CN204874764U - Chlorine dioxide aqueous solution generation system - Google Patents
Chlorine dioxide aqueous solution generation system Download PDFInfo
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- CN204874764U CN204874764U CN201520606996.0U CN201520606996U CN204874764U CN 204874764 U CN204874764 U CN 204874764U CN 201520606996 U CN201520606996 U CN 201520606996U CN 204874764 U CN204874764 U CN 204874764U
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Abstract
The utility model provides a chlorine dioxide aqueous solution generation system, gives systematized the connection with water liquid storage device, electrolyte storage device, electrolytic device, reaction unit, storage device, cooling device with belt cleaning device. The utility model provides a but systematized and bulk production puts the generation system of the chlorine dioxide aqueous solution.
Description
Technical field
The utility model is that a kind of aqueous solution of chlorine dioxide produces system, refers to a kind of systematize especially and can produce the generation system of putting aqueous solution of chlorine dioxide in a large number.
Background technology
Due to dioxide peroxide (Chlorinedioxide, ClO2) gas itself has not paired free active electrons, dioxide peroxide is made to have potent oxidation capacity, can be used to oxidizing bacteria, virus, the protein of the pathogenic agent such as mould, victory peptide, DNA or RNA, to eliminate these pathogenic agent, and user can not be provided easy to use due to the dioxide peroxide of gaseous state, therefore current in health care, food-processing, environment protection, process water, in the industry such as livestock-raising and sewage disposal, they are many by formation aqueous solution of chlorine dioxide soluble in water for dioxide peroxide, user is made to be easy to use aqueous solution of chlorine dioxide to carry out disinfection, sterilization, deodorizing.
And the production method of aqueous solution of chlorine dioxide, mainly by chlorite and acids two kinds of reagent, before use, this two reagent mix is added in appropriate water, make chlorite and acids can produce reaction with the method obtaining ClO 2 solution, but because its complex operation is complicated and need prepare several reagent to be in harmonious proportion, and there is disappearance inconvenient to use; Therefore, utilize the method for electrolyzer electrolytic saltwater to generate chlorine dioxide at present more, then by the chlorine dioxide formation aqueous solution of chlorine dioxide that makes soluble in water after generation for use.
Though the generation method of above-mentioned aqueous solution of chlorine dioxide comparatively utilizes, the mode of chlorite and acids two reagent mix is more convenient, safety; But because this aqueous solution of chlorine dioxide is utilized by chlorine dioxide mechanical means to squeeze in water liquid, make to form aqueous solution of chlorine dioxide in the water-soluble liquid of chlorine dioxide, its production capacity is limited and there is no method systematize, cause dealer that several electrolyzer and mixing apparatus need be set, and improve the preparation cost of dioxide peroxide.
Utility model content
Technical problem underlying to be solved in the utility model is, overcomes the above-mentioned defect that prior art exists, and provides a kind of aqueous solution of chlorine dioxide to produce system, and it is systematize and can produces the generation system of putting aqueous solution of chlorine dioxide in a large number.
The utility model solves the technical scheme that its technical problem adopts:
A kind of aqueous solution of chlorine dioxide produces system, comprises a water liquid storing unit, electrolytic solution storing unit, electrolyzer, reaction unit, storing unit, refrigerating unit and washing unit; Wherein:
Water liquid storing unit, in order to store water liquid and to be connected with reaction unit, makes the water liquid stored by water liquid storing unit used in combination for reaction unit;
Electrolytic solution storing unit, in order to store electrolytic solution, this electrolytic solution storing unit is also connected with electrolyzer, makes the electrolytic solution stored by electrolytic solution storing unit can input electrolyzer and carries out electrolysis;
Electrolyzer, is connected with electrolytic solution storing unit and reaction unit, in order to electrolyte to generate chlorine dioxide, and this chlorine dioxide is delivered to reaction unit to be mixed to form aqueous solution of chlorine dioxide with water liquid;
Reaction unit, is connected with water liquid storage tanks and electrolyzer, to mix make formation aqueous solution of chlorine dioxide in order to the water liquid that inputted by water liquid storing unit with the chlorine dioxide that electrolyzer inputs;
Storing unit, is connected with reaction unit, in order to deposit the aqueous solution of chlorine dioxide finished product generated mixed by reaction unit;
Refrigerating unit, is connected with electrolyzer in order to do heat exchange to electrolyzer, to cool the high temperature that electrolyzer produces because of electrolytic reaction;
Washing unit, is connected with electrolyzer, in order to clean electrolyzer electrolytic reaction complete after the alkaline waste liquor that remains;
By said apparatus, a kind of systematize is provided and the generation system of putting aqueous solution of chlorine dioxide can be produced in a large number.
The beneficial effects of the utility model are, it is systematize and can produces the generation system of putting aqueous solution of chlorine dioxide in a large number.
Accompanying drawing explanation
Below in conjunction with drawings and Examples, the utility model is further illustrated.
Fig. 1 is system block diagrams of the present utility model.
Fig. 2 is system and device figure of the present utility model.
Fig. 3 is system and device figure of the present utility model, and the first embodiment action schematic diagram ().
Fig. 4 is system and device figure of the present utility model, and the first embodiment action schematic diagram (two).
Fig. 5 is system and device figure of the present utility model, and the action schematic diagram () of the second embodiment.
Fig. 6 is system and device figure of the present utility model, and the action schematic diagram (two) of the second embodiment.
Fig. 7 is system and device figure of the present utility model, and the action schematic diagram () of the 3rd embodiment.
Fig. 8 is system and device figure of the present utility model, and the action schematic diagram (two) of the 3rd embodiment.
Fig. 9 is system and device figure of the present utility model, and the action schematic diagram (three) of the 3rd embodiment.
Figure 10 is system and device figure of the present utility model, and refrigerating unit conveying water coolant liquid is to the schematic diagram of electrolyzer.
Figure 11 is system and device figure of the present utility model, and the action schematic diagram of washing unit conveying water liquid cleaning electrolyzer.
Number in the figure illustrates:
10 water liquid storing units
11 water liquid storage tankss
12 water liquid force (forcing) pumps
13 hydraulic pipes
14 low LSs
15 inhalent siphons
151 air pressure valves
20 electrolytic solution storing units
21 electrolytic solution storage tankss
22 electrolytic solution force (forcing) pumps
23 tubings
24 low LSs
30 electrolyzers
31 electrolyzers
32 pneumatic tubes
33 delivery pipes
331 acid and alkali-resistance air pressure valves
34 water coolers
35 vent pipes
36 return lines
37 temperature-sensitive stickers
40 reaction units
41 force (forcing) pumps
411 water inlet pipes
412 rising pipes
413 gas liquid mixer
42 reactive tanks
421 first inhalent siphons
422 second inhalent siphons
423 first rising pipes
424 second rising pipes
425 air pressure valves
426 acid and alkali-resistance air pressure valves
427 acid and alkali-resistance air pressure valves
428 acid and alkali-resistance air pressure valves
43 low LSs
44 high LSs
45 redox monitoring points
50 storing units
51 finished product force (forcing) pumps
52 finished product storage tankss
53 finished product water inlet pipes
54 finished product rising pipes
541 acid and alkali-resistance air pressure valves
55 low LSs
56 high LSs
60 refrigerating units
61 cooling troughes
62 force (forcing) pumps
63 hydraulic pipes
631 air pressure valves
64 temperature-sensitive stickers
70 washing units
71 Rinsing Areas
72 pressurized freshwater pumps
73 drinking-water pipes
73 hydraulic pipes
731 air pressure valves
74 low LSs
75 inhalent siphons
751 air pressure valves
Embodiment
System diagram as shown in Figure 1, aqueous solution of chlorine dioxide of the present utility model produces system, comprises a water liquid storing unit 10, electrolytic solution storing unit 20, electrolyzer 30, reaction unit 40, storing unit 50, refrigerating unit 60 and washing unit 70; Wherein:
Water liquid storing unit 10, in order to store water liquid and to be connected with reaction unit 30, makes the water liquid stored by water liquid storing unit 10 used in combination for reaction unit 30;
Electrolytic solution storing unit 20, in order to store electrolytic solution, this electrolytic solution storing unit 20 is also connected with electrolyzer 30, makes the electrolytic solution stored by electrolytic solution storing unit 20 can input electrolyzer 30 and carries out electrolysis.
Electrolyzer 30, is connected 40 with electrolytic solution storing unit 20 and reaction unit, in order to electrolyte to generate chlorine dioxide, and this chlorine dioxide is delivered to reaction unit 40 to be mixed to form aqueous solution of chlorine dioxide with water liquid.
Reaction unit 40, is connected with water liquid storing unit 10 and electrolyzer 30, and the chlorine dioxide that water liquid and electrolyzer 30 in order to be inputted by water liquid storing unit 10 input mixes makes formation aqueous solution of chlorine dioxide.
Storing unit 50, is connected with reaction unit 40, in order to deposit the mixed aqueous solution of chlorine dioxide finished product generated of reaction unit 40.
Refrigerating unit 60, is connected with electrolyzer 30 in order to do heat exchange to electrolyzer 30, to cool the high temperature that electrolyzer 30 produces because of electrolytic reaction.
Washing unit 70, is connected with electrolyzer 30, in order to clean electrolyzer 30 electrolytic reaction complete after the alkaline waste liquor that remains.
By said apparatus, water liquid is delivered to reaction unit 40 by water liquid storing unit 10, and electrolytic solution is delivered to electrolyzer 30 electrolysis by electrolytic solution storing unit 20 makes generation chlorine dioxide, and the chlorine dioxide of generation is delivered to reaction unit 40 and is mixed to form aqueous solution of chlorine dioxide with water liquid, then aqueous solution of chlorine dioxide is delivered to storing unit 50 and deposits; Electrolyzer 30 is cooled when this refrigerating unit 60 can produce high heat when electrolyzer 30 carries out electrolysis simultaneously; Then, after treating that aqueous solution of chlorine dioxide produces operation, this washing unit 70 can clean electrolyzer 30; Whereby; A kind of systematize is provided and the generation system of aqueous solution of chlorine dioxide can be produced in a large number.
As shown in Figures 2 to 11, the technique means that the generation system about a kind of aqueous solution of chlorine dioxide of the utility model is applied and constructing apparatus thereof, further describe as follows:
Water liquid storing unit 10 (referring to shown in Fig. 2), in order to store water liquid for used in combination, this water liquid with reverse osmosis water (RO water) for good; This water liquid storing unit 10 comprises a water liquid storage tanks 11, and water liquid storage tanks 11 is connected with a water liquid force (forcing) pump 12, and this water liquid force (forcing) pump 12 is also connected with hydraulic pipe 13, and this hydraulic pipe 13 is also connected with reaction unit 40; Separately, whether this water liquid storage tanks 11 is provided with a low LS 14, very few in order to the water liquid detected in water liquid storage tanks 11; This water liquid storage tanks 11 is also provided with an inhalent siphon 15, inhalent siphon 15 the other end is then connected with water source (not disclosing in figure), inhalent siphon 15 is then provided with an air pressure valve 151, make when the low LS 14 of water liquid storage tanks 11 senses that in it, water liquid is very few, then can control to start air pressure valve 151, make water liquid can supplement input water liquid storage tanks 11 by inhalent siphon 15.
Electrolytic solution storing unit 20, (referring to shown in Fig. 2), uses for electrolyzer 30 electrolysis in order to store electrolytic solution; Comprise an electrolytic solution storage tanks 21; Electrolytic solution storage tanks 21 is connected with an electrolytic solution force (forcing) pump 22, and this electrolytic solution force (forcing) pump 22 is also connected with tubing 23, and this tubing 23 is be connected with electrolyzer 30, and this tubing 23 is also provided with an air pressure valve 231; Separately, whether this electrolytic solution storage tanks 21 is provided with a low LS 24, very few in order to the electrolytic solution detected in electrolytic solution storage tanks 21.
Electrolyzer 30 (referring to shown in Fig. 2), in order to provide electrolytic reaction, the tubing 22 of this electrolyzer 30 and electrolytic solution storage tanks 21 be connected; This electrolyzer 30 comprises electrolyzer 31, electrolyzer 31 is connected with the tubing 23 of electrolytic solution storing unit 20, electrolyzer 31 is provided with pneumatic tube 32, this pneumatic tube 32 is in order to carry chlorine dioxide to reaction unit 40, and this electrolyzer 31 is provided with delivery pipe 33, delivery pipe 33 is provided with acid and alkali-resistance air pressure valve 331, and this delivery pipe 33 is in order to discharge salt solution or rinse water in electrolyzer 31; Again, this electrolyzer 30 is provided with water cooler 34, and this water cooler 34 is in order to the electrolyzer 31 that cools, and this water cooler 34 is connected with refrigerating unit 60, and this water cooler 34 is also provided with vent pipe 35, and this vent pipe 35 is also connected with delivery pipe 33; Again, this water cooler 34 is provided with return line 36 further, and this return line 36 is connected with refrigerating unit 60.
Reaction unit 40 (referring to shown in Fig. 2), comprise a force (forcing) pump 41 and several reactive tank 42, this force (forcing) pump 41 is provided with water inlet pipe 411 and rising pipe 412, the rising pipe 412 of this force (forcing) pump 41 is provided with a gas liquid mixer 413, and the inlet end of this gas liquid mixer 413 is connected with the pneumatic tube 34 of electrolyzer 30; This reactive tank 42 is respectively provided with the first inhalent siphon 421, second inhalent siphon 422, first rising pipe 423, second rising pipe 424, this first inhalent siphon 421 is connected with the hydraulic pipe 12 of water liquid storage tanks 11, second inhalent siphon 422 is connected with the rising pipe 412 of force (forcing) pump 41, and the first rising pipe 423 is connected with the inhalent siphon 411 of force (forcing) pump 41; Again, this first inhalent siphon 421 is provided with air pressure valve 425, and this second inhalent siphon 422, first rising pipe 423 and the second rising pipe 424 are respectively provided with acid and alkali-resistance air pressure valve 426,427,428; Separately, this reactive tank 42 is provided with a low LS 43 and high LS 44, in order to detect the capacity of the aqueous solution of chlorine dioxide in reactive tank 42.
Storing unit 50 (referring to shown in Fig. 2), comprise finished product force (forcing) pump 51 and a finished product storage tanks 52, finished product force (forcing) pump 51 is provided with finished product water inlet pipe 53, this finished product water inlet pipe 53 is connected with the second rising pipe 424 of reaction unit 40, this finished product force (forcing) pump 51 is also provided with finished product rising pipe 54, and this finished product rising pipe 54 is connected with finished product storage tanks 52; Again, this finished product rising pipe 54 be provided with acid and alkali-resistance air pressure valve 541; Separately, this finished product storage tanks 52 is provided with a low LS 55 and high LS 56, in order to detect the capacity of the aqueous solution of chlorine dioxide in finished product storage tanks 52.
Refrigerating unit 60 (referring to shown in Fig. 2), comprise a cooling trough 61, cooling trough 61 is in order to reduce water liquid temp, the water side of cooling trough 61 is provided with water coolant force (forcing) pump 62, the water side of water coolant force (forcing) pump 62 is then provided with hydraulic pipe 63, hydraulic pipe 63 the other end is then connected with the feed-water end of water cooler 33 set by electrolyzer 30, and this hydraulic pipe 63 be provided with an air pressure valve 631; This cooling trough 61 is also connected with the return line 36 of electrolyzer 30; Again, whether this cooling trough 61 is also provided with low LS 65, very few in order to the water liquid sensed in cooling trough 61.
Washing unit 70 (referring to shown in Fig. 2), comprise a Rinsing Area 71, hydrogen groove 71 is in order to store clear water, this Rinsing Area 71 is connected with a pressurized freshwater pump 72, the water side of this pressurized freshwater pump 72 is then provided with hydraulic pipe 73, this hydraulic pipe 73 the other end is then connected with the water intake end of electrolyzer 30, and hydraulic pipe 73 is provided with an air pressure valve 731; Separately, whether this Rinsing Area 71 is provided with a low LS 74, very few in order to the water liquid detected in Rinsing Area 70; Again, this Rinsing Area 71 is provided with an inhalent siphon 75, inhalent siphon 75 is provided with air pressure valve 751, this inhalent siphon 75 the other end is connected with clear water water source, when in Rinsing Area 71, water liquid is lower than low LS 74, namely open the air pressure valve 751 of inhalent siphon 75, the clear water at clear water water source is supplemented in input Rinsing Area 71.
As shown in Figure 3, it only utilizes a reactive tank 42 set in reaction unit 40 to produce aqueous solution of chlorine dioxide, by said apparatus, open air pressure valve 425 and second inhalent siphon 422 of the first inhalent siphon 421 set by reactive tank 42, the acid and alkali-resistance air pressure valve 426 of the first rising pipe 423, 427, the RO water liquid controlling to deposit in the water liquid storage tanks 11 of water liquid storing unit 10 is through water liquid force (forcing) pump 12, hydraulic pipe 13, first inhalent siphon 421 inputs in the reactive tank 42 of reaction unit 40, then the force (forcing) pump 41 set by reaction unit 40 is utilized to aspirate the water liquid deposited in reactive tank 42, make water liquid through the first rising pipe 423, water inlet pipe 411, force (forcing) pump 41, rising pipe 412, gas liquid mixer 413, second water inlet pipe 422 recirculation enters in reactive tank 42, make the liquid in reactive tank 42 can do circulation export, input, simultaneously, by electrolytic solution stored in electrolytic solution storage tanks 21 set by electrolytic solution storing unit 20 through electrolytic solution force (forcing) pump 22, tubing 23 inputs electrolysis in the electrolyzer 31 of electrolyzer 30 and makes generation chlorine dioxide and alkaline waste liquor, in the chlorine dioxide input pneumatic tube 32 making this reaction generate, now, because water liquid in reaction unit 40 is by producing suction force during gas liquid mixer 413, make the chlorine dioxide in pneumatic tube 32 must enter in gas liquid mixer 413 to mix with water liquid by this suction force and make formation aqueous solution of chlorine dioxide, make this aqueous solution of chlorine dioxide must input in reactive tank 42 by the second water inlet pipe 422, then according to the concentration of set aqueous solution of chlorine dioxide, whether input again in reactive tank 42 with the water liquid controlled in water liquid storage tanks 11, the force (forcing) pump 41 water liquid whether aspirated again in circulating reaction groove 42 simultaneously controlling reaction unit 40 flows through gas liquid mixer 413, makes with chlorine dioxide remix to improve or to reduce chlorine dioxide gas concentration.
Concentration in question response groove 42 needed for aqueous solution of chlorine dioxide arrival, and the high LS 44 of reactive tank 42 is when sensing that in reactive tank 42, aqueous solution of chlorine dioxide has reached high liquid level, the force (forcing) pump 41 of off-response device 40, air pressure valve 425 set on first inhalent siphon 421 and the second inhalent siphon 422, acid and alkali-resistance air pressure valve 426 set on first rising pipe 423, 427, the water liquid of water liquid storage tanks 11 is made no longer to input in reactive tank 42, and the aqueous solution of chlorine dioxide not recirculation of depositing in reactive tank 42 and chlorine dioxide, water liquid mixes, open the acid and alkali-resistance air pressure valve 428 of the second rising pipe 424 set by reactive tank 42, to make in reactive tank 42 aqueous solution of chlorine dioxide through finished product water inlet pipe 53, finished product force (forcing) pump 51 positive delivery, entered in finished product storage tanks 52 by finished product hydraulic pipe 54 again and deposit (as shown in Figure 4), aqueous solution of chlorine dioxide finished product.
As shown in Figure 5, it utilizes two reactive tank 42A, 42B to do reaction operation to produce aqueous solution of chlorine dioxide simultaneously, by said apparatus, open two reactive tank 42A, the air pressure valve 425 of upper set first inhalent siphon 421 of 42B and the second inhalent siphon 422, the acid and alkali-resistance air pressure valve 426 of the first rising pipe 423, 427, R0 water liquid in control water liquid storage tanks 11 is through water liquid force (forcing) pump 12, hydraulic pipe 13, first inhalent siphon 421 inputs two reactive tank 42A of reaction unit 40, in 42B, then the force (forcing) pump 41 set by reaction unit 40 is utilized to aspirate two reactive tank 42A, the water liquid deposited in 42B, make water liquid through the first rising pipe 423, water inlet pipe 411, force (forcing) pump 41, rising pipe 412, gas liquid mixer 413, second water inlet pipe 422 recirculation enters two reactive tank 42A, in 42B, meanwhile, by electrolytic solution stored in electrolytic solution storage tanks 21 through electrolytic solution force (forcing) pump 22, tubing 23 inputs electrolysis in electrolyzer 31 makes generation chlorine dioxide and alkaline waste liquor, the chlorine dioxide making this reaction generate inputs in pneumatic tube 32, now, because water liquid in reaction unit 40 is by producing suction force during gas liquid mixer 413, make the chlorine dioxide in pneumatic tube 32 must enter in gas liquid mixer 413 to mix with water liquid by this suction force and make formation aqueous solution of chlorine dioxide, make this aqueous solution of chlorine dioxide must input in two reactive tank 42A, 42B by the second water inlet pipe 422, then according to the concentration of set aqueous solution of chlorine dioxide, whether input in two reactive tank 42A, 42B again with the water liquid controlled in water liquid storage tanks 11, the force (forcing) pump 41 water liquid whether aspirated again in circulating reaction groove 42 simultaneously controlling reaction unit 40 flows through gas liquid mixer 413, makes with chlorine dioxide remix to improve concentration, treat two reactive tank 42A, in 42B the concentration of aqueous solution of chlorine dioxide arrive needed for concentration after and after aqueous solution of chlorine dioxide reached high liquid level, the force (forcing) pump 41 of off-response device 40, air pressure valve 425 set on first inhalent siphon 421 and the second inhalent siphon 422, acid and alkali-resistance air pressure valve 426 set on first rising pipe 423, 427, the water liquid of water liquid storage tanks 11 is made no longer to input in two reactive tanks 42, and the aqueous solution of chlorine dioxide not recirculation that reaction unit 40 is deposited mixes with chlorine dioxide, open the acid and alkali-resistance air pressure valve 428 of the second rising pipe 424 set by reactive tank 42, make two reactive tank 42A, in 42B, aqueous solution of chlorine dioxide is through finished product water inlet pipe 53, force (forcing) pump 51 positive delivery, entered in finished product storage tanks 52 by finished product hydraulic pipe 54 again and deposit (as shown in Figure 6), therefore the present embodiment really can utilize some reactive tanks 42 to produce aqueous solution of chlorine dioxide simultaneously, there is rapidity and the production efficiency of height in fact.
Again, another embodiment is, as shown in Figure 7, reaction unit 40 of the present utility model is provided with two reactive tank 42A, 42B, when for producing aqueous solution of chlorine dioxide, first can open air pressure valve 425 and second inhalent siphon 422 of first inhalent siphon 421 of first reactive tank 42A, the acid and alkali-resistance air pressure valve 426 of the first rising pipe 423, 427, RO water liquid in same control water liquid storage tanks 11 is through water liquid force (forcing) pump 12, hydraulic pipe 13, first inhalent siphon 421 inputs in first reactive tank 42A of reaction unit 40, then the force (forcing) pump 41 set by reaction unit 40 is utilized to aspirate the water liquid deposited in first reactive tank 42A, make water liquid through the first rising pipe 423, water inlet pipe 411, force (forcing) pump 41, rising pipe 412, gas liquid mixer 413, second water inlet pipe 422 recirculation enters in first reactive tank 42A, meanwhile, by electrolytic solution stored in electrolytic solution storage tanks 21 through electrolytic solution force (forcing) pump 22, tubing 23 inputs electrolysis in electrolyzer 31 makes generation chlorine dioxide and alkaline waste liquor, the chlorine dioxide making this reaction generate inputs in pneumatic tube 32, now, because water liquid in reaction unit 40 is by producing suction force during gas liquid mixer 413, make the chlorine dioxide in pneumatic tube 32 must enter in gas liquid mixer 413 to mix with water liquid by this suction force and make formation aqueous solution of chlorine dioxide, make this aqueous solution of chlorine dioxide must input in two reactive tanks 42 by the second water inlet pipe 422, then according to the concentration of set aqueous solution of chlorine dioxide, whether the water liquid controlled according to this in water liquid storage tanks 11 inputs in first reactive tank 42A again, the water the liquid whether force (forcing) pump 41 simultaneously controlling reaction unit 40 aspirates in circulation first reactive tank 42A again flows through gas liquid mixer 413, makes with chlorine dioxide remix to improve concentration, after in first reactive tank 42A, aqueous solution of chlorine dioxide reaches required concentration, control air pressure valve 425 and second inhalent siphon 422 of first inhalent siphon 421 of closedown first reactive tank 42A, the acid and alkali-resistance air pressure valve 426 of the first rising pipe 423, 427, make first reactive tank 42A no longer carry out the circulation of water liquid to mix with aqueous solution of chlorine dioxide and generate operation, then, as shown in Figure 8, open the acid and alkali-resistance air pressure valve 428 of the second rising pipe 424 set by first reactive tank 42A, make the aqueous solution of chlorine dioxide in first reactive tank 42A and input in the finished product storage tanks 52 of finished product storing unit 50, open air pressure valve 425 and second inhalent siphon 422 of first inhalent siphon 421 of second reactive tank 42B simultaneously, the acid and alkali-resistance air pressure valve 426 of the first rising pipe 423, 427, the water liquid of water liquid storage tanks 11 is made to input in second reactive tank 42B, the water liquid that force (forcing) pump 41 by reaction unit 40 aspirates in second reactive tank 42B circulates, and the chlorine dioxide generated with electrolyzer 30 mixes through gas liquid mixer 413 and makes formation aqueous solution of chlorine dioxide, this aqueous solution of chlorine dioxide is inputted second reactive tank 42B, when aqueous solution of chlorine dioxide in second reactive tank 42B reaches high liquid level, then close air pressure valve 425 and second inhalent siphon 422 of its first inhalent siphon 421, the acid and alkali-resistance air pressure valve 426 of the first rising pipe 423, 427, make second reactive tank 42B no longer carry out the circulation of water liquid to mix with aqueous solution of chlorine dioxide and generate operation, and then control unlatching first reactive tank 42A and restart operation, now, open the acid and alkali-resistance air pressure valve 428 of the second rising pipe 424 set by second reactive tank 42B, make the aqueous solution of chlorine dioxide in first reactive tank 42A and input (as shown in Figure 9) in the finished product storage tanks 52 of finished product storing unit 50, therefore, by arranging some reactive tanks 42, make each reactive tank 42 sequentially carry out production operation, make the water liquid storing unit 10 of native system, electrolyzer 30 and reaction unit 40 can produce aqueous solution of chlorine dioxide incessantly, really can improve the production efficiency of aqueous solution of chlorine dioxide.
Separately, as shown in Figure 10, because electrolyzer 30 can produce temperature because of energising when the electrolysis operation, the temperature of electrolyzer 30 is caused to raise and reduce electrolysis benefit, native system can control the air pressure valve 631 set by hydraulic pipe 63 of open cold radiator cooler 60, make force (forcing) pump 62 cold water in cooling trough 61 can be delivered in the water cooler 34 of electrolyzer 30 and do heat exchange operation, to reduce the temperature of electrolyzer 31, the water liquid that in the water cooler 34 of then this electrolyzer 30, temperature raises through heat exchange can be back to return line 36 and lower the temperature to be recycled to cooling trough 61, again to do heat exchange operation.
As shown in figure 11, after completing aqueous solution of chlorine dioxide generation operation, set air pressure valve 331 on the delivery pipe 33 of unlatching electrolyzer 30, the alkaline waste liquor that electrolyzer 30 generates after electrolysis is flowed out row from, then air pressure valve 731 set by the pressurized freshwater pump 72 of washing unit 70 and hydraulic pipe 73 is opened, make the water liquid in Rinsing Area 71 must by the suction of pressurized freshwater pump 72 through drinking-water pipe 73, pressurized freshwater pump 72, hydraulic pipe 73 inputs in electrolyzer 30, to clean the alkaline waste liquor residued in electrolyzer 30, then this alkaline waste liquor and rinse water can by delivery pipes 33, vent pipe 35 is discharged.
Hold above-mentioned, preferred embodiment is, the electrolyzer 31 of this electrolyzer 30 is provided with temperature-sensitive sticker 37, and this temperature-sensitive sticker 37 can detect the temperature of electrolyzer 31, does the keying of heat exchange operation with controlled cooling model device 60 pairs of electrolyzers 31.
Hold above-mentioned, preferred embodiment is, the reactive tank 42 of this reaction unit 40 is provided with redox potential (ORP) monitoring point 45, in order to monitor the characteristic of reactive tank 42 internal oxidition reduction.
Hold above-mentioned, preferred embodiment is, the cooling trough 61 of this refrigerating unit 60 is provided with temperature-sensitive sticker 64, and this temperature-sensitive sticker 64 can detect the temperature of cooling trough 61, with the cooling benefit of controlled cooling model device 60.
By being, from the above, the utility model has following advantage:
(1) because water liquid storing unit 10, electrolytic solution storing unit 20 electrolyzer 30, reaction unit 40, storing unit 50, refrigerating unit 60 and washing unit 70 are connected by the utility model, and Systematical control, and then be able to simple control, operation fast, and the production system of producing aqueous solution of chlorine dioxide can be prepared fast.
(2) because reaction unit 40 of the present utility model arranges array reactive tank 42, and utilize some piping systems to be connected, and generate chlorine dioxide by electrolyzer 30 continued electrolysis, the water liquid conveying of recycling gas liquid mixer 413 is to be mixed to form aqueous solution of chlorine dioxide, and it effectively can improve the production efficiency of aqueous solution of chlorine dioxide.
(3) again, because reaction unit 40 of the present utility model arranges array reactive tank 42, it just can carry out mixing again after need not waiting for and reactive tank 42 need being emptied eliminating aqueous solution of chlorine dioxide and generate operation, and can enhance productivity and storage volume.
(4) because electrolyzer 30 of the present utility model is connected with refrigerating unit 60 further, when producing high temperature because electrolytic reaction is done in energising, this refrigerating unit 60 can utilize cold water to carry out heat exchange to electrolyzer 30, to maintain the processing temperature of electrolyzer 30 and unlikely rising, and then electrolyzer 30 can be avoided overheated and affect electrolysis benefit.
(5) another, because the utility model is provided with washing unit 70 further, after this aqueous solution of chlorine dioxide production operation completes, its water liquid can input electrolyzer 30, with by electrolyzer 30 remain alkaline waste liquor cleaning get rid of, avoid the alkaline waste liquor remained to affect follow-up electrolysis operation.
(6) because reactive tank 42 of the present utility model is provided with low LS 43 and high LS 44, it can detect the capacity of aqueous solution of chlorine dioxide in reactive tank 42, to control the keying of the acid and alkali-resistance air pressure valve 428 of the second rising pipe 424 set by reactive tank 42, to make aqueous solution of chlorine dioxide in reactive tank 42 be inputted splendid attire for operation next time in the finished product storage tanks 52 of storing unit 50, and then the production efficiency of integral production operation can be improved.
The above; be only the possible embodiments of the utility model in order to illustrate; therefore protection domain of the present utility model can not be limited with it; such as have the knack of this those skilled in the art change according to the equalization that the utility model specification sheets and claim are done or modify, all still should belong to the protection domain that the utility model is contained.
The above, it is only preferred embodiment of the present utility model, not any pro forma restriction is done to the utility model, every above embodiment is done according to technical spirit of the present utility model any simple modification, equivalent variations and modification, all still belong in the scope of technical solutions of the utility model.
In sum, the utility model is in structure design, use practicality and cost benefit, meet completely needed for industry development, and the structure disclosed also is have unprecedented innovative structure, there is novelty, creativeness, practicality, meet the regulation about utility model patent important document, therefore mention application in accordance with the law.
Claims (5)
1. aqueous solution of chlorine dioxide produces a system, it is characterized in that, comprises a water liquid storing unit, electrolytic solution storing unit, electrolyzer, reaction unit, storing unit, refrigerating unit and washing unit; Wherein:
Water liquid storing unit, in order to store water liquid and to be connected with reaction unit, makes the water liquid stored by water liquid storing unit used in combination for reaction unit;
Electrolytic solution storing unit, in order to store electrolytic solution, this electrolytic solution storing unit is also connected with electrolyzer, makes the electrolytic solution stored by electrolytic solution storing unit can input electrolyzer and carries out electrolysis;
Electrolyzer, is connected with electrolytic solution storing unit and reaction unit, in order to electrolyte to generate chlorine dioxide, and this chlorine dioxide is delivered to reaction unit to be mixed to form aqueous solution of chlorine dioxide with water liquid;
Reaction unit, is connected with water liquid storing unit and electrolyzer, to mix make formation aqueous solution of chlorine dioxide in order to the water liquid that inputted by water liquid storing unit with the chlorine dioxide that electrolyzer inputs;
Storing unit, is connected with reaction unit, in order to deposit the aqueous solution of chlorine dioxide finished product generated mixed by reaction unit;
Refrigerating unit, is connected with electrolyzer in order to do heat exchange to electrolyzer, to cool the high temperature that electrolyzer produces because of electrolytic reaction;
Washing unit, is connected with electrolyzer, in order to clean electrolyzer electrolytic reaction complete after the alkaline waste liquor that remains.
2. aqueous solution of chlorine dioxide produces a system, it is characterized in that, comprises a water liquid storing unit, electrolytic solution storing unit, electrolyzer, reaction unit, storing unit, refrigerating unit and washing unit; Wherein:
Water liquid storing unit, in order to store water liquid for used in combination, comprise a water liquid storage tanks, water liquid storage tanks is connected with a water liquid force (forcing) pump, and this water liquid force (forcing) pump is also connected with hydraulic pipe, and this hydraulic pipe is also connected with reaction unit; Separately, this water liquid storage tanks is provided with a low LS; This water liquid storage tanks is also provided with an inhalent siphon, and the inhalent siphon the other end is then connected with water source, and inhalent siphon is then provided with an air pressure valve;
Electrolytic solution storing unit, comprise an electrolytic solution storage tanks in order to store electrolytic solution for electrolyzer electrolysis use, this electrolytic solution storage tanks is connected with an electrolytic solution force (forcing) pump, and this electrolytic solution force (forcing) pump is also connected with tubing, and this tubing is connected with electrolyzer; Separately, this electrolytic solution storage tanks is provided with a low LS;
Electrolyzer, in order to provide electrolytic reaction, this electrolyzer comprises an electrolyzer, the tubing of this electrolyzer and electrolytic solution storage tanks be connected; This electrolyzer is provided with pneumatic tube, and this pneumatic tube is in order to carry chlorine dioxide, and this electrolyzer be provided with delivery pipe, delivery pipe is provided with air pressure valve; Again, this electrolyzer is also provided with water cooler, and this water cooler is in order to cool to electrolyzer, and this water cooler is connected with refrigerating unit, and this water cooler is also provided with vent pipe, and this vent pipe is also connected with delivery pipe; This water cooler is provided with a return line, and this return line is connected with refrigerating unit;
Reaction unit, comprise a force (forcing) pump and some reactive tanks, this force (forcing) pump is provided with water inlet pipe and rising pipe, and the rising pipe of this force (forcing) pump is provided with a gas liquid mixer, and the inlet end of this gas liquid mixer is connected with the pneumatic tube of electrolyzer; This reactive tank is respectively provided with the first inhalent siphon, the second inhalent siphon, the first rising pipe, the second rising pipe, this first inhalent siphon is connected with the hydraulic pipe of water liquid storage tanks, second inhalent siphon is connected with the rising pipe of force (forcing) pump, and the first rising pipe is connected with the inhalent siphon of force (forcing) pump; Again, this first inhalent siphon is provided with air pressure valve, and this second inhalent siphon, the first rising pipe and the second rising pipe are respectively provided with the air pressure valve of acid and alkali-resistance; Separately, this reactive tank is provided with a low LS and high LS;
Storing unit, comprise a finished product force (forcing) pump and a finished product storage tanks, finished product force (forcing) pump is provided with finished product water inlet pipe, and this finished product water inlet pipe is connected with the second rising pipe of reaction unit, this finished product force (forcing) pump is also provided with finished product rising pipe, and this finished product rising pipe is connected with finished product storage tanks; Again, this finished product rising pipe be provided with acid and alkali-resistance air pressure valve; Separately, this finished product storage tanks is provided with a low LS and high LS;
Refrigerating unit, comprises a cooling trough, and cooling trough is in order to reduce water liquid temp, the water side of cooling trough is provided with force (forcing) pump, the water side of force (forcing) pump is then provided with hydraulic pipe, and the hydraulic pipe the other end is then connected with the feed-water end of water cooler in electrolyzer, and this hydraulic pipe be provided with an air pressure valve;
Washing unit, comprise a Rinsing Area and a pressurized freshwater pump, this Rinsing Area utilizes drinking-water pipe to be connected with pressurized freshwater pump, and the water side of this pressurized freshwater pump is then provided with hydraulic pipe, this hydraulic pipe the other end is then connected with the water intake end of electrolyzer, and hydraulic pipe is provided with an air pressure valve; Separately, this Rinsing Area is provided with a low LS; Again, this Rinsing Area is provided with an inhalent siphon, and inhalent siphon is provided with air pressure valve.
3. a kind of aqueous solution of chlorine dioxide according to claim 2 produces system, and it is characterized in that, the electrolyzer of described electrolyzer is provided with temperature-sensitive sticker.
4. a kind of aqueous solution of chlorine dioxide according to claim 2 produces system, and it is characterized in that, the reactive tank of described reaction unit is provided with redox potential (ORP) monitoring point.
5. a kind of aqueous solution of chlorine dioxide according to claim 2 produces system, it is characterized in that, the cooling trough of described refrigerating unit is provided with temperature-sensitive sticker.
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| CN201520606996.0U CN204874764U (en) | 2015-08-13 | 2015-08-13 | Chlorine dioxide aqueous solution generation system |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107313067A (en) * | 2016-04-27 | 2017-11-03 | 曾瑞波 | Auxiliary device and system for stably producing high-purity food-grade chlorine dioxide |
| CN108796546A (en) * | 2017-05-04 | 2018-11-13 | 优尼克生技股份有限公司 | Chlorine dioxide aqueous solution production facility |
| TWI647174B (en) * | 2017-12-22 | 2019-01-11 | 曾駿閎 | A system for producing chlorine dioxide solution |
| CN110004460A (en) * | 2018-01-05 | 2019-07-12 | 庄政霖 | Electrolysis unit |
| CN111422952A (en) * | 2019-01-09 | 2020-07-17 | 台湾可林生化科技有限公司 | Automatic change electrolytic device |
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2015
- 2015-08-13 CN CN201520606996.0U patent/CN204874764U/en active Active
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107313067A (en) * | 2016-04-27 | 2017-11-03 | 曾瑞波 | Auxiliary device and system for stably producing high-purity food-grade chlorine dioxide |
| CN107313067B (en) * | 2016-04-27 | 2019-06-07 | 曾瑞波 | Auxiliary device and system for stably producing high-purity food-grade chlorine dioxide |
| CN108796546A (en) * | 2017-05-04 | 2018-11-13 | 优尼克生技股份有限公司 | Chlorine dioxide aqueous solution production facility |
| CN108796546B (en) * | 2017-05-04 | 2021-05-18 | 优尼克生技股份有限公司 | Chlorine dioxide aqueous solution production facility |
| TWI647174B (en) * | 2017-12-22 | 2019-01-11 | 曾駿閎 | A system for producing chlorine dioxide solution |
| CN110004460A (en) * | 2018-01-05 | 2019-07-12 | 庄政霖 | Electrolysis unit |
| CN110004460B (en) * | 2018-01-05 | 2020-10-13 | 庄政霖 | Electrolysis device |
| CN111422952A (en) * | 2019-01-09 | 2020-07-17 | 台湾可林生化科技有限公司 | Automatic change electrolytic device |
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