CN204607670U - For the efficient ozone contact reacts device of advanced treatment of wastewater - Google Patents
For the efficient ozone contact reacts device of advanced treatment of wastewater Download PDFInfo
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- CN204607670U CN204607670U CN201520137586.6U CN201520137586U CN204607670U CN 204607670 U CN204607670 U CN 204607670U CN 201520137586 U CN201520137586 U CN 201520137586U CN 204607670 U CN204607670 U CN 204607670U
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Abstract
The utility model discloses a kind of efficient ozone contact reacts device for advanced treatment of wastewater, comprise ozone contact tank and ozone pipeline etc., ozone contact tank is provided with N road baffle and pond body is divided into N+1 section, forms vertical folding streaming contact reacts route in pond; The first to N section reaction tank all establishes backflow water pipe, reflux pump; Every section of reaction tank water inlet pipe all establishes two inlet mouth high speed water emitter and coil pipe turbulent flow reactor, water inlet manifold access first paragraph reaction tank, and the water inlet pipe of N to N+1 section reaction tank is served as by the return line of the last period; Two inlet mouth high speed water emitter comprises water-in, jetting orifice, ozone import and ozone tail gas import, and water-in is connected with corresponding water inlet pipe end, and ozone import connects from ozone pipeline, and ozone tail gas import connects the ozone tail gas outlet of autoreaction Chi Ding.Not needing to increase ozone contact pool volume and dosage, mass-transfer efficiency and the utilization ratio of ozone in water treatment can be improved, saved construction investment, reduced running cost.
Description
Technical field
The utility model relates to a kind of advanced sewage treatment system, particularly relates to a kind of efficient ozone contact reacts system for advanced treatment of wastewater.
Background technology
Water treatment field often utilizes the strong oxidizing property of ozone, carries out disinfection, the process such as Strong oxdiative to water.But ozone is extremely unstable at normal temperatures and pressures, decay is very fast, and solubleness in water is very little; For needing to experience the slow process that mass transfer process from gas phase to liquid phase and dissolved ozone react with contamination-free in water in water treatment procedure.For improving the utilization ratio of ozone, Ozonation is often taked: a kind of is the contact reacts device selecting mass-transfer efficiency high, as fixing mixing screw, injector, micro-hole aerator, and flap mixing tank, perforation plate aerator etc.; Another kind is the duration of contact extending ozone and water, has the contact reacts pond held compared with great Chi as selected, or takes the technical measures such as multi-point adding, increase internal recycle.Above-mentioned two kinds of methods can the mass-transfer efficiency of raising ozone to a certain degree and water, improves the effective rate of utilization of ozone.But often kind of method all can not utilize ozone completely, therefore, need increase tail gas breaking plant, destroy residual ozone, in order to avoid cause secondary pollution, also requirement can not unrestrictedly increase contact reacts pool volume simultaneously, to save construction investment.
Because ozone is as a kind of generally acknowledged strong oxidizer, be widely used in water treatment every field.In order to reach good treatment effect, ozone concn higher in water must be maintained.But the solubleness of ozone in water is along with change complexity such as temperature, pH, ozone flows, and the rate of decay of ozone quickly, and initial ozone concn is higher, decays faster.For reaching the removal effect of expection, engineering of water treatment Shi Tongchang is by extending contact time and strengthening ozone dosage to realize.Like this, contact tank civil engineering costs is very high on the one hand, and ozonizer model is selected also bigger than normal, and ozone decay is often not thorough, and also need to increase a set of ozone exhaust gas treating device, construction investment is higher; On the other hand, the ozone amount of decay waste is also very large, and ozone utilization rate is not high, and running cost is high.
Utility model content
For deficiency of the prior art, the utility model provides a kind of efficient ozone contact reacts device for advanced treatment of wastewater, can when not increasing ozone contact pool volume and ozone dosage, improve mass-transfer efficiency and the utilization ratio of ozone in water treatment procedure, thus saved construction investment, reduce running cost.
In order to solve the problems of the technologies described above, a kind of efficient ozone contact reacts device for advanced treatment of wastewater of the utility model, comprise ozone contact tank and ozone pipeline, described ozone contact tank is provided with water inlet pipe and rising pipe, be provided with N road baffle in described ozone contact tank from water inlet pipe side to rising pipe side successively and described ozone contact tank is divided into N+1 section reaction tank, the water port of N road baffle goes to upper and lower successively alternately arranges, thus in described ozone contact tank, define vertical folding streaming contact reacts route; Be provided with coil pipe turbulent flow reactor respectively in every section of reaction tank, described water inlet pipe is connected with the coil pipe turbulent flow reactor in first paragraph reaction tank, and described rising pipe is arranged on N+1 section reaction tank; Be respectively equipped with a backflow water pipe in first paragraph to N section reaction tank, the top of described backflow water pipe extend in the section reaction tank of place, and described backflow water pipe is provided with a reflux pump respectively; The top of every section of reaction tank is provided with an ozone tail gas outlet respectively; Described water inlet pipe and the upper high speed water emitter being provided with a pair of inlet mouth in the junction with coil pipe turbulent flow reactor respectively of backflow water pipe, the high speed water emitter of described pair of inlet mouth comprises water-in, jetting orifice, ozone import and ozone tail gas import, the end of described backflow water pipe is connected with the water-in of the high speed water emitter of this Duan Houyi reaction tank, described ozone import is connected to described ozone pipeline, described ozone tail gas import is connected to ozone tail gas outlet, and the connection line that described ozone tail gas import and ozone tail gas export is provided with valve.
Compared with prior art, the beneficial effects of the utility model are:
The efficient ozone contact reacts device that the utility model is used for advanced treatment of wastewater adopts two inlet mouth high speed water emitter, an inlet mouth enters ozone, the ozone tail gas on ozone contact tank top collected by another inlet mouth, ozone gas is by high speed water emitter, ozone contact system is mixed into water inlet, efficiency utilization system ozone, realizes ozone utilization rate and reaches 100%.Coil pipe turbulent flow reactor is connected in two inlet mouth water sprayer rear end, ozone is made in coil pipe turbulent flow reactor, to be alternately in the different fluidised forms of turbulent flow, laminar flow from the steam water interface of water inlet, improve the contact transfer effect of ozone and water inlet, largely improve transfer ratio and the transfer rate of ozone.Adopt vertical folding streaming contact reacts pond, avoid the appearance of short stream, ensure to utilize contact reacts Chi Chi to hold to greatest extent.Improve tradition and once add the low shortcoming of utilization ratio that ozone exists, reflux pump is set, carries out multiple spot backflow, continue in return line to add ozone, realize the secondary of ozone, add for three times, improve the mass-transfer efficiency of ozone.
The utility model can be widely used in water treatment field, especially advanced treatment of wastewater field.Every ozone that utilizes carries out pre-treatment, and the water treatment field of sterilization or Strong oxdiative, all can adopt the utility model to be used for the efficient ozone contact reacts treatment process of advanced treatment of wastewater.Not only be suitable at sewage treatment area, and at Water purification, sewerage disposing field, same extensively applicable.
Accompanying drawing explanation
Fig. 1 is the efficient ozone contact reacts process schematic representation of the utility model for advanced treatment of wastewater.
1-water inlet pipe, 2-ozone contact tank, 3-rising pipe, the two inlet mouth high speed water emitter of 4-, 5-valve, 6-coil pipe turbulent flow reactor, 7-ozone pipeline, 8-reflux pump, 9-refluxes water pipe.
Embodiment
Below in conjunction with the drawings and specific embodiments, technical solutions of the utility model are described in further detail.
As shown in Figure 1, a kind of efficient ozone contact reacts device for advanced treatment of wastewater of the utility model, comprise ozone contact tank 2 and ozone pipeline 7, described ozone contact tank 2 is provided with water inlet pipe 1 and rising pipe 3, and the top of every section of reaction tank is provided with an ozone tail gas outlet respectively.N road baffle is provided with from water inlet pipe 1 side successively to rising pipe 3 side in described ozone contact tank 2, described N road baffle is at least twice baffle, described ozone contact tank 2 is divided into N+1 section reaction tank by N road baffle, the water port of N road baffle goes to upper and lower successively alternately arranges, thus in described ozone contact tank 2, define vertical folding streaming contact reacts route.
Every section of reaction tank water inlet pipe is provided with high speed water emitter 4 and the coil pipe turbulent flow reactor 6 of a pair of inlet mouth respectively, and described water inlet pipe 1 is connected with the coil pipe turbulent flow reactor 6 in first paragraph reaction tank, and described rising pipe 3 is arranged on N+1 section reaction tank; A backflow water pipe 9 and reflux pump 8 is respectively equipped with in first paragraph to N section reaction tank, the top of described backflow water pipe 9 extend in the section reaction tank of place, the end of described backflow water pipe 9, as the water inlet pipe of next section of reaction tank, is connected with the high speed water emitter 4 of two inlet mouth and coil pipe turbulent flow reactor 6; Described water inlet pipe 1 and backflow water pipe 9 are positioned at and are provided with a pair of inlet mouth high speed water emitter 4 respectively with the junction of coil pipe turbulent flow reactor 6, the described pair of inlet mouth high speed water emitter 4 to arrange on described water inlet pipe 1 or backflow water pipe 9 on the pipeline section of coil pipe turbulent flow reactor 6; The high speed water emitter 4 of described pair of inlet mouth comprises water-in, jetting orifice, ozone import and ozone tail gas import, and in the high speed water emitter 4 of described pair of inlet mouth, the bore of water-in is D
1, the bore of jetting orifice is D
2, the bore of ozone import is D
3, the bore of ozone tail gas import is D
4; Consider to determine D in the utility model based on flow and tolerance size and flow velocity
4≤ D
3< D
2< D
1, described ozone import is connected to described ozone pipeline 7, and described ozone tail gas import is connected to ozone tail gas outlet, and the connection line that described ozone tail gas import and ozone tail gas export is provided with valve 5.
When the efficient ozone contact reacts device using the utility model to be used for advanced treatment of wastewater carries out sewage disposal, ozone pipeline 7 is connected to ozone gas source, water inlet pipe 1 is connected to pending water source; The useful volume of described ozone contact tank 2 meets the minimal-contact time, division hop count N+1 >=3 of described ozone contact tank 2, in described ozone contact tank 2, ozone dosage is adjustable, minimal-contact time and ozone dosage are determined according to the test of the pollutant emission standard of the rear water outlet of organic pollutant level in pending water source and process, wherein, chemical oxygen demand COD index at least will meet GB89788-1996 " integrated wastewater discharge standard ".
The technique of ozone contact reaction is as follows:
Step one, ozone gas are introduced into the coil pipe turbulent flow reactor (6) be arranged in the middle first paragraph reaction tank of ozone contact tank (2) after being mixed with water inlet by high speed water emitter (4) carries out aqueous vapor and contacts and fully mix;
The mixed water outlet of step 2, coil pipe turbulent flow reactor continues to carry out contact at this section of reaction tank and mixes, then successively by second segment to N+1 section reaction tank;
The reflux pump (8) of the reacted water of part by refluxing in this section of reaction tank on water pipe (9) in step 3, first paragraph to N section reaction tank, be back to the two inlet mouth high speed water emitters (4) be connected with this backflow water pipe (9), and again carry out after aqueous vapor contact abundant mixing, entering in the coil pipe turbulent flow reactor (6) in rear one section of reaction tank respectively by high speed water emitter (4) with the ozone gas entered from ozone pipeline (7), the sufficient ozone tail gas of unreacted of discharging from ozone contact tank (2) top; Till the chemical oxygen demand COD index of water outlet reaches set(ting)value.
Certain chemical enterprise waste water, influent COD: 150mg/L, requires to reach water outlet COD:100mg/L, adopts ozonation technology, test.
Adopt common O3 contacted oxidation method, principal reaction device comprises: ozone contact reaction pond, ozone throwing device, ozone destruct device, and water-in and water-out pipeline, ozone adds pipeline etc.Major experimental data: during contact reacts time 60min, during ozone dosage 100mg/L ~ 120mg/L, just can reach the treatment effect of expection; Ozone utilization rate 70%.
Adopt the efficient ozone contact reacts device that the utility model provides, major experimental data: during contact reacts time 35min, during ozone dosage 70mg/L ~ 85mg/L, the treatment effect of expection can be reached; Ozone utilization rate 100%.
For this enterprise wastewater, 10000m
3/ d.Adopt common O3 contacted oxidation method and efficient ozone contact reacts device, reaction tank pond appearance is respectively: 416m
3, 243m
3; The maximum dosage of ozone is respectively: 1200kg/d, 850kg/d.
Although be described the utility model by reference to the accompanying drawings above; but the utility model is not limited to above-mentioned embodiment; above-mentioned embodiment is only schematic; instead of it is restrictive; those of ordinary skill in the art is under enlightenment of the present utility model; when not departing from the utility model aim, can also make a lot of distortion, these all belong within protection of the present utility model.
Claims (4)
1. the efficient ozone contact reacts device for advanced treatment of wastewater, comprise ozone contact tank (2) and ozone pipeline (7), described ozone contact tank (2) is provided with water inlet pipe (1) and rising pipe (3), it is characterized in that
Be provided with N road baffle from water inlet pipe (1) side successively to rising pipe (3) side in described ozone contact tank (2) and described ozone contact tank (2) is divided into N+1 section reaction tank, the water port of N road baffle goes to upper and lower successively alternately arranges, thus in described ozone contact tank (2), define vertical folding streaming contact reacts route;
Coil pipe turbulent flow reactor (6) is provided with respectively in every section of reaction tank, described water inlet pipe (1) is connected with the coil pipe turbulent flow reactor (6) in first paragraph reaction tank, and described rising pipe (3) is arranged on N+1 section reaction tank; A backflow water pipe (9) is respectively equipped with in first paragraph to N section reaction tank, the top of described backflow water pipe (9) extend in the section reaction tank of place, and described backflow water pipe (9) is provided with a reflux pump (8) respectively; The top of every section of reaction tank is provided with an ozone tail gas outlet respectively;
Described water inlet pipe (1) and backflow water pipe (9) are positioned at and are provided with a pair of inlet mouth high speed water emitter (4) respectively with the junction of coil pipe turbulent flow reactor (6), the high speed water emitter (4) of described pair of inlet mouth comprises water-in, jetting orifice, ozone import and ozone tail gas import, the end of described backflow water pipe (9) is connected with the water-in of the high speed water emitter (4) of this Duan Houyi reaction tank, described ozone import is connected to described ozone pipeline (7), described ozone tail gas import is connected to ozone tail gas outlet, the connection line that described ozone tail gas import and ozone tail gas export is provided with valve (5).
2. according to claim 1 for the efficient ozone contact reacts device of advanced treatment of wastewater, it is characterized in that, in the high speed water emitter (4) of described pair of inlet mouth, the bore of water-in is D
1, the bore of jetting orifice is D
2, the bore of ozone import is D
3, the bore of ozone tail gas import is D
4; Wherein, D
4≤ D
3< D
2< D
1.
3. according to claim 1 for the efficient ozone contact reacts device of advanced treatment of wastewater, it is characterized in that, the high speed water emitter (4) of described pair of inlet mouth arranges near described water inlet pipe (1) or refluxes water pipe (9) above on the pipeline section of coil pipe turbulent flow reactor (6).
4. according to claim 1 for the efficient ozone contact reacts device of advanced treatment of wastewater, it is characterized in that, described N road baffle is at least twice baffle.
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|---|---|---|---|
| CN201520137586.6U CN204607670U (en) | 2015-03-11 | 2015-03-11 | For the efficient ozone contact reacts device of advanced treatment of wastewater |
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| CN201520137586.6U CN204607670U (en) | 2015-03-11 | 2015-03-11 | For the efficient ozone contact reacts device of advanced treatment of wastewater |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104710001A (en) * | 2015-03-11 | 2015-06-17 | 天津市联合环保工程设计有限公司 | Efficient ozone contact and reaction device for advanced wastewater treatment and treatment process |
-
2015
- 2015-03-11 CN CN201520137586.6U patent/CN204607670U/en active Active
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104710001A (en) * | 2015-03-11 | 2015-06-17 | 天津市联合环保工程设计有限公司 | Efficient ozone contact and reaction device for advanced wastewater treatment and treatment process |
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