CN203391497U - Intramode transfer foil - Google Patents

Intramode transfer foil Download PDF

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Publication number
CN203391497U
CN203391497U CN201320133259.4U CN201320133259U CN203391497U CN 203391497 U CN203391497 U CN 203391497U CN 201320133259 U CN201320133259 U CN 201320133259U CN 203391497 U CN203391497 U CN 203391497U
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China
Prior art keywords
paper tinsel
concave
foil
convex
figuration
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Expired - Lifetime
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CN201320133259.4U
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Chinese (zh)
Inventor
渡边恵
渡边学
舩木速人
樋爪友美
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Toppan Inc
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Toppan Printing Co Ltd
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  • Decoration By Transfer Pictures (AREA)
  • Injection Moulding Of Plastics Or The Like (AREA)

Abstract

The utility model provides an intramode transfer foil. The intramode transfer foil has high surface hardness and can be used for forming high-refined concave and convex on surfaces of molding products. The intramode transfer foil is characterized by being provided with a decorative foil and a concave-convex pattern shaping foil, wherein for the decorative foil, a stripping layer, a hard coating containing ultraviolet light hardenability resin, a printing layer with a specified pattern and a first bonding layer for bonding the printing layer on the surface of the molding product are sequentially arranged on one surface of a first base membrane, a second bonding layer containing two-liquid type hardenability resin is arranged on the other surface of the first base membrane; for the concave-convex pattern shaping foil, a concave-convex forming layer comprising hot hardenability resin or ultraviolet light hardenability resin is arranged on one surface of a second base membrane; the decorative foil and the concave-convex pattern shaping foil are bonded by oppositely arranging the second bonding layer of the decorative foil and the surface of the concave-convex forming layer of the concave-convex pattern shaping foil.

Description

In-mold transfer printing paper tinsel
Technical field
The utility model relates to the in-mold transfer printing paper tinsel of the incrustation that is applicable to industrial products.
Background technology
Utilize the products formed of in-mold transfer printing paper tinsel to be used to the framework classes such as container class, electronic instrument or office appliance of instrument body, food or the various article such as commodity or daily necessities.
In-mold transfer printing paper tinsel refers to, on the basement membrane as base material, has formed the transfer foil that for example the decorative plastic moulding of peel ply, printed layers, adhesive linkage is used.In-molded is a kind of forming method, in the method, this transfer foil is supplied between a pair of die injection moulding, moulding resin in the chamber being formed by this die injection moulding (cavity) after wadding warp heating pressurization, separate afterwards basement membrane and peel ply, printed layers is transferred in to the luggage decorations of going forward side by side on moulding resin.
As for obtaining the in-mold transfer printing paper tinsel of the products formed of high surface hardness, there is a kind of following in-mold transfer printing paper tinsel: it is on the surface of peel ply, to form the hard conating consisting of uv-hardening resin, then has formed printed layers, adhesive linkage etc. thereon.In this case, when the in-mold transfer printing paper tinsel irradiation ultraviolet radiation to before moulding, and make hard conating when sclerosis, can destroy mouldability, so be preferably, after moulding, to products formed irradiation ultraviolet radiation, and make hard conating sclerosis.
Because the structure of in-mold transfer printing paper tinsel is in the past only to have printed word, pattern etc. with planar fashion on basement membrane, therefore exist products formed surface to lack relief problem.As making products formed surface there is relief method, there is a kind of following method: the method is when moulding, to form the side that the basement membrane of a pair of die injection moulding inner side in chamber docks, and has set in advance concavo-convex.But in this concavo-convex formation method, a die injection moulding can only, corresponding to a ridge design, just must be prepared a plurality of die injection mouldings corresponding to multiple ridge design, thereby produce the problem of cost up.
Therefore, as forming concavo-convex method on products formed surface, there is a kind of following method: on a face of basement membrane, possess peel ply, printed layers, for making this printed layers be bonded in the adhesive linkage on products formed surface, on a face of another basement membrane, be provided with the concave-convex stratification of utilizing printing and obtaining, and these two films be supplied in the chamber of this die injection moulding (for example, with reference to patent documentation 1) simultaneously.
Prior art document
Patent documentation 1: Japanese kokai publication hei 2-301413 communique
Utility model content
But, the so-called concavo-convex formation method of the moulding resin after in the chamber that two films is supplied in simultaneously to die injection moulding after wadding warp heating pressurization, can produce following problem: two films easily misplace, and are difficult to consistent with predefined assigned position.
In addition, because imagination industrial products are used or use under cruel environment through long-term, therefore can there are the following problems, needing the in-mold transfer printing paper tinsel that the decoration of industrial products is used is the very high transfer foil of case hardness that makes the products formed after transfer printing.
The utility model will address the above problem exactly, and its object is to provide a kind of following transfer foil: it is form concavo-convex and can not misplace with printed layers on products formed surface, and the products formed with high surface hardness can be provided.
In order to address the above problem, the technical solution of the utility model 1 is a kind of in-mold transfer printing paper tinsel, it is characterized in that, there is decoration foil and ridge design figuration paper tinsel, decoration foil possesses successively peel ply on a face of the first basement membrane, the hard conating that comprises uv-hardening resin, the printed layers with predetermined pattern, for making this printed layers be bonded in first adhesive linkage on products formed surface, and on another face of described the first basement membrane, be provided with the second adhesive linkage that comprises two-liquid type hardening resin; Ridge design figuration paper tinsel has the concave-convex stratification consisting of thermosetting resin or uv-hardening resin on a face of the second basement membrane, with the second adhesive linkage of described decoration foil and the cambial face of no concave-convex of described ridge design figuration paper tinsel, carry out opposed mode, described decoration foil and described ridge design figuration paper tinsel are carried out bonding.
In addition, the technical solution of the utility model 2 is a kind of in-mold transfer printing paper tinsels, it is characterized in that, there is decoration foil and ridge design figuration paper tinsel, decoration foil possesses successively peel ply on a face of the first basement membrane, the hard conating that comprises uv-hardening resin, the printed layers with predetermined pattern, for making this printed layers be bonded in first adhesive linkage on products formed surface, and on another face of described the first basement membrane, be provided with the second adhesive linkage that comprises two-liquid type hardening resin; Ridge design figuration paper tinsel has the concave-convex stratification consisting of thermosetting resin or uv-hardening resin on a face of the second basement membrane, with the second adhesive linkage of described decoration foil and the concave-convex stratification of described ridge design figuration paper tinsel, carry out opposed mode, described decoration foil and described ridge design figuration paper tinsel are carried out bonding.
If use transfer foil of the present utility model, when transfer printing, according to by the formed relief pattern of concave-convex stratification, can form on the surface of products formed consistent concavo-convex of decorative pattern with printed layers.In addition, in-mold transfer printing paper tinsel of the present utility model, due to by making respectively decoration foil and ridge design figuration paper tinsel, can reduce operation load, therefore can reduce cost and very economical.And, owing on decoration foil, the hard conating consisting of uv-hardening resin can being set, so can produce the products formed with high surface hardness.
Accompanying drawing explanation
Fig. 1 is the profile schema diagram of decoration foil of the present utility model and ridge design figuration paper tinsel.
Fig. 2 is the profile schema diagram of in-mold transfer printing paper tinsel of the present utility model.
Fig. 3 is the profile schema diagram of the in-mold transfer printing paper tinsel of another structure of the present utility model.
Fig. 4 is the generalized section when having used the injection mo(u)lding of the utility model in-mold transfer printing paper tinsel.
Fig. 5 is the profile schema diagram of decorated molded article of the present utility model.
Description of reference numerals
1 ... the first basement membrane
2 ... peel ply
3 ... hard conating
4 ... printed layers
5 ... the first adhesive linkage
6 ... the second adhesive linkage
7 ... decoration foil
8 ... the second basement membrane
9 ... concave-convex stratification
10 ... ridge design figuration paper tinsel
11 ... in-mold transfer printing paper tinsel
12 ... moulding resin
13 ... die injection moulding
21 ... in-mold transfer printing paper tinsel
The specific embodiment
Quoted figures below, illustrates an example of embodiment of the present utility model.
The in-mould injection method of forming is by four following injection molding methods that operation forms: (1) prepares the operation of in-mold transfer printing paper tinsel; (2) this in-mold transfer printing paper tinsel is inserted into the operation in die injection moulding; (3) by making resin carry out injection mo(u)lding and being attached to this die injection moulding, thereby in the surface transfer of this resin, there is the operation of the printed layers of in-mold transfer printing paper tinsel; (4), after cooling, open die injection moulding, the operation that separates basement membrane and peel ply and take out products formed.
In-mold transfer printing paper tinsel of the present utility model is to make decoration foil 7 and ridge design figuration paper tinsel 10 carry out bonding layer structure, described decoration foil 7 possesses successively peel ply 2 on a face of the first basement membrane 1, the hard conating 3 that comprises uv-hardening resin, the printed layers 4 with predetermined pattern, for making this printed layers be bonded in first adhesive linkage 5 on products formed surface, and on another face of the first basement membrane 1, be provided with the second adhesive linkage 6 that comprises two-liquid type hardening resin; Described ridge design figuration paper tinsel 10 is to have concave-convex stratification 9 on a face of the second basement membrane 8, and described concave-convex stratification 9 is by having used the embossing processing of thermosetting resin or uv-hardening resin to form.
As the first basement membrane 1 and the second basement membrane 8, as long as there are necessary heat resistance, mechanical strength, solvent resistance etc. in manufacture and molding procedure, can apply various materials according to purposes.Such as being polyester resin, polyamide-based resin, polyolefin resin, vinyl resins, acrylic resin, cellulosic resin etc.Viewpoint from heat resistance, mechanical strength, preferably includes: the film of the polyester resins such as PETG, PEN, wherein, most preferably is the film of pet resin.
The material of peel ply 2 so long as possess the resin of necessary fissility, be not particularly limited, but in-mold transfer printing paper tinsel of the present utility model is preferably used melamine resinoid or acrylic resin.Use the peel ply 2 and hard conating 3 combinations of melamine resinoid or acrylic resin, can give play to stable fissility.About the formation method of peel ply 2, can use known print process, rubbing method.
Hard conating 3 is while having peeled off the first basement membrane 1 after transfer printing, becomes the layer of the outmost surface of products formed.As the material of hard conating 3, can use the uv-hardening resin hardening by ultraviolet ray.So long as the hard conating of UV cured property, owing to being irradiated and be hardened immediately in products formed surface by ultraviolet ray, so the production efficiency of products formed can improve.In addition, by carry out moulding under unhardened state, and after moulding, make its sclerosis, just can realize the raising of mouldability and the raising of physical property simultaneously.As the formation method of hard conating 3, can use known print process, rubbing method.
As the material of printed layers 4, can use the coloring printing ink that contains colouring agent, described colouring agent is pigment or the dyestuff of suitable color.As the formation method of printed layers 4, can use the common print processes such as hectographic printing method, woodburytype, silk screen print method.Preferably with woodburytype, print, described woodburytype can carry out polychrome printing, expressing gradation, and is suitable for a large amount of production.In addition, in order to improve the tack with hard conating 3, tackify (anchor) layer (not shown) can be set between printed layers 4 and hard conating 3.As the formation method of adhesion promoting layer, can use the print processes such as woodburytype, silk screen print method.Especially from thickness, productive viewpoint, preferably with woodburytype, print.
The first adhesive linkage 5 is bonded in above-mentioned each layer on the surface of products formed.As the first adhesive linkage 5, can suitably utilize the resin of the thermal sensitivity or the pressure-sensitive that are applicable to moulding resin 12.As the formation method of adhesive linkage, can use the print processes such as woodburytype, silk screen print method.Especially from thickness, productive viewpoint, preferably with woodburytype, print.In addition, in printed layers 4, with respect to products formed, there is sufficient cementability, possess in the situation as the effect of adhesive linkage, the first adhesive linkage 5 can be set in addition.
The second adhesive linkage 6 is for making the decoration foil 7 that possesses above-mentioned layer structure carry out bonding with following ridge design figuration paper tinsel 10.As the material of the second adhesive linkage 6, can use two-liquid type hardening resin or thermosetting resin.But when using thermosetting resin, the heat resistance of in-mold transfer printing paper tinsel 11 declines, thereby destroy mouldability.Therefore, can use the two-liquid type hardening resins such as polyester resin or polyethers resin, form the second adhesive linkage 6.
Be arranged at the concave-convex stratification 9 on the second basement membrane 8, can print and form by woodburytype, silk screen print method.As the material of concave-convex stratification 9, can use heat in the time that transfer printing can being tolerated or thermosetting resin or the uv-hardening resin of pressure.
In addition, can utilize woodburytype, intaglio plate rubbing method, rolling method, scraper for coating method, silk screen print method, other common rubbing method or print process, after being coated with thermosetting resin or uv-hardening resin, this resin is carried out to embossing processing, thereby form concave-convex stratification 9.
By each layer carry out in the above described manner laminated after, can prepare decoration foil 7 and ridge design figuration paper tinsel 10 as shown in Figure 1.At the face that makes the second adhesive linkage 6 of decoration foil 7, form layer 9 with the no concave-convex of ridge design figuration paper tinsel 10, carry out under opposed state, these two paper tinsels are carried out bonding, just can form in-mold transfer printing paper tinsel 11(with reference to Fig. 2).Now, under the state that makes the decorative pattern of the printed layers 4 of decoration foil 7, aims at the relief pattern of the concave-convex stratification 9 of ridge design figuration paper tinsel 10, carry out bonding.
Or, also can, making the second adhesive linkage 6 of decoration foil 7, carrying out under opposed state with the face that has concave-convex stratification 9 of ridge design figuration paper tinsel 10, to these two paper tinsels, carry out bonding (with reference to Fig. 3).Now, under the state that makes the decorative pattern of the printed layers 4 of decoration foil 7, aims at the relief pattern of the concave-convex stratification 9 of ridge design figuration paper tinsel 10, carry out bonding.
Carry out by the way bondingly, can prepare in-mold transfer printing paper tinsel 11 as shown in Figure 2 or the in-mold transfer printing paper tinsel 21 shown in Fig. 3.By using these in-mold transfer printing paper tinsels to carry out in-mould injection moulding, can produce the products formed with the concave-convex surface consistent with the decorative pattern of printed layers 4.
When injection mo(u)lding, by in-mold transfer printing paper tinsel 11 or in-mold transfer printing paper tinsel 21 are exerted pressure, the part that becomes protruding place of concave-convex stratification 9, upwards pushes decoration foil 7 and makes its distortion.Thus, on the surface of the products formed of making, will form identical concavo-convex of relief pattern with concave-convex stratification 9.
Utilize Fig. 4~Fig. 5, to having used the summary of the in-mould injection moulding of in-mold transfer printing paper tinsel 11 of the present utility model or in-mold transfer printing paper tinsel 21 to describe.
At the interior insertion of die injection moulding 13 in-mold transfer printing paper tinsel of the present utility model, the first adhesive linkage 5 one sides from this in-mold transfer printing paper tinsel, to ejection formation resin 12 in this die injection moulding 13 chamber and carry out moulding, thereby there is in-mold transfer printing paper tinsel in the surface transfer of this moulding resin 12.With known order, proceed as follows: after cooling, open die injection moulding 13, and separate the first basement membrane 1, peel ply 2 and the ridge design figuration paper tinsel 10 of in-mold transfer printing paper tinsel, thereby take out products formed.
In the method, in die injection moulding 13 chamber, injection mo(u)lding has moulding resin 12, thereby in-mold transfer printing paper tinsel is exerted pressure.Now, utilize the thickness of the resin that is formed with convex portion of the concave-convex stratification 9 of in-mold transfer printing paper tinsel, upwards push the decoration foil 7 of this part and deform, and then moulding resin 12 deform too (with reference to Fig. 4).
When separating ridge design figuration paper tinsel 10 and the first basement membrane 1 and peel ply 2, become on the surface of hard conating 3 of outmost surface, just form identical concavo-convex of relief pattern with concave-convex stratification 9.Thus, on the surface of the products formed of making, will form concavo-convex (with reference to Fig. 5).
(embodiment 1)
Utilize pet resin film as the first basement membrane 1, and on the first basement membrane 1, form the peel ply 2 of melmac class, the hard conating 3 of the acrylic resin of UV cured property, then, utilize woodburytype to form the printed layers 4 of vinyl chloride vinyl acetate/polyurethanes ink, the first adhesive linkage 5 of acrylic resin.Then, this basement membrane 1, with on the face contrary side of formation peel ply 2, be coated with the indurative polyester resin of two-liquid type as the second adhesive linkage 6, thereby obtained decoration foil 7.
Then, on a face of the second basement membrane 8, utilize woodburytype be coated with UV cured property acrylic resin and as concave-convex stratification 9, by embossing be processed to form concavo-convex after, utilize high-pressure sodium lamp, from concave-convex stratification 9 one sides, having irradiated accumulative total light quantity is 1000mJ/cm 2ultraviolet ray, and make concave-convex stratification 9 sclerosis, thereby obtained ridge design figuration paper tinsel 10.
Then, at the face that makes the second adhesive linkage 6 of decoration foil 7, form layer 9 with the no concave-convex of ridge design figuration paper tinsel 10, carry out under opposed state, these two paper tinsels are carried out bonding, thereby obtained in-mold transfer printing paper tinsel 11.
This in-mold transfer printing paper tinsel 11 is fixed on to die injection moulding 13 and carries out matched moulds, and using moulding resin 12 is that PC/ABS resin has carried out injection mo(u)lding.After cooling, open die injection moulding 13, and after the first basement membrane 1 of this in-mold transfer printing paper tinsel 11 and ridge design figuration paper tinsel 10 are peeled off together with peel ply 2 from products formed, utilize high-pressure sodium lamp, to the surface irradiation of products formed accumulative total light quantity be 1000mJ/cm 2ultraviolet ray, make hard conating 3 carry out crosslinked sclerosis.
By with upper type, obtained surface and there is products formed concavo-convex and that case hardness is very high.
(comparative example 1)
Identical with embodiment 1, on a face of the second basement membrane 8, utilize woodburytype be coated with UV cured property acrylic resin and as concave-convex stratification 9, by embossing be processed to form concavo-convex after, utilize high-pressure sodium lamp, from concave-convex stratification 9 one sides, having irradiated accumulative total light quantity is 400mJ/cm 2ultraviolet ray, thereby obtained ridge design figuration paper tinsel 10.Then, in the mode identical with embodiment 1, obtained, after in-mold transfer printing paper tinsel, by injection mo(u)lding, having obtained products formed.Stripping process afterwards, also identical with embodiment 1 to the ultraviolet irradiation process on products formed surface.
(comparative example 2)
Identical with embodiment 1, on a face of the second basement membrane 8, utilize the vinyl chloride resin of woodburytype coating thermoplastic and as concave-convex stratification 9, by embossing, be processed to form concavo-convexly, and obtained ridge design figuration paper tinsel 10.Then, in the mode identical with embodiment 1, obtained, after in-mold transfer printing paper tinsel, by injection mo(u)lding, having obtained products formed.Stripping process afterwards, also identical with embodiment 1 to the ultraviolet irradiation process on products formed surface.
(evaluation)
Products formed for obtaining in above-described embodiment 1 and comparative example 1,2, has carried out following evaluation:
(1) by the concave-convex sense on ridge design figuration paper tinsel 10 formed products formed surfaces;
(2) uniformity of printed layers 4 and the position of the ridge design obtaining by ridge design figuration paper tinsel 10.
The evaluation of concave-convex sense is that surperficial for the place of 0.5m visually observes from leaving products formed, the products formed that can identify concave-convex surface is zero (good); The products formed that can not identify concave-convex surface is * (bad).
In addition, with the evaluation of the location consistency of printed layers, be to visually observe for the place of 0.5m from leaving products formed surface too, the products formed of position consistency is evaluated as zero (good); The inconsistent products formed in position is evaluated as * (bad).
In following table 1, represent these evaluation results.
[table 1]
Assessment item Embodiment 1 Comparative example 1 Comparative example 2
(1) concave-convex sense on surface × ×
(2) with the location consistency of printed layers × ×
The concave-convex stratification 9 of the ridge design figuration paper tinsel 10 of comparative example 1 is because the deficiency of ultraviolet irradiation amount causes hardening insufficient, and, the concave-convex stratification 9 of the ridge design figuration paper tinsel 10 of comparative example 2 is owing to having used thermoplastic resin, heat when therefore, the two is all because of injection mo(u)lding and pressure cause the concavo-convex general planar that becomes of concave-convex stratification 9.Thereby be considered to, the surface of products formed does not form concavo-convex.
On the other hand, if as embodiment 1, the concave-convex stratification 9 of ridge design figuration paper tinsel 10 has enough hardness, can confirm following situation: even if heat and pressure during because of injection mo(u)lding can not make the concavo-convex avalanche of concave-convex stratification 9 yet, and can form concavo-convex on products formed surface.
Utilizability in industry
Transfer foil of the present utility model can be used in the decoration of plate type part etc., and described plate type part is used to household appliances, residential equipment, office instrument, auto parts and components etc.

Claims (2)

1. an in-mold transfer printing paper tinsel, is characterized in that, has decoration foil and ridge design figuration paper tinsel,
Described decoration foil possesses successively peel ply on a face of the first basement membrane, the hard conating that comprises uv-hardening resin, the printed layers with predetermined pattern, for making described printed layers be bonded in first adhesive linkage on products formed surface, and on another face of described the first basement membrane, be provided with the second adhesive linkage that comprises two-liquid type hardening resin;
Described ridge design figuration paper tinsel has the concave-convex stratification consisting of thermosetting resin or uv-hardening resin on a face of the second basement membrane,
With the second adhesive linkage of described decoration foil and the cambial face of no concave-convex of described ridge design figuration paper tinsel, carry out opposed mode, described decoration foil and described ridge design figuration paper tinsel are carried out bonding.
2. an in-mold transfer printing paper tinsel, is characterized in that, has decoration foil and ridge design figuration paper tinsel,
Described decoration foil possesses successively peel ply on a face of the first basement membrane, the hard conating that comprises uv-hardening resin, the printed layers with predetermined pattern, for making described printed layers be bonded in first adhesive linkage on products formed surface, and on another face of described the first basement membrane, be provided with the second adhesive linkage that comprises two-liquid type hardening resin;
Described ridge design figuration paper tinsel has the concave-convex stratification consisting of thermosetting resin or uv-hardening resin on a face of the second basement membrane,
With the second adhesive linkage of described decoration foil and the concave-convex stratification of described ridge design figuration paper tinsel, carry out opposed mode, described decoration foil and described ridge design figuration paper tinsel are carried out bonding.
CN201320133259.4U 2012-03-23 2013-03-22 Intramode transfer foil Expired - Lifetime CN203391497U (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2012-067096 2012-03-23
JP2012067096A JP2013199001A (en) 2012-03-23 2012-03-23 In-mold transfer foil, decorative molded article, and method of manufacturing decorative molded article

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JP6260219B2 (en) * 2013-11-18 2018-01-17 凸版印刷株式会社 Transfer film for in-mold molding and molded product using the same
KR102251458B1 (en) * 2014-04-07 2021-05-14 미래나노텍(주) Pattern transfer film for injection and manufacturing method thereof
JP6728569B2 (en) * 2015-03-30 2020-07-22 大日本印刷株式会社 Transfer sheet and decorative resin molded product using the same
CN115056594B (en) 2017-02-16 2024-03-01 大日本印刷株式会社 Transfer sheet with integrated release member, and method for producing transfer sheet and printed matter
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JP3665907B2 (en) * 1994-08-25 2005-06-29 大日本インキ化学工業株式会社 Two-component curable adhesive composition and laminating method
JP2004255584A (en) * 2003-02-24 2004-09-16 Toppan Printing Co Ltd Method for decorating chamfered surface
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JP2012035513A (en) * 2010-08-06 2012-02-23 Dainippon Printing Co Ltd Decorative sheet and metal decorative plate using the same

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