CN204720459U - A kind of high-efficiency self-cleaning Graphene coating solar-energy photovoltaic module - Google Patents
A kind of high-efficiency self-cleaning Graphene coating solar-energy photovoltaic module Download PDFInfo
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- CN204720459U CN204720459U CN201520497180.9U CN201520497180U CN204720459U CN 204720459 U CN204720459 U CN 204720459U CN 201520497180 U CN201520497180 U CN 201520497180U CN 204720459 U CN204720459 U CN 204720459U
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Abstract
A kind of high-efficiency self-cleaning Graphene coating solar-energy photovoltaic module, comprising: Graphene coating toughened glass, Graphene rete, EVA glue-line, photovoltaic cell, backboard, terminal box and frame.This technical characteristic is that the both sides of photovoltaic module toughened glass are all coated with last layer Graphene coating, after solidification, Graphene and glass surface are with chemical bonds, what Graphene was firm is attached to glass surface formation Graphene coating toughened glass, one deck EVA glue-line is all scribbled between solar battery sheet and upper surface Graphene coating toughened glass and backboard, Graphene coating toughened glass, EVA glue-line, photovoltaic cell and backboard are integrated by hot pressing bonding, and outside attaching frame and terminal box form the solar photovoltaic battery component of certain power.
Description
Technical field
The utility model belongs to technical field of photovoltaic power generation, is specifically related to a kind of high-efficiency self-cleaning Graphene coating solar-energy photovoltaic module.
Background technology
photovoltaic panel assemblythat a kind of exposure just can produce in the sun
direct currentblast Furnace Top Gas Recovery Turbine Unit (TRT), by almost all with the thin body solid that semiconductor material (such as silicon) is made
photovoltaic cellcomposition.Owing to there is no movable part, therefore can long-time operation and can not cause any
loss.Simple photovoltaic cell can be wrist-watch and calculator provides the energy, and more complicated photovoltaic system can be house and provides illumination, and is mains supply.Photovoltaic panel assembly can make difformity, and assembly can connect, to produce more electric power.Balcony and building surface all can use photovoltaic panel assembly, and be even used as a part for window, skylight or masking device, these photovoltaic facilities are commonly called the photovoltaic system being attached to building.
The photovoltaic module primary structure of current EVA encapsulation comprises: the formations such as transparent top surface, colloid seal material, back layer and external frame composition, terminal box.And the generating efficiency of transparent superficial layer to photovoltaic module has a certain impact, the front surface material of photovoltaic module is for can being had very high transparency by the wavelength that the solar cell in photovoltaic module uses.For silicon solar cell, top surface material must have very high transparency for wavelength at the wavelength of 350nm to 1200nm scope.In addition, the reflection of front surface should be very low.Although can reduce reflection at top surface application antireflective coating in theory, in fact these antireflective coatings are all not enough to the service condition of resisting most of photovoltaic module.Another technology that can reduce reflection is textured surfaces or makes rough surface.But dust, organic dirt more may be attached on top surface in this case, and be difficult to by wind and rainwater removing.Therefore these assemblies are not " automatically cleanings ", and the loss that caused by the dust of top surface very soon of the superiority reducing reflection exceed.Except reflection and transparent characteristic, top surface material should be impermeable water, should be impact-resistant, should be stable under long-term Ultraviolet radiation, and have very low thermal resistivity.Top surface material has several selection, comprises acrylate copolymer and glass.The low iron glass of tempering is prevailing application, because the features such as cost is low, firm, stable, the high grade of transparency, waterproof and gas are widely used, but toughened glass light transmittance is low, general at initial light transmission about 90%, having dust to block light transmittance after using a period of time can decline to a great extent, and is the non-conductor of heat simultaneously, thermal resistivity is large, when summer, temperature was higher, assembly temperature can reach seventy or eighty degrees Celsius, reduces the generating efficiency of photovoltaic module.Above problem makes photovoltaic module generating efficiency degradation, and is difficult to clean, and increase maintenance cost and manpower, this is current photovoltaic power generation technology problem demanding prompt solution.
Graphene-structured is highly stable, and up to now, researcher does not find the situation having carbon atom to lack in Graphene yet.Connection in Graphene between each carbon atom is very pliable and tough, and when applying external mechanical force, carbon atom face with regard to flexural deformation, thus makes carbon atom need not rearrange to adapt to external force, also just maintains Stability Analysis of Structures.This stable lattice structure makes carbon atom have outstanding conductivity.When electronics in Graphene moves in track, or foreign atom can not be introduced and scattering occurs because of lattice defect.Because interatomic force is very strong, at normal temperatures, even if around carbon atom telescopes, the interference that in Graphene, electronics is subject to is also very little, and meanwhile, Graphene is the thinnest in the world is also the hardest nano material, it is almost completely transparent, only absorbs the light of 2.3%; Conductive coefficient is up to 5300 W/(mK), and Graphene has photocatalyst function and strong hydrophilicity nonpolar nature, Graphene can accelerate some organic decomposition and have very strong hydrophily under light illumination, Graphene coating on photovoltaic glass surface, the reflection of glass surface can be reduced, increase the conductive coefficient of glass, accelerate organic decomposition and self-cleaning function, therefore, Graphene coated glass is the optimal selection of the top surface glass that photovoltaic is transparent.
Summary of the invention
Low in order to solve current photovoltaic glass light transmittance, thermal resistivity is large, and be difficult to problems such as cleaning, the utility model provides a kind of high-efficiency self-cleaning Graphene coating solar-energy photovoltaic module, to solve the problem.
For achieving the above object, solution of the present utility model is: a kind of high-efficiency self-cleaning Graphene coating solar-energy photovoltaic module, comprising: Graphene coating toughened glass, Graphene rete, EVA glue-line, photovoltaic cell, backboard, terminal box and frame.This technical characteristic is that the both sides of photovoltaic module toughened glass are all coated with last layer Graphene coating, after solidification, Graphene and glass surface are with chemical bonds, what Graphene was firm is attached to glass surface formation Graphene coating toughened glass, one deck EVA glue-line is all scribbled between solar battery sheet and upper surface Graphene coating toughened glass and backboard, Graphene coating toughened glass, EVA glue-line, photovoltaic cell and backboard are integrated by hot pressing bonding, and outside attaching frame and terminal box form the solar photovoltaic battery component of certain power.
Preferred Graphene coating toughened glass, it is characterized in that Graphene coating tempering glass tempering glass two sides all scribbles Graphene rete, Graphene rete is monolayer carbon atomic film, carbon atom number of plies 1-15 layer.
The beneficial effects of the utility model are:
The utility model adopts Graphene coating photovoltaic glass as photovoltaic module transparent surface, Graphene coating can increase diffusion, reduce reflecting effect, add the light transmission capacity of transparent glass, Graphene rete has high-hydrophilic, makes photovoltaic glass have self-cleaning function, and Graphene can reduce thermal resistance and photocatalyst effect, above feature all can improve photovoltaic module generating efficiency greatly, and reduces maintenance cost and manpower, has very strong practicality.
Accompanying drawing explanation
Fig. 1 is a kind of high-efficiency self-cleaning Graphene of the utility model coating solar-energy photovoltaic module structure schematic diagram;
Number in the figure: 1, Graphene coating toughened glass, 11, Graphene rete, 2, EVA glue-line, 3, photovoltaic cell, 4, backboard, 5, terminal box, 6, frame.
Embodiment
In order to better understand the utility model, illustrate content of the present utility model further below in conjunction with embodiment, but the utility model content is not only confined to following specific embodiment.
Shown in composition graphs 1, be described further the utility model, a kind of high-efficiency self-cleaning Graphene coating solar-energy photovoltaic module, comprising: Graphene coating toughened glass 1, Graphene rete 11, EVA glue-line 2, photovoltaic cell 3, backboard 4, terminal box 5 and frame 6.This technical characteristic is that the both sides of photovoltaic module toughened glass are all coated with last layer Graphene coating, after solidification, Graphene and glass surface are with chemical bonds, what Graphene was firm is attached to glass surface formation Graphene coating toughened glass 1, one deck EVA glue-line 2 is all scribbled between solar battery sheet 3 and upper surface Graphene coating toughened glass 1 and backboard 4, Graphene coating toughened glass 1, EVA glue-line 2, photovoltaic cell 3 and backboard 4 are integrated by hot pressing bonding, and outside attaching frame 6 and terminal box 5 form the solar photovoltaic battery component of certain power.
Preferred Graphene coating toughened glass, it is characterized in that the toughened glass two sides of Graphene coating toughened glass 1 all scribbles Graphene rete 11, Graphene rete 11 is monolayer carbon atomic film, carbon atom number of plies 1-15 layer.
Specific embodiment 1
The present embodiment carries out as follows:
First: Graphene coating actinic glass makes
1, by deionized water, isopropyl alcohol and DMF by volume for 20-10:9-5:0.5-1 mixes, be mixed with the solution of 1L.In this step, the preparation process of dispersion soln is: first by isopropyl alcohol and DMF mixing, then mixed isopropyl alcohol and DMF are mixed with deionized water again;
2, use weak base or/and prepare the pH value of solution in weak acid regulating step 1, make its pH value between 9-11.5;
3, take the Graphene that quality is 20-50g, then slowly join in the solution in step 2;
4, the container holding step 3 solution is put into ultrasonic device and carry out ultrasonic process, wherein, supersonic frequency 30KHZ, ultrasonic power are 2000W, and ultrasonic time is 45min;
5, by graphene solution good for step 4 ultrasonic disperse by after the refinement of superhigh pressure nanometer, dispersing apparatus at least three times, can obtain dispersion fissility well, uniform particle sizes, stable graphene dispersing solution;
6, make same graphene dispersing solution again according to above-mentioned steps, until make the Standard graphite alkene dispersion liquid of 1 cubic metre, and dispersion liquid is positioned in storage tank for subsequent use.
Second: Graphene coated glass tempering
A, common glass is cut on request certain size specification after, clean, dry;
B, by glass dried for step a, be immersed in the graphene dispersing solution made, after 30-60 second, glass pulled out and air-dry;
C, by the glass of step b, put into annealing furnace and heat, the heating time of setting is about every mm of thickness glass 35 ~ 40 seconds, and the heat time is 300-450 second, and heating-up temperature is 600-750 DEG C;
D, the glass gone out from the annealing furnace thermal treatment zone is carried out quick cooling chamber temperature, the two sides of glass is purged rapidly with the cold air of drying, be divided into chilling period and cooling period, the blast of the glass chilling period that 6mm is thick is 2000Pa, cooling time Wei 50-60 second, and the blast of cooling period is 1000Pa, and cooling time is not 60 seconds, finally be cooled to room temperature, glass tempering completes.
3rd: the lamination of photovoltaic module and group frame
Utilize existing layer press polish photovoltaic assembly technology, the Graphene coated glass through tempering, be packaged in the light transmitting surface of photovoltaic module, form a kind of high-efficient graphite ene coatings photovoltaic module.
Above-described embodiment just illustrates technical conceive of the present utility model and feature, its objective is and those of ordinary skill in the art can be understood feature of the present utility model and implement according to this, can not limit protection range of the present utility model with this.Every equivalence carried out according to the essence of the utility model content changes or modifies, and all should be encompassed in protection range of the present utility model.
Claims (2)
1. a high-efficiency self-cleaning Graphene coating solar-energy photovoltaic module, comprise: Graphene coating toughened glass, EVA glue-line, photovoltaic cell, backboard, terminal box and frame, it is characterized in that the both sides of photovoltaic module toughened glass are all coated with last layer Graphene coating, after solidification, Graphene and glass surface are with chemical bonds, what Graphene was firm is attached to glass surface, form Graphene coating toughened glass, one deck EVA glue-line is all scribbled between solar battery sheet and Graphene coating toughened glass and backboard, Graphene coating toughened glass, EVA glue-line, photovoltaic cell and backboard are binded by hot pressing and are integrated, outside attaching frame and terminal box form the solar photovoltaic battery component of certain power.
2. a kind of high-efficiency self-cleaning Graphene coating solar-energy photovoltaic module according to claim 1, it is characterized in that Graphene coating tempering glass tempering glass two sides all scribbles Graphene rete, Graphene rete is monolayer carbon atomic film, carbon atom number of plies 1-15 layer.
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104916711A (en) * | 2015-07-11 | 2015-09-16 | 王子韩 | High-efficiency self-cleaning graphene coating solar photovoltaic component and preparation method |
CN106711260A (en) * | 2017-02-28 | 2017-05-24 | 刘泉 | Graphene solar panel and street lamp comprising same |
-
2015
- 2015-07-11 CN CN201520497180.9U patent/CN204720459U/en not_active Withdrawn - After Issue
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104916711A (en) * | 2015-07-11 | 2015-09-16 | 王子韩 | High-efficiency self-cleaning graphene coating solar photovoltaic component and preparation method |
CN104916711B (en) * | 2015-07-11 | 2017-07-28 | 王子韩 | A kind of high-efficiency self-cleaning graphene coating solar-energy photovoltaic module and manufacture method |
CN106711260A (en) * | 2017-02-28 | 2017-05-24 | 刘泉 | Graphene solar panel and street lamp comprising same |
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Granted publication date: 20151021 Effective date of abandoning: 20170728 |
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