CN203606180U - Rainfall contact type runoff automatic sampling device - Google Patents
Rainfall contact type runoff automatic sampling device Download PDFInfo
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- CN203606180U CN203606180U CN201320777269.1U CN201320777269U CN203606180U CN 203606180 U CN203606180 U CN 203606180U CN 201320777269 U CN201320777269 U CN 201320777269U CN 203606180 U CN203606180 U CN 203606180U
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Abstract
The utility model relates to a rainfall contact type runoff automatic sampling device which can be used for carrying out fixed-time automatic monitoring of rainstorm runoff in the field of environmental monitoring or the field of water and soil conservation. According to the sampling device, the whole sampling device is controlled by a rainfall triggering device; when the rainfall amount reaches a pre-set value, a PLC (Programmable Logic Controller) is used for sequentially starting up a stepping motor, a water pump, a peristaltic pump and the like to collect runoff water samples at different time periods and different point locations according to pre-set steps and time intervals, and distributing the runoff water samples to corresponding sampling bottles to be stored. The rainfall contact type runoff automatic sampling device can be mounted adjacently to a river needing to be sampled in advance and the collection work of the runoff water samples under an unattended condition can be automatically finished during a rainstorm period, so that the wild sampling difficulty of the rainstorm runoff can be realized and the working amount of sampling workers is relieved; the device also has the advantages of high sample reliability, low production cost and compact structure.
Description
Technical field
The utility model relates to water sampler, relates in particular to a kind of rainfall trigger-type runoff automatic sampler.
Background technology
It is one of important factor of pollution of area source that the pollutant that storm runoff produces runs off, but the sampling work of storm runoff generally all needs to carry out in the wild, and sampling condition is comparatively arduous.And the uncertainty of rainfall has caused the adequate preparation of cannot carrying out of sampling work, sample collector cannot rush for sampling position at short notice, although storm runoff can be effectively monitored in the sampling of working at a selected spot for a long time, need to expend a large amount of manpower and materials; In addition, rainfall period especially, between storm period, is often accompanied by the inclement weather such as strong wind, thunder and lightning, and when artificial sample, sample collector's safety cannot be ensured.
At present, partial monopoly is attempted storm runoff sampling apparatus, although early stage sampling apparatus has facilitated sample collector's work to a certain extent, but there is no automatic sampling functions, needs artificial timing to sample; Along with the development of automatic technology, automatic sampling device was by more developing in recent years.
(application number is 200510048184.X to be for example called " automatic sampling system for storm runoff in small watershed ", publication number is 1789954) patent, by travel switch, motor, bypass channel, mozzle etc., under the control of timing relay, timing is extracted runoff sample in river course by water pump and is injected successively sampling bottle; The patent of " automatic timing water sampling device " (application number is 201110108855.2, and publication number is 102759461A) by name, utilizes stepper motor drive shaft tube, drives water diversion disk to realize sample timing acquiring.Such device has improved the automaticity of sampling greatly, has alleviated workload.Although but in sampling process, device can be realized robotization, its startup work still needs sample collector's manual operation, this gives and cannot predict rain time and sampling distance field sampling work far away brings a very large difficult problem.
For this problem, also there is Many researchers to develop corresponding device.
(application number is 201010101367.4 to be for example called " a kind of automatic urban rainfall runoff sampler ", publication number is 101762409A) patent, it cooperatively interacts by rainfall sensor, stepper motor able to programme, rainfall gathering-device and rotating shaft, realize the Automatic continuous timing sampling of rainwater between flush period, but because its rainfall collection system does not have propulsion system, can only rely on the self gravitation of rainwater to fall, therefore limit its usable range, cannot be used for the collection of sewer line, rainwash etc.; And the annular design of its sampling bottle, makes its space availability ratio lower, limit the quantity that sampling bottle can be placed." automatic rain water collection sampling by name
Device " patent of (application number is 201310220616.5; publication number is 103335868A); its core is made up of rain gage, single-chip microcomputer, solenoid valve, submersible pump; by the Based Intelligent Control of single-chip microcomputer; can realize the automatic collection of rainwater or runoff water; but described in the same example, its space availability ratio is also lower.More seriously, according to environmental monitoring standard, when river width and the degree of depth are greater than certain value, the method that should take multidraw to mix, if and have residual sample in sampling thief or sampling bottle when water sampling, application target water sample carries out rinse, after sample collection, should add immediately preservative agent, the metabolic activity that prevents microorganism affects pollutant levels in sample, and above-mentioned two patents and most of similar sampling apparatus, all do not possess this class function, therefore, in actual monitoring, the sample accuracy obtaining with such device and reliability reduce.
In addition, along with the progress of green technology, a lot of very high instruments of automaticity all have finished product, but it involves great expense, and therefore high cost for common monitoring develops that a kind of to be applicable to the device that field storm runoff samples automatically imperative.
Summary of the invention
In order to solve the problem facing in background technology, the purpose of this utility model is to provide a kind of rainfall trigger-type runoff automatic sampler.
Rainfall trigger-type runoff automatic sampler comprises casing, sampling bottle putting hole, supporting network, osculum, divider wall, back up pad, waste liquid diversion trench, mozzle, threaded screw rod, sampling bottle, rubber hose, X-axis stepper motor, slide block, y-axis stepper motor, silicone tube, the supporting power supply of PLC, stepper motor driver, preserve liquid holding bottle, PLC controller, 24V power supply, peristaltic pump, water pump, pvc pipe, multiport valve, feed tube, screen pack, travel switch, buzzer siren, warning lamp, handle, drain pipe, rainfall flip flop equipment,
Bottom half is provided with vertical divider wall, between divider wall one side and cabinet wall, be provided with supporting network, the wall box of supporting network below is provided with osculum, the wall box of supporting network top is provided with travel switch, supporting network is provided with several sampling bottle putting holes, sampling bottle is placed in sampling bottle putting hole, a waste liquid diversion trench is set before every row's sampling bottle putting hole, sampling bottle top is provided with two threaded screw rods that are decussation, threaded screw rod end is separately installed with X-axis stepper motor and y-axis stepper motor, article two, on threaded screw rod, be all installed with a coupling slide block, the threaded screw rod of Y direction is fixed on the slide block of X-direction, between the cabinet wall of divider wall opposite side, be provided with back up pad, the supporting power supply of PLC is placed in back up pad below, stepper motor driver, preserve liquid holding bottle, PLC controller, back up pad is provided with 24V power supply, peristaltic pump, water pump, peristaltic pump import is connected with drain pipe with preservation liquid holding bottle respectively by silicone tube with outlet, pump outlet is through mozzle, rubber hose is connected with drain pipe one end, drain pipe is fixed on slide block, the liquid outlet of drain pipe is above sampling bottle, pump intake is through pvc pipe, multiport valve is connected with feed tube one end, the feed tube other end is provided with screen pack, casing top is provided with buzzer siren, , warning lamp, handle, rainfall flip flop equipment, PLC controller is connected on the supporting power supply of PLC by travel switch and rainfall flip flop equipment, PLC controller and stepper motor driver simultaneously, water pump, peristaltic pump is connected, stepper motor driver and X-axis stepper motor, y-axis stepper motor is connected, water pump, buzzer siren, warning lamp is all connected with 24V power supply by travel switch, peristaltic pump is directly connected on 24V power supply.
Described rainfall flip flop equipment comprises water-collecting tray, the post that catchments, electrolyte, electrode, rule, wire, base, catchment post, rule is arranged on base, the column bottom of catchmenting is provided with electrolyte, the post top of catchmenting is provided with electrode, electrode is connected in the feed circuit of PLC controller by wire, and the column top of catchmenting connects water-collecting tray.
The beneficial effects of the utility model are automatic sampling works of storm runoff of having realized in unmanned situation, greatly reduce the difficulty of storm runoff field sampling, have alleviated sample collector's workload.Meanwhile, the multiple spot mixed sample acquisition function of this device and preservative agent add function and have also improved accuracy and the science of sample collection automatically.And this apparatus structure compactness, easy for installation, and compared with having the device of function of the same type, cost is lower, is applicable to field sampling.
Accompanying drawing explanation
Below in conjunction with drawings and Examples, the utility model is described in further detail;
Fig. 1 is the structural representation of rainfall trigger-type runoff automatic sampler;
Fig. 2 is vertical view of the present utility model;
Fig. 3 is the floor plan of the utility model inside;
Fig. 4 is the structural representation of rainfall flip flop equipment of the present utility model;
Fig. 5 is multi-way valve structure schematic diagram of the present utility model;
In figure: casing 1, sampling bottle putting hole 2, supporting network 3, osculum 4, divider wall 5, back up pad 6, waste liquid diversion trench 7, water-collecting tray 8, post 9 catchments, electrolyte 10, electrode 11, mozzle 12, threaded screw rod 13, sampling bottle 14, rubber hose 15, X-axis stepper motor 16, slide block 17, y-axis stepper motor 18, silicone tube 19, the supporting power supply 20 of PLC, stepper motor driver 21, preserve liquid holding bottle 22, PLC controller 23, 24V power supply 24, peristaltic pump 25, water pump 26, pvc pipe 27, multiport valve 28, feed tube 29, screen pack 30, travel switch 31, buzzer siren 32, warning lamp 33, handle 34, rule 35, wire 36, base 37, drain pipe 38.
Embodiment
Below in conjunction with accompanying drawing, the technical solution of the utility model is described further.
As Figure 1-5, rainfall trigger-type runoff automatic sampler comprises casing 1, sampling bottle putting hole 2, supporting network 3, osculum 4, divider wall 5, back up pad 6, waste liquid diversion trench 7, mozzle 12, threaded screw rod 13, sampling bottle 14, rubber hose 15, X-axis stepper motor 16, slide block 17, y-axis stepper motor 18, silicone tube 19, the supporting power supply 20 of PLC, stepper motor driver 21, preserve liquid holding bottle 22, PLC controller 23, 24V power supply 24, peristaltic pump 25, water pump 26, pvc pipe 27, multiport valve 28, feed tube 29, screen pack 30, travel switch 31, buzzer siren 32, warning lamp 33, handle 34, drain pipe 38, rainfall flip flop equipment, casing 1 bottom is provided with vertical divider wall 5, between divider wall 5 one sides and casing 1 inwall, be provided with supporting network 3, casing 1 sidewall of supporting network 3 belows is provided with osculum 4, casing 1 sidewall of supporting network 3 tops is provided with travel switch 31, supporting network 3 is provided with several sampling bottle putting holes 2, sampling bottle 14 is placed in sampling bottle putting hole 2, before every row's sampling bottle putting hole 2, a waste liquid diversion trench 7 is set, sampling bottle top is provided with two threaded screw rods 13 that are decussation, threaded screw rod 13 ends are separately installed with X-axis stepper motor 16 and y-axis stepper motor 18, article two, on threaded screw rod 13, be all installed with a coupling slide block 17, the threaded screw rod 13 of Y direction is fixed on the slide block 17 of X-direction, between casing 1 inwall of divider wall 5 opposite sides, be provided with back up pad 6, the supporting power supply 20 of PLC is placed in back up pad 6 belows, stepper motor driver 21, preserve liquid holding bottle 22, PLC controller 23, back up pad 6 is provided with 24V power supply 24, peristaltic pump 25, water pump 26, peristaltic pump 25 imports are connected with drain pipe 38 with preservation liquid holding bottle 22 respectively by silicone tube 19 with outlet, water pump 26 water delivering orifices are through mozzle 12, rubber hose 15 is connected with drain pipe 38 one end, drain pipe 38 is fixed on slide block 17, the liquid outlet of drain pipe 38 is above sampling bottle 14, water pump 26 water inlets are through pvc pipe 27, multiport valve 28 is connected with feed tube 29 one end, feed tube 29 other ends are provided with screen pack 30, casing 1 top is provided with buzzer siren 32, , warning lamp 33, handle 34, rainfall flip flop equipment, PLC controller 23 is connected on the supporting power supply 20 of PLC by travel switch 31 and rainfall flip flop equipment, PLC controller 23 and stepper motor driver 21 simultaneously, water pump 26, peristaltic pump 25 is connected, stepper motor driver 21 and X-axis stepper motor 16, y-axis stepper motor 18 is connected, water pump 26, buzzer siren 32, warning lamp 33 is all connected with 24V power supply 24 by travel switch 31, peristaltic pump 25 is directly connected on 24V power supply 24.
Described rainfall flip flop equipment comprises water-collecting tray 8, the post 9 that catchments, electrolyte 10, electrode 11, rule 35, wire 36, base 37, catchment post 9, rule 35 is installed on base 37, post 9 bottoms of catchmenting are provided with electrolyte 10, post 9 tops of catchmenting are provided with electrode 11, electrode 11 is connected in the feed circuit of PLC controller 23 by wire 36, and post 9 tops of catchmenting connect water-collecting tray 8.
In the utility model, to adopt commercially available model be the controller of the FX3U-80MR/DS of Mitsubishi to PLC controller 23, it can adopt Mitsubishi's GX Developer software to programme, the supporting power supply 20 of PLC adopts commercially available 24V UPS power supply, and the elements such as X-axis stepper motor 16, y-axis stepper motor 18, stepper motor driver 21,24V power supply 24, peristaltic pump 25, travel switch 31 are commercially available prod.
Described casing 1, shape is rectangular parallelepiped, and top is can Unclosing structure, and handle 34 is housed, and the convenient post-sampling personnel that sampled take out sample; Divider wall 5 in casing 1 is water-tight structure, can, by casing 1 dimidiation, prevent the various electronic components of the Water Damage splashing; Described rainfall flip flop equipment is connected in PLC control circuit, carrys out the startup of control PLC controller 23 and closes by changing the feed circuit on off operating mode of PLC controller 23; The water-collecting tray 8 on its top is back taper, to centroclinal, is convenient to rainwater to inject the post 9 that catchments; Wire 36 penetrates by the default aperture in post 9 upper ends that catchments post 9 inner sides being connected with two electrodes 11 of catchmenting, two electrodes 11 do not contact each other, wire 36 is fixed on rule 35, can contrast rule 35, by moving up and down to adjust electrode 11 at the interior residing height of the post 9 that catchments, in the time being dissolved with the rainwater of electrolyte 10 and not having electrode 11 bottom, circuit just can be switched on.Described PLC controller 23 can, by programming in advance, change sampling interval and control sequence.Described multiport valve 28 is four to enter one and go out structure, and each water inlet has controlled valve, can sampled point quantity as required select to open quantity.
The automatic method of sampling of rainfall trigger-type runoff comprises the steps:
1) press time interval of sampling request, utilize supporting PLC programming software to programme in advance to PLC controller 23;
2) comparatively smooth plot is chosen on the bank, river course of sampling at needs, by the placement of sampling thief level on the ground;
3) the sampled point quantity required according to sampling request, opens or closes the controlled valve of corresponding multiport valve 28 water inlets, and feed tube 29 ends is positioned over to the relevant position of target sampled point;
4) according to the projected area of water-collecting tray 8, the projected area of the post 9 that catchments and the minimum rainfall amount of sampling request, conversion obtains electrode 11 bottoms at the height at post 9 planted agent places that catchments, contrast rule 35, is adjusted to corresponding height by moving up and down wire 36 by electrode 11;
5) after rainfall starts, post 9 middle water levels of catchmenting rise, flooded behind electrode 11 bottoms, PLC controller 23 feed circuit are connected, PLC controller 23 is controlled X-axis stepper motor 16 successively according to the step of setting, y-axis stepper motor 18, water pump 26, peristaltic pump 25, gather multiple spot water sample and distribute and preserve, after sampling finishes, open casing 1 taking-up and more renew sampling bottle 14, and reset stroke switch 31, PLC controller 23, pour out the rainwater that rainfall trigger catchments in post 9, change electrolyte 10, sampling is not over yet after last sampling bottle 14 sampling work if complete, travel switch 31 commutation circuits, sampling work stops, alarm signal is sent, in time open casing 1 by the handle 34 of casing 1 top, more renew sampling bottle 14, and reset stroke switch 31 and PLC controller 23, continue sampling.
The course of work of the present utility model is as follows: place sampling thief according to sampling thief using method, when original state, as shown in Figure 2, drain pipe outlet is positioned at first row waste liquid diversion trench 7 center lines and first row sampling bottle 14 center line intersection point places.After rainfall starts, the water-collecting tray 8 of rainfall flip flop equipment starts to collect rainwater, fall into the post 9 that catchments, and the electrolyte 10 of post 9 bottoms of catchmenting is dissolved in rainwater, in the time that the rainwater water level catchmenting in post 9 arrives the position at electrode 11 places, bottom, due to the electric action of electrolyte solution, electrode 11 is switched on, the PLC controller 23 being connected on the supporting power supply 20 of PLC is powered, and starts to start.According to the time of prior setting and boot sequence, PLC controller 23 starts water pump 26, sampled point water sample flows out by feed tube 29, multiport valve 29, pvc pipe 27, water pump 26, mozzle 12, rubber hose 15 and drain pipe 38 successively, water sample residual in pipeline is discharged by target water sample, reach rinse object, waste liquid is discharged by waste liquid diversion trench 7 and osculum 4; Then PLC controller 23 switches off the pump 26, and control step motor driver 21 is worked, make stepper motor driver 21 send pulse to y-axis stepper motor 18, control slide block 17 and carry out fixed length motion, drain pipe 38 outlets arrive directly over first sampling bottle 14, PLC controller 23 starts water pump 26 again, by in water sample suction sampling bottle 14, after collection, PLC controller 23 stops water pump 26, open peristaltic pump 25, according to the preservation liquid addition of prior setting, by silicone tube 19 and feed tube 38, preservation liquid is quantitatively added in sampling bottle 14; After preserving liquid interpolation, PLC controller 23 again control step motor driver 21 is worked, make stepper motor driver 21 send pulse to y-axis stepper motor 18, controlling slide block 17 moves, drain pipe 12 is moved to directly over second row waste liquid diversion trench 7, so far complete the collection of an instantaneous water sample.According to the sampling time interval of prior setting, reach after the sampling time next time, PLC controller 23 starts again, completes second sampling according to said sequence.Preserve after liquid interpolation when completing last sampling bottle 14 of Y-axis first row, PLC controller 23 control step motor drivers 21, make it send pulse to y-axis stepper motor 18 and X-axis stepper motor 16 successively, make the liquid outlet of feed tube 38 move to first row waste liquid diversion trench 7 center lines and secondary series sampling bottle 14 center line intersection point places, then sample by sampling routine.After having sampled, should, according to described in sampling thief using method, take out sample reset samples device.
Claims (2)
1. a rainfall trigger-type runoff automatic sampler, it is characterized in that comprising casing (1), sampling bottle putting hole (2), supporting network (3), osculum (4), divider wall (5), back up pad (6), waste liquid diversion trench (7), mozzle (12), threaded screw rod (13), sampling bottle (14), rubber hose (15), X-axis stepper motor (16), slide block (17), y-axis stepper motor (18), silicone tube (19), the supporting power supply of PLC (20), stepper motor driver (21), preserve liquid holding bottle (22), PLC controller (23), 24V power supply (24), peristaltic pump (25), water pump (26), pvc pipe (27), multiport valve (28), feed tube (29), screen pack (30), travel switch (31), buzzer siren (32), warning lamp (33), handle (34), drain pipe (38), rainfall flip flop equipment,
Casing (1) bottom is provided with vertical divider wall (5), between divider wall (5) one sides and casing (1) inwall, be provided with supporting network (3), casing (1) sidewall of supporting network (3) below is provided with osculum (4), casing (1) sidewall of supporting network (3) top is provided with travel switch (31), supporting network (3) is provided with several sampling bottle putting holes (2), sampling bottle (14) is placed in sampling bottle putting hole (2), every row's sampling bottle putting hole (2) arranges a waste liquid diversion trench (7) before, sampling bottle top is provided with two threaded screw rods (13) that are decussation, threaded screw rod (13) end is separately installed with X-axis stepper motor (16) and y-axis stepper motor (18), article two, on threaded screw rod (13), be all installed with a coupling slide block (17), the threaded screw rod (13) of Y direction is fixed on the slide block (17) of X-direction, between casing (1) inwall of divider wall (5) opposite side, be provided with back up pad (6), the supporting power supply of PLC (20) is placed in back up pad (6) below, stepper motor driver (21), preserve liquid holding bottle (22), (PLC) controller (23), back up pad (6) is provided with 24V power supply (24), peristaltic pump (25), water pump (26), peristaltic pump (25) import is connected with drain pipe (38) with preservation liquid holding bottle (22) respectively by silicone tube (19) with outlet, water pump (26) water delivering orifice is through mozzle (12), rubber hose (15) is connected with drain pipe (38) one end, drain pipe (38) is fixed on slide block (17), the liquid outlet of drain pipe (38) is in sampling bottle (14) top, water pump (26) water inlet is through pvc pipe (27), multiport valve (28) is connected with feed tube (29) one end, feed tube (29) other end is provided with screen pack (30), casing (1) top is provided with buzzer siren (32), warning lamp (33), handle (34), rainfall flip flop equipment, PLC controller (23) is connected on the supporting power supply of PLC (20) by travel switch (31) and rainfall flip flop equipment, PLC controller (23) and stepper motor driver (21) simultaneously, water pump (26), peristaltic pump (25) is connected, stepper motor driver (21) and X-axis stepper motor (16), y-axis stepper motor (18) is connected, water pump (26), buzzer siren (32), warning lamp (33) is all connected with 24V power supply (24) by travel switch (31), peristaltic pump (25) is directly connected on 24V power supply (24).
2. a kind of rainfall trigger-type runoff automatic sampler according to claim 1, it is characterized in that described rainfall flip flop equipment comprises water-collecting tray (8), post (9) catchments, electrolyte (10), electrode (11), rule (35), wire (36) and base (37), post (9) catchments, rule (35) is arranged on base (37), catchment post (9) bottom is provided with electrolyte (10), post (9) top of catchmenting is provided with electrode (11), electrode (11) is connected in the feed circuit of PLC controller (23) by wire (36), post (9) top connection water-collecting tray (8) catchments.
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| CN201320777269.1U CN203606180U (en) | 2013-12-02 | 2013-12-02 | Rainfall contact type runoff automatic sampling device |
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| CN201320777269.1U CN203606180U (en) | 2013-12-02 | 2013-12-02 | Rainfall contact type runoff automatic sampling device |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103698159A (en) * | 2013-12-02 | 2014-04-02 | 浙江大学 | Raindrop triggering type runoff automatic sampling device and method |
| CN104964853A (en) * | 2015-07-20 | 2015-10-07 | 清华大学深圳研究生院 | Event mean concentration sampler |
| CN106525510A (en) * | 2016-11-03 | 2017-03-22 | 温岭市职业技术学校 | Timing sampler and method for runoff samples on basis of rainfall amount control |
| CN107764591A (en) * | 2017-09-30 | 2018-03-06 | 黄河流域水土保持生态环境监测中心 | A kind of small watershed bayonet socket station runoff and sediment automatic sampling system |
| CN108680402A (en) * | 2018-05-18 | 2018-10-19 | 山东建筑大学 | A kind of greenery patches runoff automatic sampling device and method |
| CN109000976A (en) * | 2018-07-06 | 2018-12-14 | 中国水利水电科学研究院 | Storm runoff samples automatically, monitoring device and method |
| CN110220751A (en) * | 2019-07-08 | 2019-09-10 | 深圳市海德邦科技有限公司 | A kind of Water quality automatic sampling device that can remotely monitor |
| CN112798753A (en) * | 2021-03-26 | 2021-05-14 | 湖南慧泽生物医药科技有限公司 | Automatic digestion instrument and sampling device thereof |
-
2013
- 2013-12-02 CN CN201320777269.1U patent/CN203606180U/en not_active Withdrawn - After Issue
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103698159A (en) * | 2013-12-02 | 2014-04-02 | 浙江大学 | Raindrop triggering type runoff automatic sampling device and method |
| CN104964853A (en) * | 2015-07-20 | 2015-10-07 | 清华大学深圳研究生院 | Event mean concentration sampler |
| CN104964853B (en) * | 2015-07-20 | 2018-03-23 | 清华大学深圳研究生院 | A kind of event mean concentrations sampler |
| CN106525510A (en) * | 2016-11-03 | 2017-03-22 | 温岭市职业技术学校 | Timing sampler and method for runoff samples on basis of rainfall amount control |
| CN107764591A (en) * | 2017-09-30 | 2018-03-06 | 黄河流域水土保持生态环境监测中心 | A kind of small watershed bayonet socket station runoff and sediment automatic sampling system |
| CN108680402A (en) * | 2018-05-18 | 2018-10-19 | 山东建筑大学 | A kind of greenery patches runoff automatic sampling device and method |
| CN109000976A (en) * | 2018-07-06 | 2018-12-14 | 中国水利水电科学研究院 | Storm runoff samples automatically, monitoring device and method |
| CN110220751A (en) * | 2019-07-08 | 2019-09-10 | 深圳市海德邦科技有限公司 | A kind of Water quality automatic sampling device that can remotely monitor |
| CN112798753A (en) * | 2021-03-26 | 2021-05-14 | 湖南慧泽生物医药科技有限公司 | Automatic digestion instrument and sampling device thereof |
| CN112798753B (en) * | 2021-03-26 | 2021-07-02 | 湖南慧泽生物医药科技有限公司 | Automatic digestion instrument and sampling device thereof |
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| C14 | Grant of patent or utility model | ||
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| AV01 | Patent right actively abandoned |
Granted publication date: 20140521 Effective date of abandoning: 20141119 |
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| RGAV | Abandon patent right to avoid regrant |