CN203545746U - Microelectrolysis equipment for advanced treatment of penicillin wastewater - Google Patents
Microelectrolysis equipment for advanced treatment of penicillin wastewater Download PDFInfo
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- CN203545746U CN203545746U CN201320651691.2U CN201320651691U CN203545746U CN 203545746 U CN203545746 U CN 203545746U CN 201320651691 U CN201320651691 U CN 201320651691U CN 203545746 U CN203545746 U CN 203545746U
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- cylindrical shell
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- distributor
- advanced treatment
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- 239000002351 wastewater Substances 0.000 title claims abstract description 51
- 229930182555 Penicillin Natural products 0.000 title claims abstract description 28
- JGSARLDLIJGVTE-MBNYWOFBSA-N Penicillin G Chemical compound N([C@H]1[C@H]2SC([C@@H](N2C1=O)C(O)=O)(C)C)C(=O)CC1=CC=CC=C1 JGSARLDLIJGVTE-MBNYWOFBSA-N 0.000 title claims abstract description 28
- 229940049954 penicillin Drugs 0.000 title claims abstract description 28
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 44
- 239000000945 filler Substances 0.000 claims description 15
- 238000012856 packing Methods 0.000 claims description 12
- 230000004888 barrier function Effects 0.000 claims description 9
- 238000013022 venting Methods 0.000 claims description 8
- 239000007789 gas Substances 0.000 abstract description 10
- 238000004519 manufacturing process Methods 0.000 abstract description 6
- 239000000126 substance Substances 0.000 abstract description 4
- 238000004065 wastewater treatment Methods 0.000 abstract description 4
- 238000007599 discharging Methods 0.000 abstract 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 125000004122 cyclic group Chemical group 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000010802 sludge Substances 0.000 abstract 1
- 238000005868 electrolysis reaction Methods 0.000 description 8
- 238000000034 method Methods 0.000 description 7
- 230000003647 oxidation Effects 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 238000010586 diagram Methods 0.000 description 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 208000014451 palmoplantar keratoderma and congenital alopecia 2 Diseases 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000010865 sewage Substances 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 241000628997 Flos Species 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000003570 air Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 229940088710 antibiotic agent Drugs 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000003851 biochemical process Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 239000010842 industrial wastewater Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- -1 polypropylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 235000019600 saltiness Nutrition 0.000 description 1
Images
Abstract
The utility model provides a microelectrolysis equipment for advanced treatment of penicillin wastewater. The microelectrolysis equipment comprises a barrel (4), a water/gas discharging device (1) and a water/gas charging device (3), wherein the water /gas discharging device (1) is arranged at the top of the barrel (4); and the water/gas charging device (3) is arranged at the bottom of the barrel (4). The microelectrolysis equipment is capable of solving the problems in the treatment of penicillin wastewater; verified by practical production, the microelectrolysis equipment can work stably and is relatively low in equipment manufacture cost; the COD (Chemical Oxygen Demand) removal rate of the penicillin wastewater which is subjected to CASS (Cyclic Activated Sludge System) treatment reaches 50%; the discharged COD is up to the national standard; and the wastewater treatment cost is relatively low.
Description
Technical field
The present invention relates to the treatment unit of penicillin wastewater, relate to or rather a kind of micro-electrolyzer for penicillin wastewater advanced treatment.
Background technology
Penicillin is the most frequently used clinically antibacterials, and the mankind's health has been made to huge contribution.It is still global problem at present that yet waste water produced from penicillin production is administered, wherein main manifestations be that quantity discharged is large, organic content is high, saltiness is high, large etc. containing difficult degradation chemical combination object height, difficulty of governance, conventionally the scheme adopting is chemical oxidation process, if chlorine is catalyzed oxidation, ozone oxidation, hydrogen peroxide oxidation etc.Biochemical process has various ways, as anaerobism, aerobic, SBR, A/O, A/A/O, USBR, CASS, application high-efficiency strain etc.But there is the problem of the poor or somewhat expensive for the treatment of effect in these methods.
Micro electrolysis tech is the principle of utilizing metallic corrosion, forms the method that galvanic cell is processed waste water, at present, there is no open report and administers penicillin wastewater use the method.
The technology of relevant micro-electrolysis in other industrial wastewater treatment directly applies to penicillin wastewater deep treatment and has following problem: reactor design is unreasonable, reaction process pH can not normally maintain, reaction can not normally be carried out, and COD clearance is difficult to reach requirement; Use micro-electrolysis stuffing insufficient strength, filler consumes too fast; Packing specific area is too low, and filler usage quantity is large; Because the existence of suspended substance in waste water and colloid causes filler to harden, processing efficiency reduces; Periodical operation, is unfavorable for the continuous operation of wastewater treatment, etc.
Therefore, develop a kind of micro-electrolyzer that is applicable to penicillin wastewater deep treatment, significant.
Summary of the invention
For the deficiency of existing processing waste water produced from penicillin production treatment process, the invention provides a kind of micro-electrolyzer for penicillin wastewater advanced treatment.
Technical problem of the present invention is realized by following technical scheme.
For a micro-electrolyzer for penicillin wastewater advanced treatment, it comprises cylindrical shell, water outlet gas barrier and water inlet diffuser, it is characterized in that, water outlet gas barrier is located at cylindrical shell top, and water inlet diffuser is located at cylinder body bottom.
Above-mentioned micro-electrolyzer for penicillin wastewater advanced treatment, described water outlet gas barrier comprises that annular overflow weir water leg, water outlet, venting port and filler add mouth; Described annular overflow weir water leg is located in cylindrical shell; Described water outlet is located at cylindrical shell outside, and the bottom margin of its lower rim and annular overflow weir water leg is on same level line; Described venting port is located at cylindrical shell outside, and its lower rim is higher than the top of annular overflow weir water leg; Described filler is added mouth and is located at the outer top of cylindrical shell.
Above-mentioned micro-electrolyzer for penicillin wastewater advanced treatment, described water inlet diffuser comprises inlet mouth, water-in, air-distributor, waste water sparger, packing support dividing plate, evacuation port, column; Described inlet mouth, water-in, evacuation port are all located at cylindrical shell outside, and three reduces successively in the level height of cylindrical shell vertical direction; Described air-distributor connects inlet mouth; Described waste water sparger connects water-in; Described packing support dividing plate is located at inlet mouth top; Described air-distributor, waste water sparger, packing support dividing plate three below are provided with column.
Preferably, above-mentioned micro-electrolyzer for penicillin wastewater advanced treatment, the arm of described air-distributor and waste water sparger is shaped as " rich " font.Under each arm of described air-distributor, solarization air cap is evenly set.Oblique lower 45 ° of described each arm of waste water sparger evenly arranges prosopyle.
Micro-electrolyzer for penicillin wastewater advanced treatment of the present invention can be used alone, and also can the series connection of 1-10 level use, and for solving different sewage, provides different schemes.
The invention has the beneficial effects as follows:
1, a kind of micro-electrolyzer for penicillin wastewater advanced treatment provided by the invention, can solve the difficult problem that penicillin wastewater is administered, and through actual production checking, operates steadily, and device fabrication cost is relatively low;
2, a kind of micro-electrolyzer for penicillin wastewater advanced treatment provided by the invention can reach 50% by penicillin wastewater COD clearance after CASS processes, and cost for wastewater treatment is relatively low.
Accompanying drawing explanation
Fig. 1 micro-electrolysis reactor front view.
Fig. 2 micro-electrolysis reactor right view.
Fig. 3 micro-electrolysis reactor vertical view.
Fig. 4 packing support dividing plate schematic diagram.
Fig. 5 intake water-in and waste water sparger connection diagram in diffuser.
Fig. 6 intake inlet mouth and air-distributor connection diagram in diffuser.
Embodiment
Below in conjunction with embodiment, the present invention is described in further detail.
Micro-electrolyzer forms as shown in Figure 1, Figure 2, shown in Fig. 3, Fig. 4, Fig. 5, Fig. 6, in figure, each label is: 1 water outlet gas barrier, 2 micro-electrolysis reaction regions are also that a part, 3 water inlet diffusers, 4 cylindrical shells, 5 packing support dividing plates, 6 air-distributors, 7 waste water spargers, 8 annular overflow weir water legs, 9 water outlets, 10 venting ports, 11 evacuation ports, 12 fillers of cylindrical shell 4 are added mouth, 13 inlet mouths, 14 water-ins, 15 columns, 16 solarization air caps, 17 prosopyles.
Wherein, water outlet gas barrier 1 is located at cylindrical shell 4 tops, and water inlet diffuser 3 is located at cylindrical shell 4 bottoms.
Waste water, air enter micro-electrolyzer from water inlet diffuser 3.
The arm of air-distributor 6 and waste water sparger 7 is shaped as " rich " font.Under each arm of air-distributor 6, solarization air cap 16 is evenly set.For fear of situation about occur stopping up, oblique lower 45 ° of waste water sparger 7 each arms evenly arrange prosopyle 17.
Water outlet gas barrier 1 comprises that annular overflow weir water leg 8, water outlet 9, venting port 10 and filler add mouthfuls 12; Described annular overflow weir water leg 8 is located in cylindrical shell 4; Described water outlet 9 is located at cylindrical shell 4 outsides, and the bottom margin of its lower rim and annular overflow weir water leg 8 is on same level line; Described venting port 10 is located at cylindrical shell 4 outsides, and its lower rim is higher than the top of annular overflow weir water leg 8; Described filler is added mouth 12 and is located at the outer top of cylindrical shell 4.Filler adds mouthfuls 12 can suitably add filler according to COD clearance in reactor operational process, and venting port 10 both can exhausted air, guarantees the atmospheric pressure environment of reactor, also can discharge the foam, floss etc. that are suspended in waste water surface.
For the ease of equipment, overhaul, change filler, water inlet diffuser 3 adopts the mode of flange to be connected with micro-electrolysis reaction district 2.
Micro-electrolyzer for penicillin wastewater advanced treatment of the present invention is used separately or the series connection of 1-10 level is used, and can be used for the improvement of different sewage.
The explanation of above embodiment is just for helping to understand the utility model; make professional and technical personnel in the field can realize or use the utility model; be not limited to the utility model; all within spirit of the present utility model and principle; any modification of doing, be equal to replacement, improvement etc., within all should being included in protection domain of the present utility model.
Claims (4)
1. the micro-electrolyzer for penicillin wastewater advanced treatment, it comprises cylindrical shell (4), water outlet gas barrier (1) and water inlet diffuser (3), it is characterized in that, water outlet gas barrier (1) is located at cylindrical shell (4) top, and water inlet diffuser (3) is located at cylindrical shell (4) bottom; Described water outlet gas barrier (1) comprises that annular overflow weir water leg (8), water outlet (9), venting port (10) and filler add mouthful (12); Described annular overflow weir water leg (8) is located in cylindrical shell (4); Described water outlet (9) is located at cylindrical shell (4) outside, and the bottom margin of its lower rim and annular overflow weir water leg (8) is on same level line; Described venting port (10) is located at cylindrical shell (4) outside, and its lower rim is higher than the top of annular overflow weir water leg (8); Described filler is added mouthful (12) and is located at the outer top of cylindrical shell (4); Described water inlet diffuser (3) comprises inlet mouth (13), water-in (14), air-distributor (6), waste water sparger (7), packing support dividing plate (5), evacuation port (11), column (15); Described inlet mouth (13), water-in (14), evacuation port (11) are all located at cylindrical shell (4) outside, and three reduces successively in the level height of cylindrical shell (4) vertical direction; Described air-distributor (6) connects inlet mouth (13); Described waste water sparger (7) connects water-in (14); Described packing support dividing plate (5) is located at inlet mouth (13) top; Described air-distributor (6), waste water sparger (7), packing support dividing plate (5) three below are provided with column (15).
2. the micro-electrolyzer for penicillin wastewater advanced treatment according to claim 1, is characterized in that, the arm of described air-distributor (6) and waste water sparger (7) is shaped as " rich " font.
3. the micro-electrolyzer for penicillin wastewater advanced treatment according to claim 1 and 2, is characterized in that, solarization air cap (16) is evenly set under each arm of described air-distributor (6).
4. the micro-electrolyzer for penicillin wastewater advanced treatment according to claim 3, is characterized in that, oblique lower 45 ° of each arm of described waste water sparger (7) evenly arranges prosopyle (17).
Priority Applications (1)
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CN201320651691.2U CN203545746U (en) | 2013-10-22 | 2013-10-22 | Microelectrolysis equipment for advanced treatment of penicillin wastewater |
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CN201320651691.2U CN203545746U (en) | 2013-10-22 | 2013-10-22 | Microelectrolysis equipment for advanced treatment of penicillin wastewater |
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CN201320651691.2U Expired - Lifetime CN203545746U (en) | 2013-10-22 | 2013-10-22 | Microelectrolysis equipment for advanced treatment of penicillin wastewater |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103936113A (en) * | 2014-05-14 | 2014-07-23 | 湖南景翌湘台环保高新技术开发有限公司 | Iron carbon reactor facility and technique for treating high-concentration organic wastewater |
-
2013
- 2013-10-22 CN CN201320651691.2U patent/CN203545746U/en not_active Expired - Lifetime
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103936113A (en) * | 2014-05-14 | 2014-07-23 | 湖南景翌湘台环保高新技术开发有限公司 | Iron carbon reactor facility and technique for treating high-concentration organic wastewater |
CN103936113B (en) * | 2014-05-14 | 2015-12-09 | 湖南景翌湘台环保高新技术开发有限公司 | A kind of iron charcoal reactor apparatus and treatment process processing high concentrated organic wastewater |
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C14 | Grant of patent or utility model | ||
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Granted publication date: 20140416 |