CN204830989U - Anticorrosive scale control coating heat exchanger - Google Patents
Anticorrosive scale control coating heat exchanger Download PDFInfo
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- CN204830989U CN204830989U CN201520538863.4U CN201520538863U CN204830989U CN 204830989 U CN204830989 U CN 204830989U CN 201520538863 U CN201520538863 U CN 201520538863U CN 204830989 U CN204830989 U CN 204830989U
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
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Abstract
The utility model relates to an anticorrosive scale control coating heat exchanger relates to the coating heat exchanger in a chemical industry field, and this anticorrosive scale control coating includes inlayer articulamentum and outer titanium nanometer layer, adds the metallic element of anionic surface active agent and strong heat conductivity in the articulamentum, plays the effect of conducting heat and preventing that the skin from coming off, and titanium nanometer layer surface is smooth, is difficult for the incrustation scale and concentrates, has the function of anticorrosive scale control. This coating can coat at various heat exchanger heat transfer positions, can improve the phenomenon of the perishable easy scale deposit of heat exchange tube or heat transfer board to surface coating is difficult for droing, can improve heat exchange efficiency simultaneously, increases the life of heat exchanger.
Description
Technical field
The utility model relates to a kind of heat exchanger of chemical field, particularly a kind of heat exchanger of band coating, especially a kind of anti-corrosion anti-scale Coated Exchangers.
Background technology
Heat exchanger is widely used in the industrial process such as petrochemical industry, Coal Chemical Industry, aluminium oxide, power plant, clean energy resource utilization, and it is connected and composed jointly by heat exchanger tube or heat exchanger plates and housing.When for liquid working substance heat exchange, the material especially containing perishable easy fouling in liquid working substance, there will be fouling corrosion phenomenon in heat exchanger During Process of Long-term Operation, can produce bring huge loss to enterprise.
The liquid heat-exchanger of current industrial use adopts stainless steel material usually, although considerably increase material cost and manufacturing cost to be used for reducing corrosion, but still fundamentally can not solve Anticorrosion, if sulphion, chloride ion content are slightly high in liquid, still can cause Cavitations in its commissure, cause housing, heat exchanger tube or heat exchanger plates to lose efficacy.
Another hang-up that the heat exchanger of industrial use faces is internal incrustation problem.Have various salt in liquid, along with the rising of temperature, solubility reduces, can deposit in heat exchanger, accumulates over a long period to form one deck densification, hard incrustation scale at heat exchanger inner surface.Because the heat transfer coefficient of incrustation scale is extremely low, thus the thermal efficiency of heat exchanger constantly declines.In addition incrustation scale is for a long time in heat exchanger accumulated inside, also can block water inlet pipe and water outlet pipe, and cause water outlet freely maybe can not go out water problem, periodic cleaning makes enterprise's at substantial human and material resources.Therefore, the exploitation of anti-corrosion anti-scale heat exchanger is an important directions of heat exchanger development always.
Manufactory solved anticorrosion and scale problems in the past, and the normal method adopted has: (1) Ni-P coating film treatment, but pollutes the environment; (2) nitridation technique corrosion resistance is better, but the problem causing tubing fragility to become large after being difficult to solve fouling and high-temperature process; (3) introduction of foreign technology and coating, although effect is better, expensive, be also difficult to popularize; Also have some other method, but equal Shortcomings part.
Along with the development of nanometer technology and material technology, by the serial anti-corrosion anti-scale coating that nano material processing, synthesis are produced, there is the incomparable characteristics and advantages of conventional coating, be applied to industrial system also only to start soon, existing heat exchanger coating technology is not exclusively ripe, subject matter concentrates in surface treatment and manufacturing process, there will be coming off of coating in industry practical application, still can not meet the target of long-term operation.
Because the defect that above-mentioned existing heat exchanger exists, the utility model people is based on being engaged in the practical experience and professional knowledge that this type of product design manufacture enriches for many years, and coordinate the utilization of scientific principle, actively in addition research and innovation, to founding a kind of new anti-corrosion anti-scale Coated Exchangers, the problem of perishable easy fouling when existing heat exchanger uses can be improved, make it have more practicality.Through constantly research, design, and through repetition test and after improving, finally create the utility model had practical value.
Summary of the invention
The purpose of this utility model is, a kind of anti-corrosion anti-scale Coated Exchangers is provided, technical problem to be solved is the coating material that coating has anti-corrosion anti-scale function on heat exchanger inwall and heat exchanger tube or heat exchanger plates, improve the phenomenon of heat exchanger tube or the perishable easy fouling of heat exchanger plates, and face coat difficult drop-off, can heat exchange efficiency be improved simultaneously, increase the service life of heat exchanger.
The purpose of this utility model and solve its technical problem and realize by the following technical solutions.
According to a kind of anti-corrosion anti-scale Coated Exchangers that the utility model proposes, wherein, described anti-corrosion anti-scale coating comprises articulamentum and titanium nanometer layer; Wherein, articulamentum is internal layer, and thickness is 40-80nm, and titanium nanometer layer is outer, and thickness is 50-150nm; Anion surfactant and the stronger metallic element of thermal conductivity is added in articulamentum.
The purpose of this utility model and solve its technical problem and also can be applied to the following technical measures to achieve further.
Aforesaid a kind of anti-corrosion anti-scale Coated Exchangers, wherein, described metallic element is at least the one in Zn-ef ficiency, silver element, titanium elements.
Aforesaid a kind of anti-corrosion anti-scale Coated Exchangers, wherein, applies anti-corrosion anti-scale coating on the surface of heat exchanger inwall and heat exchanger tube or heat exchanger plates.
Aforesaid a kind of anti-corrosion anti-scale Coated Exchangers, wherein, described anti-corrosion anti-scale coating can be coated on various metal material and tubular heat exchanger tube or heat exchanger plates and form anti-corrosion anti-scale heat exchanger, as stainless steel bare tube, carbon steel light pipe, bronzing pipe, stainless steel twisted tube, carbon steel twisted tube etc.
Aforesaid a kind of anti-corrosion anti-scale Coated Exchangers, wherein, the painting method of described coating can be existing general method, as infusion process, spraying process, spread coating, magnetron sputtering method etc.
A kind of anti-corrosion anti-scale Coated Exchangers that the utility model proposes, its manufacture craft comprises the following steps:
(1) the polishing polishing that eliminates rust reaches 100nm;
(2) cleaning is under hyperacoustic effect, in 40-60 DEG C of liquid environment, by heat exchanger tube or the first alkali cleaning 10-15min of heat exchanger plates, then pickling 2-3min, then clean with distilled water flushing;
(3) clean heat exchanger tube or heat exchanger plates are placed in ultrasonic wave alcohol solution 5-10min, drying of drying fast by drying;
(4) spray articulamentum by step (3) process after heat exchanger tube or heat exchanger plates spray, after spraying, carry out the process that homogenizes, by rotation or dither realizes articulamentum and metallic matrix fully merges;
(5) baking-curing utilizes electric furnace to carry out heated baking to the product after the process of spraying homogeneous, and baking temperature, at 300-600 DEG C, is progressively warming up to baking temperature from room temperature, is more progressively cooled to room temperature;
(6) cleaning distilled water cleans, and now surface roughness is less than 50nm;
(7) spray titanium nanometer layer and ammonium titanium fluoride, boric acid are mixed with homogeneous solution respectively, filter and obtain settled solution, the heat exchanger tube after step (6) being processed or heat exchanger plates spray; After spraying, carry out the process that homogenizes, by rotate or dither realizes articulamentum and titanium nanometer layer fully merges;
(8) baking-curing utilizes electric furnace to carry out heated baking to the product after the process of spraying homogeneous, and baking temperature, at 300-600 DEG C, is progressively warming up to baking temperature from room temperature, is more progressively cooled to room temperature;
(9) cleaning distilled water cleans, and now coating surface distilled water contact angle is 89.2 degree, and surface energy is 30.5mJ/m
2.
The utility model compared with prior art has obvious advantage and beneficial effect.By technique scheme, a kind of anti-corrosion anti-scale of the utility model Coated Exchangers can reach suitable technological progress and practicality, and has the extensive value in industry, and it at least has following advantages:
(1) this coating adopts double-decker, adds transition articulamentum, and local coatings not easily occurs and comes off, reliability is high;
(2) be rich in metallic element, good heat conductivity in the articulamentum of this coating, the heat exchange efficiency of heat exchanger can be improved 10%-30%;
(3) this coating has fine and close molecular structure, and the performance of anticorrosive wear-resistant is strong, and coefficient of friction is little, and surface energy is low, thus effectively inhibits the surface scale of heat exchanger tube or heat exchanger plates, improves heat transfer efficiency, extends service life.
In sum, a kind of anti-corrosion anti-scale Coated Exchangers of the utility model has significant progress technically, and has obvious good effect, is really a new and innovative, progressive, practical new design.
Above-mentioned explanation is only the general introduction of technical solutions of the utility model, in order to technological means of the present utility model can be better understood, and can be implemented according to the content of description, and can become apparent to allow above and other object of the present utility model, feature and advantage, below especially exemplified by preferred embodiment, and coordinate accompanying drawing, be described in detail as follows.
Accompanying drawing explanation
Fig. 1 is the structure diagram of the utility model anti-corrosion anti-scale coating heat exchanger tube.
Fig. 2 is the structure diagram of the utility model anti-corrosion anti-scale coating heat exchanger plates.
[main element symbol description]
1: metal surface
2: articulamentum
3: titanium nanometer layer
Detailed description of the invention
For further setting forth the utility model for the technological means reaching predetermined goal of the invention and take and effect, below in conjunction with accompanying drawing and preferred embodiment, to a kind of anti-corrosion anti-scale Coated Exchangers that foundation the utility model proposes, its detailed description of the invention, structure, feature and effect thereof, be described in detail as follows.
A kind of anti-corrosion anti-scale Coated Exchangers of the utility model, the technical scheme adopted is: respectively apply the titanium sodium rice coating that one deck has anticorrosion, antiscale, heat-conducting effect on the surface of heat exchanger inwall and heat exchanger heat transfer position (heat exchanger tube or heat exchanger plates).Titanium nano coating has superior antiseptic property, and not only can efficient solution to determine the problem of stainless heat exchanger internal weld seams corrosion for heat exchanger inwall, also available other steel replacement stainless steel, greatly reduces costs, and can obtain better antiseptic effect.And titanium nano coating smooth surface, not easily incrustation scale is concentrated, make incrustation scale be shape in small, broken bits separate out and non-cohesive heat exchanger inside formed scale crust.
The utility model needs the position to adding coating to do special surface treatment before using, this is also a core technology of the present utility model, by special surface treatment, is conducive to the combination of coating and metal body, form firmly superficial layer, being not easily at high temperature heated comes off.
The technical scheme that special surface process adopts is: first add one deck articulamentum in the inside of titanium nanometer layer, this articulamentum is mainly used in the connection to processed heat exchanger tube or heat exchanger plates metal surface and titanium nanometer layer, form the effect of a transition, the fastness of strengthening titanium nano coating entirety.Add surfactant in articulamentum, to reduce the surface tension of coating, make coating easily in the coating of heat exchanger tube surface evenly, improve metal surface quality.In connection coating, add metallic element simultaneously, improve articulamentum thermal conductivity.Surfactant in articulamentum is anionic surfactant, such as alkylsulfonate or sulfuric acid etc.; The metallic element added in articulamentum is the metallic element that thermal conductivity is stronger, such as zinc, silver, titanium etc.
Anti-corrosion anti-scale heat conducting coating of the present utility model can be coated on various metal material and tubular heat exchanger tube or heat exchanger plates and form anti-corrosion anti-scale heat exchanger, as stainless steel bare tube, carbon steel light pipe, bronzing pipe, stainless steel twisted tube, carbon steel twisted tube etc.
To sum up, anti-corrosion anti-scale heat conducting coating described in the utility model comprises two-layer, and internal layer is articulamentum, and skin is titanium nanometer layer.Internal layer articulamentum adds anion surfactant and the stronger metallic element of thermal conductivity, and mainly the outer overall fastness of strengthening, prevents skin from coming off, and have thermal conductivity; Skin is titanium nanometer layer, mainly forms the quite smooth anti-corrosion anti-scale layer of one deck, metallic heat exchanging tube or heat exchanger plates and liquid working substance is isolated.
The painting method of coating described in the utility model can be existing general method, as infusion process, spraying process, spread coating, magnetron sputtering method etc.; The tubing of heat exchanger tube can be copper, steel etc., tubularly can be common light pipe or all kinds of special-shaped enhanced tube, and finned tube needs to do other specially treated and painting method.
Innovative point of the present utility model is: the technological process of prior art is mainly used for signal layer coating technology, and technological process of the present utility model is mainly used for two layers of coatings.Original coating technology the most important thing is prior surface process, needs to be polished to below surface roughness 50nm, could improve the reliability of coating, but from 100nm to 50nm, belong to essence throw, cost is higher, and labour intensity is high, cannot ensure the uniformity of all positions roughness simultaneously.And the utility model proposes two layers of coatings technology, increase articulamentum, articulamentum effects on surface roughness less demanding, 100nm, when not increasing heat transmission resistance, improves the reliability of coating, reduces labour intensity.
The manufacture craft of anti-corrosion anti-scale Coated Exchangers described in the utility model is:
(1) eliminate rust polishing
Mainly comprise exchange heat pipe, heat exchanger plates derusting by sandblasting, polishing reaches 100nm.
(2) clean
Under hyperacoustic effect, in 40-60 DEG C of liquid environment, first alkali cleaning 10-15min, then pickling 2-3min, fully can ensure that surperficial fine recesses inside also cleans up like this, clean groove is conducive to the fusion of articulamentum, then clean with distilled water flushing.
(3) dry
Clean heat exchanger tube or heat exchanger plates are placed in ultrasonic wave alcohol solution 5-10 minute, drying of drying fast.
(4) articulamentum is sprayed
The surfactant added in articulamentum is anionic surfactant, such as alkylsulfonate or sulfuric acid etc.; The metallic element that thermal conductivity is stronger is added, such as zinc, silver, titanium etc., preferred titanium in articulamentum.Spraying method selects Typical spray method as required.After spraying, carry out the process that homogenizes, by rotate or dither realizes articulamentum and metallic matrix fully merges.The coating layer thickness of articulamentum is 40-80nm.
(5) baking-curing
Utilize electric furnace to carry out heated baking to the product after the process of spraying homogeneous, baking temperature, at 300-600 DEG C, is progressively warming up to baking temperature from room temperature, is more progressively cooled to room temperature;
(6) clean
With distilled water cleaning, now surface roughness is less than 50nm.
(7) titanium nanometer layer is sprayed
Chemical pure ammonium titanium fluoride, analytically pure boric acid are mixed with homogeneous solution respectively, and impurity screening obtains settled solution, the concentration through mixing ammonium titanium fluoride, boric acid in obtained mixed liquor is respectively 0.5mol/L and 0.07mol/L.Spraying method selects Typical spray method as required.After spraying, carry out the process that homogenizes, by rotate or dither realizes articulamentum and titanium nanometer layer fully merges.Titanium nanometer layer thickness is 50-150nm.
(8) baking-curing
Utilize electric furnace to carry out heated baking to the product after the process of spraying homogeneous, baking temperature, at 300-600 DEG C, is progressively warming up to baking temperature from room temperature, is more progressively cooled to room temperature;
(9) clean
With distilled water cleaning, now coating surface distilled water contact angle is 89.2 degree, and surface energy is 30.5mJ/m
2.
The technological innovation of the above-mentioned a kind of anti-corrosion anti-scale Coated Exchangers of the utility model made as the method, all has many saving graces for technical staff of the same trade now, and the progressive that really possesses skills.
The above, it is only preferred embodiment of the present utility model, not any pro forma restriction is done to the utility model, although the utility model discloses as above with preferred embodiment, but and be not used to limit the utility model, any those skilled in the art, do not departing within the scope of technical solutions of the utility model, make a little change when the technology contents of above-mentioned announcement can be utilized or be modified to the Equivalent embodiments of equivalent variations, in every case be the content not departing from technical solutions of the utility model, according to any simple modification that technical spirit of the present utility model is done above embodiment, equivalent variations and modification, all still belong in the scope of technical solutions of the utility model.
Claims (3)
1. an anti-corrosion anti-scale Coated Exchangers, is characterized in that: described anti-corrosion anti-scale coating comprises articulamentum and titanium nanometer layer; Wherein, articulamentum is internal layer, and thickness is 40-80nm, and titanium nanometer layer is outer, and thickness is 50-150nm; Anion surfactant and metallic element is added in articulamentum.
2. a kind of anti-corrosion anti-scale Coated Exchangers according to claim 1, is characterized in that: described metallic element is at least the one in Zn-ef ficiency, silver element, titanium elements.
3. a kind of anti-corrosion anti-scale Coated Exchangers according to claim 1, is characterized in that: apply anti-corrosion anti-scale coating on the surface of heat exchanger inwall and heat exchanger tube or heat exchanger plates.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201520538863.4U CN204830989U (en) | 2015-07-23 | 2015-07-23 | Anticorrosive scale control coating heat exchanger |
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| CN201520538863.4U CN204830989U (en) | 2015-07-23 | 2015-07-23 | Anticorrosive scale control coating heat exchanger |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105115349A (en) * | 2015-07-23 | 2015-12-02 | 洛阳三信石化设备有限公司 | Heat exchanger with anticorrosion and scale-preventing coating and manufacturing process thereof |
| CN110579131A (en) * | 2019-09-20 | 2019-12-17 | 江阴市亚龙换热设备有限公司 | highly corrosion-resistant heat exchanger |
| CN111748269A (en) * | 2019-03-29 | 2020-10-09 | 青岛海尔智能技术研发有限公司 | Preservative for aluminum alloy micro-channel heat exchanger, protection method of preservative and heat exchanger |
-
2015
- 2015-07-23 CN CN201520538863.4U patent/CN204830989U/en active Active
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105115349A (en) * | 2015-07-23 | 2015-12-02 | 洛阳三信石化设备有限公司 | Heat exchanger with anticorrosion and scale-preventing coating and manufacturing process thereof |
| CN105115349B (en) * | 2015-07-23 | 2017-11-07 | 洛阳三信石化设备有限公司 | A kind of anti-corrosion anti-scale Coated Exchangers and its manufacture craft |
| CN111748269A (en) * | 2019-03-29 | 2020-10-09 | 青岛海尔智能技术研发有限公司 | Preservative for aluminum alloy micro-channel heat exchanger, protection method of preservative and heat exchanger |
| CN110579131A (en) * | 2019-09-20 | 2019-12-17 | 江阴市亚龙换热设备有限公司 | highly corrosion-resistant heat exchanger |
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