CN203910747U - Device for rapid analysis of volatile organic compound online - Google Patents

Device for rapid analysis of volatile organic compound online Download PDF

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Publication number
CN203910747U
CN203910747U CN201320876307.9U CN201320876307U CN203910747U CN 203910747 U CN203910747 U CN 203910747U CN 201320876307 U CN201320876307 U CN 201320876307U CN 203910747 U CN203910747 U CN 203910747U
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China
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ion
volatile organic
ion trap
vacuum
ionization source
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CN201320876307.9U
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Chinese (zh)
Inventor
程平
薛兵
孙露露
黄正旭
高伟
傅忠
丁力
周振
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Kunshan Hexin Mass Spectrometry Technology Co ltd
Guangzhou Hexin Instrument Co Ltd
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GUANGZHOU HEXIN ANALYTICAL INSTRUMENT CO Ltd
KUNSHAN HEXIN ZHIPU TECHNOLOGY CO LTD
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Abstract

The utility model discloses a device for rapid analysis of a volatile organic compound online. The device comprises a membrane sampling device, a membrane heating device, a vacuum ultraviolet single-photon ionization source, a focus electrode group, a digital linear ion trap, an ion detection device, a data collection device, a central control unit and the like. According to the utility model, by the use of the vacuum ultraviolet single-photon ionization source, the molecular ion reaction is avoided, the spectrogram is greatly simplified, and components of complex samples can be analyzed and identified directly; the ionization source and the digital ion trap of secondary series connection mass analysis are organically combined, so that a compound can be quickly and accurately analyzed and thus the loss of ions during transmission can be greatly reduced; and in addition, the use of a silicone rubber membrane structure requires no complex sample pre-treatment, the response time is short, the sampling is rapid and the needs of online analysis are conformed. The device for rapid analysis of the volatile organic compound online can be widely used in the technical field of analytical instrument detection.

Description

A kind of device of online rapid analysis volatile organic matter
Technical field
The utility model relates to analytical instrument detection technique field, especially a kind of device of online rapid analysis volatile organic matter.
Background technology
Digital linear ion trap technology is to grow up on the basis of traditional ion trap technology.The geometry of ion strap mass analyzer has experienced the evolution from traditional three-dimensional ion trap to linear ion hydrazine, and the electrode shape that forms ion trap also has hyperboloid electrode, and cylindrical electrode is to a series of variation of rectangular electrode etc.Traditional linear ion hydrazine generally all forms quadrupole ion trap system by hyperboloid electrode.
The society of science and technology high speed development, in the face of complicated analysis environments, conventional mass spectrometer cannot meet particular surroundings and the detection of occasion to harmful substance, as environmental emergency detection, fast searching pollutant sources, crude oil monitoring and severe wild environment detection etc.Therefore develop fast detecting, the organic portable mass spectrometer of on-line analysis is significant to the application in the various fields such as environment.
Utility model content
In order to solve the problems of the technologies described above, the purpose of this utility model is: a kind of portable device that the online rapid analysis volatile organic matter of Accurate Analysis result can be provided in complex analyses environment is provided.
The technical scheme that the utility model adopts is: a kind of device of online rapid analysis volatile organic matter, include film sampling device, described film sampling device arranged outside has film heating device, on described film heating device, be provided with gas access and gas vent, the downstream of described film sampling device is provided with vacuum-ultraviolet light single photon ionization source, the downstream of described vacuum-ultraviolet light single photon ionization source is provided with focusing electrode group, the downstream of described focusing electrode group is provided with the digital linear ion trap for two-stage tandem quality analysis, the side of described digital linear ion trap is provided with ion detection device, described ion detection device is connected with data acquisition unit, described data acquisition unit is connected with central control unit, described central control unit also respectively with film heating device, vacuum-ultraviolet light single photon ionization source, focusing electrode group, digital linear ion trap is connected with ion detection device.
Further, in described digital linear ion trap, also include for the pulse gas generator of collision gas is provided.
Further, described vacuum-ultraviolet light single photon ionization source includes ionization chamber, and described ionization chamber is arranged at the downstream of film sampling device inner side, and described focusing electrode group is arranged at the downstream of ionization chamber.
Further, described vacuum-ultraviolet light single photon ionization source also includes the vacuum UV lamp that is arranged at ionization chamber side, and described vacuum UV lamp is connected with central control unit.
Further, in described film sampling device, use silicone rubber membrane.
Further, include high voltagehigh frequency module in described central control unit, described high voltagehigh frequency module is connected with control figure linear ion hydrazine.
Further, described ion detection device includes dynode, detector and small-signal check-out console, described central control unit is connected with detector with dynode respectively, the output of described detector is connected to the input of small-signal check-out console, and described small-signal check-out console is connected with data acquisition unit.
The beneficial effects of the utility model are: the utility model device is used vacuum-ultraviolet light single photon ionization source, avoided molecular ion reaction, fragment ion seldom, the spectrogram producing is mainly molecular ion peak, greatly simplify spectrogram, can directly complex sample composition analyzed and be differentiated, be suitable as very much on-line monitoring mass ion source, and the digital ion trap of this ionization source and two-stage tandem quality analysis is organically combined, make it analysis of compounds rapidly and accurately; In addition, silicone rubber membrane is simple in structure, allows gas or fluid sample directly to enter into spectrometer system, and without carrying out complicated sample pre-treatments, the response time is short, and sample introduction is rapid, meets the needs of on-line analysis.
Accompanying drawing explanation
Fig. 1 is the overall structure schematic diagram of the utility model device;
Fig. 2 is the schematic diagram of the utility model device film heating device and ionization source part;
Fig. 3 is the control section high voltagehigh frequency module diagram of the utility model device;
Fig. 4 is the detector schematic diagram of the utility model device.
Embodiment
Below in conjunction with accompanying drawing, embodiment of the present utility model is described further:
With reference to Fig. 1, a kind of device of online rapid analysis volatile organic matter, include film sampling device 1, described film sampling device 1 arranged outside has film heating device 2, on described film heating device 2, be provided with gas access 3 and gas vent 4, the downstream of described film sampling device 1 is provided with vacuum-ultraviolet light single photon ionization source 5, the downstream of described vacuum-ultraviolet light single photon ionization source 5 is provided with focusing electrode group 6, the downstream of described focusing electrode group 6 is provided with the digital linear ion trap 7 for two-stage tandem quality analysis, the side of described digital linear ion trap 7 is provided with ion detection device 8, described ion detection device 8 is connected with data acquisition unit 9, described data acquisition unit 9 is connected with central control unit 10, described central control unit 10 also respectively with film heating device 2, vacuum-ultraviolet light single photon ionization source 5, focusing electrode group 6, digital linear ion trap 7 is connected with ion detection device 8.
The electrode of digital linear ion trap, under radio-frequency power supply drives, produces and take quadrupole field as main Electric Field Distribution.Cation or anion enter after quadrupole field, will for example, collide coolingly with collision gas (inert gas), and under the effect of electric field, are strapped in the region that hyperboloid electrode surrounds, and ion is just stored like this.When need to be to being stored in ion in ion trap while carrying out quality analysis, can load alternating voltage and the frequency on four utmost point electrodes by variation, allow the ion of different mass-to-charge ratioes excite successively by resonant excitation or border to be expelled out of (axially or radially all can), detect and record dispossessed ion signal, can obtain the result of mass spectral analysis.It is large that linear ion hydrazine has capacity than mass analyzers such as quadrupole rods, highly sensitive, the radio-frequency voltage needing during normal power supply work is lower, vacuum degree requires the multiple advantageous feature such as low, ion trap mass spectrometer also can be realized temporal cascade simultaneously, when analyzing Various Complex compound, can identify by cascade mass-spectrometric technique, there is higher selectivity.So ion strap mass analyzer can be used for quick Site Detection analysis and some has the special compound of strict restriction to instrument volume and weight.
TT&C system produces digital signal, utilizes Digital Signals high voltage switch circuit, produces the high pressure that drives digital linear ion trap.This device has avoided reduction driving voltage to cause reduction resolution, and has solved the problem that reduces digital noise.Than sine wave drive, it is high that this this device has resolution, and mass range is wide, the feature such as consume energy low, and under particular surroundings, there is the characteristic that anti-interference is high.
The ion source of digital ion trap is selected SPI ionization source, i.e. vacuum-ultraviolet light single photon ionization source.Ionized sample is often carried out with the gaseous mixture generation vacuum-ultraviolet light of Krypton and a small amount of other gases in SPI source, and single photon energy is now 10.5eV-10.6eV, higher than the ionization energy of most of organic compound, is therefore conducive to analysis and the detection of organic compound.Use this ion source under vacuum state, to use photo ionization to avoid molecular ion reaction, seldom, the spectrogram of generation is mainly molecular ion peak to fragment ion, has greatly simplified spectrogram, can directly complex sample composition be analyzed and be differentiated, be suitable as very much on-line monitoring mass ion source.
In sample introduction process, sample molecule when film inner side (being inlet side) desorption enters ionized region, thereby in film at low pressure side, carry out enrichment, cause the residual of sample molecule be the memory effect of film and easily pollute, thereby again during sample introduction, the memory effect of film will affect testing result.If in the time of more than film being heated to 150 ℃, not only can improve the infiltration rate of sample molecule on film, can also eliminate the memory effect of film, greatly improve instrumental sensitivity, make film at low pressure side dead volume little, memory-less effect.Therefore before film sampling device, add film heating device, can improve the sensitivity of digital linear ion trap, and be conducive to quick and precisely analysis of compounds.
In the utility model device, the ionization source that is placed in vacuum environment is ionizable by the sample organic substance of film.Its process is the photon that tested organic molecule is launched by absorbing SPI source, and causing outer-shell electron to be overflowed becomes ion.The focusing electrode that is positioned at ion source downstream not only can focus on transmission by sample ions and introduce digital linear ion hydrazine, and can accelerate to sample ions.
Be further used as preferred embodiment, in described digital linear ion trap 7, also include for the pulse gas generator of collision gas is provided.
In the utility model device, digital linear ion trap also further can comprise pulse gas generator, by ram charging mode, provides cooling required collision gas for digital linear ion trap.
In linear ion trap electrodes, apply rectangle high pressure, and unbalanced pulse gas generator, the sample ions and the collision gas that by focusing electrode, accelerate transmission are collided, and caught by digital linear ion trap, by the electrode to digital linear ion trap, apply dipole voltage again, produce resonant excitation, and by the frequency of rectangular voltage in scanning digital ion trap electrodes, according to mass-to-charge ratio size, selectively evict the ion in ion trap from detector, to form one-level mass spectrum.
In digital linear ion trap, apply several rectangle high pressure, and unbalanced pulse gas generator, the sample ions and the collision gas that by focusing electrode, accelerate to transmit are collided, and caught by digital linear ion trap, implement again mass of ion isolation, in trap, leave the compound of required further analysis, the compound of further analyzing is cooling, after resonant excitation, smashed, generated second order ms figure.
With reference to Fig. 2, be further used as preferred embodiment, described vacuum-ultraviolet light single photon ionization source 5 includes ionization chamber 11, and described ionization chamber 11 is arranged at the downstream of film sampling device 1 inner side, and described focusing electrode group 6 is arranged at the downstream of ionization chamber 11.
With reference to Fig. 2, be further used as preferred embodiment, described vacuum-ultraviolet light single photon ionization source 5 also includes the vacuum UV lamp that is arranged at ionization chamber 11 sides, and described vacuum UV lamp is connected with central control unit 10.
Be further used as preferred embodiment, in described film sampling device 1, use silicone rubber membrane.
In order better to improve the sensitivity detecting, ask, organic substance is waved in the online rapid analysis of the utility model device ion trap can selective membrane input mode.The selection permeability of the film of different materials is different, silicone rubber membrane (PDMS film) has high permeability to organic substance, permeability to main components such as the nitrogen in air and the aqueous solution, oxygen G&Ws is very low, use silicone rubber membrane can realize organic initial gross separation and enrichment, thus reach to volatile organic matter carry out fast, the object of High Sensitive Analysis.And it is simple in structure simultaneously, allow gas or fluid sample directly to enter into spectrometer system, without carrying out complicated sample pre-treatments, the response time is short, and sample introduction is rapid, meets the needs of on-line analysis.
With reference to Fig. 3, be further used as preferred embodiment, in described central control unit 10, include high voltagehigh frequency module, described high voltagehigh frequency module is connected with control figure linear ion hydrazine 7.
With reference to Fig. 4, be further used as preferred embodiment, described ion detection device 8 includes dynode, detector and small-signal check-out console, described central control unit 10 is connected with detector with dynode respectively, the output of described detector is connected to the input of small-signal check-out console, and described small-signal check-out console is connected with data acquisition unit 9.
Dynode, claims again dynode, dynode.Because be in (anode) anode and (cathode) between negative electrode, so English called after dynode.It is the responsive plate of a kind of electronics, by high energy electron, as after photoelectron impacts, is sent the secondary electron of a large amount of (at least 2 times), thereby causes cascade enlarge-effect.The gain of photomultiplier (generally having 7~13 dynodes) is index variation with the voltage between dynode.
Digital linear ion trap in the utility model is the mass analyzer that possesses ion storing function, and it collects ion storage, cooling, scanning, and parent ion isolation, collision induced dissociation, daughter ion scans in one.Said process completes completely in the same space, i.e. tandem mass spectrometry in time series.The tandem mass spectrometry in Traditional Space sequence, can greatly reduce the loss of ion in transmitting procedure.
The research and development success of digital linear ion trap tandem mass spectrometry has not only made up the deficiency of portable digital ion trap aspect detection isomer, can carry out step analysis and discriminating to complicated organic substance simultaneously.
On digital linear ion strap mass analyzer, apply numeral (rectangle) high pressure, and unbalanced pulse gas generator, the sample cation and the collision gas that by focusing electrode, accelerate transmission are collided, and caught by digital linear ion trap, by the electrode to digital linear ion trap, apply dipole voltage again, produce resonant excitation, by the frequency of rectangular voltage in scanning digital ion trap electrodes, according to mass-to-charge ratio size, selectively evict the ion in ion trap from detector portion.Ion detector increases ion by secondary multiplication with e index, ion signal is detected with small-signal detection mode simultaneously, and under the control of master control borad CCS, complete information interaction with PC, to form one-level mass spectrum.
Before tandem mass spectrometry, to carry out the mass spectrographic scanning of one-level, determine parent ion to be analyzed.The one-level mass spectrogram obtaining by scanning, the parent ion that selection will be isolated.
Ion trap enters tandem mass spectrometry pattern, all samples ion is introduced to ion trap cooling, is formed on the linear ion cloud that ion trap axis distributes, and kinetic energy falls and approaches zero, and now all conditions of work are with the condition in one-level mass spectral analysis.
Parent ion is comformed and is separated and be retained in ion trap in polyion, and except parent ion, the ion of other mass-to-charge ratioes is all discharged outside ion trap.The isolation of parent ion quality, can utilize SWIFT (Stored Waveform Inverse Fourier Transform) technology to realize.
Parent ion is after isolation stage, more cooling, and then on the pole piece of ion trap, applies the excitation signal close with ion resonance frequency, now parent ion vibration aggravation, so that approach very much resonance, but do not shake outside trap.Ion absorbs the energy of excitation signal in the process of resonant excitation, is converted into kinetic energy.Improve the air pressure of collision gas, collision gas molecule increases in a large number in trap, when ion and collision gas constantly bump, kinetic energy can be converted to interior energy simultaneously, interior can increase in the chemistry that overcomes ion inside can time, parent ion dissociates, formation daughter ion.
Daughter ion is caught by digital linear ion trap, by linear ion hydrazine detector portion and data acquisition unit, then generates second order ms figure.
More than that better enforcement of the present utility model is illustrated, but the utility model is created and is not limited to described embodiment, those of ordinary skill in the art can also make all equivalents or replacement under the prerequisite without prejudice to the utility model spirit, and the distortion that these are equal to or replacement are all included in the application's claim limited range.

Claims (6)

1. the device of an online rapid analysis volatile organic matter, it is characterized in that: include film sampling device (1), in described film sampling device (1), use silicone rubber membrane, described film sampling device (1) arranged outside has film heating device (2), on described film heating device (2), be provided with gas access (3) and gas vent (4), the downstream of described film sampling device (1) is provided with vacuum-ultraviolet light single photon ionization source (5), the downstream of described vacuum-ultraviolet light single photon ionization source (5) is provided with focusing electrode group (6), the downstream of described focusing electrode group (6) is provided with the digital linear ion trap (7) for two-stage tandem quality analysis, the side of described digital linear ion trap (7) is provided with ion detection device (8), described ion detection device (8) is connected with data acquisition unit (9), described data acquisition unit (9) is connected with central control unit (10), described central control unit (10) also respectively with film heating device (2), vacuum-ultraviolet light single photon ionization source (5), focusing electrode group (6), digital linear ion trap (7) is connected with ion detection device (8).
2. the device of a kind of online rapid analysis volatile organic matter according to claim 1, is characterized in that: in described digital linear ion trap (7), also include for the pulse gas generator of collision gas is provided.
3. the device of a kind of online rapid analysis volatile organic matter according to claim 1, it is characterized in that: described vacuum-ultraviolet light single photon ionization source (5) includes ionization chamber (11), described ionization chamber (11) is arranged at the downstream of film sampling device (1) inner side, and described focusing electrode group (6) is arranged at the downstream of ionization chamber (11).
4. the device of a kind of online rapid analysis volatile organic matter according to claim 3, it is characterized in that: described vacuum-ultraviolet light single photon ionization source (5) also includes the vacuum UV lamp that is arranged at ionization chamber (11) side, described vacuum UV lamp is connected with central control unit (10).
5. the device of a kind of online rapid analysis volatile organic matter according to claim 1, is characterized in that: described central control unit includes high voltagehigh frequency module in (10), and described high voltagehigh frequency module is connected with control figure linear ion hydrazine (7).
6. the device of a kind of online rapid analysis volatile organic matter according to claim 1, it is characterized in that: described ion detection device (8) includes dynode, detector and small-signal check-out console, described central control unit (10) is connected with detector with dynode respectively, the output of described detector is connected to the input of small-signal check-out console, and described small-signal check-out console is connected with data acquisition unit (9).
CN201320876307.9U 2013-12-27 2013-12-27 Device for rapid analysis of volatile organic compound online Expired - Lifetime CN203910747U (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103730325A (en) * 2013-12-27 2014-04-16 昆山禾信质谱技术有限公司 Device and method for on-line rapid analysis of volatile organic compound

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103730325A (en) * 2013-12-27 2014-04-16 昆山禾信质谱技术有限公司 Device and method for on-line rapid analysis of volatile organic compound

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Address after: 3 building, building 2, building 828, Pudong Software Park, 215311 Xueyuan Road, Kunshan, Suzhou, Jiangsu

Patentee after: KUNSHAN HEXIN MASS SPECTROMETRY TECHNOLOGY Co.,Ltd.

Patentee after: GUANGZHOU HEXIN INSTRUMENT Co.,Ltd.

Address before: 3 building, building 2, building 828, Pudong Software Park, 215311 Xueyuan Road, Kunshan, Suzhou, Jiangsu

Patentee before: KUNSHAN HEXIN MASS SPECTROMETRY TECHNOLOGY Co.,Ltd.

Patentee before: GUANGZHOU HEXIN ANALYTICAL INSTRUMENT Co.,Ltd.

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Granted publication date: 20141029

CX01 Expiry of patent term