CN204803426U - Plating bath is kept apart with electroplating baffle - Google Patents

Plating bath is kept apart with electroplating baffle Download PDF

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Publication number
CN204803426U
CN204803426U CN201520367982.8U CN201520367982U CN204803426U CN 204803426 U CN204803426 U CN 204803426U CN 201520367982 U CN201520367982 U CN 201520367982U CN 204803426 U CN204803426 U CN 204803426U
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CN
China
Prior art keywords
plate body
electroplating
plating
plating tank
baffle plate
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Expired - Fee Related
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CN201520367982.8U
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Chinese (zh)
Inventor
徐永昌
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Without Sillim Letter Surface Treatment Co Ltd
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Without Sillim Letter Surface Treatment Co Ltd
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Abstract

The utility model discloses a plating bath is kept apart with electroplating baffle, which comprises a plate body, both ends are equipped with silicon fluorubber piece about the plate body, and the side all is equipped with polytetrafluoroethylene absorption sponge around the plate body, and the plate body lower surface is smooth, and the plate body upper end is equipped with hasp spare and handle, the one end that the plate body was kept away from to silicon fluorubber piece is equipped with nanometer impression structure, on the silicon fluorubber piece, be equipped with lock water layer with surface parallel's before the plate body side, one side that lock water layer kept away from silicon fluorubber piece is equipped with the pellicle, polytetrafluoroethylene absorption sponge is woven by fibrous porous polytetrafluoroethylene adsorption material and obtains. The utility model discloses the plating bath is kept apart with electroplating baffle who provides first is for electroplating a widget in the production, the accurate plating solution region of cutting apart accessible time, and real effective utilization of realizing the plating bath is satisfied different quantity products and is electroplated the requirement, can also guarantee same batch of product and electroplate the effect, simultaneously still there is throughput in advance to the organic matter, is applicable to the electroplating trade.

Description

A kind of plating tank isolation plating baffle plate
Technical field
The utility model relates to a kind of disrupter, is specifically related to a kind of plating tank isolation plating baffle plate, for the flexible partition in electroplate liquid region.
Background technology
In prior art, interconnection structure is to adopt alloy for main raw, specifically can adopt metal level or the film of following method deposit alloy: physical vapor deposition (PVD) method, chemical vapour deposition (CVD) method and electrochemical plating.Wherein, electrochemical plating can easily obtain highly purified metal level or film, and not only the formation speed of metal level or film is fast, but also can control the thickness of metal level or film with comparalive ease, and therefore electrochemical plating become main stream approach.Plating refers in the saline solution containing pre-metallizing, with plated matrix metal for negative electrode, by electrolytic action, the positively charged ion of pre-metallizing in plating solution is deposited in base metal surface, forms a kind of method of surface finish of coating.Coating performance is different from matrix metal, has new feature.Electroplate the difference according to plating, the electroplating technology groove arranged also is not quite similar, but before the electroplating process that general plated item completes an electroplating technology groove enters next electroplating technology groove, all to wash at washing bath, the effect of washing bath is the residual electroplate liquid wash clean above workpiece, do not affect lower one technique to carry out, do not pollute electroplate liquid in lower one plating tank, thus ensure the quality of plating.
Plating needs to carry out at a certain temperature.In general, improve temperature, the electroconductibility of plating solution can be increased, improve the current density that reaction allows, also can improve speed of response and coating uniformity.On the impact of additive also clearly, temperature raises temperature, and current density can raise, and this is favourable to the adsorption potential reaching optical brightener.At present, the type of heating of bath solution generally can divide two kinds: one is direct-fired mode, namely heat exchanger is directly inserted in electroplate liquid, direct heating; A mode for indirect heating, as water jacket method, adjustment channel process.The thermal source of bath solution heating generally comprises: calrod, steam, high-temperature-hot-water etc.
Galvanic anode baffle plate is added in the power line division board between workpiece to be plated (i.e. negative electrode) and plated source metal (i.e. anode) in plating tank.Its effect is that the size by arranging position of opening and hole controls power line homogeneity, guarantees that workpiece to be plated coating is even, under the condition ensureing thickness of coating quality, plated source metal consumption is controlled.Plating tank close to being the position that in electric field, the density of electric fluxline is maximum bottom liquid level position and plating tank, be high current density region, and the plating tank medium position position that to be the density of electric fluxline minimum, electric current is minimum, and current density is minimum, is low current density district.The plated film of the workpiece of high current density region is thicker, sometimes also there will be " burning " long burr phenomena because electric current is large, impact assembling and outward appearance, and the workpiece plated film in low current density district is thinner, impact assembling or product performance.
Plating tank is most basic supporting in electroplating device.There is the cell body of the various materials such as titanium plating tank, PP material, PVC material, PVDF material, glass fibre reinforced plastic groove material, stainless steel tank material, block grouan material, tetrafluoroethylene material.Plating tank is used for device solution, for zinc-plated, copper facing, nickel plating, gold-plated etc.Movable cathode plating tank serves as a contrast the cell body of soft polyvinyl chloride plastic, electric installation, steam heating tube and cathode moving device etc. by steel tank and forms.Cell body also can serve as a contrast Vybak manufacture with steelframe, and the factor such as character and temperature of bath solution is depended in the selection of trough body structure.It is made up of electric motor, speed reduction unit, eccentric disk, connecting rod and pole bar supporting rollern.
Plating tank is generally rectangle, and width is 600 ~ 1000mm, and the degree of depth is 800 ~ 1200mm.Plating tank in-site installation is inside plating shop, and generally different electroplate liquids is placed in different plating tanks, and a plating tank size is fixed, and capacity can not change.There is certain problem: a certain plating tank size is fixed, once plated item quantity changes, electroplate liquid region cannot the carrying out of science adjust, when plated item quantity reduces, the volume of electroplate liquid does not change, because no matter be a plated item, or some plated items, it requires that electroplate liquid can not have plated item, therefore in the nonadjustable situation in electroplate liquid region, the minimizing of plated item quantity can waste electroplate liquid and corresponding energy consumption, when plated item quantity increases suddenly, a plating tank cannot meet, a plating tank can not be increased again, only has batch treatment, bring efficiency slow like this, the consequence of streaking, in addition, different electroplate liquids is placed on different plating tanks, seems and is independent of each other, and can increase equipment cost, can increase operation especially in the process of plated item that moves around, and electroplate liquid also can be made disorderly to drip, contaminate environment.
In addition, in electroplate liquid, except the metal ion mainly existed, also there are some organism, these organism are unfavorable to plating, also can cause environmental pollution, general Electroplate Factory only can carry out wastewater treatment to particle, metal, much ignores or does not want to remove organism.
So effectively utilize to realize the real of plating tank, need to research and develop a kind of plating tank isolation plating baffle plate, it can be used in the flexible differentiation in electroplate liquid region; Also need there is pretreatment potentiality to organism simultaneously.
Summary of the invention
Goal of the invention of the present utility model is to provide a kind of plating tank isolation plating baffle plate, can effectively split electroplate liquid region, can also adsorb organic compound, has very strong stopping property and erosion resistance especially.
To achieve the above object of the invention, the technical solution adopted in the utility model is:
A kind of plating tank isolation plating baffle plate, comprise plate body, two ends, described plate body left and right are provided with fluosilicic sheet rubber, and before and after plate body, side is equipped with tetrafluoroethylene absorption sponge, and plate body lower surface is smooth, and plate body upper end is provided with fastener member and handle; Described fluosilicic sheet rubber is provided with nano impression structure away from one end of plate body; On described fluosilicic sheet rubber, the side parallel with plate body front surface is provided with lock water layer; Described lock water layer is provided with semi-permeable membranes away from the side of fluosilicic sheet rubber; Described tetrafluoroethylene absorption sponge is woven by fibrous porous tetrafluoroethylene sorbing material and obtains.
In the utility model, using electroplate baffle plate actual use time state limit as orientation, two surfaces of its contact electricity plating solution are front-back, and the face contacted with bottom plating tank is lower surface, and the face contacted with plating tank biside plate is face, left and right.Plate body lower surface is smooth, be conducive to baffle plate under self gravitation effect with the sealing of plating tank, in order to reach sealing effectiveness better, bottom fluosilicic sheet rubber, also shiny surface is set.
In the utility model, described semi-permeable membranes is the semi-permeable membranes made through special process with macromolecular material, its only allow water molecules through, and do not allow solute to pass through; Water molecules in electroplate liquid just can enter opposite side through semi-permeable membranes, thus is absorbed by lock water layer, and the inorganic salt of dissolving in electroplate liquid and non-dissolving, heavy metal ion, the materials such as organism cannot pass through semi-permeable membranes, can only stay respective plating tank region.
In technique scheme, lock water layer material is a kind of new functional macromolecule material, the macromole containing hydrophilic radical and crosslinking structure.It has the high absorbent function of the heavy hundreds of of specific absorption self to several thousand times of water, and water retention property is excellent, before water suction, macromolecular chain draws close tangle up mutually, be cross-linked to each other and reticulate structure, thus it is fastening to reach on the whole, when contacting with water, water molecules penetrates in resin by wicking action and diffusion, ionizing group on chain ionizes in water, macromolecular chain is made to stretch due to the electrostatic repulsion between homo-ion on chain swelling, due to electric neutrality requirement, gegenion can not move to resin outside, ionic concn difference between the solution of resin inside and outside forms reverse osmotic pressure, water enters further in resin under the effect of reverse osmotic pressure, formed swelling, simultaneously, the cross-linked structure of resin itself and hydrogen bond action, again limit the unlimited expansion of gel, can not produce interface layer effect and destroy.
In the utility model, water molecules in electroplate liquid can be transported to trifluoropropyl siloxane sheet one side by electroplate liquid one side by semi-permeable membranes, through lock water layer, lock water macromolecular material starts water suction, microcosmic expands, thus the gap filled up on microcosmic between trifluoropropyl siloxane sheet and electroplating cell body, both compensate for the gap of plating baffle plate and plating tank, effective sealing electroplate liquid region; And only have that water molecules can be limited through semi-permeable membranes, some metal ions worked in electroplate liquid are unaffected, ensure that electroplate liquid quality.
Fibrous polymer sorbing material of the present utility model has certain intensity, and have vesicular structure, effectively increase specific surface area, lipophilic group does not exist only in fiber surface, also exists in micropore in a large number, accelerates fibers adsorption speed and improves loading capacity further.
In the utility model, the density of tetrafluoroethylene absorption sponge is 600-650g/L; Thickness is 16-18mm; The thickness of spongy polymer adsorbing material and density very important to practical application.Too thin, sorbing material intensity difference, can not tolerate the impact of current when practical application, more cannot bear the mechanical force of relevant equipment, can not meet the requirement of dispose of wastewater; Sorbing material is too thick, then affect absorption property, can not realize quick adsorption and Large Copacity absorption, can not meet the requirement disposed fast equally; It is not good that thing protected by the too small sorbing material of density, and density is crossed conference and affected its rate of adsorption.In order to not affect the sealing of baffle plate and plating tank, tetrafluoroethylene adsorbs bottom sponge and plating tank and sidewall leaves gap.
In order to increase organic absorption further, tetrafluoroethylene absorption sponge is provided with globoidal structure, and further, the projection of globoidal structure is towards electroplate liquid region.
Adsorption technology is the object being reached process by the sorbing material trapping nuisance entered in environment, the destruction to environment can be avoided, its core is sorbing material, take gac as the defect that traditional sorbing material of representative and relevant adsorption technology exist in adsorption effect and technological operation, industrialized improvement requirement cannot be reached, especially when granular active carbon is used for the disposal of wastewater through organic matter pollution incident, the clearing and retrieving to floating on water toxic organic pollutant cannot be realized at all, the utility model utilizes polymer adsorption sponge first, effectively solve the organic pollutant in electroplating wastewater, turn avoid existing chemical treatment, the side effect that bioremediation is brought.
In the utility model, plate body is polyolefine plate body or toughened glass plate body; Described semi-permeable membranes thickness is 0.5mm; Described lock water layer thickness is 0.2mm.The swelling lock water layer of such water molecule energy, but it is stable to be unlikely to destroy contact surface.
In technique scheme, plate body upper end is provided with fastener member and handle, and handle, in order to moving stop, can adopt Mechanical Moving method, utilizes automatic shifting instrument, prevents artificial accidental injury, handle welding or one-body molded with on plate body.
Fastened structure can close, and the air squeezed out between fluosilicic sheet rubber and plating tank sidewall contact face makes it seal closely, prevents electroplate liquid from moving; Be provided with fastener member two portions by the base and plate body upper end that are positioned at plating tank sidewall to form; In order to increase tension effect further, preferred plate body left and right sides is all provided with fastener member.
In technique scheme, nano impression structure can be cylindricality or linear structure, and nano-micro structure contributes to the sealing of fluosilicic rubber plate and plating tank; Fluosilicic rubber plate side can be prepared in by nano impression mode; Fluosilicic rubber plate can be combined with plate body by hot pressing mode; The mode that tetrafluoroethylene absorption sponge can adopt screw to connect is connected with plate body.Better in order to electroplate guard seal, before and after baffle plate fluosilicic sheet rubber, semi-permeable membranes and lock water layer can be all set in side.
In the utility model, plating tank inside sidewalls is provided with groove, the fluosilicic sheet rubber of plating baffle plate and matching grooves, and can move from top to bottom along groove, nano impression structure, semi-permeable membranes and lock water layer can be good at sealing, and prevent electroplate liquid from oozing out; Fastener member is tensioned to base, with understructure fastening, further increases the sealing effectiveness of plating baffle plate; Last polymer adsorption sponge effectively removes the organism in electroplate liquid, protection of the environment.
Because technique scheme is used, the utility model compared with prior art has following advantages:
1. semi-permeable membranes is applied to plating tank isolation with lock water layer and electroplates baffle plate by the utility model first, in two-layer arrangement, water molecules in electroplate liquid is adsorbed, lock water layer is caused to expand, synergistic is formed with nano impression structure, effectively solve the sealing problem of plating baffle plate and plating tank, ensure that electroplate liquid is non-leakage.
2. nano impression structure is applied to plating tank isolation plating baffle plate by the utility model first, utilizes nanostructure micro-nano surface effect to play the interfacial effect in the face of being in contact with it efficiently, has stepped up the stopping property of electroplating baffle plate; Fastener member adopts and withholds mode simultaneously, ensure that electroplate liquid is not revealed.
3. spongy polymer adsorbing material is applied to plating tank isolation plating baffle plate by the utility model first, the object of process is reached by the sorbing material trapping nuisance entered in environment, the destruction to environment can be avoided, effectively solve the organic pollutant in electroplate liquid, turn avoid existing chemical treatment, side effect that bioremediation is brought.
4. the plating tank isolation plating baffle plate that the utility model provides first is a widget in Electroplating Production, can segmentation electroplate liquid region promptly and accurately, realize the real of plating tank effectively to utilize, meet different quantities product plating requirement, same batch products electroplating effect can also be ensured; Also there is pretreatment potentiality to organism simultaneously, be applicable to electroplating industry.
Accompanying drawing explanation
Fig. 1 is plating tank isolation plating baffle arrangement schematic diagram in embodiment;
Fig. 2 is that in embodiment, schematic diagram is looked on a plating tank isolation plating baffle plate left side;
Fig. 3 is fastener member structural representation on plating tank isolation plating baffle plate;
Fig. 4 is plating tank isolation plating baffle plate using state reference drawing;
Wherein, plate body 1, fluosilicic sheet rubber 2, tetrafluoroethylene absorption sponge 3, screw 31, fastener member 4, base 41, handle 5, nano impression structure 6, semi-permeable membranes 7, lock water layer 8, plating tank 9.
Embodiment
Below in conjunction with drawings and Examples, the utility model is further described:
Embodiment one:
See accompanying drawing 1-2, a kind of plating tank isolation plating baffle plate, comprise polypropylene sheet 1, two ends, described plate body left and right are provided with fluosilicic sheet rubber 2, and on described fluosilicic sheet rubber, the one end away from plate body is provided with cylindricality nano impression structure 6; Side is provided with the thick semi-permeable membranes of 0.5mm 7, the thick lock water layer 8 of 0.2mm; Described tetrafluoroethylene absorption sponge is woven by fibrous porous tetrafluoroethylene sorbing material and obtains, and density is 600g/L; Thickness is 18mm; Before and after plate body, side is equipped with the tetrafluoroethylene absorption sponge 3 connected by screw 31, and plate body lower surface is smooth, and plate body upper end is provided with fastener member 4 and handle 5.
See accompanying drawing 3, being fastener member structural representation, is optional another kind of structure, and it forms crimping device with the base 41 being arranged on plating tank outer side wall, is buckled on base, forms the tightening force to baffle plate by fastener member 4.
Embodiment two
A kind of plating tank isolation plating baffle plate, be similar to embodiment one main body, wherein plate body is toughened glass; Polymer adsorption sponge is woven by fibrous polymer sorbing material and obtains, and density is 650g/L; Thickness is 16mm; Tetrafluoroethylene absorption sponge is provided with the protruding globoidal structure towards electroplate liquid region.
Embodiment three
During actual use, catch handle, plating baffle plate is moved to desired location, desired location plating tank 9 inner side-wall has groove, and mate with the trifluoropropyl siloxane sheet on baffle plate 1, outer side wall is equipped with base 41, mates with the fastener member 4 on baffle plate.Along groove, lower plug-in plating baffle plate until with plating tank bottom fit, fastener member is buckled on base, forms the pulling force to baffle plate, ensure stopping property, as accompanying drawing 4; Put into electroplate liquid, along with water molecules enters lock water layer by semi-permeable membranes, lock water layer expands, and with nano impression structure synergistic, ensures that electroplate liquid is non-leakage; After plating for some time, absorption sponge 3 can active adsorption organism, existing plating tank, arranges the plating tank of the utility model baffle plate, after same electroplating processes, organic content in electroplating wastewater differs greatly, and drops to 26.1mg/L by existing 184.2mg/L.Can find out, while device of the present utility model effective sealed electrical plating solution region, electroplating wastewater organic content be reduced, meet the requirement of different size plated item batch processing.When electroplate liquid region is adjustable, plated item quantity reduces and suitably reduces electroplate liquid area, electroplate liquid and corresponding energy consumption can not be wasted, according to Theoretical Calculation, when electroplate liquid region area reduces 1/3rd, process, with the cost reduction about 15% of batch plated item, effectively increases profit margin; When plated item quantity increases suddenly, regulating fender expands electroplate liquid region, avoid existing only have batch treatment to bring efficiency is slow, the consequence of streaking, according to statistics, process same batch plated item, yield rate comparatively twice plating raising about 10% of one batch of plating; In addition, avoid increasing operation in the process of plated item that moves around, electroplate liquid is disorderly dripped, the problem of contaminate environment.

Claims (7)

1. a plating tank isolation plating baffle plate, it is characterized in that: described plating baffle plate comprises plate body, two ends, described plate body left and right are provided with fluosilicic sheet rubber, and before and after plate body, side is equipped with tetrafluoroethylene absorption sponge, plate body lower surface is smooth, and plate body upper end is provided with fastener member and handle; Described fluosilicic sheet rubber is provided with nano impression structure away from one end of plate body; On described fluosilicic sheet rubber, the side parallel with plate body front surface is provided with lock water layer; Described lock water layer is provided with semi-permeable membranes away from the side of fluosilicic sheet rubber; Described tetrafluoroethylene absorption sponge is woven by fibrous porous tetrafluoroethylene sorbing material and obtains.
2. plating tank isolation, with electroplating baffle plate, is characterized in that: described nano impression structure is cylindricality or linear structure according to claim 1.
3. plating tank isolation, with electroplating baffle plate, is characterized in that according to claim 1: the mode that described tetrafluoroethylene absorption sponge adopts screw to connect is connected with plate body.
4. plating tank isolation, with electroplating baffle plate, is characterized in that according to claim 1: described tetrafluoroethylene absorption sponge is provided with globoidal structure.
5. plating tank isolation, with electroplating baffle plate, is characterized in that according to claim 1: the density of described tetrafluoroethylene absorption sponge is 600-650g/L; Thickness is 16-18mm.
6. plating tank isolation, with electroplating baffle plate, is characterized in that: described plate body is polyolefine plate body or toughened glass plate body according to claim 1.
7. plating tank isolation, with electroplating baffle plate, is characterized in that: described semi-permeable membranes thickness is 0.5mm according to claim 1; Described lock water layer thickness is 0.2mm.
CN201520367982.8U 2015-05-29 2015-05-29 Plating bath is kept apart with electroplating baffle Expired - Fee Related CN204803426U (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI707990B (en) * 2019-10-14 2020-10-21 捷得寶科技股份有限公司 Method and equipment for horizontal and double-sided simultaneous electroplating of solar cells
CN112941604A (en) * 2021-01-25 2021-06-11 沛县卓凡科技服务中心 Electroplating method for precision instrument

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI707990B (en) * 2019-10-14 2020-10-21 捷得寶科技股份有限公司 Method and equipment for horizontal and double-sided simultaneous electroplating of solar cells
CN112941604A (en) * 2021-01-25 2021-06-11 沛县卓凡科技服务中心 Electroplating method for precision instrument

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CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20151125

Termination date: 20180529

CF01 Termination of patent right due to non-payment of annual fee