CN204753110U - Spray various some thick liquid of cation coating and dye equipment assembly - Google Patents
Spray various some thick liquid of cation coating and dye equipment assembly Download PDFInfo
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- CN204753110U CN204753110U CN201520067213.6U CN201520067213U CN204753110U CN 204753110 U CN204753110 U CN 204753110U CN 201520067213 U CN201520067213 U CN 201520067213U CN 204753110 U CN204753110 U CN 204753110U
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Abstract
The utility model discloses a spray various some thick liquid of cation coating and dye equipment assembly, including the permanent tension polycell that connects gradually receive and release a roll system, plasma processing system, spray cation pigment dyeing system, ultrasonic wave vibroseis, the preliminary treatment of infrared ray constant temperature, the wet short system of evaporating, intelligent fixation, drying system, sizing system, permanent tension store up through the system, divide hank system and rolling system. Through the plasma processing system, with the wax layer activation on yarn surface, make to combine more easily between cation coating and the warp, cation coating through on the ultrasonic wave vibroseis messenger warp further permeates and spreads the formation vestige, gives first place to with the coulomb force by relying on intermolecular force to become behind the graft modification to improve the dye -uptake and the fixation rate of dyestuff.
Description
Technical field
The utility model belongs to pulp technical field, is specifically related to a kind of cation paint coloured silk that sprays and puts pulp equipment assembly.
Background technology
It is more and more harsher that environmental protection and the ecological awareness allow the textiles of people to the title have human body Second Skin require; therefore; in the overall process of textile processing; people pursue environmental protection, ecology, technique simple, invest low, equipment is few, economize the energy, need not wash, require simultaneously without or few discharging of waste liquid with protection of the environment.
Coating dye printing technology, exactly can meet above-mentioned requirements substantially.Along with the developmental research of high-tech fast development and New-type adjuvant, oneself reaches higher level to make coating dye printing technology, substantially can meet changeable consumer market demand.
COAT PRINTING is with a long history, is a kind of not only ancient but also young textile processing method.Just there is application in the Western Han Dynastry before more than 2000 years period, and COAT PRINTING fabric fastness is at that time poor, and feel is not good, cannot be mentioned in the same breath with modern coatings PRINTED FABRIC.After the 1950's, more American-European companies are proposed new composite adhesives and emulsion thickening, and make COAT PRINTING technology obtain high speed development, Printing grows with each passing day.In the 70-80 age, along with the development of domestic petroleum chemical industry, the coating dye printing industry of ` China steps into Rapid development stage.So far, the proportion of COAT PRINTING textiles is own rises to about 50% from 25%.Not only for natural fabrics such as cottons, and become the main flow printing method of chemical fibre and BLENDED FABRIC thereof.
The market trend of whole world printing in textiles shows, COAT PRINTING occupies critical positions.Claim according to German De Sida company profile, coating accounts for that global printing textile share is 48%, activity accounts for 27%, reduction accounts for 5%, Naphthol accounts for 1%, acidity accounts for 3%, other account for 3%.Predict recently according to BASF AG, textile coating stamp, by from 11,000,000,000 m of 2002, is increased to 15,000,000,000 m in 2012.This illustrates that the development speed of coating dye printing industry is very surprising.
Pigment dyeing just has patent and research report to deliver as far back as the sixties in 20th century, but is far from being widely used as COAT PRINTING.Pigment dyeing experienced by the development in more than 40 years, existing own extend over the entire globe.The pigment dyeing of China is started late, and the middle and later periods eighties just starts test and application and dropped into production in enormous quantities.Since the nineties, pigment dyeing technique has had very fast development, has occurred the auxiliary agent of some function admirables, obviously can improve feel and the COLOR FASTNESS of fabric after shallow, middle look pigment dyeing.
Traditional pigment dyeing is carried out on padding mangles, and Pigment Padding is that continous mode is produced, and output is high, and aberration is easy to control, and be suitable for producing in enormous quantities, current technology is comparatively ripe.But also there are some problems in Pigment Padding product, as migration, feel, fastness, look change and quality stability etc.Further, because natural fabric dye-uptake in dye liquor is low, fixation rate variance, so the waste that can cause dye material, increases the discharge capacity of coloured sewage, has both added the cost of factory process and pollution plot, cause again serious problem of environmental pollution.
For above problem, lot of domestic and foreign dyer author has carried out large quantity research, proposes the modification of natural fabric cation graft, makes fiber surface with positive charge.Exhaust dyeing with pigment technology carries out preliminary treatment by cation modifier to fiber exactly, it is made to have affinity to the coating with negative electrical charge, thus significantly improve the dye-uptake of coating, reduce the residual volume of coating in dye bath, improve colour fixation, alleviate the burden of the blowdown after dyeing, reduce dyeing integrated cost, improve ecological environment simultaneously.In addition, exhaust dyeing with pigment adapts to small lot, the fast reaction of multi items is produced, and can meet the current changeable market demand.Exhaust dyeing with pigment technique can also produce the multi-effects such as granite-wash, mill white, green line, is also widely used in fields such as garment dyeing, yarn dyeing, dyeing knitted fabrics.Therefore, exhaust dyeing with pigment technique can make up the deficiency of knot dyeing technology to a certain extent, has broad application prospects, in recent years attention.
Compared with dyestuff, coating dye printing has that technique is simple, chromatogram is complete, bright in colour, fast light fastness to weathering is good, colorant match convenience, favorable reproducibility, pollution is little, cost is low and be suitable for the advantages such as various fabrics, is more and more subject to the welcome of textile industry.Along with the development of coating variety, gorgeous fluorescent paint, whitewash and other fastness of color and luster is superior, bright-colored, the coating that fastness to sublimation is good is come out one after another, and when some dyestuff current can not meet product quality requirement, pigment dyeing seems even more important.But current coating dye printing product still comes with some shortcomings part, and the feel being mainly manifested in fabric is more thick and stiff, colour brightness is lower, the aspects such as Dry Sack is not dark, crock fastness is poor, particularly particularly remarkable on dye deep-colour fabric, thus limit its scope of application.
Printing and dyeing circle is carrying out the research of the clearer production technology about yarn dyeing always, ites is desirable to realize the technological break-through in energy-saving and emission-reduction meaning.Patent: 200820302612.6,201010606689.4,201010606689.4,201010606690.7,201310515068.9 provide a kind of space dyeing device, solve the technical barrier of cheese space dye.Patent 201010580702.3, 201010580702.3, 201010580707.6, 201010580707.6, 201010580707.6, 201010580709.5, 201010606687.5 colouring methods containing cotton utilize bearing warp thread cation-modified containing cotton technology, wish the technical barrier solving continuous knot dyeing technology: the dyefastness of continuous knot dyeing technology, the problem of saturating core degree and dye level, can to save in theory before dyeing course or among kiering operation or there is the pretreatment procedure of kiering effect, eliminate kiering from source or there is the energy resource consumption in the pretreatment procedure of kiering effect, disposal of pollutants.But fixation problem is the current insurmountable problem of this technique class, occur in cation dyes, after particularly cation paint occurs, such technique seems complicated, does not have slashing technique simultaneously, fails the performance of complete release device and technology.
Patent of invention 200610085843.1,201010580702.3,201010580705.7,201010580707.6,201010580709.5,201320893047.6 proposes the technique of coating warp thread continuous dyeing, has significant progress in theory in energy-saving and emission-reduction.But in the application of this technology, coating can not effectively penetrate into yarn fibers inside, causes many serious technology and quality problems thus: one is that dyefastness is poor, and particularly crock fastness is poor, can only produce for the dyed yarn needed for ready-made clothes polishing, washing aspect; Two is that the saturating core degree of dyeing is poor, and yam surface catches color but inner whiting, and namely yarn twist in subsequent processes loosens exposes white point; Three is that dye-uptake is low, and when dye is dark, difficulty is high, quality is unstable, and it is serious that roller is stained with by adhesive.For these problems, adopt the yarn as described in utility model patent 200620075024.4 repeatedly to circulate circlewise the method for repeatedly padding, adopt the method increasing bleeding agent, adhesive, all cannot obtain obvious effect.The change of matter particularly cannot be obtained in COLOR FASTNESS.The example COLOR FASTNESS oneself provided as patent 201010580702.3 just can reach 2-3 level.
The device of patent 201010606687.5 section of giving dye, owing to not providing complete technological process, dyeing COLOR FASTNESS aspect has problems equally.Patent 201010606689.4 gives the device of kinckebocker yarn, and Fastness Problems reality annoyings industrial circle always.Patent 03215189.6 spraying decoration device for textile machinery, directly to spraying decoration on fabric, the technology that patent 200510034711.1 proposes is through actual verification, the problem that to occur that COLOR FASTNESS is low, dye level is shallow etc. serious, apply in light washed denim cloth and can also accept, other application of dress material aspects cannot meet the requirement in market.Owing to being that accessory form occurs, product stability is poor.The appearance being badly in need of modular system improves the performance of its device.Patent 201305755Y, 201125326Y just solve the automatic problem that yarn line segment catches look, and other fixation, sizing problem do not relate to, and also need a large amount of manpowers in actual applications, and automaticity is still very low.Through actual verification, the method that patent 201010580702.3 proposes finds that COLOR FASTNESS can not meet the demand in market, general COLOR FASTNESS is not higher than 3 grades.
Utility model content
For problems of the prior art, the utility model provides a kind of and sprays cation paint coloured silk point pulp equipment assembly.Add plasma apparatus on a production line, can directly promote dyefastness reach 4 grades and more than.Chromonema directly increases slashing technique simultaneously, save manpower, enhance productivity.
For solving the problem, the utility model by the following technical solutions:
A kind of spray cation paint coloured silk point pulp equipment assembly, comprise connect successively identical tension multiple-unit unwinding and rewinding system, plasma process system, injection cation paint coloring system, vibration of ultrasonic wave system, the preliminary treatment of infrared ray constant temperature, wet short steaming system, intelligent fixation, drying system, slashing system, identical tension storage is through system, leasing system and winding system.
Described identical tension multiple-unit unwinding and rewinding system comprises unreeling structure, rolling-up mechanism, and unwinding and rewinding mechanism controls tension variation and adjustment by following control system, runs according to the tension range of setting; Described control system comprises: Programmable Logic Controller, tension pick-up, pressure sensor, cylinder and proportioning valve, after tension pick-up obtains signal, contrast through Programmable Logic Controller, trigger cylinder and proportioning valve, pressure sensor obtains the motion of signal feedback controller adjusting cylinders and proportioning valve, keep unwinding and rewinding mechanism constant tension, tension adjustment also can control tension variation by the range set of servomotor moment of torsion.
Described plasma process system adopts the form of microwave plasma or radio frequency plasma or high-voltage glow-discharge Cement Composite Treated by Plasma.
Described injection cation paint coloring system adopts electrostatic spraying, hyperbar spray pattern that is jet, piezoelectricity air brushing carries out coating injection.
Described vibration of ultrasonic wave system connects the stainless steel bar that shakes by supersonic generator and forms.
Described intelligent fixation drying system comprises drying cylinder and dehumidification system.
Described slashing system comprises frame, stock tank and baking oven, is provided with stock tank, rear is provided with baking oven above described frame, is provided with pulp-inlet pipe, below is provided with discharge pipe above described stock tank, and described stock tank is tandem sizing box or single stock tank.
Described identical tension storage comprises storage through frame, tensile members and jacking system through system, described storage has fixed support and the lifting support system by Driven by Hydraulic Cylinder on frame, it is described when tensile members obtains the signal that tension variation differs greatly, hydraulic-driven lifting support system motion, tensile members is kept to obtain the constant signal of stable tension, by storage through the change of frame storage through amount, maintain the constant tension of warp.
Compared with prior art, the beneficial effects of the utility model are: 1. by plasma process system, activated by the wax layer of yam surface, make more easily to combine between cation paint and warp; 2. the cation paint on warp is made to permeate further and diffuse to form vestige by vibration of ultrasonic wave system, modified from relying on molecular separating force to become based on Coulomb force, thus improve dye-uptake and the degree of fixation of dyestuff; 3. injection cation paint coloring system is adopted to carry out cation paint injection to warp, replace contaminating operation, pollution-free, avoid and contaminate the residual of coating in bath, alleviate the burden of the blowdown after dyeing, reduce dyeing integrated cost, improve ecological environment simultaneously; 4. the utility model forms the coloured pattern of tool on warp, meets demand and client's change in taste in market, solves the technical problem that current dyeing market pattern changes all the time; 5. the utility model technique is simple, chromatogram is complete, bright in colour, colorant match convenient, efficient, low stain, extremely low sewage discharge, cost is low and be suitable for various through advantages such as wire fabrics, more and more be subject to the welcome of textile industry, the whole process of the utility model without the need to washing, no pollution discharge, Color is good; 6. from the saving angle of material, speed and the amount of cation paint coloring system are sprayed in adjustment, determine the coating consumption figure that final cation paint dyes, and under the prerequisite ensureing Color, reduce the consumption of dye material.7. this equipment can be directly used in processing and the dyeing and printing formation pattern of grey cloth.
The utility model starching part also can be waxed, and meets the demand of knitting yarn.
Accompanying drawing explanation
Fig. 1 is structural representation of the present utility model.
Detailed description of the invention
embodiment 1
As shown in Figure 1, the present embodiment sprays cation paint coloured silk point pulp equipment assembly, comprise connect successively identical tension multiple-unit unwinding and rewinding system 1, plasma process system 2, spray cation paint coloring system 3, vibration of ultrasonic wave system 4, the preliminary treatment of infrared ray constant temperature, wet short steaming system 5, intelligent fixation drying system 6, slashing system 7, identical tension storage through system 8, leasing system 9 and winding system 10.
The present embodiment identical tension multiple-unit unwinding and rewinding system comprises unreeling structure, rolling-up mechanism, and unwinding and rewinding mechanism controls tension variation and adjustment by following control system, runs according to the tension range of setting; Described control system comprises: Programmable Logic Controller, tension pick-up, pressure sensor, cylinder and proportioning valve, after tension pick-up obtains signal, contrast through Programmable Logic Controller, trigger cylinder and proportioning valve, pressure sensor obtains the motion of signal feedback controller adjusting cylinders and proportioning valve, keeps unwinding and rewinding mechanism constant tension.
The present embodiment plasma process system adopts the form of Microwave plasma treatment; Spraying cation paint coloring system adopts electrostatic spraying spray pattern to carry out coating injection.
The present embodiment vibration of ultrasonic wave system connects the stainless steel bar that shakes by supersonic generator and forms; Intelligence fixation drying system comprises drying cylinder and dehumidification system.
The present embodiment slashing system comprises frame, stock tank and baking oven, and described frame front end is provided with stock tank, rear is provided with baking oven, is provided with pulp-inlet pipe, below is provided with discharge pipe above described stock tank, and described stock tank is single stock tank.
The storage of the present embodiment identical tension comprises storage through frame, tensile members and jacking system through system, described storage has fixed support and the lifting support system by Driven by Hydraulic Cylinder on frame, it is described when tensile members obtains the signal that tension variation differs greatly, hydraulic-driven lifting support system motion, tensile members is kept to obtain the constant signal of stable tension, by storage through the change of frame storage through amount, maintain the constant tension of warp.
Utilize the present embodiment to spray cation paint coloured silk and put the method that pulp equipment assembly carries out pulp, comprise the following steps: warp is placed in identical tension multiple-unit unwinding and rewinding system by (1), warp, by plasma process system, makes the wax layer on warp surface activate; (2) warp after being activated by step (1) wax layer carries out injection cation paint, permeates on warp according to specific direction coating and diffuse to form vestige; (3) make warp permeates further and diffuses to form vestige by vibration of ultrasonic wave system, modified from relying on molecular separating force to become based on Coulomb force, thus improve dye-uptake and the degree of fixation of dyestuff; (4) the scarred warp of tool step (3) obtained through the preliminary treatment of infrared ray constant temperature, wet short steaming system and intelligent fixation, drying system, is dried and fixation the warp after dyeing successively; (5) step (4) described warp is placed in the stock tank filling slurries to soak into, drying system is dried the warp after hydrofuge and is stored on fixed support through the jacking system of Driven by Hydraulic Cylinder, then through leasing system and winding system by yarn rolling.
embodiment 2
As shown in Figure 1, the present embodiment sprays cation paint coloured silk point pulp equipment assembly, comprise connect successively identical tension multiple-unit unwinding and rewinding system 1, plasma process system 2, spray cation paint coloring system 3, vibration of ultrasonic wave system 4, the preliminary treatment of infrared ray constant temperature, wet short steaming system 5, intelligent fixation, drying system 6, slashing system 7, identical tension storage through system 8, leasing system 9 and winding system 10.
The present embodiment identical tension multiple-unit unwinding and rewinding system comprises unreeling structure, rolling-up mechanism, and unwinding and rewinding mechanism controls tension variation and adjustment by following control system, runs according to the tension range of setting; Described control system comprises: Programmable Logic Controller, tension pick-up, pressure sensor, cylinder and proportioning valve, after tension pick-up obtains signal, via controller contrasts, trigger cylinder and proportioning valve, pressure sensor obtains the motion of signal feedback controller adjusting cylinders and proportioning valve, keeps unwinding and rewinding mechanism constant tension.
The present embodiment plasma process system adopts the form of RF plasma processing; Spraying cation paint coloring system adopts the spray pattern of piezoelectricity air brushing to carry out coating injection.
The present embodiment vibration of ultrasonic wave system connects the stainless steel bar that shakes by supersonic generator and forms; Intelligence fixation drying system comprises drying cylinder and dehumidification system.
The present embodiment slashing system comprises frame, stock tank and baking oven, is provided with stock tank, rear is provided with baking oven above described frame, is provided with pulp-inlet pipe, below is provided with discharge pipe above described stock tank, and described stock tank is tandem sizing box.
The storage of the present embodiment identical tension comprises storage through frame, tensile members and jacking system through system, described storage has fixed support and the lifting support system by Driven by Hydraulic Cylinder on frame, it is described when tensile members obtains the signal that tension variation differs greatly, hydraulic-driven lifting support system motion, tensile members is kept to obtain the constant signal of stable tension, by storage through the change of frame storage through amount, maintain the constant tension of warp.
Utilize the present embodiment to spray cation paint coloured silk and put the method that pulp equipment assembly carries out pulp, comprise the following steps: warp is placed in identical tension multiple-unit unwinding and rewinding system by (1), warp, by plasma process system, makes the wax layer on warp surface activate; (2) warp after being activated by step (1) wax layer carries out injection cation paint, permeates on warp according to specific direction coating and diffuse to form vestige; (3) make warp permeates further and diffuses to form vestige by vibration of ultrasonic wave system, modified from relying on molecular separating force to become based on Coulomb force, thus improve dye-uptake and the degree of fixation of dyestuff; (4) the scarred warp of tool step (3) obtained through the preliminary treatment of infrared ray constant temperature, wet short steaming system and intelligent fixation, drying system, is dried and fixation the warp after dyeing successively; (5) step (4) described warp is placed in the stock tank filling slurries by step to soak into, drying system is dried the warp after hydrofuge and is stored on fixed support through the jacking system of Driven by Hydraulic Cylinder, then through leasing system and winding system by yarn rolling.
embodiment 3
As shown in Figure 1, the present embodiment sprays cation paint coloured silk point pulp equipment assembly, comprise connect successively identical tension multiple-unit unwinding and rewinding system 1, plasma process system 2, spray cation paint coloring system 3, vibration of ultrasonic wave system 4, the preliminary treatment of infrared ray constant temperature, wet short steaming system 5, intelligent fixation, drying system 6, slashing system 7, identical tension storage through system 8, leasing system 9 and winding system 10.
The present embodiment identical tension multiple-unit unwinding and rewinding system comprises unreeling structure, rolling-up mechanism, and unwinding and rewinding mechanism controls tension variation and adjustment by following control system, runs according to the tension range of setting; Described control system comprises: Programmable Logic Controller, tension pick-up, pressure sensor, cylinder and proportioning valve, after tension pick-up obtains signal, via controller contrasts, trigger cylinder and proportioning valve, pressure sensor obtains the motion of signal feedback controller adjusting cylinders and proportioning valve, keeps unwinding and rewinding mechanism constant tension.
The present embodiment plasma process system adopts the form of high-voltage glow-discharge Cement Composite Treated by Plasma; Spraying cation paint coloring system adopts the jet spray pattern of hyperbar to carry out coating injection.
The present embodiment vibration of ultrasonic wave system connects the stainless steel bar that shakes by supersonic generator and forms; Intelligence fixation drying system comprises drying cylinder and dehumidification system.
The present embodiment slashing system comprises frame, stock tank and baking oven, is provided with stock tank, rear is provided with baking oven above described frame, is provided with pulp-inlet pipe, below is provided with discharge pipe above described stock tank, and described stock tank is single stock tank.
The storage of the present embodiment identical tension comprises storage through frame, tensile members and jacking system through system, described storage has fixed support and the lifting support system by Driven by Hydraulic Cylinder on frame, it is described when tensile members obtains the signal that tension variation differs greatly, hydraulic-driven lifting support system motion, tensile members is kept to obtain the constant signal of stable tension, by storage through the change of frame storage through amount, maintain the constant tension of warp.
Utilize the present embodiment to spray cation paint coloured silk and put the method that pulp equipment assembly carries out pulp, comprise the following steps: warp is placed in identical tension multiple-unit unwinding and rewinding system by (1), warp, by plasma process system, makes the wax layer on warp surface activate; (2) warp after being activated by step (1) wax layer carries out injection cation paint, permeates on warp according to specific direction coating and diffuse to form vestige; (3) make warp permeates further and diffuses to form vestige by vibration of ultrasonic wave system, modified from relying on molecular separating force to become based on Coulomb force, thus improve dye-uptake and the degree of fixation of dyestuff; (4) the scarred warp of tool step (3) obtained through the preliminary treatment of infrared ray constant temperature, wet short steaming system and intelligent fixation, drying system, is dried and fixation the warp after dyeing successively; (5) step (4) described warp is placed in the stock tank filling slurries by step to soak into, drying system is dried the warp after hydrofuge and is stored on fixed support through the jacking system of Driven by Hydraulic Cylinder, then through leasing system and winding system by yarn rolling.
Claims (6)
1. spray a cation paint coloured silk point pulp equipment assembly, it is characterized in that: comprise connect successively identical tension multiple-unit unwinding and rewinding system (1), plasma process system (2), spray cation paint coloring system (3), vibration of ultrasonic wave system (4), the preliminary treatment of infrared ray constant temperature, wet short steaming system (5), intelligent fixation, drying system (6), slashing system (7), identical tension storage through system (8), leasing system (9) and winding system (10).
2. injection cation paint coloured silk point pulp equipment assembly according to claim 1, it is characterized in that: described identical tension multiple-unit unwinding and rewinding system comprises unreeling structure, rolling-up mechanism, described rolling-up mechanism, unreeling structure control tension variation and adjustment by following control system, run according to the tension range of setting; Described control system comprises: Programmable Logic Controller, tension pick-up, pressure sensor, cylinder and proportioning valve.
3. injection cation paint coloured silk point pulp equipment assembly according to claim 1, is characterized in that: described plasma process system adopts the form of microwave plasma or radio frequency plasma or high-voltage glow-discharge Cement Composite Treated by Plasma.
4. injection cation paint according to claim 1 coloured silk point pulp equipment assembly, is characterized in that: described vibration of ultrasonic wave system connects the stainless steel bar that shakes by supersonic generator and forms.
5. injection cation paint coloured silk point pulp equipment assembly according to claim 1, it is characterized in that: described slashing system comprises frame, stock tank and baking oven, be provided with stock tank above described frame, rear is provided with baking oven, above described stock tank, be provided with pulp-inlet pipe, below is provided with discharge pipe, described stock tank is tandem sizing box or single stock tank.
6. injection cation paint coloured silk point pulp equipment assembly according to claim 1, it is characterized in that: described identical tension storage comprises storage through frame, tensile members and jacking system through system, and described storage has fixed support and the lifting support system by Driven by Hydraulic Cylinder on frame.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201520067213.6U CN204753110U (en) | 2015-01-30 | 2015-01-30 | Spray various some thick liquid of cation coating and dye equipment assembly |
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| CN201520067213.6U CN204753110U (en) | 2015-01-30 | 2015-01-30 | Spray various some thick liquid of cation coating and dye equipment assembly |
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| CN204753110U true CN204753110U (en) | 2015-11-11 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105986387A (en) * | 2015-01-30 | 2016-10-05 | 中原工学院 | Spray cationic paint color-spot sizing-dyeing equipment assembly and sizing-dyeing method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105986387A (en) * | 2015-01-30 | 2016-10-05 | 中原工学院 | Spray cationic paint color-spot sizing-dyeing equipment assembly and sizing-dyeing method thereof |
| CN105986387B (en) * | 2015-01-30 | 2019-11-08 | 中原工学院 | A kind of injection cation paint color spot pulp equipment assembly and its pulp method |
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| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20151111 Termination date: 20220130 |