio-reactor (6) is connected with the entrance producing water pot (5).
2. the treatment unit of trade effluent according to claim 1, it is characterized in that, described catalytic ozonation reactor (4) comprises reactor body, film pipe (42), central tube (41), waterwater entrance (43), water outlet (44) and drain (45); Reactor body upper end is provided with drain (45), and the side of reactor body is provided with water outlet (44); Be provided with central tube (41) in reactor body, described central tube (41) bottom is provided with waterwater entrance (43), and the two ends of central tube (41) are fixed by tube sheet; Described film pipe (42) two ends are fixed by tube sheet and seal, film pipe (42) is around central tube (41) circumferentially shape arrangement, intercommunication between each film pipe (42), central tube (41) is communicated with film pipe (42).
3. the treatment unit of trade effluent according to claim 1 and 2, it is characterized in that, the film pipe (42) of described catalytic ozonation reactor (4) is ceramic-film tube or titanium alloy bar or titanium alloy tube, and this film pipe (42) is 5 ~ 10 microns, aperture, the pipe of diameter 20 ~ 40 millimeters, length 1 ~ 1.5 meter.
4. the treatment unit of trade effluent according to claim 1 and 2, is characterized in that, described central tube (41) for diameter be vitrified pipe or the stainless steel tube of 100 ~ 300 millimeters.
5. the treatment unit of trade effluent according to claim 1, it is characterized in that, described bio-reactor (6) comprises reactor body, boiling ball reaction bed (62), waterwater entrance (63), air intlet (64), hand hole (65), water outlet (66) and drain (67), described reactor body inside is provided with boiling ball reaction bed (62), boiling ball reaction bed (62) there is at least one boiling ball (69), the acrylic sphere that described boiling ball (69) is diameter 30-70 millimeter, this boiling ball (69) there is aperture 2-5 millimeter mesh, boiling ball (69) inside is divided into central core (610) and outer (61), central core (610) fills iron-carbon filling material and polypropylene hollow ball, outer (61) fill volcanics and leca, composition proportion is the boiling ball (69) of 0.8-1.5, the lower end of reactor body is provided with waterwater entrance (63) and air intlet (64), the upper end of reactor body is provided with drain (67), the side of reactor body is provided with hand hole (65), and opposite side is provided with water outlet (66).
6. the treatment unit of trade effluent according to claim 1 or 5, it is characterized in that, described bio-reactor (6) inside is also provided with volcanics filtering layer (68).
7. the treatment unit of trade effluent according to claim 1, is characterized in that, this treatment unit also comprises vacuum pump (10), air cleaning unit (7), air compressor machine (8) and produces water pump (11).
8. the treatment unit of trade effluent according to claim 7, it is characterized in that, described vacuum pump (10) is connected with the venting port producing water pot (11), and described air cleaning unit (7) and air compressor machine (8) are connected in series with bio-reactor (6); Described product water pump (11) is connected with the output terminal producing water pot (5).
CN201520687894.6U 2015-09-08 2015-09-08 Industrial waste water's processing apparatus Withdrawn - After Issue CN204958680U (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105174615A (en) * 2015-09-08 2015-12-23 邓万军 Treatment device and treatment method of industrial wastewater
CN107445292A (en) * 2017-09-18 2017-12-08 北京欧奏普尔环保设备有限公司 Efficiently catalyzing and oxidizing reaction unit

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105174615A (en) * 2015-09-08 2015-12-23 邓万军 Treatment device and treatment method of industrial wastewater
CN107445292A (en) * 2017-09-18 2017-12-08 北京欧奏普尔环保设备有限公司 Efficiently catalyzing and oxidizing reaction unit

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Legal Events

Date Code Title Description
C14 Grant of patent or utility model
GR01 Patent grant
C41 Transfer of patent application or patent right or utility model
TR01 Transfer of patent right

Effective date of registration: 20160127

Address after: 116021, building 17, No. 267, Wuyi Road, Shahekou District, Liaoning, Dalian, 301C1

Patentee after: Dalian Bishuilantian Environmental Protection Technology Engineering Co., Ltd.

Address before: 116021, building 17, No. 267, Wuyi Road, Shahekou District, Liaoning, Dalian, 301C1

Patentee before: Deng Wanjun

AV01 Patent right actively abandoned
AV01 Patent right actively abandoned

Granted publication date: 20160113

Effective date of abandoning: 20171222