CN203777863U - Air purifier - Google Patents
Air purifier Download PDFInfo
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- CN203777863U CN203777863U CN201320839876.6U CN201320839876U CN203777863U CN 203777863 U CN203777863 U CN 203777863U CN 201320839876 U CN201320839876 U CN 201320839876U CN 203777863 U CN203777863 U CN 203777863U
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- Prior art keywords
- air
- liquid
- gas
- air purifier
- solid
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- 239000007788 liquid Substances 0.000 claims abstract description 60
- 239000001301 oxygen Substances 0.000 claims abstract description 35
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 35
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 32
- 239000007787 solid Substances 0.000 claims abstract description 32
- 230000004913 activation Effects 0.000 claims abstract description 16
- 239000007789 gas Substances 0.000 claims description 45
- 238000013461 design Methods 0.000 claims description 14
- 238000006073 displacement reaction Methods 0.000 claims description 12
- 210000005056 cell body Anatomy 0.000 claims description 9
- 229910052751 metal Inorganic materials 0.000 claims description 9
- 239000002184 metal Substances 0.000 claims description 9
- 238000000465 moulding Methods 0.000 claims description 8
- 239000004033 plastic Substances 0.000 claims description 8
- 229920003023 plastic Polymers 0.000 claims description 8
- 230000005484 gravity Effects 0.000 claims description 4
- 230000001133 acceleration Effects 0.000 claims description 3
- 238000009826 distribution Methods 0.000 claims description 3
- 239000003054 catalyst Substances 0.000 abstract description 47
- 239000000463 material Substances 0.000 abstract description 26
- 238000001914 filtration Methods 0.000 abstract description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 20
- 230000000694 effects Effects 0.000 abstract description 11
- 230000005684 electric field Effects 0.000 abstract description 10
- 230000001954 sterilising effect Effects 0.000 abstract description 8
- 239000012528 membrane Substances 0.000 abstract description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 abstract description 5
- 238000000746 purification Methods 0.000 abstract description 5
- 239000002608 ionic liquid Substances 0.000 abstract description 4
- 150000002978 peroxides Chemical class 0.000 abstract description 3
- 238000000926 separation method Methods 0.000 abstract description 3
- 238000004887 air purification Methods 0.000 abstract description 2
- 239000002638 heterogeneous catalyst Substances 0.000 abstract description 2
- 230000000249 desinfective effect Effects 0.000 abstract 1
- 239000003344 environmental pollutant Substances 0.000 abstract 1
- 150000002366 halogen compounds Chemical class 0.000 abstract 1
- 231100000719 pollutant Toxicity 0.000 abstract 1
- 238000001179 sorption measurement Methods 0.000 abstract 1
- 239000002245 particle Substances 0.000 description 28
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 23
- 238000004140 cleaning Methods 0.000 description 18
- 230000009931 harmful effect Effects 0.000 description 12
- -1 inorganic peracid salt Chemical class 0.000 description 10
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 9
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 9
- 241000700605 Viruses Species 0.000 description 8
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 8
- 238000000034 method Methods 0.000 description 8
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- 231100000331 toxic Toxicity 0.000 description 8
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- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 7
- 230000003213 activating effect Effects 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- 150000003254 radicals Chemical class 0.000 description 6
- 229910000420 cerium oxide Inorganic materials 0.000 description 5
- 229960004643 cupric oxide Drugs 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- 239000002585 base Substances 0.000 description 4
- 230000001413 cellular effect Effects 0.000 description 4
- 230000007812 deficiency Effects 0.000 description 4
- 230000006870 function Effects 0.000 description 4
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 4
- 238000004659 sterilization and disinfection Methods 0.000 description 4
- 241000894006 Bacteria Species 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 3
- 150000003863 ammonium salts Chemical class 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- TXKMVPPZCYKFAC-UHFFFAOYSA-N disulfur monoxide Inorganic materials O=S=S TXKMVPPZCYKFAC-UHFFFAOYSA-N 0.000 description 3
- 231100001261 hazardous Toxicity 0.000 description 3
- 230000036541 health Effects 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 231100000614 poison Toxicity 0.000 description 3
- 230000007096 poisonous effect Effects 0.000 description 3
- 239000001103 potassium chloride Substances 0.000 description 3
- 235000011164 potassium chloride Nutrition 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 159000000000 sodium salts Chemical class 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical compound S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 159000000007 calcium salts Chemical class 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
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- 238000011161 development Methods 0.000 description 2
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- 125000002485 formyl group Chemical group [H]C(*)=O 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 229910001385 heavy metal Inorganic materials 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 159000000003 magnesium salts Chemical class 0.000 description 2
- 229910052748 manganese Inorganic materials 0.000 description 2
- 239000011572 manganese Substances 0.000 description 2
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 2
- 230000000813 microbial effect Effects 0.000 description 2
- 125000004430 oxygen atom Chemical group O* 0.000 description 2
- 239000012286 potassium permanganate Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 2
- 238000010099 solid forming Methods 0.000 description 2
- 239000007790 solid phase Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 230000004083 survival effect Effects 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- VIOPEXJGUFDKDZ-UHFFFAOYSA-M 1-butyl-3,5-dimethylpyridin-1-ium;bromide Chemical compound [Br-].CCCC[N+]1=CC(C)=CC(C)=C1 VIOPEXJGUFDKDZ-UHFFFAOYSA-M 0.000 description 1
- BMQZYMYBQZGEEY-UHFFFAOYSA-M 1-ethyl-3-methylimidazolium chloride Chemical compound [Cl-].CCN1C=C[N+](C)=C1 BMQZYMYBQZGEEY-UHFFFAOYSA-M 0.000 description 1
- JHWIEAWILPSRMU-UHFFFAOYSA-N 2-methyl-3-pyrimidin-4-ylpropanoic acid Chemical compound OC(=O)C(C)CC1=CC=NC=N1 JHWIEAWILPSRMU-UHFFFAOYSA-N 0.000 description 1
- HTPLIUHHIVJPGO-UHFFFAOYSA-K CCCCN1C=CN(C)C1.[B+3].[F-].[F-].[F-].F Chemical compound CCCCN1C=CN(C)C1.[B+3].[F-].[F-].[F-].F HTPLIUHHIVJPGO-UHFFFAOYSA-K 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- AFVAAKZXFPQYEJ-UHFFFAOYSA-N anthracene-9,10-dione;sodium Chemical compound [Na].C1=CC=C2C(=O)C3=CC=CC=C3C(=O)C2=C1 AFVAAKZXFPQYEJ-UHFFFAOYSA-N 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 244000052616 bacterial pathogen Species 0.000 description 1
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical class C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- MKHFCTXNDRMIDR-UHFFFAOYSA-N cyanoiminomethylideneazanide;1-ethyl-3-methylimidazol-3-ium Chemical compound [N-]=C=NC#N.CCN1C=C[N+](C)=C1 MKHFCTXNDRMIDR-UHFFFAOYSA-N 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- SOCTUWSJJQCPFX-UHFFFAOYSA-N dichromate(2-) Chemical compound [O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O SOCTUWSJJQCPFX-UHFFFAOYSA-N 0.000 description 1
- 230000005686 electrostatic field Effects 0.000 description 1
- 238000005421 electrostatic potential Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 244000144992 flock Species 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 239000002815 homogeneous catalyst Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000010954 inorganic particle Substances 0.000 description 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
- 238000005374 membrane filtration Methods 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 239000002923 metal particle Substances 0.000 description 1
- MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000006916 nutrient agar Substances 0.000 description 1
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- 230000003647 oxidation Effects 0.000 description 1
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- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000011949 solid catalyst Substances 0.000 description 1
- 239000002195 soluble material Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
Landscapes
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
Abstract
The utility model provides an air purifier. The air purifier comprises an air inlet region and an air outlet region. The air purifier is characterized in that the air inlet region is communicated with the air outlet region through an air liquid passing and oxygen activation region and a solid-liquid separation region; liquid of the air liquid passing and oxygen activation region at least comprises water, glycerol or ionic liquid; an oxygen activation catalyst is added into the liquid and oxygen in the air is activated into high-activity oxygen by the catalyst in the liquid; preferably, a solid heterogeneous catalyst is net-shaped, sieve-shaped, annular or honeycomb-shaped; the specific surface area of the solid molded catalyst is not lower than 150m<2>/g. The air purifier does not use any filtering material including a filtering membrane and an adsorption material; meanwhile, a high-voltage electric field, strong ultraviolet rays, peroxides, halogen compounds and the like, which cause secondary pollutants, are not used for disinfecting and sterilizing. The air purifier is not only suitable for indoor purification of a limited space, but also can be used for outdoor air purification of a large space, even an infinite space.
Description
Technical field
The utility model relates to a kind of air purifier.
Background technology
Air is the necessity of human survival, and when quality is normal, the mankind are to this without any sensation, and a denier air goes wrong, and the mankind will experience the importance of air at once.On the earth, mankind's gathering occupies residence, particularly industrial area and urban area, comprises China, along with economic fast development, and the progress of medical technology, the liberalization that the mankind migrate, waits many reasons, has caused the explosive growth of population.In order to maintain the survival and development of a large amount of populations of the mankind, on on the basis of current scientific and technological level, the consumption fast rise of fossil organic matter (for example oil) and coal, causes the content of dust, heavy metal particles (as mercury, chromium, cadmium, lead, nickel etc.) and the microbe granular (as virus, germ, fungi etc.) of organic particle in earth surface (we live around) gas, volatile organic matter (as aromatic hydrocarbons, formaldehyde etc.), parcel inorganic matter (as sulfuric acid, nitric acid etc.) significantly to exceed standard.In addition, the concentration of various toxic and harmfuls (as nitrogen oxide, sulfur oxide etc.) increases simultaneously constantly, adds the generation of the earth's surface inversion layer that global warming causes, and often produces haze, has a strong impact on the mankind's health.
The purification of air is that the mankind resist one of air-polluting important means, although be dependent response, but, before the mankind's science and technology does not have to realize and can avoid the technological break-through of air pollution deposits yields completely, air cleaning will also can exist for a long time in the mankind's life, and can constantly be optimized and improve.
Air cleaning, the content that comprises two aspects.The one,, remove the suspended particulates such as airborne solid and liquid, comprise various microorganisms (such as germ, virus etc.); The 2nd, remove in air, contain to the poisonous and hazardous gas component of human body, as formaldehyde, benzene, sulfur oxide, nitrogen oxide etc.Although the mankind have designed and developed out a variety of air purifiers,, all there is larger deficiency in current air cleaning system.Known air cleaning system, according to their design and technology, is mainly divided into two kinds of the first generation and the second generations, all relies on filtering technique.First generation air purifier is more original, is by filtration system, to complete the filtering type clarifier of air cleaning completely, and filter comprises sorbing material and filter membrane.Their operation principle is: by sorbing material, adsorb toxic and harmful, utilize filter membrane to come the airborne microorganism of filtering and molecule (as pm2.5 particle).First generation air purifier is more original, there are two crucial weak points: the one, need to change frequently and filter and sorbing material, the 2nd,, because filtration system does not have efficient sterilizing function, cause the germ filtering out to assemble in filtration system, these germs that flock together can, by cutting one another's throats, only have the most powerful germ to survive, be actually cultivating superbug, people's health is existed to great potential danger.Second generation air cleaning system, has obvious improvement than the first generation.Second generation air purifier is used high-energy electric field (comprising intensive ultraviolet) to realize sterilizing virus killing function, or use inorganic peracid salt (as potassium permanganate, sodium dichromate etc.) to carry out sterilization and disinfection, then by the airborne solid of filter filtering and toxic and harmful.Under individual cases, also there is the method for the washing of being designed to carry out microorganism and the non-microorganism particle in wash-out and build-up of air, then the ultraviolet ray producing by high-energy electric field (or /) and ozone carry out kill virus germ, finally by filter filtering liquid without life particle.The high-energy electric field (as electrostatic field, ultraviolet ray etc.) of second generation air purifier, their effect is for the oxygen in activating air, make it to become highly reactive form of oxygen ion, these highly reactive form of oxygen ions hit and kill airborne microorganism, or the aerosol particle of destruction haze makes it to be polymerized to bulky grain.Due to these ultraviolet ray and electrostatic potential usually up to nearly 20,000 volts, in running, can cause a large amount of ionization of air molecule, thereby produce a large amount of free radicals and ozone.Free radical and ozone have been generally acknowledged conclusions to the harm of health.Although this design is compared with the improvement that has been designed with of first generation air purifier,, still must use filter to remove solid particle, do not break away from equally the filtering material that frequent replacement cost is high.In addition, because the design of the air purifier of the first generation and the second generation all must be used filtering material, these filtering materials can produce obstruction, therefore, they cannot carry out vast scale and amplify use, and large public place is because the quantity of particulate is countless, and filtering material may just stop up after several hours completely in start, up to now, outdoor public cannot be used known air clarifier to carry out air cleaning.For example, the gas on square, power plant dispatch from the factory gas, etc. purification.Current, power plant etc. are used the boiler of coal burning, and the general purification of tail gas is simple washing just, the harmful substances such as pm2.5 particle, formaldehyde, and major part is released in air.If adopt the material absorption such as membrane filtration or resin, price is extremely high, and disposal cost surpasses even the value of generating.
The air purifier of a kind of brand-new design of human needs, it is third generation air purifier, it need to overcome the deficiency of all first generation and second generation air purifier, can meet and remove in airborne various liquid-solid particles (comprising microorganism) and air the poisonous and hazardous gas of the mankind simultaneously.The air purifier of a new generation, otherwise use filtering material, do not use ultraviolet ray and high voltage electric field to avoid producing the secondary pollution harmful substances such as free radical or ozone, preferably also can not use clorox, potassium permanganate etc. can produce the disinfectant of secondary pollution.The utility model people is under the guidance of above-mentioned three basic demands, through constantly exploring, contrast, complete on the basis of thousands of kinds of designs, success utility model goes out third generation air purifier, overcome the deficiency of the first generation and second generation air purifier, realized and do not used high voltage electric field, but can realize efficient virus killing sterilizing; Do not use filter membrane or sorbing material, but can meet, remove all particles, can remove all the time the target of toxic and harmful again simultaneously.Third generation air purifier, owing to not needing to use filtering material to remove airborne particle, so this design can be both small size home appliance, it can be again main equipment, the clarifier that purifies for the large-scale air such as public place and commercial process.
Utility model content
Technical problem to be solved in the utility model is to provide a kind of brand-new air purifier, has overcome the deficiency of the first generation and second generation air purifier, has realized and has not used high voltage electric field, just can realize efficient virus killing sterilizing.
The utility model solves the problems of the technologies described above adopted technical scheme: a kind of air purifier, and it includes Ji Chu gas area, air inlet area, it is characterized in that air inlet area crosses liquid and oxygen region of activation and gas and He Chu gas area, solid-liquid displacement zone through air and be communicated with;
Described air crosses liquid and oxygen region of activation adopts opening cell body or opening casing, and the underrun cavity of cell body or casing and air inlet area are communicated with;
In described gas and solid-liquid displacement zone, be provided with gas-liquid-solid separator, isolate gas;
Described gas-liquid-solid separator adopts artificial gravity acceleration apparatus class gas-liquid-solid separator or cyclone separator.
Preferably, described air is crossed liquid and oxygen region of activation and gas and solid-liquid displacement zone and is arranged from below to up.
Further improve, described gas-liquid-solid separator comprises gauze cone or stage body, and is arranged in the High Rotation Speed device of gauze cone or stage body top, on all bases of ring of gauze cone or stage body, is connected with the drip ring limit of up extending.
Further improve, described High Rotation Speed device, is made by plastics and metal, or adopts planar design, or adopts cone table moulding, cone table moulding, and the number of degrees of cone table angle ɑ are between 90 degree~180 degree.
Preferred again, the number of degrees of the cone table angle ɑ of described High Rotation Speed device are between 120 degree~180 degree.
Preferably, described High Rotation Speed device rotating speed is between 300 revs/min~3000 revs/min.
Preferably, described gauze cone or stage body, made by plastics or metal, and the diameter of mesh is between 1-3 millimeter.
Further improve, described gauze cone or stage body are provided with solid collection groove below its periphery.
Finally, described goes out gas area above gas and solid-liquid displacement zone, and is provided with distribution of gas dish in end face gas outlet.
Compared with prior art,
First feature of air purifier of the present utility model is not need to carry out filtering gas with filtering material, but can effectively remove airborne molecule;
Second feature of air purifier of the present utility model be, with high voltage electric field and intensive ultraviolet, do not produce ozone or free radical, contour active particle, but realized the necessary efficient virus killing sterilizing of air cleaning;
The 3rd feature of the present utility model is with sorbing material, not adsorb, but can realize all the time the target that removes toxic and harmful.
Thereby can realize, do not use high voltage electric field, just can realize efficient virus killing sterilizing, do not use filter membrane or sorbing material, just can meet and remove most particles, can realize all the time the target that removes toxic and harmful again simultaneously.
The utility model has also been realized, do not use and can produce the compound of secondary pollution, as peroxide, clorox, other halogen material, and the peracid salt of heavy metal, as permanganate, bichromate etc., but the effect of disinfection reaches the par of above-mentioned substance.
The full air purifier disclosing in the utility model, do not use expensive expendable material, for example do not need to use filter membrane to remove airborne particle, do not use the toxic and harmful in sorbing material absorbed air, so do not carry out sterilization with the compound that can produce secondary pollution yet, simultaneously, do not use again high voltage electric field or the intensive ultraviolet that can produce harmful gas, this design can be both small size home appliance, it can be again main equipment, the clarifier purifying for large-scale airs such as public place and commercial processes, practicality rational in infrastructure, use cost is low, can not bring the first generation and the side effect of second generation air purifier.
Accompanying drawing explanation
Fig. 1. the brand-new type air purifier function regional structure schematic diagram that the utility model discloses;
Fig. 2. the full air purifier that the utility model discloses forms structural representation;
Fig. 3 .1 and Fig. 3 .2. plane High Rotation Speed device top view and side schematic view;
Fig. 4. angled High Rotation Speed device side generalized section;
Fig. 5 .1 and Fig. 5 .2. gauze cone side schematic view and top view;
The specific embodiment
Below in conjunction with embodiment, the utility model is described in further detail.
As Fig. 1-5, the full air purifier that utility model discloses, as follows by functional regional division:
Functional area one is air inlet area 1: need the air of purification, through this region, enter air cleaning system.Air inlet can be negative pressure suction, can be also malleation press mode, and air inlet area is arranged on the foot space of air purifier conventionally, and the lower side of air purifier has air inlet 1.1;
Functional area two is that air is crossed liquid and oxygen region of activation 2: this region consists of opening cell body or an opening casing that holds liquid, holds the oxygen activating catalyst that is placed with solid in the cell body of liquid or casing.Oxygen activating catalyst can be prepared into graininess, netted, sieve shape, ring-type, cellular or other shape, as long as can allow air pass through, liquid can touch catalyst surface just.Catalyst is by the nano particle of manganese oxide (weight content 1-5%), cerium oxide (weight content 1-5%), cupric oxide (weight content 1-5%) and aluminium oxide (weight content 85-97%) etc., through mechanical presses, make, catalyst is netted, sieve shape, ring-type or cellular preferably, the catalyst of solid forming, specific area is not less than 150m
2/ g, solid heterogeneous catalyst, catalyst granules addition is no less than 20g/L liquid; Water-soluble homogeneous catalyst, the addition of catalyst is no less than 5g/L liquid.
The opening cell body or the interior liquid of opening casing that hold liquid can be the ionic liquids of water, glycerine or meta-alkalescence, generally, make water as selected liquid.Airborne molecule, is surrounded by liquid herein, destroys the charge layer on molecule surface, makes it to be polymerized to larger particle, airborne oxygen, be placed on the oxygen activating catalyst activation in liquid, become highly reactive form of oxygen, these highly reactive form of oxygens comprise oxygen radical (being linked together by two oxygen atoms), ozone (being linked together by 3 oxygen atoms), hydrated hydroxide root free radical (being formed by oxygen-hydrogen-hydrone), and and water, metal, the complexings such as organic matter together, the highly reactive form of oxygen particle that structure is more complicated, the effect of highly reactive form of oxygen has two, the one, kill airborne microorganism, the 2nd, destroy airborne volatile organic matter (VOC), make them be converted into water miscible material.Air is crossed the position, middle and lower part that liquid and oxygen region of activation 2 arrange air purifier, above air inlet area 1, the underrun cavity of opening cell body or opening casing and air inlet area 1 is communicated with.
Certainly, oxygen activating catalyst can be solid catalyst, can be also the material being dissolved in liquid phase.Conventional catalyst comprises that structure is suc as formula the anthraquinone salt shown in (I):
In formula (I), R
1, R
2independent is separately the substituting group of sylvite, sodium salt, ammonium salt, calcium salt or magnesium salts that sulfonic group, formyl or hydroxyl are corresponding, and the position that they replace is respectively 1,2,3,4,5,6,7,8, it can be any combination of these positions, can be two replacements, three replace, four replace, five replace, six replace, seven replace, eight replace, include, but are not limited to, for example, 1, 5-bis-replaces, 1, 6-bis-replaces, 1, 7-bis-replaces, 1, 8-bis-replaces, 2, 5-bis-replaces, 2, 6-bis-replaces, 2, 7-bis-replaces, 2, 8-bis-replaces, 3, 5-bis-replaces, 3, 6-bis-replaces, 3, 7-bis-replaces, 3, 8-bis-replaces, 4, 5-bis-replaces, 4, 6-bis-replaces, 4, 7-bis-replaces, 4, 8-bis-replaces, 1, 2-bis-replaces, 1, 3-bis-replaces, 1, 4-bis-replaces, 2, 3-bis-replaces, 2, 4-bis-replaces, 3, 4-bis-replaces etc.
Or the bis-phenol salt as shown in (II): in structural formula, M represents corresponding sylvite, sodium salt, ammonium salt; R
1, R
2independent separately be sulfonic group, formyl or halogen atom, although in the molecular structure of example, be only presented at monosubstituted on each phenyl ring, the actual 1-4 of comprising of the utility model replaces entirely, three replace, two replacements and monosubstituted,
Or the catalyst of solid state, generally comprises manganese oxide, cupric oxide, cerium oxide.These catalyst can be used separately, also can be combined use.In order to reach best catalytic effect, preferably they are prepared as to nano level graininess, be then distributed in solid phase carrier.Use separately, their the consumption generally weight content on carrier is 1-5%, and carrier often selects alkali alumina as carrier.For example, manganese oxide/aluminium oxide catalyst of 2%, cupric oxide/aluminium oxide catalyst of 5%, cerium oxide/aluminium oxide catalyst of 2%, manganese oxide-cupric oxide/aluminium oxide catalyst of 1% etc.The catalyst that three kinds of oxides upload on solid carrier simultaneously is also often used, for example manganese oxide-cupric oxide-cerium oxide/aluminium oxide catalyst.In three kinds of catalyst that simultaneously use, its component is that the weight content of nanoscale manganese oxide in catalyst is that 1-5%, the weight content of nanoscale cerium oxide in catalyst are that 1-5%, the weight content of nanoscale cupric oxide in catalyst are that 1-5%, the alumina in Nano level weight content in catalyst is 85-97%, extruding and granulation shape, netted, sieve shape, ring-type or cellular.Preferably netted, sieve shape, ring-type or cellular, the catalyst of solid forming, specific area is not less than 150m
2/ g.
In solution, possesses in addition certain dissolubility, but the low material of solubility is as oxygen activating catalyst, they are poly oxometallate (Polyoxometalates), comprise all salts that have their correspondences of higher solubility in water, include but not limited to that poly tungstates is (as [PW
12o
40]
3-anion), poly vanadium molybdate is (as [PV
2mo
10o
40]
5-anion) etc.The water soluble salt that comprises alkali metal, alkaline-earth metal and part transition metal.For example, sylvite, sodium salt, ammonium salt, calcium salt, magnesium salts, mantoquita, molysite etc.
It is at room temperature liquid ionic liquid that ionic liquid adopts, for example, chlorination-1-ethyl-3-methylimidazole (1-Ethyl-3-methylimidazoliumchloride), 1-ethyl-3-methylimidazole dicyan amine salt (1-Ethyl-3-methylimidazoliumdicyanamide), bromination-1-butyl-3, 5-lutidines (1-butyl-3, 5-dimethylpyridiniumbromide), 1-butyl-3-methylimidazole tetrafluoride boron (1-butyl-3-methylimidazoliumtetrafluoroborate), N-methyl-N-butyl hexafluorophosphate (N-methyl-N-butylpyrrolidiniumhexafluorophosphate) etc.
Functional area three is gas and solid-liquid displacement zone 3: from airborne molecule, after air is crossed liquid and oxygen region of activation, be converted into the particle that particle diameter is large; Volatile organic matter gas originally, after the oxidation of overactivation oxygen, becomes liquid; Their density can reach oxygen and density of nitrogen several thousand up to ten thousand times, utilize the difference of this density, at gas and solid-liquid displacement zone, be provided with gas-liquid-solid separator, isolate gas, be transported to out gas area 4, and liquid and solid be blocked be most possibly retained in opening cell body or opening casing to go, in object lesson, be the rotating disk that adopts High Rotation Speed, gas is completely separated with solid.Gas and solid-liquid displacement zone 3 arrange the upper position of air purifier, above air is crossed liquid and oxygen region of activation 2, and are communicated with.
The present embodiment is to adopt simple and efficient gas-liquid-solid separator, this gas-liquid-solid separator is mainly by gauze cone 3.1, and the High Rotation Speed device 3.2 that is arranged in gauze cone top combines, on all bases of ring of gauze cone 3.1, be connected with the drip ring limit 3.3 of up extending, gauze cone 3.1 is directly fixed on opening tank and opening casing, gauze cone 3.1 is made by plastics or metal, and the diameter of mesh is between 1-3 millimeter; High Rotation Speed device 3.2, by plastics and metal, made, or employing planar design, or adopt cone table moulding, cone table moulding, the number of degrees of cone table angle ɑ are between 90 degree~180 degree, and preferably, between 120 degree~180 degree, High Rotation Speed device 3.2 rotating speeds are between 300 revs/min~3000 revs/min.Solid collection groove 5 is arranged on the periphery below of gauze cone 3.1.
Can be as the means of gas-solid-liquid separation, artificial gravity acceleration apparatus (artificialgravity) except High Rotation Speed recited above, because the adjustment form areal charge of most dust particles by water distributes, particle diameter increases a lot, substantially can both be greater than 30 microns, so the separation of solid can also adopt the cyclone separator after cyclone separator (cyclonic separator) or improvement, these technological means can be with reference to traditional design.
Functional area four is gas area 4: be seated in the topmost portion of air purifier, and be communicated with gas and the solid-liquid displacement zone 3 of below, thereby can be directly upwards to give vent to anger, also can give vent to anger side.The present embodiment is to be provided with distribution of gas dish 4.1 in air purifier end face gas outlet.
The brand-new type air cleaner structure disclosing according to the utility model, designs successful air purifier as shown in Figure 2, and the effect flow process of air cleaning is as follows:
The air that outside needs purify, first through the air inlet of air inlet area, enters the holding in liquid casing (being liquid storage pool) of air purifier.Hold the catalyst that is placed with activation oxygen in liquid casing, in water, the highly reactive form of oxygen overwhelming majority of activation is present in catalyst surface, and the highly reactive form of oxygen that part is left catalyst surface is wrapped up by hydrone, and they cannot leave liquid phase.These highly reactive form of oxygens can react by the organic matter rapidly and in gas, comprise microorganism and small organic molecule, destroy their structure, thereby realize the airborne microbial disinfection malicious object of going out, and after airborne small organic molecule and active oxygen combination, be converted into high water soluble material, and can from air, be removed easily.
The air of crossing through water soaking, becomes large particle and has been converted into water miscible small organic molecule with particle diameter, under the drive of moving air, by gauze cone, is left and is held liquid casing.Gauze cone can be made by plastics or metal, and the diameter of mesh is between 1-3 millimeter.Airborne solid and liquid, when touching the wall of High Rotation Speed device, liquid and solid are accelerated to throw back gauze cone by gravity, and solid and small part liquid drop in solid collection groove along the surface of gauze cone, are removed after being accumulated to some; Most liquid is got back to and is held in liquid casing by the opening of gauze cone, and the liquid that part tumbles together with solid, is blocked on the dash limit of gauze cone, also gets back to and holds in liquid casing.
High Rotation Speed device can be made by plastics and metal, can be both planar design (as shown in Figure 3), can be also convex cone moulding (as shown in Figure 4).If use convex cone moulding, the number of degrees of cone angle ɑ, should be greater than 90 degree, approach 180 degree, more preferably greater than 120 degree, approach 180 degree.
The rotating speed of High Rotation Speed device, generally need to be higher than 500 revs/min, like this, in air the clearance of particle can reach 99.9% or more than.
Be removed the air of particle and toxic and harmful, by going out the gas outlet of gas area, leave air purifier, complete the flow process of air cleaning.
The workflow of the air purifier disclosing from the utility model can find out, novel air purifier, only needs water consumption, has just completed all air cleaning targets: remove airborne various particle, comprise inorganic particle and microbe granular; Removal, to the poisonous and hazardous gas of human body, comprises volatile organic matter; Reached simultaneously, when purifying air, do not produced any harmful secondary pollution, as ozone, free radical, halogen contained compound, peroxide etc.Owing to not using filtering material, the particle being removed in air etc., after being accumulated to some, can be taken away from air purifier, and therefore, this novel air purifier, can be used in large public place.
As no specific instructions, various raw material of the present utility model all can obtain by commercially available; Or prepare according to the conventional method of this area.Unless otherwise defined or described herein, the familiar meaning of all specialties used herein and scientific words and those skilled in the art is identical.In addition any method similar or impartial to described content and material all can be applicable in the utility model method.
Other aspects of the present utility model, due to disclosure herein, are apparent to those skilled in the art.
Below in conjunction with concrete Application Example, further set forth the utility model.Should be understood that these embodiment are only not used in restriction scope of the present utility model for the utility model is described.The experimental technique of unreceipted actual conditions in the following example, measures according to national standard conventionally.If there is no corresponding national standard, according to general international standard, normal condition or the condition of advising according to manufacturer, carry out.Unless otherwise indicated, otherwise all umbers are weight portion, and all percentages are weight percentage.
Experimental test carries out in the insulating space of 30 cubic metres, and airborne amounts of particles adopts Fluke985 corpuscular counter (particle size scope is 0.3-10.0 micron, i.e. PM0.3-PM10.0) to measure.
Airborne microbial count adopts colonometer to detect the method for total number of bacteria in air: natural sedimentation collected specimens.During sampling, the nutrient agar panel after aseptic process is placed in to sampled point, opens ware lid, in air, expose 5min, cover ware lid, upset is dull and stereotyped, after 37 ℃, 24h are cultivated, count the clump count of growing on every flat board, obtain the average clump count of whole sampled points.According to Mei Liang Si base formula difficult to understand, calculate air-borne bacteria sum.Total number of bacteria (cfu/m
3)=50000N/AT, in formula: A: platen area (cm
2); T: plate exposure time (min); N: average clump count (cfu/ plate).
Airborne volatile organic matter detects, and adopts the VOC detector of FID function, and minimum precision reaches 0.01ppm.
Application Example
According to the structure of accompanying drawing 2, build an air purifier.
Air inlet adopts negative pressure suction type, and air inflow is 600 cubic metres per hour (10 cubic meters per minute); Place 1% the aqueous sodium carbonate of 10 liters in water tank (cistern), this is in order to maintain the meta-alkalescence of liquid, because, prolongation along with service time, airborne sulfur oxide, nitrogen oxide, etc., liquid can be converted into acidity slowly, in theory, acidic materials can start the utmost point and corrode slowly the oxide in catalyst, and then have influence on the catalytic effect of catalyst, although we also observe obvious catalyst effect, do not decline, in water, put into the sieve shape catalyst (manganese oxide-aluminium oxide-cerium oxide/aluminium oxide) of 100-1000 gram; Gauze cone consists of stainless steel, aperture 1-1.5mm, and cone angle 60 degree, cone and water tank junction are disc, diameter 180mm, dash hem width degree 30mm; High Rotation Speed device adopts circular flat structure, diameter 220mm, the interval 300-3000 rev/min of variable speed.
For the consumption of catalyst and the rotating speed of High Rotation Speed device, measure air purification effect respectively.
Table 1. original air is analyzed the air cleaning result of the different High Rotation Speed device rotating speeds of Data Comparison (the closed test space of 30 cubic metres, moves 2 hours continuously, 200 grams of catalyst, the mean value of at least 3 secondary data)
Result shows, is using under the condition of 200 grams of catalyst, and rotating speed reaches 500 revs/min, and all three crucial air quality parameters, all can decline more than 99%.
Use anthraquinone salt to make oxygen activating catalyst (1,5-diphenol sodium anthraquinone, consumption is 10 grams, is dissolved in water), the operational effect of air purifier is consistent with solid-phase catalyst.
Table 2. original air is analyzed the air cleaning result of Data Comparison different catalysts consumption (the closed test space of 30 cubic metres, moves 2 hours continuously, 800 revs/min of High Rotation Speed device rotating speeds, the mean value of at least 3 secondary data)
Result shows, is using under the condition of 800 revs/min of turn ups, and when consumption reaches 200 grams of catalyst, all three crucial air quality parameters, all can decline more than 99%.
Table 3. original air is analyzed the different number of run of Data Comparison (the closed test space of 30 cubic metres, during each test, the gas of enclosure space is all original gas, each test air purifier moves 2 hours continuously, fixedly High Rotation Speed device rotating speed is 800 revs/min, 200 grams of catalyst, all data are all the mean value of at least 3 measured values) air cleaning result
Result shows, under the condition of 800 revs/min of turn ups of using High Rotation Speed device, during 200 grams of catalyst, moves continuously 100 hours, and the effect purifying air of air purifier is without any reduction, and this design effect is fine, reliable and stable.
Table 4. air purifier moves on square, at the rotating speed that uses High Rotation Speed device, be fixed as under the condition of 800 revs/min 200 grams of catalyst, every operation 24 hours, to water tank, add the pure water of 200ml, the particle weight (weight in wet base) that statistics is removed from air.
From data, can see, the air purifier that the utility model discloses, in open space, from air, remove the ability of particle, maintain for a long time stable performance, this air purifier can be for the air cleaning of outdoor public, and the consumptive material of consumption is pure water.
The closed test space that table 5. rotating speed is 800 revs/min, 30 cubes, move continuously the air cleaning result of the liquid different (mean values of at least 3 secondary data) in 2 hours, 200 grams of catalyst, liquid storage pool
Result shows, three kinds of different liquid, and the ability of air cleaning is consistent.
Claims (8)
1. an air purifier, it includes Ji Chu gas area, air inlet area, it is characterized in that air inlet area crosses liquid and oxygen region of activation and gas and He Chu gas area, solid-liquid displacement zone through air and be communicated with;
Described air crosses liquid and oxygen region of activation adopts opening cell body or opening casing, and the underrun cavity of cell body or casing and air inlet area are communicated with;
In described gas and solid-liquid displacement zone, be provided with gas-liquid-solid separator, isolate gas;
Described gas-liquid-solid separator adopts artificial gravity acceleration apparatus class gas-liquid-solid separator or cyclone separator.
2. air purifier according to claim 1, is characterized in that described air crosses liquid and oxygen region of activation and gas and solid-liquid displacement zone and arrange from below to up.
3. air purifier according to claim 1, it is characterized in that described gas-liquid-solid separator comprises gauze cone or stage body, and be arranged in the High Rotation Speed device above gauze cone or stage body, on all bases of ring of gauze cone or stage body, be connected with the drip ring limit of up extending.
4. air purifier according to claim 3, is characterized in that described High Rotation Speed device, by plastics and metal, is made, or employing planar design, or adopt cone table moulding, cone table moulding, the number of degrees of cone table angle ɑ are between 90 degree~180 degree.
5. air purifier according to claim 4, is characterized in that the number of degrees of cone table angle ɑ of described High Rotation Speed device are between 120 degree~180 degree.
6. air purifier according to claim 4, is characterized in that described gauze cone or stage body, by plastics or metal, is made, and the diameter of mesh is between 1-3 millimeter.
7. air purifier according to claim 4, is characterized in that described gauze cone or stage body are provided with solid collection groove below its periphery.
8. air purifier according to claim 1, is characterized in that described going out gas area above gas and solid-liquid displacement zone, and is provided with distribution of gas dish in end face gas outlet.
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104588127A (en) * | 2014-10-13 | 2015-05-06 | 宁波市雨辰环保科技有限公司 | Catalyst activation method |
CN104645766A (en) * | 2015-01-14 | 2015-05-27 | 宁波市雨辰环保科技有限公司 | Air filter |
WO2015089889A1 (en) * | 2013-12-18 | 2015-06-25 | 宁波市雨辰环保科技有限公司 | Air purifier |
-
2013
- 2013-12-18 CN CN201320839876.6U patent/CN203777863U/en not_active Expired - Lifetime
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2015089889A1 (en) * | 2013-12-18 | 2015-06-25 | 宁波市雨辰环保科技有限公司 | Air purifier |
CN104588127A (en) * | 2014-10-13 | 2015-05-06 | 宁波市雨辰环保科技有限公司 | Catalyst activation method |
CN104588127B (en) * | 2014-10-13 | 2018-06-05 | 宁波市雨辰环保科技有限公司 | A kind of catalyst activation process |
CN104645766A (en) * | 2015-01-14 | 2015-05-27 | 宁波市雨辰环保科技有限公司 | Air filter |
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