CN204731142U - A kind of gas cylinder volumetric expansion device for accurately measuring - Google Patents

A kind of gas cylinder volumetric expansion device for accurately measuring Download PDF

Info

Publication number
CN204731142U
CN204731142U CN201520513952.3U CN201520513952U CN204731142U CN 204731142 U CN204731142 U CN 204731142U CN 201520513952 U CN201520513952 U CN 201520513952U CN 204731142 U CN204731142 U CN 204731142U
Authority
CN
China
Prior art keywords
gas cylinder
sump
pipeline
gas
volumetric expansion
Prior art date
Application number
CN201520513952.3U
Other languages
Chinese (zh)
Inventor
王德发
赵玉祥
Original Assignee
中国计量科学研究院
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 中国计量科学研究院 filed Critical 中国计量科学研究院
Priority to CN201520513952.3U priority Critical patent/CN204731142U/en
Application granted granted Critical
Publication of CN204731142U publication Critical patent/CN204731142U/en

Links

Abstract

The utility model relates to a kind of gas cylinder volumetric expansion device for accurately measuring and comprises sump part, liquid level gauging part and ventilating control part, wherein, described sump part comprises sump upper cover, sump main body and sump base, and the inside of sump main body is also sealed with gas cylinder to be measured; Described liquid level gauging part comprises device for measuring volumetric flow of fluid with accurate scale and the second rubber plug; Described ventilating control part comprises bottled high-pressure air source, pipeline, stop valve, needle-valve and tensimeter composition.The utility model is by accurately measuring dissimilar gas cylinder, after being filled with the gas of different pressures, the increase situation of gas cylinder volume, set up the correlation curve of gaseous tension added value in such gas cylinder volume added value and gas cylinder, obtain the volume expansivity of such gas cylinder and then realize in different pressurising situation the accurate estimation of gas cylinder volumetric expansion, thus accurately can calculate the added value of gas cylinder aerostatic buoyancy after filling gas, accurate correction air buoyancy is on the impact of gas cylinder weighing result.

Description

A kind of gas cylinder volumetric expansion device for accurately measuring
Technical field
The utility model relates to a kind of measurement mechanism, particularly, relates to a kind of gas cylinder volumetric expansion device for accurately measuring.
Background technology
Gas composition analysis is extensively present in the fields such as industry and atmosphere environment supervision.For ensureing the reliability of measurement result, the indicating value of normal mixture body to analytical instrument usually needing concentration known is calibrated.The preparation of normal mixture body mainly contains two kinds, the dynamic genetic method that Zhou Zeyi, beam Jianping, Gai Liangjing etc. propose in " research of anemostat calibrating gas and dynamic air-distributing method thereof " and " ISO6142 gas analysis, the preparation of demarcation mixed gas, weight method " middle weighing method two kinds proposed.The common practices of weighing method preparation standard mixed gas will determine that different types of unstrpped gas of quality is filled in gas cylinder by an air distributing device, and different types of gas mixes in gas cylinder, obtains the normal mixture body of aimed concn.
The quality joining the unstripped gas in gas cylinder obtains by weighing inflation front and back the of poor quality of gas cylinder.After gas cylinder is filled with the gas of certain mass, the volume of gas cylinder can slightly expand, and the volume of this expansion can cause the aerial buoyancy of gas cylinder to increase.In order to realize accurate weighing, this buoyancy effect must be deducted, therefore needing accurate evaluation gas cylinder volume expansion status after inflation.The reference data provided in " ISO 6142 gas analysis, the preparation of demarcation mixed gas, weight method " is at present: for the gas cylinder of 5L, charge pressure is 20mL to gas cylinder volumetric expansion during 150MPa; And document " A.Alink and A.M.H.van der Veen.Uncertaintycalculations for the preparation of primary gas mixtures.Metrologia, 2000,37 (6): 641 ~ 650 " reference data provided is: for the aluminium alloy gas cylinder of 5L, and gas cylinder volumetric expansion when charge pressure reaches 12MPa is (12 ± 1) mL.Data in visible two documents have very large gap, and do not illustrate it is respectively with where method is measured.In addition, China's calibrating gas industry generally uses the aluminium alloy gas cylinder of 4L and 8L, and the data referential on foreign literature is not strong.
Further, fill with in preparation process at calibrating gas, often kind of unstripped gas is not be all filled with 12MPa or 15MPa.In fact in gas cylinder, the increase of gaseous tension and the quality of insufflation gas have relation closely.Such as, when room temperature about 25 DEG C, 4L aluminium alloy gas cylinder is used to prepare Co mixed gas in the nitrogen of 5% (mol/mol).First the quality being filled with unstripped gas carbon monoxide in gas cylinder is needed to be about 22.6g, and the added value of gaseous tension is about 0.5MPa in gas cylinder, and then the quality being filled with unstripped gas nitrogen in gas cylinder is about 429.4g, in gas cylinder, gaseous tension increases 9.5MPa more again on the basis of 0.5MPa, and last general pressure reaches 10MPa.Visible in this filling process, the added value that each unstripped gas fills gaseous tension in rear gas cylinder is significantly less than the reference value of document, so directly use reference data may cause the inaccurate of aerostatic buoyancy correction, and then cause the inaccurate of gas cylinder weighing result.
Want accurately to know that often kind of gas cylinder is after being filled with the gas of different pressures, how the volume of gas cylinder changes, and must measure accurately, but also do not report such device both at home and abroad at present to the volume of gas cylinder in different pressurising situation.
Utility model content
The utility model is intended to accurately measure dissimilar gas cylinder, after being filled with the gas of different pressures, the situation of change of gas cylinder volume, and then the correlation curve of gaseous tension added value in such gas cylinder volume added value and gas cylinder can be set up, realize in different pressurising situation, the accurate estimation of gas cylinder volumetric expansion, thus the added value that accurately can calculate gas cylinder aerostatic buoyancy after filling gas, accurate correction air buoyancy is on the impact of gas cylinder weighing result.
The technical scheme that the utility model solves the problems of the technologies described above is as follows:
A kind of gas cylinder volumetric expansion device for accurately measuring comprises sump part, liquid level gauging part and ventilating control part, wherein, described sump part comprises sump upper cover, sump main body and sump base, flange seal is accompanied between described sump upper cover and sump main body, the center of sump upper cover is provided with a circular open, the sidewall of sump main body is provided with the arm of L-type, and the inside of sump main body is also sealed with gas cylinder to be measured;
Described liquid level gauging part comprises device for measuring volumetric flow of fluid with accurate scale and the second rubber plug, described device for measuring volumetric flow of fluid is fixedly connected on the horizontal opening place of arm by the second rubber stopper seal, transfer pipet is utilized directly to measure gas cylinder volumetric expansion numerical value, because transfer pipet there is accurate scale, and scale does not exist the problems such as zero point drift, to make in structural design simpler, more convenient operation, measurement more accurate thus;
Described ventilating control part comprises bottled high-pressure air source, first pipeline, inlet stop valve, entrance needle-valve, tensimeter, vent needle valve, outlet shutoff valve, second pipeline and the 3rd pipeline composition, described bottled high-pressure air source is connected with criss-cross second pipeline by the first pipeline, the horizontal pipeline of the second pipeline is connected with inlet stop valve in turn, entrance needle-valve, vent needle valve and outlet shutoff valve, utilize the pressure that entrance needle-valve and vent needle valve can accurately control in the speed of insufflation gas in gas cylinder to be measured and gas cylinder, and inlet stop valve and outlet shutoff valve can be utilized, the gaseous tension in gas cylinder is made to stop at arbitrary spot pressure, thus the volumetric expansion situation of gas cylinder under different charge pressure can be measured easily, the vertical duct of described second pipeline is fixed on the opening part of sump upper cover through the first rubber stopper seal, one end of the vertical duct of described second pipeline is connected with tensimeter, and the other end is connected with gas cylinder to be measured by the 3rd pipeline.
Preferably, the height at the horizontal opening place of described arm is lower than the height of sump upper cover, so that after sump topped up with water, the water in arm can rise to liquid level gauging part.
Preferably, described flange seal is the flange seal that centre accompanies rubber ring, and what sump upper cover was connected with sump main body is tightr.
Preferably, described sump main body is a cylindrical water vat, and the shape of described sump upper cover is dome-type, can not leave a large amount of bubble during to ensure water filling in sump.
Preferably, the 50mL transfer pipet of described device for measuring volumetric flow of fluid to be minimum scale be 0.1mL.
Preferably, described first pipeline is 1/16 ' inch or 1/8 ' inch stainless steel pipeline, to reduce the impact of pipe stress on ventilating control part-structure stability; Described second pipeline is 1/4 ' inch stainless steel pipeline, and this part-structure is stablized; Described 3rd pipeline is 1/16 ' inch stainless steel pipeline, facilitates the movement of gas cylinder in sump main body.
Preferably, tap water or pure water is filled in described sump main body.
Preferably, the gases at high pressure in described bottled high-pressure air source are inert gas, can not have influence on the chemical property of gas cylinder inside surface.
In addition, the gaseous tension in bottled high-pressure air source will enough large (high pure nitrogen of such as 40L, internal pressure 15MPa), guarantee after inflating gas cylinder to be measured, in gas cylinder to be measured the maximum pressure of gas can reach 10MPa and more than.Manometric range is greater than or equals the maximum pressure of gas in bottled high-pressure air source, and precision is not less than 0.1MPa.
The beneficial effects of the utility model are: structure of the present utility model is safer, and reliably, measurement result is more precisely directly perceived, and can by accurately measuring dissimilar gas cylinder, after being filled with the gas of different pressures, the increase situation of gas cylinder volume, set up the correlation curve of gaseous tension added value in such gas cylinder volume added value and gas cylinder, obtain the volume expansivity of such gas cylinder, and under can be implemented in different pressurising situation according to this volume expansivity, the accurate estimation of gas cylinder volumetric expansion, thus accurately can calculate the added value of gas cylinder aerostatic buoyancy after filling gas, accurate correction air buoyancy is on the impact of gas cylinder weighing result, solve the problem that gas cylinder volumetric expansion cannot accurately be estimated in weighing method gas reference material development process.
Accompanying drawing explanation
Fig. 1 is the schematic diagram of gas cylinder volumetric expansion device for accurately measuring of the present utility model.
Embodiment
Be described principle of the present utility model and feature below in conjunction with accompanying drawing, example, only for explaining the utility model, is not intended to limit scope of the present utility model.
As shown in Figure 1, the utility model provides a kind of gas cylinder volumetric expansion device for accurately measuring and comprises sump part 100, liquid level gauging part 200 and ventilating control part 300, wherein, described sump part 100 comprises sump upper cover 10, sump main body 13 and sump base 15, flange seal 11 is folded with between described sump upper cover 10 and sump main body 13, the center of sump upper cover 10 is provided with an opening, the sidewall of sump main body 13 is provided with the arm 16 of L-type, and the inside of sump main body 13 is also sealed with gas cylinder 14 to be measured;
Described liquid level gauging part 200 comprises device for measuring volumetric flow of fluid 18 with accurate scale and the second rubber plug 17, described device for measuring volumetric flow of fluid 18 is sealedly and fixedly connected at the horizontal opening place of arm 16 by the second rubber plug 17, transfer pipet is utilized directly to measure gas cylinder volumetric expansion numerical value, because transfer pipet there is accurate scale, and scale does not exist the problems such as zero point drift, to make in structural design simpler, more convenient operation thus and measure more accurate;
Described ventilating control part 300 draws together bottled high-pressure air source 1, first pipeline 2, inlet stop valve 3, entrance needle-valve 4, tensimeter 5, vent needle valve 6, outlet shutoff valve 7, second pipeline 8, 3rd pipeline 12 and gas cylinder to be measured 14 form, described bottled high-pressure air source 1 is connected with criss-cross second pipeline 8 by the first pipeline 2, the horizontal pipeline of the second pipeline 8 is connected with inlet stop valve 3 in turn, entrance needle-valve 4, vent needle valve 6 and outlet shutoff valve 7, utilize the pressure that entrance needle-valve 4 and vent needle valve 6 can accurately control in the speed of insufflation gas in gas cylinder to be measured and gas cylinder, and inlet stop valve 3 and outlet shutoff valve 7 can be utilized, the gaseous tension in gas cylinder is made to stop at arbitrary spot pressure, thus the volumetric expansion situation of gas cylinder under different charge pressure can be measured easily, the vertical duct of described second pipeline 8 is fixed on the opening part of sump upper cover 10 through the first rubber plug 9 sealing, one end of the vertical duct of described second pipeline 8 is connected with tensimeter 5, and the other end is connected with gas cylinder 14 to be measured by the 3rd pipeline 12.
In addition, the height at the horizontal opening place of described arm 16 is lower than the height of sump upper cover 10, so that after sump topped up with water, water in arm can rise to liquid level gauging part, described flange seal 11 is the middle flange seal accompanying rubber ring, makes the better tightness between sump upper cover and sump main body; Described sump main body 13 is a cylindrical water vat, and the shape of described sump upper cover 10 is dome-type, can not leave a large amount of bubble during to ensure water filling in sump; The 50mL transfer pipet of described device for measuring volumetric flow of fluid 18 to be minimum scales be 0.1mL.
Further, described first pipeline 2 is 1/16 ' inch or 1/8 ' inch stainless steel pipeline, to reduce the impact of pipe stress on ventilating control part-structure stability; Described second pipeline 8 is 1/4 ' inch stainless steel pipeline, and this part-structure is stablized; Described 3rd pipeline 12 is 1/16 ' inch stainless steel pipeline, facilitates the movement of gas cylinder in sump main body 13; Tap water or pure water is filled in described sump main body 13; Gases at high pressure in described bottled high-pressure air source 1 are inert gas, can not have influence on the chemical property of gas cylinder inside surface.
In addition, the gaseous tension in bottled high-pressure air source will enough large (high pure nitrogen of such as 40L, internal pressure 15MPa), guarantee after inflating gas cylinder to be measured, in gas cylinder to be measured the maximum pressure of gas can reach 10MPa and more than.Manometric range is greater than or equals the maximum pressure of gas in bottled high-pressure air source, and precision is not less than 0.1MPa.
In actual mechanical process, be first that the gas cylinder to be measured 14 of normal pressure is connected with ventilating control part by the 3rd pipeline 12 by inside, and guarantee that junction impermeability is good, there will not be gas leak phenomenon.Then open the angle valve of gas cylinder 14 bottleneck to be measured, the gas cylinder to be measured 14 connected is put into empty sump main body 13, by flange 11 by sump upper cover 10 and sump main body 13 compact siro spinning technology, guarantee good seal, do not have water and spill.The outlet shutoff valve 7 of ventilating control part is closed, vent needle valve 6 is transferred to minimum; Entrance needle-valve is adjusted 4 to minimum, inlet stop valve 3 is closed; By 1/16 ' inch or 1/8 ' inch stainless steel pipeline, bottled high-pressure air source 1 is connected with ventilating control part, and guarantees that junction impermeability is good, there will not be gas leak phenomenon; By rubber plug 17, transfer pipet 18 is fixed to the L-type arm upper end of sump, and guarantee good seal, do not have water to expose from rubber plug 17, and suitably adjustment transfer pipet 18 gos deep into the degree of depth in the arm 16 of sump, ensured before insufflation gas in gas cylinder 14 to be measured after topped up with water in sump, liquid level in arm 16 can rise to more than the scale bottom of transfer pipet 18, ensure after being filled with the gas of top pressure in gas cylinder 14 to be measured, the liquid level in arm 16 rises to below the highest scale of transfer pipet 18 simultaneously.Open rubber plug 9, water filling in sump, until water overflows from the opening part of rubber plug 9, jam-pack rubber plug 9, guarantees good seal, and does not have water when inflating to gas cylinder 14 to be measured and overflow from here.Now in gas cylinder to be measured, the pressure of gas is 1 atmospheric pressure (about 0.1MPa), records the accurate calibration of liquid level in transfer pipet 18 and the accurate indicating value of tensimeter 5.Then the valve of bottled high-pressure air source 1 is opened, open outlet shutoff valve 7 and inlet stop valve 3, regulate vent needle valve 6 and entrance needle-valve 4, slow insufflation gas in gas cylinder 14 to be measured, when tensimeter 5 show pressure reach about 1MPa time, close outlet shutoff valve 7 and inlet stop valve 3, record the accurate calibration of liquid level in transfer pipet 18 and the accurate indicating value of tensimeter 5, now the indicating value of tensimeter 5 is the force value of gas in gas cylinder 14 to be measured, so far completes the record of one group of data.Again open outlet shutoff valve 7 and inlet stop valve 3, continue above-mentioned gas replenishment process, when pressure reaches about 2MPa, 3MPa respectively, until during 10MPa, close outlet shutoff valve 7 and inlet stop valve 3 respectively, record the accurate calibration of liquid level and the accurate indicating value of tensimeter 5 in corresponding transfer pipet 18.So just can do a fitting a straight line according to the accurate calibration value of liquid level in the accurate indicating value of many groups tensimeter 5 of record and transfer pipet 18, the slope of this straight line is the volume expansivity of this gas cylinder to be measured, the unit of described volume expansivity is mL/MPa, namely when in gas cylinder, gaseous tension often increases 1MPa, the expansion status of gas cylinder volume.
As can be seen here, the utility model solves in weighing method gas reference material development process, the accurate estimation problem of gas cylinder volumetric expansion.By accurately measuring dissimilar gas cylinder, after being filled with the gas of different pressures, the increase situation of gas cylinder volume, sets up the correlation curve of gaseous tension added value in such gas cylinder volume added value and gas cylinder, obtains the volume expansivity of such gas cylinder.Under can be implemented in different pressurising situation according to this volume expansivity, the accurate estimation of gas cylinder volumetric expansion, thus the added value that accurately can calculate gas cylinder aerostatic buoyancy after filling gas, accurate correction air buoyancy is on the impact of gas cylinder weighing result.
The foregoing is only preferred embodiment of the present utility model, not in order to limit the utility model, all within spirit of the present utility model and principle, any amendment done, equivalent replacement, improvement etc., all should be included within protection domain of the present utility model.

Claims (8)

1. a gas cylinder volumetric expansion device for accurately measuring, is characterized in that, comprises sump part (100), liquid level gauging part (200) and ventilating control part (300), wherein,
Described sump part (100) comprises sump upper cover (10), sump main body (13) and sump base (15), flange seal (11) is folded with between described sump upper cover (10) and sump main body (13), the center of sump upper cover (10) is provided with a circular open, the sidewall of sump main body (13) is provided with the arm (16) of L-type, and the inside of sump main body (13) is also sealed with gas cylinder to be measured (14);
Described liquid level gauging part (200) comprises device for measuring volumetric flow of fluid (18) with accurate scale and the second rubber plug (17), and described device for measuring volumetric flow of fluid (18) is sealedly and fixedly connected at the horizontal opening place of arm (16) by the second rubber plug (17);
Described ventilating control part (300) comprises bottled high-pressure air source (1), first pipeline (2), inlet stop valve (3), entrance needle-valve (4), tensimeter (5), vent needle valve (6), outlet shutoff valve (7), second pipeline (8), 3rd pipeline (12) and gas cylinder to be measured (14), described bottled high-pressure air source (1) is connected with criss-cross second pipeline (8) Single port by the first pipeline (2), the horizontal pipeline of the second pipeline (8) is connected with inlet stop valve (3) in turn, entrance needle-valve (4), vent needle valve (6) and outlet shutoff valve (7), the vertical duct of described second pipeline (8) is fixed on the circular open place of sump upper cover (10) through the first rubber plug (9) sealing, the upper end of the vertical duct of described second pipeline (8) is connected with tensimeter (5), the other end is connected with gas cylinder to be measured (14) by the 3rd pipeline (12), described gas cylinder to be measured (14) is sealed in the inside of sump main body (13).
2. gas cylinder volumetric expansion device for accurately measuring according to claim 1, is characterized in that, the height at the horizontal opening place of described arm (16) is lower than the height of sump upper cover (10).
3. gas cylinder volumetric expansion device for accurately measuring according to claim 1, is characterized in that, described flange seal (11) is the middle flange seal accompanying rubber ring.
4. gas cylinder volumetric expansion device for accurately measuring according to claim 1, is characterized in that, the shape of described sump upper cover (10) is dome-type, and described sump main body (13) is a cylindrical water vat.
5. gas cylinder volumetric expansion device for accurately measuring according to claim 1, is characterized in that, the 50mL transfer pipet of described device for measuring volumetric flow of fluid (18) to be minimum scale be 0.1mL.
6. gas cylinder volumetric expansion device for accurately measuring according to claim 1, is characterized in that, described first pipeline (2) is 1/16 ' inch or 1/8 ' inch stainless steel pipeline; Described second pipeline (8) is 1/4 ' inch stainless steel pipeline; Described 3rd pipeline (12) is 1/16 ' inch stainless steel pipeline.
7. gas cylinder volumetric expansion device for accurately measuring according to claim 1, is characterized in that, fills tap water or pure water in described sump main body (13).
8. gas cylinder volumetric expansion device for accurately measuring according to claim 1, is characterized in that, the gases at high pressure in described bottled high-pressure air source (1) are inert gas.
CN201520513952.3U 2015-07-15 2015-07-15 A kind of gas cylinder volumetric expansion device for accurately measuring CN204731142U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201520513952.3U CN204731142U (en) 2015-07-15 2015-07-15 A kind of gas cylinder volumetric expansion device for accurately measuring

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201520513952.3U CN204731142U (en) 2015-07-15 2015-07-15 A kind of gas cylinder volumetric expansion device for accurately measuring

Publications (1)

Publication Number Publication Date
CN204731142U true CN204731142U (en) 2015-10-28

Family

ID=54389481

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201520513952.3U CN204731142U (en) 2015-07-15 2015-07-15 A kind of gas cylinder volumetric expansion device for accurately measuring

Country Status (1)

Country Link
CN (1) CN204731142U (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105004663A (en) * 2015-07-15 2015-10-28 中国计量科学研究院 Gas cylinder volume expansion accurate measurement device

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105004663A (en) * 2015-07-15 2015-10-28 中国计量科学研究院 Gas cylinder volume expansion accurate measurement device
CN105004663B (en) * 2015-07-15 2019-03-12 中国计量科学研究院 A kind of gas cylinder volume expansion device for accurately measuring

Similar Documents

Publication Publication Date Title
CN205138940U (en) Test coal body gas adsorbs desorption heat effect experimental system
CN101470016B (en) Apparatus for measuring volume by built-in method
CN205246498U (en) Infiltration consolidation apparatus
CN201207031Y (en) Tester for air content of cement concrete
CN203043861U (en) Standard gas distribution device
CN105588796B (en) A kind of device of accurate quick measure soil permeability coefficient
CN204346638U (en) A kind of pressure calibration/calibrating installation
CN102297818B (en) System and method for measuring true density of powder sample in absence of water and oxygen
CN101303289B (en) High pressure solid clay pervasion test device
CN106168564B (en) A kind of device and method measuring refrigerator oil and refrigerant blending agent
CN106198297A (en) A kind of accurate calculating methane is the method for true adsorbance on shale
CN102226803B (en) Detection method of early autogenous shrinkage of cement mortar
CN104959049B (en) ultra-pure mixed gas preparation system and method
CN204177710U (en) A kind of varying head permeability apparatus preventing infiltration cutting ring side seam from leaking
CN203981234U (en) Pneumatic process volume measurement device
CN101373162B (en) Method for drafting differential pressure and leakage amount relation curve in leak detection of seal article
CN202033067U (en) Solid volume measurement instrument
CN206248296U (en) One kind is used for gas meter, flow meter ball valve air-tightness pressure detecting instrument
CN103041724B (en) Novel air distributing device in static volume method and air distributing method
CN103528909B (en) A kind of using method of the determinator of gas solubility
CN203139972U (en) Standard mixed gas preparation apparatus
CN101201286A (en) Device for testing product hermeticity
CN101526343B (en) Correction method for weighing results of hydraulic pressure test deflection of air bottle
CN104897253A (en) Weighing equipment for liquid flow standard devices
CN104316144A (en) Visual measurement device for underground water level under negative pressure condition and measurement method

Legal Events

Date Code Title Description
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20151028

Termination date: 20180715