CN203663678U - Novel deodorant sterilizer with photocatalyst - Google Patents
Novel deodorant sterilizer with photocatalyst Download PDFInfo
- Publication number
- CN203663678U CN203663678U CN201320784382.2U CN201320784382U CN203663678U CN 203663678 U CN203663678 U CN 203663678U CN 201320784382 U CN201320784382 U CN 201320784382U CN 203663678 U CN203663678 U CN 203663678U
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- CN
- China
- Prior art keywords
- catalyst carrier
- cold catalyst
- photocatalyst
- carrier
- source body
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 239000011941 photocatalyst Substances 0.000 title claims abstract description 32
- 239000002781 deodorant agent Substances 0.000 title claims abstract description 18
- 239000003054 catalyst Substances 0.000 claims abstract description 65
- 238000006243 chemical reaction Methods 0.000 claims abstract description 14
- 230000000844 anti-bacterial effect Effects 0.000 claims description 14
- 230000003287 optical effect Effects 0.000 claims description 14
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 6
- 229910052799 carbon Inorganic materials 0.000 claims description 6
- 239000000919 ceramic Substances 0.000 claims description 6
- 229910052878 cordierite Inorganic materials 0.000 claims description 6
- JSKIRARMQDRGJZ-UHFFFAOYSA-N dimagnesium dioxido-bis[(1-oxido-3-oxo-2,4,6,8,9-pentaoxa-1,3-disila-5,7-dialuminabicyclo[3.3.1]nonan-7-yl)oxy]silane Chemical compound [Mg++].[Mg++].[O-][Si]([O-])(O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2)O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2 JSKIRARMQDRGJZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000004744 fabric Substances 0.000 claims description 6
- 230000002687 intercalation Effects 0.000 claims description 3
- 238000009830 intercalation Methods 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- DNJIEGIFACGWOD-UHFFFAOYSA-N ethanethiol Chemical compound CCS DNJIEGIFACGWOD-UHFFFAOYSA-N 0.000 abstract description 6
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 abstract description 6
- 241000894006 Bacteria Species 0.000 abstract description 3
- 230000036632 reaction speed Effects 0.000 abstract description 3
- 150000007524 organic acids Chemical class 0.000 abstract description 2
- 230000001590 oxidative effect Effects 0.000 abstract 2
- 239000003344 environmental pollutant Substances 0.000 abstract 1
- 239000002957 persistent organic pollutant Substances 0.000 abstract 1
- 231100000719 pollutant Toxicity 0.000 abstract 1
- 230000002035 prolonged effect Effects 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 239000010949 copper Substances 0.000 description 4
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 4
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
- 241000588724 Escherichia coli Species 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 229910052748 manganese Inorganic materials 0.000 description 2
- 239000011572 manganese Substances 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 229910001961 silver nitrate Inorganic materials 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 206010008631 Cholera Diseases 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- 208000037386 Typhoid Diseases 0.000 description 1
- 238000004378 air conditioning Methods 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000002158 endotoxin Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- MIVBAHRSNUNMPP-UHFFFAOYSA-N manganese(2+);dinitrate Chemical class [Mn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MIVBAHRSNUNMPP-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 230000010355 oscillation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 1
- GPNDARIEYHPYAY-UHFFFAOYSA-N palladium(ii) nitrate Chemical compound [Pd+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O GPNDARIEYHPYAY-UHFFFAOYSA-N 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000002510 pyrogen Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- OLGONLPBKFPQNS-UHFFFAOYSA-M sodium 2-(4-phenylphenyl)butanoate Chemical compound [Na+].CCC(C([O-])=O)c1ccc(cc1)-c1ccccc1 OLGONLPBKFPQNS-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 201000008297 typhoid fever Diseases 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
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- Catalysts (AREA)
Abstract
The utility model discloses a novel deodorant sterilizer with a photocatalyst. The deodorant sterilizer comprises a housing and a reaction chamber body, wherein the reaction chamber body comprises an ultraviolet light source body, a front cold catalyst carrier, a rear cold catalyst carrier, and a photocatalyst carrier; the ultraviolet light source body is arranged in the centre between the front cold catalyst carrier and the rear cold catalyst carrier; cold catalyst layers cover the front cold catalyst carrier and the rear cold catalyst carrier; a photocatalyst layer is adhered on the photocatalyst carrier. The novel deodorant sterilizer with the photocatalyst combines the photocatalyst and a cold catalyst; use time is prolonged; oxidizing reaction speed is higher than the oxidizing reaction speed of ordinary deodorisers in a low-temperature environment at high concentration of pollutants; the deodorant sterilizer can clean up organic pollutants and microbes in the air continuously and effectively, remove peculiar smell in the air, catalyze and degrade bacteria to convert into CO2, H2O and organic acid; removal ratio of ethyl mercaptan is higher than 96%; removal ratio of trimethylamine is higher than 95%; bacteriostasis rate of colibacillus is higher than 92%.
Description
Technical field
The invention belongs to and belong to nanometer purification techniques field, be specifically related to a kind of Novel photocatalyst deodorant and bactericidal unit.
Background technology
Since nano material is found, photocatalyst, as a nova of field of nanometer material technology, is widely used in catalyst field, in environmental protection, and water treatment, organic substance degraded, there is important application the aspects such as inefficacy degradation of pesticide.Nano-TiO
2, Cu
+, Ag
+aspect the decoration of refrigerator, air-conditioning, medicine equipment, operating room, be widely used, general conventional bactericide Cu
+, Ag
+deng killing after bacterium, discharge pyrogenicity and poisonous component endotoxin, may cause the diseases such as typhoid fever cholera.Photocatalyst normally presents pulverulent solids or lyosol simultaneously, therefore, need to provide and be convenient to the carrier that photocatalyst adheres to, but the amount of the photocatalyst carrying due to existing catalyst carrier is little, effect is very weak, and the utilization rate of photocatalyst is very low, and the result of use of product is bad.
Summary of the invention
The object of the invention is to solve above-mentioned problems of the prior art, a kind of Novel photocatalyst deodorant and bactericidal unit is provided.
The object of the invention is to be achieved through the following technical solutions:
A kind of Novel photocatalyst deodorant and bactericidal unit, comprise housing and reaction cavity, described reaction cavity is made up of ultraviolet source body and front cold catalyst carrier, rear cold catalyst carrier, optical catalyst carrier, and described ultraviolet source body is located at the central authorities of described front cold catalyst carrier, rear cold catalyst carrier; On described front cold catalyst carrier and rear cold catalyst carrier, be coated with cold catalyst layer, described optical catalyst carrier adheres to photocatalyst layer.
Described front cold catalyst carrier and rear cold catalyst carrier are cordierite honeycomb ceramic sheet; Described cold catalyst layer is that two or more combinations in Cu, Mn, Ni, Fe, Zn or Pt are coated on cold catalyst carrier and make.
Described optical catalyst carrier is carbon cloth, the porosity 60-80% of described carbon cloth, density 0.50-1.6g/cm
3, thickness 2-3mm.
Described photocatalyst layer is coated on optical catalyst carrier by nano titanium oxide silver-doped ion and makes.
Described ultraviolet source body is 1-3 LED uviol lamp, and the wavelength of described LED uviol lamp is 365-385nm, and power is 0.2W.
The bottom of described reaction cavity is set to metal reflective plate, for ultraviolet reflection of light, and the utilization ratio of raising ultraviolet light.
Described ultraviolet source body, front cold catalyst carrier, rear cold catalyst carrier and optical catalyst carrier intercalation are in housing, for convenience detach.
Compared to the prior art, beneficial effect of the present invention:
Novel photocatalyst deodorant and bactericidal unit of the present invention, in conjunction with photocatalyst and cold catalyst, extend service time, under low temperature environment, when high pollution substrate concentration, oxidation reaction speed, higher than common deodoriser, can continue, remove efficiently airborne organic pollution and microorganism, can also remove airborne peculiar smell, catalytic degradation bacterium is converted into CO
2, H
2o and organic acid, ethyl mercaptan clearance is greater than 96%; Trimethylamine clearance is greater than 95%; Escherichia coli bacteriostasis rate is greater than to 92%.
Brief description of the drawings
Fig. 1 is the structural representation of Novel photocatalyst deodorant and bactericidal unit of the present invention.
In Fig. 1,1-housing, 2-optical catalyst carrier, cold catalyst carrier before 3.1-, cold catalyst carrier after 3.2-, 4-ultraviolet source body, 5-reaction cavity.
Detailed description of the invention
By specific embodiment, the present invention is further expalined to explanation.
As described in Figure 1, a kind of Novel photocatalyst deodorant and bactericidal unit, comprise housing 1 and reaction cavity 5, described reaction cavity 5 is made up of ultraviolet source body 4 and front cold catalyst carrier 3.1, rear cold catalyst carrier 3.2, optical catalyst carrier 2, and described ultraviolet source body 4 is located at the central authorities of described front cold catalyst carrier 3.1, rear cold catalyst carrier 3.2; On described front cold catalyst carrier 3.1 and rear cold catalyst carrier 3.2, be coated with cold catalyst layer, described optical catalyst carrier 2 adheres to photocatalyst layer; Described ultraviolet source body, front cold catalyst carrier, rear cold catalyst carrier and optical catalyst carrier intercalation are in housing.
Described front cold catalyst carrier 3.1 and rear cold catalyst carrier 3.2 are cordierite honeycomb ceramic sheet, and the concrete specification of described cordierite honeycomb ceramic sheet is: mesh: 300-400 hole, size: 69 × 36 × 10mm.
Described cold catalyst layer is that two or more combinations in Cu, Mn, Ni, Fe, Zn or Pt are coated on cordierite honeycomb ceramic sheet and make.
The preparation of the cold catalyst layer of the present embodiment:
9 grams, copper sulphate, 15 grams of manganese nitrates, 0.2 gram of palladium nitrate is dissolved in deionized water, mixes, be coated on cordierite ceramic sheet, at 120-260 DEG C of temperature, dry 1-3 hour, cooling.
Described optical catalyst carrier 2 is carbon cloth, the porosity 60-80% of described carbon cloth, density 0.50-1.6g/cm
3, thickness 2-3mm, the concrete specification of described carbon cloth is: size 90 × 40 × 3mm.
Described photocatalyst layer is coated on optical catalyst carrier by nano titanium oxide silver-doped ion and makes.
The preparation of photocatalyst layer described in the present embodiment:
5 grams of nano titanium oxides, 0.1 gram of silver nitrate, 15 milliliters of absolute alcohols, 200 milliliters of deionized waters, nano titanium oxide, silver nitrate add appropriate amount of deionized water and mix, and disperse 15 minutes in ultrasonic oscillation device, then be transferred to 500 milliliters of reactors, add absolute alcohol and excess water, heat up, open mixer, open condensed water, keep reactant liquor to reflux, reaction temperature 170-180 DEG C is reacted 2 hours, stop reaction, cooling, filtration, dry.
Described ultraviolet source body 4 is 2 LED uviol lamps, and the wavelength of described LED uviol lamp is 365-385nm, and power is 0.2W.
The bottom of described reaction cavity 5 is set to metal reflective plate, for ultraviolet reflection of light, and the utilization ratio of raising ultraviolet light.
In application the present invention, install ethyl mercaptan clearance 96.6%; Trimethylamine clearance 95.4%; To Escherichia coli bacteriostasis rate 92.1%.
Claims (6)
1. a Novel photocatalyst deodorant and bactericidal unit, it is characterized in that comprising housing and reaction cavity, described reaction cavity is made up of ultraviolet source body and front cold catalyst carrier, rear cold catalyst carrier, optical catalyst carrier, and described ultraviolet source body is located at the central authorities of described front cold catalyst carrier, rear cold catalyst carrier; On described front cold catalyst carrier and rear cold catalyst carrier, be coated with cold catalyst layer, described optical catalyst carrier adheres to photocatalyst layer.
2. Novel photocatalyst deodorant and bactericidal unit according to claim 1, is characterized in that described front cold catalyst carrier and rear cold catalyst carrier are cordierite honeycomb ceramic sheet.
3. Novel photocatalyst deodorant and bactericidal unit according to claim 1, is characterized in that described optical catalyst carrier is carbon cloth.
4. Novel photocatalyst deodorant and bactericidal unit according to claim 1, is characterized in that described ultraviolet source body is 1-3 LED uviol lamp.
5. Novel photocatalyst deodorant and bactericidal unit according to claim 1, is characterized in that the bottom of described reaction cavity is set to metal reflective plate.
6. Novel photocatalyst deodorant and bactericidal unit according to claim 1, is characterized in that described ultraviolet source body, front cold catalyst carrier, rear cold catalyst carrier and optical catalyst carrier intercalation are in housing.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201320784382.2U CN203663678U (en) | 2013-12-03 | 2013-12-03 | Novel deodorant sterilizer with photocatalyst |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201320784382.2U CN203663678U (en) | 2013-12-03 | 2013-12-03 | Novel deodorant sterilizer with photocatalyst |
Publications (1)
Publication Number | Publication Date |
---|---|
CN203663678U true CN203663678U (en) | 2014-06-25 |
Family
ID=50960013
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201320784382.2U Expired - Lifetime CN203663678U (en) | 2013-12-03 | 2013-12-03 | Novel deodorant sterilizer with photocatalyst |
Country Status (1)
Country | Link |
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CN (1) | CN203663678U (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107091499A (en) * | 2017-05-12 | 2017-08-25 | 程艳青 | A kind of multi-staged air cleaning system |
CN109647060A (en) * | 2018-12-05 | 2019-04-19 | 广东炜田环保新材料股份有限公司 | A kind of high-efficient energy-saving environment friendly health formula idle call filtering material |
-
2013
- 2013-12-03 CN CN201320784382.2U patent/CN203663678U/en not_active Expired - Lifetime
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107091499A (en) * | 2017-05-12 | 2017-08-25 | 程艳青 | A kind of multi-staged air cleaning system |
CN109647060A (en) * | 2018-12-05 | 2019-04-19 | 广东炜田环保新材料股份有限公司 | A kind of high-efficient energy-saving environment friendly health formula idle call filtering material |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
CX01 | Expiry of patent term | ||
CX01 | Expiry of patent term |
Granted publication date: 20140625 |