CN204725951U - A kind of ABS plastic surface plating structure adopting nano composite plating layer material - Google Patents
A kind of ABS plastic surface plating structure adopting nano composite plating layer material Download PDFInfo
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- CN204725951U CN204725951U CN201520414886.4U CN201520414886U CN204725951U CN 204725951 U CN204725951 U CN 204725951U CN 201520414886 U CN201520414886 U CN 201520414886U CN 204725951 U CN204725951 U CN 204725951U
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Abstract
The utility model relates to polymer surface coating structure field, a kind of ABS plastic surface plating structure adopting nano composite plating layer material in particular, adopt cerium oxide and zinc bi-material, corrosion resistance is good, wearability is good, hardness is large, added in ABS plastic and ABS plastic can be made to become very fine and close, toughness, intensity also make moderate progress, and water proofing property strengthens.Nanometer composite layer contacts with ABS plastic surface.First nickel-phosphorus alloy functionally gradient deposit contacts with nanometer composite layer.Basic plating layers of copper contacts with the first nickel-phosphorus alloy functionally gradient deposit.Nickel-chrome alloy layer contacts with basic plating layers of copper, and nickel-chrome alloy layer is positioned at the outside of basic plating layers of copper.Second nickel-phosphorus alloy functionally gradient deposit and nickel-chrome alloy layer contact, and the second nickel-phosphorus alloy functionally gradient deposit is positioned at the outside of nickel-chrome alloy layer.<pb pnum="1" />
Description
Technical field
The utility model relates to polymer surface coating structure field, is a kind of ABS plastic surface plating structure adopting nano composite plating layer material in particular.
Background technology
The ABS plastic part that automotive trim is used requires the outward appearance with light, wear-resistant, corrosion-resistant, especially requires resistance to temperature shock.Prior art ABS plastic overlay coating comprises electroless nickel layer, burnt layers of copper, high light nickel dam and chromium coating, owing to adopting nickel dam as high photosphere in this structure, although it is fine to have certain thickness nickel dam texture, but nickel dam is different with the coefficient of expansion of layers of copper, cause thermal deformation different, the thermal stress produced easily causes coming off of coating, under the vibration environment of running car, under the induction of substrate ABS plastic generating period miniature deformation, easily there is situation about departing from adjacent burnt layers of copper in thicker nickel dam, coating is finally made to occur coming off, so design a kind of ABS plastic surface plating structure adopting nano composite plating layer material.
Summary of the invention
The technical problem that the utility model mainly solves is to provide a kind of ABS plastic surface plating structure adopting nano composite plating layer material, adopt cerium oxide and zinc bi-material, corrosion resistance is good, wearability is good, hardness is large, added in ABS plastic and ABS plastic can be made to become very fine and close, toughness, intensity also make moderate progress, and water proofing property strengthens.
For solving the problems of the technologies described above, the utility model relates to polymer surface coating structure field, a kind of ABS plastic surface plating structure adopting nano composite plating layer material in particular, comprise ABS plastic surface, nanometer composite layer, first nickel-phosphorus alloy functionally gradient deposit, basic plating layers of copper, nickel-chrome alloy layer and the second nickel-phosphorus alloy functionally gradient deposit, adopt cerium oxide and zinc bi-material, corrosion resistance is good, wearability is good, hardness is large, added in ABS plastic and ABS plastic can be made to become very fine and close, toughness, intensity also makes moderate progress, and water proofing property strengthens.
Nanometer composite layer contacts with ABS plastic surface, and nanometer composite layer is positioned at the outside on ABS plastic surface.First nickel-phosphorus alloy functionally gradient deposit contacts with nanometer composite layer, and the first nickel-phosphorus alloy functionally gradient deposit is positioned at the outside of nanometer composite layer.Basic plating layers of copper contacts with the first nickel-phosphorus alloy functionally gradient deposit, and basic plating layers of copper is positioned at the outside of the first nickel-phosphorus alloy functionally gradient deposit.Nickel-chrome alloy layer contacts with basic plating layers of copper, and nickel-chrome alloy layer is positioned at the outside of basic plating layers of copper.Second nickel-phosphorus alloy functionally gradient deposit and nickel-chrome alloy layer contact, and the second nickel-phosphorus alloy functionally gradient deposit is positioned at the outside of nickel-chrome alloy layer.
As the further optimization of the technical program, a kind of thickness of the nanometer composite layer described in ABS plastic surface plating structure of nano composite plating layer material that adopts of the utility model is 5 microns to 15 microns.
As the further optimization of the technical program, a kind of thickness adopting the first nickel-phosphorus alloy functionally gradient deposit described in ABS plastic surface plating structure of nano composite plating layer material of the utility model is 20 microns to 50 microns.
As the further optimization of the technical program, a kind of thickness of the basic plating layers of copper described in ABS plastic surface plating structure of nano composite plating layer material that adopts of the utility model is 10 microns to 20 microns.
As the further optimization of the technical program, a kind of thickness of the nickel-chrome alloy layer described in ABS plastic surface plating structure of nano composite plating layer material that adopts of the utility model is 5 microns to 15 microns.
As the further optimization of the technical program, a kind of thickness adopting the second nickel-phosphorus alloy functionally gradient deposit described in ABS plastic surface plating structure of nano composite plating layer material of the utility model is 20 microns to 100 microns.
A kind of beneficial effect of the ABS plastic surface plating structure of nano composite plating layer material that adopts of the utility model is:
A kind of ABS plastic surface plating structure adopting nano composite plating layer material of the utility model, adopt cerium oxide and zinc bi-material, corrosion resistance is good, wearability is good, hardness is large, added in ABS plastic and ABS plastic can be made to become very fine and close, toughness, intensity also make moderate progress, and water proofing property strengthens.
Accompanying drawing explanation
Below in conjunction with accompanying drawing and specific implementation method, the utility model is described in more detail.
Fig. 1 is a kind of structural representation adopting the ABS plastic surface plating structure of nano composite plating layer material of the utility model.
In figure: ABS plastic surface 1; Nanometer composite layer 2; First nickel-phosphorus alloy functionally gradient deposit 3; Basic plating layers of copper 4; Nickel-chrome alloy layer 5; Second nickel-phosphorus alloy functionally gradient deposit 6.
Detailed description of the invention
Detailed description of the invention one:
Below in conjunction with figure, present embodiment is described, the utility model relates to polymer surface coating structure field, a kind of ABS plastic surface plating structure adopting nano composite plating layer material in particular, comprise ABS plastic surface 1, nanometer composite layer 2, first nickel-phosphorus alloy functionally gradient deposit 3, basic plating layers of copper 4, nickel-chrome alloy layer 5 and the second nickel-phosphorus alloy functionally gradient deposit 6, adopt cerium oxide and zinc bi-material, corrosion resistance is good, wearability is good, hardness is large, added in ABS plastic and ABS plastic can be made to become very fine and close, toughness, intensity also makes moderate progress, and water proofing property strengthens.
Nanometer composite layer 2 contacts with ABS plastic surface 1, and nanometer composite layer 2 is positioned at the outside on ABS plastic surface 1, nanometer composite layer 2 is made up of cerium oxide and zinc bi-material, can the wearability of reinforced ABS, corrosion resistance and hardness, added in ABS plastic and ABS plastic can be made to become very fine and close, toughness, intensity also make moderate progress, and water proofing property strengthens.First nickel-phosphorus alloy functionally gradient deposit 3 contacts with nanometer composite layer 2, and the first nickel-phosphorus alloy functionally gradient deposit 3 is positioned at the outside of nanometer composite layer 2.The phosphorus content gradient that first nickel-phosphorus alloy functionally gradient deposit 3 and the second nickel-phosphorus alloy functionally gradient deposit 6 have and the distribution of thermal coefficient of expansion gradient can alleviate the thermal stress issues that coating causes because thermal coefficient of expansion does not mate with contact layer effectively, first nickel-phosphorus alloy functionally gradient deposit 3 and the second nickel-phosphorus alloy functionally gradient deposit 6 dynamically can change electroplating voltage in electroplating process, by the graded of phosphorus content, progressively realize being changed by the gradient of crystal to amorphous, and the adaptability of the lattice surface thermal deformation of non-crystalline material improves, can effectively reduce the thermal stress caused because thermal coefficient of expansion does not mate, avoid the fatigue cracking of coating under microseismic activity environment.Amorphous nickel-phosphorus alloy has wear-resisting characteristic simultaneously.Basic plating layers of copper 4 contacts with the first nickel-phosphorus alloy functionally gradient deposit 3, and basic plating layers of copper 4 is positioned at the outside of the first nickel-phosphorus alloy functionally gradient deposit 3.Nickel-chrome alloy layer 5 contacts with basic plating layers of copper 4, and nickel-chrome alloy layer 5 is positioned at the outside of basic plating layers of copper 4.Second nickel-phosphorus alloy functionally gradient deposit 6 and nickel-chrome alloy layer 5 contact, and the second nickel-phosphorus alloy functionally gradient deposit 6 is positioned at the outside of nickel-chrome alloy layer 5.
Detailed description of the invention two:
Below in conjunction with Fig. 1, present embodiment is described, present embodiment is described further embodiment one, and the thickness of described nanometer composite layer 2 is 5 microns to 15 microns.
Detailed description of the invention three:
Below in conjunction with Fig. 1, present embodiment is described, present embodiment is described further embodiment one, and the thickness of the first described nickel-phosphorus alloy functionally gradient deposit 3 is 20 microns to 50 microns.
Detailed description of the invention four:
Below in conjunction with Fig. 1, present embodiment is described, present embodiment is described further embodiment one, and the thickness of described basic plating layers of copper 4 is 10 microns to 20 microns.
Detailed description of the invention five:
Below in conjunction with Fig. 1, present embodiment is described, present embodiment is described further embodiment one, and the thickness of described nickel-chrome alloy layer 5 is 5 microns to 15 microns.
Detailed description of the invention six:
Below in conjunction with Fig. 1, present embodiment is described, present embodiment is described further embodiment one, and the thickness of the second described nickel-phosphorus alloy functionally gradient deposit 6 is 20 microns to 100 microns.
Certainly; above-mentioned explanation is not limitation of the utility model; the utility model is also not limited only to above-mentioned citing, the change that those skilled in the art make in essential scope of the present utility model, remodeling, interpolation or replacement, also belongs to protection domain of the present utility model.
Claims (6)
1. one kind adopts the ABS plastic surface plating structure of nano composite plating layer material, comprise ABS plastic surface (1), nanometer composite layer (2), the first nickel-phosphorus alloy functionally gradient deposit (3), basic plating layers of copper (4), nickel-chrome alloy layer (5) and the second nickel-phosphorus alloy functionally gradient deposit (6), it is characterized in that: nanometer composite layer (2) contacts with ABS plastic surface (1), and nanometer composite layer (2) is positioned at the outside of ABS plastic surface (1); First nickel-phosphorus alloy functionally gradient deposit (3) contacts with nanometer composite layer (2), and the first nickel-phosphorus alloy functionally gradient deposit (3) is positioned at the outside of nanometer composite layer (2); Basic plating layers of copper (4) contacts with the first nickel-phosphorus alloy functionally gradient deposit (3), and basic plating layers of copper (4) is positioned at the first nickel-phosphorus alloy functionally gradient deposit (3)) outside; Nickel-chrome alloy layer (5) contacts with basic plating layers of copper (4), and nickel-chrome alloy layer (5) is positioned at the outside of basic plating layers of copper (4); Second nickel-phosphorus alloy functionally gradient deposit (6) and nickel-chrome alloy layer (5) contact, and the second nickel-phosphorus alloy functionally gradient deposit (6) is positioned at the outside of nickel-chrome alloy layer (5).
2. a kind of ABS plastic surface plating structure adopting nano composite plating layer material according to claim 1, is characterized in that: the thickness of described nanometer composite layer (2) is 5 microns to 15 microns.
3. a kind of ABS plastic surface plating structure adopting nano composite plating layer material according to claim 1, is characterized in that: the thickness of the first described nickel-phosphorus alloy functionally gradient deposit (3) is 20 microns to 50 microns.
4. a kind of ABS plastic surface plating structure adopting nano composite plating layer material according to claim 1, is characterized in that: the thickness of described basic plating layers of copper (4) is 10 microns to 20 microns.
5. a kind of ABS plastic surface plating structure adopting nano composite plating layer material according to claim 1, is characterized in that: the thickness of described nickel-chrome alloy layer (5) is 5 microns to 15 microns.
6. a kind of ABS plastic surface plating structure adopting nano composite plating layer material according to claim 1, is characterized in that: the thickness of the second described nickel-phosphorus alloy functionally gradient deposit (6) is 20 microns to 100 microns.
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CN201520414886.4U CN204725951U (en) | 2015-06-16 | 2015-06-16 | A kind of ABS plastic surface plating structure adopting nano composite plating layer material |
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CN201520414886.4U CN204725951U (en) | 2015-06-16 | 2015-06-16 | A kind of ABS plastic surface plating structure adopting nano composite plating layer material |
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CN201520414886.4U Expired - Fee Related CN204725951U (en) | 2015-06-16 | 2015-06-16 | A kind of ABS plastic surface plating structure adopting nano composite plating layer material |
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2015
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C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20151028 Termination date: 20160616 |
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CF01 | Termination of patent right due to non-payment of annual fee |