CN204749406U - Antibiotic radiation protection isolation cloth and isolation clothes of making by isolation cloth - Google Patents
Antibiotic radiation protection isolation cloth and isolation clothes of making by isolation cloth Download PDFInfo
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- CN204749406U CN204749406U CN201520400085.2U CN201520400085U CN204749406U CN 204749406 U CN204749406 U CN 204749406U CN 201520400085 U CN201520400085 U CN 201520400085U CN 204749406 U CN204749406 U CN 204749406U
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Abstract
The utility model provides a have the isolation cloth of excellent antibiotic radiation protection and obey by the isolation that isolation cloth made, belong to antibiotic radiation protection fabrics technical field. The utility model discloses an antibiotic radiation protection isolation cloth's structure is one deck basis cloth and two -layer metallic titanium and two -layer argent, and the isolation cloth of above -mentioned antibiotic radiation protection distinguishes anchoring one deck metallic titanium at the positive and negative of basic cloth, then at metallic titanium surface anchoring one deck argent again. The utility model discloses an isolation cloth is through tailorring and processing and prepare into isolation clothes, and the clothes is comfortable and easy to wear, does not have any injury to the health, and the effect of keeping apart the electric field simultaneously is obvious, the utility model discloses antibiotic radiation protection isolation cloth can avoid the health to receive injuries such as power frequency, radio frequency electric field well.
Description
Technical field
The isolation clothes that the utility model relates to a kind of antibiotic radiation proof isolation cloth and is made up of isolation cloth, it specifically belongs to the textile field of antibiotic radiation proof.
Background technology
Radiation refers to energy with ripple or the kenel transmission of subatomic particle movement.The energy of radiation is from radiation source outside all directions straight radial.Can be generally ionising radiation or Non-ionizing radiation according to the height of its energy and the Capability Categories of ionization material.Ionising radiation has enough energy can by atom or molecular ionization, and Non-ionizing radiation is then no.Radiation activated material refers to the material that can radiate ionising radiation.Ionising radiation mainly contains three kinds: α, β and γ radiation (or claiming ray).
Wherein ionising radiation refer to have enough high-octane radiation can atomic ionization.Because cell is made up of atom, ionization can cause cancer.A cell is approximately made up of a many trillion atom.Ionising radiation causes that the probability of cancer depends on radiation dose rate and accepts the irritability of irradiating biological.But the energy of Non-ionizing radiation is weak compared with ionising radiation.Non-ionizing radiation can not ionization material, and can change the rotation of molecule or atom, vibration or valence shell electron rail state.Different Non-ionizing radiations can produce the biological action of difference.
Also there is general electromagenetic wave radiation in daily life, mechanism mainly fuel factor, non-thermal effect and the build-up effect etc. of its radiation hazradial bundle human body.We live in a huge magnetic field environment, have the harm of human body: under the electromagnetic field of high frequency of some strength is irradiated, the harm that human body receives mainly central nervous system function imbalance, it is embodied in nerve and declines symptom, as dizzy, memory weakens, it is bad to sleep, headache, weak and some vegetative dystonias, as hidrosis, poor appetite, cardio palmus shape.In addition, high frequency irradiation can produce people's alopecia, stretch arm be point slightly tremble, the symptom such as dermatograph exception, hypopsia, male sexual hypofunction, female menstrual disorder.More obvious to the injury of health under the irradiation of hyperfrequency and superfrequency electromagnetic field: neurasthenia symptom increases the weight of, vegetative nerve numerous imbalances, as bradycardia or acceleration, blood pressure raises or there are constriction, pain of the heart area etc. in reduction, palpitaition, heart district.
For the harm of above-mentioned microwave, electromagnetic radiation, and then how research carries out electromagnetic shielding.So-called electromagnetic shielding is exactly utilize conduction or permeability magnetic material electromagnetic radiation to be limited in the spatial dimension of a certain regulation.Its objective is and adopt shield to surround electromagnetic interference source, suppress electromagnetic interference source to the interference of the receiver of surrounding space, or adopt shield to surround receiver, to avoid interference source, interference is caused to it.
Current early development and the antibacterial textile moldproof, anti-odour processing method always continued into the present adopt post-processing approach.This method can have selects organic antibacterial agent, easy to process easily, no matter is fabric or ready-made clothes, can obtains antibiotic effect by Final finishing mode.But the lasting effect of adopting the antibiotic property of the cloth obtained in this way is undesirable, and the weakness that existence one is fatal, namely to human body, be there is certain toxicity by the organic antibacterial agent selected.In addition, adopt physics or chemical method the antiseptic of bacteria growing inhibiting can introduce fiber surface and inside, by the diffusion of fibrous inside balance, keep the spin processes of lasting antibacterial deodourizing effect.This kind of antiseptic has broad-spectrum antimicrobial effect, harmless, Heat stability is good.But there is persistence difference, prompt effect difference and antimicrobial spectrum defect wide not in the antibacterial fabric of existing commercially co-blended spinning.Its main cause is that selected antiseptic is too single; Antiseptic and fiber in conjunction with defective tightness, experience use for a long time and wash easily and fiber depart from, and then lose antibacterial effect.
Utility model content
The utility model provides one to have the radiation-resistant isolation cloth of excellent antibacterial, and the cloth of isolation cloth of the present utility model is comfortable and easy to wear, to health without any injury, isolates the successful in magnetic field simultaneously.
The utility model provides a kind of antibiotic radiation proof isolation cloth, and it is by one deck basis cloth, and double layer of metal titanium and double layer of metal silver are formed.
Above-mentioned antibiotic radiation proof isolation cloth comprises one deck basis cloth, double layer of metal titanium and double layer of metal silver, respectively grappling upper strata Titanium and lower metal titanium in the both sides of described basic cloth, then grappling upper strata argent and lower metal silver again on the surface of Titanium.
It is inner and surperficial that the utility model adopts ultrahigh vacuum deep ion anchoring techniques titanium metal ions and silver metal ion to be embedded in firmly textile fiber (basic cloth).
Particularly, the fiber of above-mentioned basic cloth at least comprises the one in terylene, polypropylene fibre, acrylic fibers, polyamide fibre and aramid fiber.
Particularly, above-mentioned basic cloth positive and negative grappling upper strata Titanium and lower metal titanium, its thickness is 0.1 ~ 5 μm.
Particularly, above-mentioned metallic titanium surface grappling upper strata argent and lower metal silver, its thickness is 0.1 ~ 3 μm.
The utility model adopts ultravacuum deep ion anchoring techniques first to carry out pretreatment to basic cloth surface, in the container installing titanium target and silver-colored target, be filled with inert gas, utilizes vacuum equipment to make pressure drop in container to vacuum 10
-1~ 10
-5torr, pass into nitrogen, the pressure controlled in container is 2 ~ 10mtorr, temperature is 20 ~ 100 DEG C, direct current is passed into titanium target and silver-colored target with predetermined power, produce the electric discharge of electricity slurry, by basic cloth in the mode of retracting at the uniform velocity and pass into titanium target and silver-colored target successively, the tow sides making basic cloth are evenly and after the titanium of grappling layer of metal successively, then at metallic titanium surface grappling layer of metal silver.
Wherein, the maximum deposition rate of above-mentioned titanium target, silver-colored target is 50 ~ 800nm/min, cuts cloth, Che Bian, vacuum packaging, cloth is delivered to radiation irradiation center, again degerming and bacterium colony.
Above-mentioned cloth through vacuum ion anchoring technology is prepared in the method for antibiotic radiation proof isolation cloth, and the pressure controlled in container is 1 ~ 10mtorr, temperature is 15 ~ 150 DEG C, and wherein galvanic voltage is 200 ~ 500V, current density: 4 ~ 15mA/cm; Power density is: 2 ~ 20w/cm.
The antimicrobial spectrum of the various metals in antibiotic radiation proof isolation cloth of the present utility model covers the germ kind easily causing infection clinically, suppresses all kinds of harmful bacteria to be bred, can not destroy the microecological balance of skin surface microorganism, have security and durability.
A kind of antibiotic radiation proof isolation clothes of the present utility model are processed into through cutting by above-mentioned antibiotic radiation proof isolation cloth.
Advantage of the present utility model: the utility model antibiotic radiation proof isolation cloth solves effect instantaneity, the persistent problem that antibiotic radiation proof textile exists, avoid the various defects of traditional organic anti-bacterial product, nonhazardous, to have no side effect, effectively can prevent the cross-infection in hospital, effectively reduce the infection rate of patient and medical personnel, effectively reduce the infection rate of patient and medical personnel, when effective reduction wartime and disaster, the infection rate of rescue personnel and the wounded, fills up domestic blank.
Accompanying drawing explanation
The cross section of Fig. 1 the utility model antibiotic radiation proof isolation cloth
1 Titanium 22 lower metal titanium 31 upper strata, basic cloth 21 upper strata argent 32 lower metal silver.
detailed description of the invention:
Titanium dioxide antibiotic antiviral property TiO
2the destruction of the too little effects on surface antigen of concentration is little, and with the increase of concentration, destruction manifests gradually.When concentration reaches TiO
2time 1% (wt%), effect is obviously, and simultaneously along with time lengthening, surface antigen is destroyed gradually, at 12h, and 1% (wt%) TiO
2under concentration conditions, HbsAg transfers feminine gender to by the positive, and TiO is described
2good destruction is had to HbsAg.
The experimental result of titanium dioxide anti-hepatitis B virus
TiO
2be irradiated by light rear generation electronics (e-)-hole (h+) right, with OH-and O of adsorption
2activity hydroxy (OH), superoxide ion (O that effect generates
2-), hydroperoxyl (OOH) and hydrogen peroxide (H
2o
2), the oxidisability that tool is very strong, thus has effect of oxidation, killing microorganisms.TiO
2powder increases according to surface area, and its killing action also strengthens thereupon.We are when actual fabrication anti-bacteria and anti-virus isolation cloth, with reference to the Ministry of Public Health " disinfection technology standard ", devise and detect TiO
2metal material destroys the experimental arrangement of HBsAg effect in Different Light and different irradiation time.Consider TiO
2certain non-selective adsorption effect may be there is, thus when setting up control group, unless TiO to protein (HBsAg)
2contrast (Nc) under same light is shone outward, also set up metal material contrast (NO) of (shading) under non-illumination condition, and tire as radix to carry out the calculating of destructive rate using HBsAg in its eluent, to get rid of because the error of absorption generation is from result of the test, TiO
2metal material is at high Hg lamp irradiation (uitraviolet intensity 10 μ w/cm
2), non-direct sunlight (uitraviolet intensity 20 μ w/cm
2) and uviol lamp (uitraviolet intensity 430 μ w/cm
2) under irradiation, to HBsAg, there is good destruction, particularly under strong ultraviolet radiation, 2mins destructive rate reaches 99.90%, 5mins and reaches 99.97%, 10mins and almost reach 100%.But not TiO
2metal material destructive rate after the Ultraviolet radiation 10mins of same intensity only has 93.75%(mainly ultraviolet killing action).
The antivirus action of argent
Argent is a kind of typical metallized metal material, there is great specific area (being inversely proportional to particle diameter), particle size is less, percentage shared by its surface atom increases, surface atom number just increases, lack adjacent atom around, then there is many unsaturated bonds, show the unstable atom with high surface energy.This structure provides a lot of Contact-sorption sites and reagentia point to various reaction, and be easy to combine with foreign atom by chemical bond, the ability of their viral adsorptions improves greatly, and the chemical reaction ability mutually produced between virus also strengthens fast.
At present, the Antiviral Mechanism of argent primarily of following theory primarily of: 1, argent is to the mechanicalness absorption of virus and fixation, the polymer that metallic nanoparticles surface coverage one deck 5 ~ 10nm is thick, a large amount of protein and enzyme can be fixed, especially polysaccharide, many polysaccharose substances may stop the absorption of virus and host cell, thus show stronger antiviral activity; Simultaneously due to colloidal stability and the strong adsorptivity of metallic material particles, virus is made to lose life condition and dead.2, argent can stop cell entry host cell, suppresses virus to be combined with cell receptor, thus stops the infection of virus to host cell.Some metal Small molecular can suppress virus and acceptor interaction in conjunction with the conservative space structure of virus surface proteins, and metal material can stop viropexis, carries out direct deactivation to virus, likely similar with its kill bacteria.3, argent can be combined with viral nucleic acid, makes viral DNA or RNA structural change, affects copying of DNA or RNA, virus is lost activity.Argent resisting HIV (HIV) activity and security
Silver has very strong antibacterial characteristics, by blocking the respiratory enzyme system of bacterium, kill bacteria.But silver ion unstability in the solution.Argent is than silver ion stable chemical nature.Metallic silver particles is directly entered people's thalline and can be combined with the metabolic enzyme containing sulfydryl, causes bacterium and fungi death: argent also can be combined with the DNA of bacterium and fungi, causes its structural change, suppresses DNA replication dna, causes fungi to lose activity.Result of study shows, argent has very strong sterilizing ability, has good inhibitory action to various bacteria, saccharomycete, mould and virus, has broad-spectrum antiseptic characteristic.
The fabric of antibacterial anti-virus of the present utility model is mainly used in hospital: in hospital, various types for the treatment of produces power frequency radiation and radio-frequency radiation, electromagnetic pulse, the electromagnetic exposure etc. of high strength with diagnostic device section; And communication, electric power, broadcasting and TV, microwave (military and civilian microwave radar station), civil aviaton, railway, factory's (in factory, main equipment can produce the power frequency radiation of high strength).
Preferably, the ready-made clothes that the isolation cloth of the antibiotic radiation proof that the utility model provides is made, can be applicable to Hospital staff dress well, simultaneously isolation cloth with the antibacterial, antiviral of the ready-made clothes prepared and radiation-proof effect excellent.In addition the isolation cloth obtained according to this practicality technical scheme can be used for military active phase control array radar, and private information data storehouse shields, military boats and ships electromagnetic shielding, Aero-Space electromagnetic shielding.
Antibiotic radiation proof isolation cloth of the present utility model consist of basic cloth and double layer of metal titanium and double layer of metal silver, on the basis of basic cloth after grappling double layer of metal titanium and double layer of metal silver, isolation cloth fabric is still soft, experience still has good taking after repeatedly washing, ready-made clothes is washable, and the effect of the antibiotic radiation proof of isolation cloth does not subtract simultaneously.
Above-mentioned pretreatment uses electrophoresis removing cloth pollutant, the mixed liquor of organic solvent to be acetone and ethanol be by volume 1 ~ 3:4 ~ 7; Above-mentioned inert gas is nitrogen.Described container arranges the magnetic field being parallel to titanium target or silver-colored target surface, and the intensity in described magnetic field is about 100 ~ 250G.
A kind of antibiotic radiation proof isolation cloth of the present utility model adopts cloth through vacuum ion anchoring technology to manufacture isolation cloth.Above-mentioned concrete grammar comprises the following steps: 1), to design on fabric surface carry out pretreatment, is undertaken cleaning successively and drying under vacuum under Ultrasonic Conditions by organic solvent and deionized water; 2), titanium target and silver-colored target are installed, and Titanium and argent are anchored on successively equably the positive and negative of basic cloth.
Embodiment 1
1) pretreatment is carried out to the basic cloth surface (11) of terylene and polypropylene fibre blending, clean by organic solvent and deionized water successively under Ultrasonic Conditions, scavenging period is respectively 5 minutes, last under vacuum in 20 DEG C of dryings 0.5 hour, described organic solvent is the volume ratio of acetone and ethanol is 1 ︰ 1 mixed liquor; 2) argon gas is filled with, vacuum 10 in container in the container then installing titanium target and silver-colored target
-1torr, passes into nitrogen, and the pressure in container is 5mtorr, temperature 70 C, direct current is passed into titanium target and silver-colored target, produces the electric discharge of electricity slurry, wherein galvanic voltage: 300V, current density: 6mA/cm, power density: 5W/cm; 3) by cloth to furl mode at the uniform velocity and successively by titanium target and silver-colored target, make two metal ion species be anchored at fibrous inside and outer rim successively; The sedimentation rate of titanium target and silver-colored target is 50 ~ 80nm/min; 4) cloth is cut, Che Bian, vacuum packaging; 5) cloth is delivered to radiation irradiation center, again degerming and bacterium colony.The thickness that above-mentioned employing vacuum anchoring techniques obtains upper strata Titanium (21) and lower metal titanium (22) is 2 ~ 4 μm, and the thickness of upper strata argent (31) and lower metal silver (32) is 1 ~ 2 μm.Conductance 0.05 ~ 100 Ω/m of the isolation cloth of the antibiotic radiation proof having above-mentioned technique to obtain
2, have excellent antibiotic property, anti-electromagnetic-radiation, its shield effectiveness reaches 52 ~ 63dB, is 99.99999% to electromagnetic stop rate.
Embodiment 2
1) basic cloth (11) surface is obtained to acrylic fibers and aramid fiber blending and carry out pretreatment, clean by organic solvent and deionized water successively under Ultrasonic Conditions, scavenging period is respectively 7 minutes, last under vacuum in 30 DEG C of dryings 0.2 hour, described organic solvent is the volume ratio of acetone and ethanol is 1 ︰ 3 mixed liquor; 2) argon gas is filled with, vacuum 10 in container in the container then installing titanium target and silver-colored target
-1torr, passes into nitrogen, and the pressure controlled in container is 10mtorr, temperature is 50 DEG C, direct current is passed into titanium target and silver-colored target, produces the electric discharge of electricity slurry, wherein galvanic voltage: 250V, current density: 5mA/cm, power density: 6W/cm; 3) by cloth to furl mode at the uniform velocity and successively by titanium target and silver-colored target, make two metal ion species be anchored at fibrous inside and outer rim successively; The sedimentation rate of titanium target and silver-colored target is 50 ~ 80nm/min; 4) cloth is cut, Che Bian, vacuum packaging; 5) cloth is delivered to radiation irradiation center, again degerming and bacterium colony.The thickness that above-mentioned employing vacuum anchoring techniques obtains upper strata Titanium (21) and lower metal titanium (22) is 2 ~ 3 μm, and the thickness of upper strata argent (31), lower metal silver (32) is 0.5 ~ 2 μm.The conductance of the isolation cloth of the antibiotic radiation proof obtained by above-mentioned technique is antibacterial, anti-electromagnetic-radiation, and it is 99.999999% that shield effectiveness reaches 70dB-80dB. to electromagnetic stop rate.The fabric good hand touch of the ready-made clothes be made up of said method, comfortable and easy to wear while wash resistant.
Embodiment 3
1) basic cloth (11) surface is obtained to terylene and aramid fiber blending and carry out pretreatment, clean by organic solvent and deionized water successively under Ultrasonic Conditions, scavenging period is respectively 10 minutes, last under vacuum in 30 DEG C of dryings 0.5 hour, described organic solvent is the volume ratio of acetone and ethanol is 3 ︰ 5 mixed liquors; 2) argon gas is filled with, vacuum 10 in container in the container then installing titanium target and silver-colored target
-1torr, passes into nitrogen, and the pressure controlled in container is 10mtorr, temperature is 70 DEG C, direct current is passed into titanium target and silver-colored target, produces the electric discharge of electricity slurry, wherein galvanic voltage: 220V, current density: 6mA/cm, power density: 5W/cm; 3) by cloth to furl mode at the uniform velocity and successively by titanium target and silver-colored target, make two metal ion species be anchored at fibrous inside and outer rim successively; The sedimentation rate of titanium target and silver-colored target is 100 ~ 120nm/min; 4) cloth is cut, Che Bian, vacuum packaging; 5) cloth is delivered to radiation irradiation center, again degerming and bacterium colony.Above-mentioned employing vacuum anchoring techniques obtains upper strata Titanium (21), the thickness of lower metal titanium (22) is 1 ~ 3 μm, and the thickness of upper strata argent (31) and lower metal silver (32) is 1 ~ 2 μm.Obtaining ready-made clothes shield effectiveness by above-mentioned technique and reach 70dB-80dB, is 99.999999% to electromagnetic stop rate.The ready-made clothes fabric thickness of the isolation cloth obtained by above-mentioned technique is 0.08-0.095mm, conductance is 0.02-0.06 Ω/cm, is applicable to High voltage power frequence electric field and the high-power RF electromagnetic wave of Medical Devices.
Be only preferred embodiment of the present invention described in upper, not in order to limit the present invention, within the spirit and principles in the present invention all, any amendment done, equivalent replacement, improvement etc., all should be included within protection scope of the present invention.
Claims (4)
1. an antibiotic radiation proof isolation cloth, it is characterized in that: comprise one deck basis cloth (1), double layer of metal titanium and double layer of metal silver, at the both sides of described basic cloth (1) difference grappling one deck upper strata Titanium (21) and lower metal titanium (22), then silver-colored in the surface grappling layer of metal again of upper strata Titanium (21) and lower metal titanium (22).
2. a kind of antibiotic radiation proof isolation cloth according to claim 1, is characterized in that: the thickness of described basic cloth positive and negative grappling upper strata Titanium (21) and lower metal titanium (22) is 0.1 ~ 5 μm.
3. a kind of antibiotic radiation proof isolation cloth according to claim 1, is characterized in that: the thickness of described metallic titanium surface grappling upper strata argent (31) and lower metal silver (32) is 0.1 ~ 3 μm.
4. antibiotic radiation proof isolation clothes are made up of the antibiotic radiation proof isolation cloth described in any one of claim 1 ~ 3.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108421173A (en) * | 2017-02-13 | 2018-08-21 | 台北医学大学 | Accessory for breast cancer radiation treatment |
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2015
- 2015-06-11 CN CN201520400085.2U patent/CN204749406U/en active Active
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108421173A (en) * | 2017-02-13 | 2018-08-21 | 台北医学大学 | Accessory for breast cancer radiation treatment |
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