CN204952727U - Machine is mixed in succession to anti -oxidant vertical four -axis of skinning loam automatic blending of scribbling - Google Patents

Machine is mixed in succession to anti -oxidant vertical four -axis of skinning loam automatic blending of scribbling Download PDF

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Publication number
CN204952727U
CN204952727U CN201520497575.9U CN201520497575U CN204952727U CN 204952727 U CN204952727 U CN 204952727U CN 201520497575 U CN201520497575 U CN 201520497575U CN 204952727 U CN204952727 U CN 204952727U
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China
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main shaft
shaft
driven pulley
stirrer paddle
back taper
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CN201520497575.9U
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王东
常少文
马桂红
王连波
马琳
魏士博
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Anshan Yongheng Special Refractory Material Manufacturing Co Ltd
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Anshan Yongheng Special Refractory Material Manufacturing Co Ltd
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Abstract

The utility model discloses a machine is mixed in succession to anti -oxidant vertical four -axis of skinning loam automatic blending of scribbling installs on the main shaft on passing through the shaft coupling with motor, cycloidal -pin gear speed reducer, and the action wheel through installation on the main shaft drives driven round three rotation, drives the antiport of supplementary axle from this, installs stirring paddle leaf about the main shaft on the main shaft, and the main shaft bottom is connected with back taper disc branch and spills the dish, the three supplementary epaxial stirring paddle leaf that installs separately, the inside middle part of barrel is provided with back taper baffling board, stirring paddle leaf is opposite with three supplementary epaxial respective stirring paddle leaf direction of rotation about the feasible main epaxial main shaft, the main shaft is mixed the paddle from top to bottom and is to one side 45 angles mixed stirring down to one side down, supplementary epaxial three stirring paddle leaf separately 45 last angles to one side goes up mixed stirring to one side, form the sinuous flow, the stirring that bumps mixes, make mixed stirring effect dispersibility better, utilize the collision to smash gathering conglobate granule, make it to reach mixed stirring effect.

Description

The vertical four axle continuous mixers of anti-oxidant coating automatic blending
Technical field
The utility model relates to technical field of fire resistant material production, particularly relates to the vertical four axle continuous mixers of a kind of anti-oxidant coating automatic blending.
Background technology
For ensureing that blast furnace normally runs; promote prolonging campaign, at blast furnace inwall with the entity of refractory material laying for blast furnace lining, its effect one is to form blast furnace working space; two is the heat loss reducing blast furnace, and three is protect furnace shell and other metal structure from thermal stress and chemical erosion.Blast furnace lining in use, because blast furnace lining is under furnace high-temperature oxidizing atmosphere, can there is surface oxidation phenomenon in furnace lining surface, oxidation not only causes the loss of furnace lining gradually, also can cause the dilution of alloying element in steel, have a strong impact on steel product quality and mechanical performance; Therefore, need to use anti-oxidant coating regularly to carry out safeguarding and repairing, stable lining thickness can be maintained, extend the life of the blast furnace, promote steel product quality and mechanical performance.Anti-oxidant coating is a kind of amorphous refractory, and its composition general quantitatively mixing by the Inorganic Non-metallic Materials of Multiple components forms, and need different compositions to measure respectively when producing, quantitatively mix according to a certain ratio, this process is called batching.
But along with the progress of science and technology, the demand of all trades and professions to anti-oxidant coating presents diversified trend, anti-oxidant coating product is towards small lot multi items future development, to meet the different demands segmented market, anti-oxidant coating manufacturing enterprise is just strided forward towards Automation of Manufacturing Process direction, and adopt automatic blending line production system to produce, blending process is a complex process, need each process units coordinated operation of Ingredient Production Line, but the batching continuous mixer of equipment in use at present, there is the irrational problem of project organization, make the uniformity of mixed anti-oxidant coating product quality, less stable, cause unstable product quality, easily cause quality accident.In addition, the target of application percentage >=50% of amorphous refractory once repeatedly drafted by China's refractory material circle, but due to many-sided reasons such as technology and economy, so far the target of application percentage >=50% is not yet realized, amorphous refractory production, the automation of application, intelligent level should be carried forward vigorously thus, improve amorphous refractory quality and stability thereof, reduce the production cost of high-quality amorphous refractory, accelerate to advance and improve amorphous refractory application percentage, reach the average level that developed country has, save energy and reduce the cost further.Therefore, a kind of technical scheme is needed to solve the problem.
Summary of the invention
For above the deficiencies in the prior art, the purpose of this utility model is to provide the vertical four axle continuous mixers of a kind of anti-oxidant coating automatic blending, ensures that the production of anti-oxidant coating automatic batching system is carried out smoothly.
For achieving the above object, the utility model realizes by the following technical solutions:
Motor, the cycloidal planetary gear speed reducer as Power Drive Unit is provided with in the center of cover, charging aperture A, charging aperture B, charging aperture C with cover center for round dot, trisection is distributed on cover, between charging aperture with cover center for round dot, also trisection is evenly equipped with asessory shaft A end cap, asessory shaft B end cap, asessory shaft C end cap.
As motor, the cycloidal planetary gear speed reducer of Power Drive Unit, connected by joint on shaft coupling main shaft by cycloidal planetary gear speed reducer axle head, it is provided with driving wheel, bearing block is arranged on the top board of cylindrical shell by bolt, main shaft saves and saves by main shaft adpting flange under main shaft and be bolted together, main shaft is provided with stirrer paddle on main shaft, is connected with back taper disc bottom main shaft and divides and spread dish; The bosom position of cylindrical shell is provided with back taper deflection plate, and the bottom of cylindrical shell is designed to inverted cone-shaped, and bottom is provided with star discharge valve, discharging opening, separately cylindrical shell bottom is provided with manhole.
Be provided with in the center of cylindrical shell as power-actuated driving wheel, driven pulley B, driven pulley A, driven pulley C take body centre as round dot, trisection is distributed on cylindrical shell, driven pulley B, driven pulley A, driven pulley C and driving wheel are by spur gear engaged transmission, driving shaft is driven to rotate by cycloidal planetary gear speed reducer the outputting power of motor, and rotating drive driven pulley B, driven pulley A, driven pulley C synchronized rotation in the other direction by the driving wheel on driving shaft, drive asessory shaft B, asessory shaft A, asessory shaft C rotate the mix and blend carrying out refractory material thus.
On main shaft lower stirring paddle leaf and main shaft, stirrer paddle is arranged on main shaft in the same way, stirrer paddle B, stirrer paddle A, stirrer paddle A are installed on respective asessory shaft respectively, but stirrer paddle is oppositely installed on installation direction and main shaft lower stirring paddle leaf and main shaft, the stirrer paddle B, the stirrer paddle A that make asessory shaft is installed, stirrer paddle C tiltedly go up the tiltedly upper mix and blend of 45o angle, and the tiltedly lower mix and blend of blade in oblique lower 45o angle mixed up and down by the main shaft on main shaft.
Inner barrel middle part is provided with back taper deflection plate, makes anti-oxidant coating wander the bottom of cylindrical shell fast by its baffling blending, through the aperture of back taper deflection plate, under main shaft, joint bottom is provided with back taper disc and divides and spread dish.
Divide to spread in back taper disc and dish is provided with radial point spreads spoke, card is provided with material-dropping hole, and its percent opening is about 20%, and aperture is at 1-10mm, object makes most refractory material divide spread out by point spreading dish surrounding equably, and remaining part is fallen by material-dropping hole.
Beneficial effect: the utility model as the motor of Power Drive Unit, cycloidal planetary gear speed reducer by shaft coupling being arranged on main shaft, three driven pulleys are driven to rotate by the driving wheel that main shaft is installed, asessory shaft is driven to rotate backward thus, main shaft is provided with the upper and lower stirrer paddle of main shaft, is connected with back taper disc bottom main shaft and divides and spread dish, three asessory shafts are provided with stirrer paddle separately, the bosom position of cylindrical shell is provided with back taper deflection plate, make the upper and lower stirrer paddle of the main shaft on main shaft contrary with stirrer paddle direction of rotation respective on three asessory shafts like this, the tiltedly lower mix and blend of blade in oblique lower 45o angle mixed up and down by main shaft, respective three stirrer paddles on asessory shaft tiltedly go up the tiltedly upper mix and blend of 45o angle, form sinuous flow, collide and be uniformly mixed, make mix and blend better effects if, dispersed better, utilize collision that the particle of the group of being polymerized to is smashed, make it the effect reaching mixing and stirring.
Accompanying drawing explanation
Fig. 1 is top view of the present utility model;
Fig. 2 is the A-A cross-sectional view of the utility model Fig. 1;
Fig. 3 is the B-B cross-sectional view of the utility model Fig. 1;
Fig. 4 is the C-C cross-sectional view of the utility model Fig. 1;
Fig. 5 is the D-D cross-sectional view of the utility model Fig. 2;
Fig. 6 is the E-E cross-sectional view of the utility model Fig. 2;
Fig. 7 is the F-F cross-sectional view of the utility model Fig. 2;
Fig. 8 is the G-G cross-sectional view of the utility model Fig. 2;
Fig. 9 is that back taper disc of the present utility model is divided and spread dish structural representation;
In figure: 1-charging aperture A, 2-motor, 3-asessory shaft A end cap, 4-cycloidal planetary gear speed reducer, 5-charging aperture B, 6-asessory shaft B end cap, 7-cover, 8-bearing, 9-charging aperture C, 10-asessory shaft C end cap, 11-shaft coupling saves, 12-reductor shaft end clamp plate, 13-main-axis end pressing plate, save under 14-shaft coupling, 15-principal shaft locking round nut, 16-driven pulley B, 17-asessory shaft B bearing, 18-outside framework oil seal B, 19-sealing ring B, 20-asessory shaft B, 21-stirrer paddle B, 22-back taper deflection plate, 23-divides and spreads dish connecting bolt, 24-star discharge valve, 25-discharging opening, 26-back taper disc is divided and is spread dish, 27-main shaft lower stirring paddle leaf, 28-cylindrical shell, save under 29-main shaft, 30-main shaft adpting flange and bolt, stirrer paddle on 31-main shaft, 32-main shaft saves, 33-main shaft seal circle, 34-main shaft outside framework oil seal, 35-bearing block, 36-driving wheel, 37-stirrer paddle A, 38-asessory shaft A, 39-sealing ring A, 40-outside framework oil seal A, 41-asessory shaft A bearing, 42-driven pulley A, 43-stripped nut A, 44-cover connecting bolt, 45-driven pulley C, 46-stirrer paddle A, 47-asessory shaft C, 48-main shaft bearing, 49-divides and spreads spoke, 50-material-dropping hole, 51-bolt hole, 52-asessory shaft C bearing, 53-stripped nut B.
Detailed description of the invention
Below in conjunction with Figure of description, the utility model is described in detail, but it should be noted that enforcement of the present utility model is not limited to following embodiment.
As shown in Fig. 1-Fig. 9, the utility model composition structure comprises charging aperture A1, motor 2, asessory shaft A end cap 3, cycloidal planetary gear speed reducer 4, charging aperture B5, asessory shaft B end cap 6, cover 7, bearing 8, charging aperture C9, asessory shaft C end cap 10, shaft coupling saves 11, reductor shaft end clamp plate 12, main-axis end pressing plate 13, 14 are saved under shaft coupling, principal shaft locking round nut 15, driven pulley B16, asessory shaft B bearing 17, outside framework oil seal B18, sealing ring B19, asessory shaft B20, stirrer paddle B21, back taper deflection plate 22, divide and spread dish connecting bolt 23, star discharge valve 24, discharging opening 25, back taper disc is divided and is spread dish 26, main shaft lower stirring paddle leaf 27, cylindrical shell 28, 29 are saved under main shaft, main shaft adpting flange and bolt 30, stirrer paddle 31 on main shaft, main shaft saves 32, main shaft seal circle 33, main shaft outside framework oil seal 34, bearing block 35, driving wheel 36, mix blade A37, asessory shaft A38, sealing ring A39, outside framework oil seal A40, asessory shaft A bearing 41, driven pulley A42, stripped nut A43, cover connecting bolt 44, driven pulley C45, stirrer paddle A46, asessory shaft C47, main shaft bearing 48, divide and spread spoke 49, material-dropping hole 50, bolt hole 51, asessory shaft C bearing 52, stripped nut B53, its structural design adopts the design of vertical cylinder body, and Power Drive Unit is arranged on cover 7 central upper portion position, and cylindrical shell bottom is designed to inverted cone-shaped, and its underpart is provided with star discharge valve 24, discharging opening 25.
As shown in Figure 1, it is top view of the present utility model, motor 2, the cycloidal planetary gear speed reducer 4 as Power Drive Unit is provided with in the center of cover 7, charging aperture A1, charging aperture B5, charging aperture C9 with cover 7 center for round dot, trisection is distributed on cover 7, between charging aperture with cover 7 center for round dot, also trisection is evenly equipped with asessory shaft A end cap 3, asessory shaft B end cap 6, asessory shaft C end cap 10.
As shown in Figure 2, it is the A-A cross-sectional view of the utility model Fig. 1, Power Drive Unit is arranged on cover 7 central upper portion position, as the motor 2 of Power Drive Unit, cycloidal planetary gear speed reducer 4 is arranged on bearing 8 after connecting, bearing 8 is arranged on cover 7 central upper portion position by bolt, shaft coupling will save the axle head that 11 are fixedly mounted on cycloidal planetary gear speed reducer 4 by flat key and reductor shaft end clamp plate 12, the upper axial that 14 are fixedly mounted on joint 32 on main shaft will be saved under shaft coupling by flat key and main-axis end pressing plate 13, the upper position that main shaft saves 32 is provided with driving wheel 36, shaft shoulder step below the location of driving wheel 36 on axle is respectively and above principal shaft locking round nut 15, the position that on main shaft, the middle part of joint 32 is on the upper side is provided with stirrer paddle 31 on main shaft, support main shaft saving 32 is that the main shaft bearing 48 in dead eye by being arranged on bearing block 35 supports, main shaft bearing 48 is main shaft outside framework oil seal 34 below, dead eye inner underside is processed with sealing ring annular groove, main shaft seal circle 33 is installed in annular groove, bearing block 35 is arranged on the top board of cylindrical shell 28 by bolt, under main shaft saving 32 and main shaft, joint 29 is linked together by main shaft adpting flange and bolt 30, the position that under main shaft, the bottom of joint 29 is on the upper side is provided with main shaft lower stirring paddle leaf 27, be connected with back taper disc and divide by point spreading dish connecting bolt 23 and spread dish 26 bottom it, cover 7 upper left-hand position is provided with charging aperture A1, and charging aperture A1 enters cylindrical shell 28 inside through the top board of cover 7 and cylindrical shell 28, cover 7 upper right position is provided with driven pulley B16, driving wheel 36 and driven pulley B16 are by spur gear engaged transmission, the outputting power of motor 2 is passed to asessory shaft B20, make it do to rotate backward with main shaft, shaft shoulder step below the location of driven pulley B16 on asessory shaft B20 is respectively and above stripped nut B53, the upper shaft head position of asessory shaft B20 be provided with asessory shaft B bearing 17 as on the strong point, another asessory shaft B bearing 17 is installed as lower support point in the dead eye on the bearing block 35 below shaft shoulder step, outside framework oil seal B18 below asessory shaft B bearing 17, dead eye inner underside is processed with sealing ring annular groove, sealing ring B19 is installed in annular groove, the bottom of asessory shaft B20 is provided with stirrer paddle B21, stirrer paddle B21 is arranged on stirrer paddle 31 centre position on main shaft lower stirring paddle leaf 27 and main shaft, asessory shaft B end cap 6 is bolted on cover 7, the bosom position of cylindrical shell 28 is provided with back taper deflection plate 22, and the bottom of cylindrical shell 28 is designed to inverted cone-shaped, and bottom is provided with star discharge valve 24, discharging opening 25, separately cylindrical shell 28 bottom is provided with manhole.
As shown in Figure 3, it is the B-B cross-sectional view of the utility model Fig. 1, cover 7 upper left-hand position is provided with driven pulley A42, driving wheel 36 and driven pulley A42 are by spur gear engaged transmission, the outputting power of motor 2 is passed to asessory shaft A38 to make it do to rotate backward with main shaft, shaft shoulder step below the location of driven pulley A42 on asessory shaft A38 is respectively and above stripped nut A43, the upper shaft head position of asessory shaft A38 be provided with asessory shaft A bearing 41 as on the strong point, another asessory shaft A bearing 41 is installed as lower support point in the dead eye on the bearing block 35 below shaft shoulder step, outside framework oil seal A40 below asessory shaft A bearing 41, dead eye inner underside is processed with sealing ring annular groove, sealing ring A39 is installed in annular groove, asessory shaft A38 bottom is provided with stirrer paddle A37, stirrer paddle A37 is arranged on stirrer paddle 31 centre position on main shaft lower stirring paddle leaf 27 and main shaft, asessory shaft A end cap 3 is bolted on cover 7.
As shown in Figure 4, be the C-C cross-sectional view of the utility model Fig. 1, charging aperture A1, charging aperture C9 are symmetricly set on cover 7 center line both sides respectively, and the top board that charging aperture A1, charging aperture C9 are each passed through cover 7 and cylindrical shell 28 enters cylindrical shell 28 inside; Cover 7 is fixed on cylindrical shell 28 by cover connecting bolt 44.
As shown in Figure 5, it is the D-D cross-sectional view of the utility model Fig. 2, be provided with in the center of cylindrical shell 28 as power-actuated driving wheel 36, driven pulley B16, driven pulley A42, driven pulley C45 with cylindrical shell 28 center for round dot, trisection is distributed on cylindrical shell 28, driven pulley B16, driven pulley A42, driven pulley C45 and driving wheel 36 are by spur gear engaged transmission, the outputting power of motor 2 is passed to driven pulley B16 from driving wheel 36, driven pulley A42, driven pulley C45, it is made to do and driving wheel 36 rightabout, the rotation of same rotational speed, its objective is and drive driving shaft to rotate by cycloidal planetary gear speed reducer 4 outputting power of motor 2, and rotate drive driven pulley B16 by the driving wheel 36 on driving shaft, driven pulley A42, driven pulley C45 synchronized rotation in the other direction, drive asessory shaft B20 thus, asessory shaft A38, asessory shaft C47 rotates the mix and blend carrying out refractory material.
As shown in Figure 6, it is the E-E cross-sectional view of the utility model Fig. 2, bearing block 35 version outline drawing triangular in shape, asessory shaft B bearing 17, asessory shaft B20, asessory shaft A38, asessory shaft A bearing 41, asessory shaft C47, asessory shaft C bearing 52 respectively with on main shaft save 32, main shaft bearing 48 for the radius concentric circles triangular structures such as the center of circle is setting; Further top board by cover 7, cylindrical shell 28, bearing block 35, asessory shaft A end cap 3, asessory shaft B end cap 6, asessory shaft C end cap 10, charging aperture A1, charging aperture B5, charging aperture C9 form driving wheel 36, the gear case body of driven pulley B16, driven pulley A42, driven pulley C45 jointly thus.
As shown in Figure 7, be the F-F cross-sectional view of the utility model Fig. 2, asessory shaft B20, stirrer paddle B21, stirrer paddle A37, asessory shaft A38, stirrer paddle A46, asessory shaft C47 are respectively to save 29 for the radius concentric circles triangular structures such as the center of circle is setting under main shaft lower stirring paddle leaf 27, main shaft, on further main shaft lower stirring paddle leaf 27 and main shaft, stirrer paddle 31 is arranged on main shaft in the same way, stirrer paddle B21, stirrer paddle A37, stirrer paddle A46 is installed on respective asessory shaft respectively, but stirrer paddle 31 is oppositely installed on installation direction and main shaft lower stirring paddle leaf 27 and main shaft, its objective is the stirrer paddle B21 that asessory shaft is installed, stirrer paddle A37, the tiltedly upper mix and blend of stirrer paddle A46 in oblique upper 45o angle, the tiltedly lower mix and blend of stirrer paddle 31 in oblique lower 45o angle on main shaft lower stirring paddle leaf 27 on main shaft and main shaft, the effect making it be uniformly mixed is more thorough, the uniformity of its product quality and stability are obtained improve further.
As shown in Figure 8, it is the G-G cross-sectional view of the utility model Fig. 2, cylindrical shell 28 bosom position is provided with back taper deflection plate 22, its objective is and make anti-oxidant coating wander the bottom of cylindrical shell 28 fast by its baffling blending, through the aperture of back taper deflection plate 22, save under main shaft and back taper disc is installed bottom 29 divides and spread dish 26.
As shown in Figure 9, that back taper disc of the present utility model is divided and spread dish structural representation, divide to spread in back taper disc and dish 26 is provided with radial point spreads spoke 49, card is provided with material-dropping hole 50, its percent opening is about 20%, aperture is at 1-10mm, centre card is plane and is provided with construction bolt hole 51, its objective is and make most refractory material divide spread out by point spreading dish four state equably, remaining part is fallen by material-dropping hole 50, and bolt hole 51 back taper disc is divided to spread under dish 26 is arranged on main shaft by connecting bolt to save bottom 29.

Claims (5)

1. the vertical four axle continuous mixers of anti-oxidant coating automatic blending, it is characterized in that: as the motor of Power Drive Unit, cycloidal planetary gear speed reducer is arranged on the center of cover, cycloidal planetary gear speed reducer axle head is by shaft coupling connection main shaft saves, it is provided with driving wheel, bearing block is arranged on the top board of cylindrical shell by bolt, main shaft saves and saves by main shaft adpting flange under main shaft and be bolted together, main shaft is provided with the upper and lower stirrer paddle of main shaft, be connected with back taper disc bottom main shaft to divide and spread dish, the bosom position of cylindrical shell is provided with back taper deflection plate, the bottom of cylindrical shell is designed to inverted cone-shaped, bottom is provided with star discharge valve, discharging opening.
2. the vertical four axle continuous mixers of one according to claim 1 anti-oxidant coating automatic blending, it is characterized in that: be provided with in the center of cylindrical shell as power-actuated driving wheel, driven pulley B, driven pulley A, driven pulley C take body centre as round dot, trisection is distributed on cylindrical shell, driven pulley B, driven pulley A, driven pulley C and driving wheel are by spur gear engaged transmission, driving shaft is driven to rotate by cycloidal planetary gear speed reducer the outputting power of motor, and rotate drive driven pulley B by the driving wheel on driving shaft, driven pulley A, driven pulley C synchronized rotation in the other direction, drive asessory shaft B thus, asessory shaft A, asessory shaft C rotates the mix and blend carrying out anti-oxidant coating.
3. the vertical four axle continuous mixers of one according to claim 1 anti-oxidant coating automatic blending, it is characterized in that: on main shaft lower stirring paddle leaf and main shaft, stirrer paddle is arranged on main shaft in the same way, stirrer paddle B, stirrer paddle A, stirrer paddle A is installed on respective asessory shaft respectively, but stirrer paddle is oppositely installed on installation direction and main shaft lower stirring paddle leaf and main shaft, make the stirrer paddle B that asessory shaft is installed, stirrer paddle A, stirrer paddle C tiltedly goes up the tiltedly upper mix and blend of 45° angle degree, the tiltedly lower mix and blend of blade in oblique lower 45° angle degree mixed up and down by main shaft on main shaft.
4. the vertical four axle continuous mixers of one according to claim 1 anti-oxidant coating automatic blending, it is characterized in that: inner barrel middle part is provided with back taper deflection plate, anti-oxidant coating is made to wander the bottom of cylindrical shell fast by its baffling blending, through the aperture of back taper deflection plate, under main shaft, joint bottom is provided with back taper disc and divides and spread dish.
5. the vertical four axle continuous mixers of one according to claim 1 anti-oxidant coating automatic blending, it is characterized in that: divide to spread in back taper disc and dish is provided with radial point spreads spoke, card is provided with material-dropping hole, its percent opening is 20%, aperture is at 1-10mm, object makes most anti-oxidant coating divide spread out by point spreading dish surrounding equably, and remaining part is fallen by material-dropping hole.
CN201520497575.9U 2015-07-12 2015-07-12 Machine is mixed in succession to anti -oxidant vertical four -axis of skinning loam automatic blending of scribbling Active CN204952727U (en)

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Application Number Priority Date Filing Date Title
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107701230A (en) * 2017-10-18 2018-02-16 张培 A kind of automatically controlled automatic slag-discharging water draining device of gas drainage system of coal mine
CN112546988A (en) * 2019-09-26 2021-03-26 中昊晨光化工研究院有限公司 Reaction device for solid phase surface fluorination

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107701230A (en) * 2017-10-18 2018-02-16 张培 A kind of automatically controlled automatic slag-discharging water draining device of gas drainage system of coal mine
CN112546988A (en) * 2019-09-26 2021-03-26 中昊晨光化工研究院有限公司 Reaction device for solid phase surface fluorination

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