CN203346355U - Raw gas purification, burning and recycling device for pyrolysis gasification of coal gangue - Google Patents
Raw gas purification, burning and recycling device for pyrolysis gasification of coal gangue Download PDFInfo
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- CN203346355U CN203346355U CN 201320196116 CN201320196116U CN203346355U CN 203346355 U CN203346355 U CN 203346355U CN 201320196116 CN201320196116 CN 201320196116 CN 201320196116 U CN201320196116 U CN 201320196116U CN 203346355 U CN203346355 U CN 203346355U
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Abstract
The utility model discloses a raw gas purification, burning and recycling device for pyrolysis gasification of coal gangue. The device comprises a coal gangue pyrolysis device and a water gas reaction device of a coal gangue pyrolysis gasification device, a raw gas exporting device and a dry-method activated coke recoverer, wherein the coal gangue pyrolysis device comprises a pyrolysis gasification chamber, an pouter gas heating device, an inner gas heating device and a gas reversing device; the water gas reaction device comprises a material cooling device and a steam generating device; the raw gas exporting device comprises a raw gas concentration chamber, an inner exporting passageway, an outer exporting passageway, a main exporting passageway and an annular exporting passageway, and a raw gas exporting outlet is formed in the annular guiding passageway; the dry-method activated coke recoverer comprises a recoverer casing, an absorption bin, an unsaturated activated coke feeding bin and a saturated activated coke storage bin, a purified gas output pipe is arranged at the upper part of the recoverer casing, and the lower part of the recoverer casing is communicated with a second coal gas conveying pipe; and the second coal gas conveying pipe is communicated with the raw gas exporting outlet, and the purified gas output pipe is communicated with a coal gas fan of the gas reversing device.
Description
Technical field
The utility model relates to the technology of coal gangue pyrolytic gasification, particularly coal gangue pyrolytic gasification raw gas purification of combustion recycling device.
Background technology
Coal gangue---the stone of selecting from raw coal, be the waste residue of coal separating plant, bad processing, China has the coal gangue of more than one hundred million tons not utilize every year, and still continues to discharge about 100Mt every year, not only piles up and takes up an area, and can also the spontaneous combustion polluted air or cause fire, cause serious environmental pollution.
Due to the incoalation of 1 years, contain carbon, oil, the gas material of 20-30% in coal gangue, wherein oil gas accounts for 11-15%, carbon accounts for 7-15%.The coal gangue pyrolytic gasification, (composition is the compositions such as silicon-dioxide, aluminium sesquioxide, ferric oxide, titanium dioxide, calcium oxide, magnesium oxide, potassium oxide, sodium oxide, Vanadium Pentoxide in FLAKES, manganese oxide, sulphur trioxide to obtain the solid product of oil gas product and 70-80%, the grog of sal refractory materials), economic worth is arranged, social benefit is more arranged.
The inventor to the research of physical property and the high-temperature coal pyrolytic gasification technique of coal gangue, innovates a set of brand-new coal gangue high temperature pyrolysis and gasification composite technology and device for a long time.
Summary of the invention
The utility model provides coal gangue pyrolytic gasification raw gas purification of combustion recycling device, carbon, oil, gas substance combustion that this device makes the coal gangue pyrolytic gasification utilize and contains in self loop, do not need to increase extra energy consumption, high-efficiency environment friendly, cost savings.
Realize that the technical scheme that above-mentioned purpose is taked is:
Coal gangue pyrolytic gasification raw gas purification of combustion recycling device, mainly comprise coal gangue pyrolysis gasifying device, raw gas take-up gear, activated coke dry method withdrawer, described coal gangue pyrolysis gasifying device, mainly comprise coal gangue pyrolysis installation and water-gas reaction device, described coal gangue pyrolysis installation is arranged on the body of heater middle part, mainly by pyrolysis vaporizer, outer combustion gas heating unit, interior gas-operated thermal bath facility, gas reversing system, center support bow, formed, described pyrolysis vaporizer forms an annulus by the inside and outside ringwall of fire-resistant thermally conductive material, being centered around pyrolysis vaporizer's exterior wall ring periphery is outer combustion gas heating unit, in the indoor ringwall ring of pyrolytic gasification, is interior gas-operated thermal bath facility, described outer combustion gas heating unit is mainly some groups of identical associated the first combustion heaters of structure, the second combustion heater forms, described the first combustion heater mainly comprises the first combustion chamber, the first coal gas enters arm and the first regenerative heat exchanger, the first coal gas enters arm and leads in the first combustion chamber through the body of heater exterior wall, the body of heater exterior wall that the first combustion chamber is made by refractory materials and fire-resistant thermally conductive material are made the gas-fired quirk that pyrolysis vaporizer's outer ring wall and outer quirk partition wall surround a relative closure, described the first regenerative heat exchanger comprises the first accumulation of heat chamber, the first heat storage, the first air enters arm and the first combustion exhaust exhaust outlet, the first accumulation of heat chamber is arranged in the body of heater exterior wall, the first heat storage arranges in the first accumulation of heat chamber, the first accumulation of heat chamber one end leads to the first bottom, combustion chamber, the other end is connected to respectively the first air and enters arm and the first combustion exhaust exhaust outlet, in like manner identical the second combustion heater of structure also mainly comprises the second combustion chamber, the second coal gas enters arm and the second regenerative heat exchanger, between the second combustion chamber of described the first combustion chamber and next-door neighbour, the top of outer quirk partition wall is provided with the combustion chamber through hole, the combustion chamber through hole is connected the second combustion chamber of the first combustion chamber and next-door neighbour to form associated one group, described interior gas-operated thermal bath facility is mainly by some groups of association the 3rd combustion heaters that structure is identical, the 4th combustion heater, its structure and associated the first burning heater, the second burning heater forms almost completely identical, the gas-fired quirk that the indoor ringwall of pyrolytic gasification and internal-quirk partition wall surround a relative closure is made by fire-resistant thermally conductive material in the 3rd combustion chamber of different is the 3rd combustion heater, the 3rd coal gas enter arm below the bar bow of center support bow through upwards leading to the 3rd combustion chamber, the 3rd accumulation of heat chamber is arranged on the body of heater of bar bow below, the 3rd heat storage is placed in the 3rd accumulation of heat chamber, lead to the 3rd bottom, combustion chamber through extending upward below the bar bow that the 3rd accumulation of heat chamber one end bends from center support by the extension passage, the 3rd accumulation of heat chamber the other end is connected to respectively the 3rd air and enters arm and the 3rd combustion exhaust exhaust outlet, between described the 3rd combustion chamber and next-door neighbour's the 4th combustion chamber, the top of internal-quirk partition wall is provided with chamber passage, chamber passage is connected the 3rd combustion chamber and next-door neighbour's the 4th combustion chamber to form associated one group, described gas reversing system comprises dish, lower wall, the rotation reversing motor, air blower, gas fan, exhaust gas fan, lower wall is connected to respectively an air supervisor and the first air is in charge of, the second air is in charge of, a coal gas is responsible for and the first gas manifold, the second gas manifold, combustion exhaust supervisor and the second combustion exhaust are in charge of, the first combustion exhaust is in charge of, wherein the second combustion exhaust is in charge of with the first combustion exhaust and is in charge of with the first air and is in charge of and is in charge of with the second air and the setting of the first gas manifold and the second gas manifold is just exchanged, upper dish is fitted in the lower wall top, upper dish correspondence respectively is provided with the air pipe connecting, the coal gas pipe connecting, the combustion exhaust pipe connecting, thereby the rotation reversing motor drives upper dish reciprocating rotation on lower wall and realizes that the air supervisor constantly is in charge of with the second air and is in charge of and is connected and cut off conversion with the first air, the coal gas supervisor is constantly connected and is cut off conversion with the first gas manifold and the second gas manifold, combustion exhaust supervisor constantly be in charge of with the first combustion exhaust and be in charge of and connected and cut off conversion with the second combustion exhaust, wherein, described the first air is in charge of and is entered arm, the 3rd air with the first air and enter arm and connect, simultaneously, described the first gas manifold and the first coal gas enter arm, the 3rd coal gas enters arm and connects, now simultaneously, described the first combustion exhaust is in charge of with the first combustion exhaust exhaust outlet, the 3rd combustion exhaust exhaust outlet and is connected, in like manner, the second air is in charge of and is entered arm, the 4th air with the second air and enter arm and connect, simultaneously, the second gas manifold and the second coal gas enter arm, the 4th coal gas enters arm and connects, meanwhile, the second burning gas is in charge of with the second combustion exhaust exhaust outlet, the 4th combustion exhaust exhaust outlet and is connected, described water-gas reaction device comprises pyrolysis vaporizer, the material heat sink, steam generation device, the pyrolysis vaporizer of described pyrolysis vaporizer and coal gangue pyrolysis installation is same chamber, pyrolysis vaporizer is positioned at center support bow top, described material heat sink, steam generation device is positioned at center support bow below, described material heat sink comprises high temperature cooling chamber, low temperature cooling chamber, cooling chamber's bridge bow, the top of high temperature cooling chamber communicates bottom pyrolysis vaporizer, high temperature cooling chamber and low temperature cooling chamber are setting up and down, cooling chamber's bridge bow is arranged between high temperature cooling chamber and low temperature cooling chamber, described cooling chamber bridge bow comprises the bridge bow, steam chest, steam enters siphunculus, bridge bow middle part forms steam chest, the lower openings of steam chest is towards low temperature cooling chamber, steam enters siphunculus and is arranged in the bridge bow, steam enters siphunculus one end and leads to steam chest, the other end stretches out outside stove, described steam generation device comprises annular hollow metal casing, steam pockets and drum input tube, the drum output tube, annular hollow metal casing is arranged on bottom of furnace body, the interior annular space chamber of annular hollow metal casing is connected to the low temperature cooling chamber bottom of material heat sink, form sealing relatively for the body of heater water bag of storage of water in annular hollow metal casing case, body of heater water bag is connected to water inlet pipe and drum input tube, water inlet pipe communicates with water tank, drum input tube and steam pockets are connected, the drum output tube of steam pockets enters the siphunculus the other end with the steam of material heat sink and communicates, described raw gas take-up gear comprises the raw gas concentration chamber, interior derivation passage, outer derivation passage, derive main channel, derive circuit, it is integrally formed that described raw gas concentration chamber is arranged on top and the pyrolysis vaporizer of pyrolysis vaporizer, in interior derivation channel setting quirk partition wall, interior derivation feeder connection leads to pyrolysis vaporizer through interior ringwall middle part, the raw gas concentration chamber that interior derivation channel outlet is led to the pyrolysis vaporizer top through interior ringwall, in the exterior wall of described outer derivation channel setting body of heater, lower outside derivation feeder connection, upper outside derivation feeder connection leads to pyrolysis vaporizer through the outer ring wall middle part, the raw gas concentration chamber that outer derivation channel outlet is led to the pyrolysis vaporizer top through outer ring wall, described derivation main channel is arranged in the exterior wall of body of heater of coal heat decomposition stove, derivation main channel entrance communicates with the raw gas concentration chamber and extends up in the exterior wall top derivation circuit that body of heater is set again, derive circuit and be provided with the raw gas export mouth, described activated coke dry method withdrawer comprises that recycling shell collector, absorption storehouse, unsaturated activated coke enter storehouse, saturated active coke storage silo, recycling shell collector is a cavity container, recycling shell collector top purified gas output tube, recycling shell collector bottom and the second gas conveying tube link, the absorption storehouse is arranged in the sky recycling shell collector between purified gas output tube and the second gas conveying tube, top, the bottom in absorption storehouse are the filtration net structure, absorption top, storehouse enters storehouse with the unsaturated activated coke that is arranged on the recycling shell collector top and links, absorption top, storehouse and unsaturated activated coke enter between storehouse the first recovery gate valve are set, bottom, absorption storehouse links with the saturated active coke storage silo with being arranged on the recycling shell collector bottom, between bottom, absorption storehouse and saturated active coke storage silo, is provided with the second recovery gate valve, the second gas conveying tube of described activated coke dry method withdrawer communicates with the raw gas export mouth of raw gas take-up gear, and in the purified gas output tube on activated coke dry method withdrawer top and the coal gangue pyrolysis installation of coal gangue pyrolysis gasifying device, the gas fan of gas reversing system is connected by pipeline.
Described coal gangue pyrolytic gasification raw gas purification of combustion recycling device also comprises the raw gas condensing works, and described raw gas condensing works comprises condensation housing, regulating wheel, threaded adjusting bar, valve gap, valve seat, effuser, ammoniacal liquor shower nozzle, the condensation housing is relative sealing long barrel shape, its side wall upper part offers the raw gas admission port, the ammoniacal liquor shower nozzle is arranged on the top in the condensation housing, threaded adjusting bar one end stretches out and the regulating wheel thread connection from the condensation case top, the threaded adjusting bar the other end and valve gap are connected to a fixed, valve seat is arranged on middle and lower part in the condensation housing and divides upper and lower two portions by the condensation housing, the valve seat middle part is formation like funnelform annular cavity, valve gap is back taper, valve gap is placed in annular cavity, the control to the uninterrupted of raw gas is realized in the gap of the inner ring surface of the male cone (strobilus masculinus) of threaded adjusting bar by driving valve gap and annular cavity, effuser is arranged on the condensation housing bottom, described raw gas condensing works is arranged between described raw gas take-up gear and activated coke dry method withdrawer, the raw gas export mouth of described raw gas take-up gear first communicates with the raw gas admission port of raw gas condensing works, and the effuser of raw gas condensing works communicates with the second gas conveying tube of described activated coke dry method withdrawer again.
Described coal gangue pyrolysis installation also comprises that two groups of bustle pipes are arranged on the periphery of body of heater, comprises the first air bustle pipe, the first coal gas bustle pipe, the first combustion exhaust bustle pipe; The second air bustle pipe, the second coal gas bustle pipe, the second combustion exhaust bustle pipe; Wherein said the first air is in charge of and is entered arm, the 3rd air by the first air bustle pipe and the first air and enter arm and connect, simultaneously, described the first gas manifold enters arm, the 3rd coal gas by the first coal gas bustle pipe and the first coal gas and enters arm and connect, now simultaneously, described the first combustion exhaust is in charge of by the first combustion exhaust bustle pipe and is connected with the first combustion exhaust exhaust outlet, the 3rd combustion exhaust exhaust outlet; In like manner, the second air is in charge of and is entered arm, the 4th air by the second air bustle pipe and the second air and enter arm and connect, simultaneously, the second gas manifold enters arm, the 4th coal gas by the second coal gas bustle pipe and the second coal gas and enters arm and connect, meanwhile, the second burning gas is in charge of by the second combustion exhaust bustle pipe and is connected with the second combustion exhaust exhaust outlet, the 4th combustion exhaust exhaust outlet.
The first air of described the first combustion heater enters between arm and the first accumulation of heat chamber and is provided with the first one-way air valve, and the first one-way air valve allows air to enter pipe and the first accumulation of heat chamber flows into the first combustion chamber from the first air; Be provided with the first unidirectional waste gas valve between the first combustion exhaust exhaust outlet and the first accumulation of heat chamber, the first unidirectional waste gas valve allows the gas-fired waste gas first accumulation of heat chamber of flowing through from the first combustion chamber, finally from the first combustion exhaust exhaust outlet, discharges; The second air of described the second combustion heater enters between arm and the second accumulation of heat chamber and is provided with the second one-way air valve, and the second one-way air valve allows air to enter pipe and the second accumulation of heat chamber flows into the second combustion chamber from the second air; Be provided with the second unidirectional waste gas valve between the second combustion exhaust exhaust outlet and the second accumulation of heat chamber, the second unidirectional waste gas valve allows the gas-fired waste gas second accumulation of heat chamber of flowing through from the second combustion chamber, finally from the second combustion exhaust exhaust outlet, discharges; In like manner the 3rd combustion heater, the 4th combustion heater also comprise one-way air valve, unidirectional waste gas valve, arrange identical with the first combustion heater, the second combustion heater.
Described outer combustion gas heating unit mainly is divided into the heating of upper, middle and lower segment formula, and every section consists of 9 groups of identical first combustion heaters of structure and the second combustion heater.
Described interior gas-operated thermal bath facility mainly is divided into upper and lower two-section type heating, and every section consists of 6 groups of identical the 3rd combustion heaters of structure and the 4th combustion heater.
The utility model advances by gas two regenerative heat exchange that a mode of operation out can realize two groups of combustion heater alternate combustion and two groups of regenerative heat exchangers, make the combustion heater burning more efficient, guarantee coal gangue required temperature and heat in coal hot gas, make the coal gangue pyrolytic gasification carry out smoothly, utilize again the solid product after the coal gangue pyrolytic gasification directly to contact the generation superheated vapour with water vapor, superheated vapour and the coal gangue that is in high temperature pyrolysis swash that to produce the gas that water-gas and coal gangue high temperature pyrolysis discharge be raw gas mutually, raw gas is derived and purified, purified gas after purification is burnt provides needed heat and temperature to the coal gangue pyrolytic gasification, utilize again the waste heat of the solid product after the coal gangue pyrolytic gasification to produce water vapor, make the coal gangue pyrolytic gasification utilize the carbon contained in self, oil, the gas substance combustion loops, do not need to increase extra energy consumption, high-efficiency environment friendly, cost savings.
The accompanying drawing explanation
Below in conjunction with accompanying drawing, embodiment of the present utility model is described in further detail.
Fig. 1 is coal gangue pyrolytic gasification stove schematic diagram of the present utility model;
Fig. 2 is gas reverser schematic diagram of the present utility model;
Fig. 3 coils schematic diagram on gas reverser of the present utility model;
Fig. 4 is gas reverser lower wall schematic diagram of the present utility model;
Fig. 5 is c-c place cross-sectional schematic in Fig. 3;
Fig. 6 is gas reverser of the present utility model and combustion heater pipe network connection diagram;
Fig. 7 is t-t place schematic cross-section in Fig. 1;
Fig. 8 is u-u place schematic cross-section in Fig. 1;
Fig. 9 is v-v place schematic cross-section in Fig. 1;
Figure 10 is center support bow schematic diagram (x-x place schematic cross-section in Fig. 1) of the present utility model;
Figure 11 is vapour passage intention of the present utility model (y-y place schematic cross-section in Fig. 1);
Figure 12 is steam pockets pipeline schematic diagram of the present utility model (z-z place schematic cross-section in Fig. 1);
Figure 13 is industry control central electrical connection diagram of the present utility model;
Figure 14 is that gas-liquid separator of the present utility model and air cooler form schematic diagram;
Figure 15 is gas fan group of the present utility model, activated coke dry method withdrawer, activated coke bucket elevator, activated coke revivifier, cut tower, oil gas air cooler assembly schematic diagram.
Embodiment
The specific embodiment of the comprehensive utilization of coal gangue pyrolytic gasification of the present utility model is mainly introduced in detail following.
First part's coal gangue granularity is controlled
Coal gangue processing is broken into to 0～20mm granularity, in this size range, the coal gangue particle is dehydrated, fully dry, dewatering efficiency is high, but this does not form the restriction to needed coal gangue to the utility model.
Second section coal gangue damping dehydration
The hot waste gas produced after purified gas burning after the raw gas recovery of chemical products that coal gangue high temperature pyrolysis and water-gas reaction are produced purifies carries out the damping dehydration for the coal gangue pellet after fragmentation entering stokehold.
In order to keep the neat and tidy of environment, after the damping dehydration, tail gas is washed one's hair and is purified rear qualified discharge by water.
Third part coal gangue high temperature pyrolysis and gasification (pyrolysis heating, water-gas are sent out and answered)
The high temperature pyrolysis heating of first segment coal gangue
As shown in Figure 1, coal gangue pyrolysis installation 6 is arranged on body of heater 91 middle parts, mainly pyrolysis vaporizer 61, outer combustion gas heating unit 64, interior gas-operated thermal bath facility 67, gas reversing system 66, center support bow 65, consists of, as Fig. 8, shown in Fig. 9: pyrolysis vaporizer 61 is by fire-resistant thermally conductive material, outer ring wall 612, 611 form an annulus, being centered around pyrolysis vaporizer's exterior wall 611 ring peripheries is outer combustion gas heating unit 64, in indoor ringwall 612 rings of pyrolytic gasification, it is interior gas-operated thermal bath facility 67, wherein outer combustion gas heating unit 64 is mainly first combustion heater 62 of some groups of (9 groups of this examples) identical associations of structure, the second combustion heater 60 forms (sees Fig. 1, Fig. 2), as Fig. 1, Fig. 8, shown in Fig. 9: because pyrolysis vaporizer 61 is highly higher, wherein outer combustion gas heating unit 64 mainly is divided into, in, lower Three-section type heating, every section first combustion heater 62 by 9 groups of identical associations of structure and the second combustion heater 60 form, interior gas-operated thermal bath facility 67 mainly is divided into, lower two-section type heating, every section consists of 6 groups of identical the 3rd combustion heaters 68 mutually of structure and the 4th combustion heater 69.
As Fig. 1, Fig. 9 show, described the first combustion heater 62 mainly comprises that the first combustion chamber 621, the first coal gas enter arm 622 and the first regenerative heat exchanger 624, the first coal gas and enters arm 622 and lead in the first combustion chamber 621 through body of heater 91 exterior walls.
As shown in Fig. 1, Fig. 9: body of heater 91 exterior walls that the first combustion chamber 621 is made by refractory materials and fire-resistant thermally conductive material are made the gas-fired quirk that pyrolysis vaporizer's outer ring wall 611 and outer quirk partition wall 625 surround a relative closure.
As shown in Fig. 1, Fig. 9, the first regenerative heat exchanger 624 comprises that the first accumulation of heat chamber 626, the first heat storage 623, the first air enter arm 627 and the first combustion exhaust exhaust outlet 628; The first accumulation of heat chamber 626 is arranged in body of heater 91 exterior walls, the first heat storage 623 arranges in the first accumulation of heat chamber 626, the first accumulation of heat chamber 626 1 ends lead to 621 bottoms, the first combustion chamber, and the other end is connected to respectively the first air and enters arm 627 and the first combustion exhaust exhaust outlet 628.
As shown in Figure 9, enter between arm 627 and the first accumulation of heat chamber 626 and be provided with the first one-way air valve 629, the first one-way air valves 629 and allow air to enter pipe the 627 and first accumulation of heat chamber 626 from the first air to flow into the first combustion chambers 621 at the first air; Be provided with the first unidirectional waste gas valve 620 between the first combustion exhaust exhaust outlet 628 and the first accumulation of heat chamber 626, the first unidirectional waste gas valve 620 allows the gas-fired waste gas first accumulation of heat chamber 626 of flowing through from the first combustion chamber 621, finally from the first combustion exhaust exhaust outlet 628, discharge (certainly, adopt gas reversing system 66 as described below, be in charge of 6671 connections when air supervisor the 667 and first air, air supervisor the 667 and second air is in charge of 6673 in cutting off; Meanwhile, combustion exhaust supervisor 669 is in charge of 6691 with the first combustion exhaust and also cuts off mutually, and corresponding combustion exhaust supervisor the 669 and second combustion exhaust is in charge of 6693 in being connected, can play the effect that replaces the first one-way air valve 629 and the first unidirectional waste gas valve 620).
In like manner, as shown in Figure 9: identical the second combustion heater 60 of structure mainly comprises that the second combustion chamber 601, the second coal gas enter arm 602 and the second regenerative heat exchanger 604.
As shown in Figure 9: body of heater 91 exterior walls that the second combustion chamber 601 is made by refractory materials and fire-resistant thermally conductive material are made the gas-fired quirk that pyrolysis vaporizer's outer ring wall 611 and outer quirk partition wall 625 surround a relative closure.
As shown in Fig. 1, Fig. 9: the second coal gas enters arm 602 and leads in the first combustion chamber 601 through body of heater 91 exterior walls.
As shown in Figure 9: the second regenerative heat exchanger 604 comprises the second accumulation of heat chamber 606, the second heat storage 603, the second air enters arm 607 and the second combustion exhaust exhaust outlet 608, the second accumulation of heat chamber 606 is arranged in body of heater 91 exterior walls, the second heat storage 603 arranges in the second accumulation of heat chamber 606, the second accumulation of heat chamber 606 1 ends lead to 601 bottoms, the second combustion chamber, the other end is connected to respectively the second air and enters arm 607 and the second combustion exhaust exhaust outlet 608, enter between arm 607 and the second accumulation of heat chamber 606 and be provided with the second one-way air valve 609 at the second air, the second one-way air valve 609 allows air to enter pipe the 607 and second accumulation of heat chamber 606 from the second air and flows into the second combustion chamber 601, be provided with the second unidirectional waste gas valve 600 between the second combustion exhaust exhaust outlet 608 and the second accumulation of heat chamber 606, the second unidirectional waste gas valve 600 allows the gas-fired waste gas second accumulation of heat chamber 606 of flowing through from the second combustion chamber 601, finally from the second combustion exhaust exhaust outlet 608, discharge (certainly, adopt gas reversing system 66 as described below, when air supervisor the 667 and first air is in charge of 6671 cut-outs, air supervisor the 667 and second air is in charge of 6673 in connecting, meanwhile, combustion exhaust supervisor the 669 and first combustion exhaust is in charge of 6691 and also is connected, and corresponding combustion exhaust supervisor 669 is in charge of 6693 also cut-outs mutually with the second combustion exhaust, can play the effect that replaces the second one-way air valve 609 and the second unidirectional waste gas valve 600).
As shown in Fig. 1, Fig. 8, between the second combustion chamber 601 of the first combustion chamber 621 and next-door neighbour, the top of outer quirk partition wall 625 is provided with combustion chamber through hole 6251, combustion chamber through hole 6251 is connected the second combustion chamber 601 of the first combustion chamber 621 and next-door neighbour to form associated one group, in this example, outer combustion gas heating unit 64 is provided with quirk partition wall 625 partition walls outside 18 roads altogether, forms 9 groups of associated burning groups; In addition, as shown in Figure 1; Because pyrolysis vaporizer 61 is highly higher, wherein outer combustion gas heating unit 64 mainly is divided into upper, middle and lower segment formula heating, and every section by 9 groups of structures, identical and associated the first combustion heater 62 and the second combustion heater 60 form.
As shown in Figure 1: on body of heater 91 exterior walls, each combustion chamber also is provided with chamber temperature monitoring holes 6201 and combustion chamber spy hole 6202, combustion chamber spy hole 6202 is convenient to the gas-fired situation that the technician intuitively observes each combustion chamber, be provided with chamber temperature table 6203 in chamber temperature monitoring holes 6201 for the temperature monitoring to combustion chamber, to the assessment of pyrolysis of coal process.
As shown in Figure 3: chamber temperature table 6203 links with industry control center 90, by industry control center 90, automatically gathers the temperature data of chamber temperature table 6203.
As Fig. 2, Fig. 3, Fig. 4, Fig. 5, Fig. 6, gas reversing system 66 comprises dish 661, lower wall 662, rotation reversing motor 663, air blower 664, gas fan 665, exhaust gas fan 666, lower wall 662 is connected to respectively air supervisor 667 and first air and is in charge of 6671, the second air is in charge of 6673, coal gas supervisor 668 and first gas manifold 6681, the second gas manifold 6683, combustion exhaust supervisor 669 and second combustion exhaust is in charge of 6693, the first combustion exhaust is in charge of 6691, wherein, the second combustion exhaust is in charge of the 6693 and first combustion exhaust and is in charge of the 6691 and first air and is in charge of the 6671 and second air and is in charge of the setting of the 6673 and first gas manifold 6681 and the second gas manifold 6683 and just exchanges (Fig. 3, Fig. 4, shown in Fig. 6).
As Fig. 3, Fig. 4, Fig. 5, shown in Fig. 6: above coil 661 and be fitted in lower wall 662 tops, upper dish 661 correspondence respectively is provided with air pipe connecting 6672, coal gas pipe connecting 6682, combustion exhaust pipe connecting 6692, thereby rotation reversing motor 663 drives upper dish 661 reciprocating rotation on lower wall 662 and realizes that air supervisor 667 constantly is in charge of the 6671 and second air with the first air and is in charge of 6673 and is connected and cut off conversion, coal gas supervisor 668 is constantly connected and is cut off conversion with the first gas manifold 6681 and the second gas manifold 6683, combustion exhaust supervisor 669 constantly is in charge of the 6693 and first combustion exhaust with the second combustion exhaust and is in charge of 6691 and is connected and cut off conversion (with the first air, be in charge of the 6671 and second air to be in charge of the switching of the 6673 and first gas manifold 6681 and the second gas manifold 6683 just contrary).
As shown in Fig. 1, Fig. 6, also be provided with two groups of bustle pipes in the periphery of body of heater 91, comprise the first air bustle pipe 6674, the first coal gas bustle pipe 6684, the first combustion exhaust bustle pipes 6694; The second air bustle pipe 6675, the second coal gas bustle pipe 6685, the second combustion exhaust bustle pipes 6695.
As shown in Fig. 1, Fig. 6, the first air bustle pipe 6674 is in charge of the 6671 and first air by the first air and is entered arm 627 and link up, by the first air be in charge of the 6671, first air bustle pipe 6674, the first air enters arm 627, the first accumulation of heat chamber 626 and the first combustion chamber 621 and forms same path;
Meanwhile, the first coal gas bustle pipe 6684 enters arm 622 by the first gas manifold 6681 and the first coal gas and links up, and the first gas manifold 6681, the first coal gas bustle pipe 6684, the first coal gas is entered to arm 622 and the first combustion chamber 621 forms same path;
Simultaneously now, the first combustion exhaust bustle pipe 6694 is the first combustion exhaust to be in charge of to the 6691 and first combustion exhaust exhaust outlet 628 link up, and the first combustion exhaust is in charge of to the 6691, first combustion exhaust bustle pipe 6694, the first combustion exhaust exhaust outlet 628, the same path of the first 626Yu combustion chamber, accumulation of heat chamber 621 formation.
In like manner, the second air bustle pipe 6675 is in charge of the 6673 and second air by the second air and is entered arm 607 and link up, by the second air be in charge of the 6673, second air bustle pipe 6675, the second air enters arm 607, the second accumulation of heat chamber 606 and the second combustion chamber 601 and forms same path;
Meanwhile, the second coal gas bustle pipe 6685 enters arm 602 by the second gas manifold 6683 and the second coal gas and links up, and the second gas manifold 6683, the second coal gas bustle pipe 6685, the second coal gas is entered to arm 602 and the second combustion chamber 601 forms same path;
Meanwhile, the second combustion exhaust bustle pipe 6695 is in charge of the 6693 and second combustion exhaust exhaust outlet 608 by the second burning gas and is linked up, and the second combustion exhaust is in charge of to the 6693, second combustion exhaust bustle pipe 6695, the second combustion exhaust exhaust outlet 608, the second accumulation of heat chamber 606 and the second combustion chamber 601 and forms same path.
In addition; as shown in Figure 3; this example also comprises that gas reversing system controller 906 is for controlling rotation reversing motor 663, air blower 664, gas fan 665, exhaust gas fan 666; gas reversing system electric controller 906 links with upper industry control center 90 again; certainly from electric control theory; in this example, rotation reversing motor 663, air blower 664, gas fan 665, exhaust gas fan 666 are controlled by also can directly at industry control center 90, so the restriction that gas reversing system controller 906 does not form this routine protection domain is set herein.
Shown in as shown in Figure 1, Figure 2～Fig. 5, Fig. 6, Fig. 3: the heating means of this outer combustion gas heating unit 64 are:
(1) industry control center 90 startup rotation reversing motors 663 drive the rotation on lower wall 662 of upper dish 661, and air supervisor the 667 and first air is in charge of 6671 connections, and air supervisor the 667 and second air is in charge of 6673 in dissengaged positions; Simultaneously, coal gas supervisor the 668 and first gas manifold 6681 also is connected, and coal gas supervisor the 668 and second gas manifold 6683 is in dissengaged positions; Meanwhile, combustion exhaust supervisor 669 is in charge of 6691 with the first combustion exhaust and also cuts off mutually, and corresponding combustion exhaust supervisor the 669 and second combustion exhaust is in charge of 6693 in the state of being connected;
(2) industry control center 90 starts air blower 664, gas fan 665, exhaust gas fan 666, air blower 664 by air blast air supervisor 667, air enter successively through air pipe connecting 6672, the first air be in charge of the 6671, first air bustle pipe 6674, the first air enters arm 627 and enters into the first accumulation of heat chamber 626, after the heat that utilizes the first heat storage 623 to discharge is heated air, enter in the first combustion chamber 621, simultaneously, gas fan 665 obtains raw gas purified gas and blasts coal gas supervisor 668 after recovery of chemical products purifies, coal gas enters coal gas pipe connecting 6682 successively, the first gas manifold 6681, the first coal gas bustle pipe 6684, the first coal gas enters arm 622 and enters in the first combustion chamber 621 and burnt, meanwhile, because combustion exhaust supervisor 669 is in charge of 6691 in the phase dissengaged positions with the first combustion exhaust, and corresponding combustion exhaust supervisor the 669 and second combustion exhaust is in charge of 6693 in the state of being connected, so the waste gas in the first combustion chamber 621 after gas-fired can only enter into the second combustion chamber 601 by the combustion chamber through hole 6251 on outer quirk partition wall 625 tops, again through in the second accumulation of heat chamber 606, after the second heat storage 603 in the second accumulation of heat chamber 606 carries out absorbing and cooling temperature from the second combustion exhaust exhaust outlet 608, the second combustion exhaust bustle pipe 6695, the second combustion exhaust is in charge of 6693, combustion exhaust supervisor 669 discharges by exhaust gas fan 666,
(3) reach and set combustion time, industry control center 90 starts the upper dish 661 of rotation reversing motor 663 drive and rotates backward on lower wall 662, air supervisor the 667 and first air is in charge of 6671 cut-outs, air supervisor the 667 and second air is in charge of 6673 in on-state, simultaneously, coal gas supervisor 668 also cuts off mutually with the first gas manifold 6681, coal gas supervisor the 668 and second gas manifold 6683 on-states, meanwhile, combustion exhaust supervisor the 669 and first combustion exhaust is in charge of 6691 and also is connected, and corresponding combustion exhaust supervisor the 669 and second combustion exhaust is in charge of 6693 also phase dissengaged positions,
(4) air blower 664 by air blast air supervisor 667, air enter successively through air pipe connecting 6672, the second air be in charge of the 6673, second air bustle pipe 6675, the second air enters arm 607 and enters into the second accumulation of heat chamber 606, after the heat that utilizes the second heat storage 603 in the second accumulation of heat chamber 606 to discharge is heated air, enter in the second combustion chamber 601, simultaneously, gas fan 665 obtains raw gas purified gas and blasts coal gas supervisor 668 after reclaiming only, coal gas enters coal gas pipe connecting 6682 successively, the second gas manifold 6683, the second coal gas bustle pipe 6685, the second coal gas enters arm 602 and enters in the second combustion chamber 601 and burnt, meanwhile, because combustion exhaust supervisor the 669 and first combustion exhaust is in charge of 6691 and is connected, and corresponding combustion exhaust supervisor the 669 and second combustion exhaust is in charge of 6693 in the phase dissengaged positions, so the waste gas in the second combustion chamber 601 after gas-fired can only enter by the combustion chamber through hole 6251 on outer quirk partition wall 625 tops in the first combustion chamber 621, again through the first accumulation of heat chamber 626, after the first heat storage 603 in the first accumulation of heat chamber 626 carries out absorbing and cooling temperature, finally from the first combustion exhaust exhaust outlet 628, the first combustion exhaust bustle pipe 6694, the first combustion exhaust is in charge of 6691, combustion exhaust supervisor 669 discharges by exhaust gas fan 666, so outer combustion gas heating unit 64 combustion principle are the waste gas generated after gas-fired in the first combustion chamber 621 and enter the second combustion chamber 601 from combustion chamber through hole 6251, after the second heat storage 603 in the second combustion chamber 601 and the second accumulation of heat chamber 606 is to its exhaust-heat absorption cooling, discharge, otherwise, the waste gas generated after gas-fired in the second combustion chamber 601 enters the first combustion chamber 621 from combustion chamber through hole 6251, after the first heat storage 603 in the first combustion chamber 621 and the first accumulation of heat chamber 606 is to its exhaust-heat absorption cooling, discharge.
In sum, this gas by the gas reversing system two advances the mode of operation of the regenerative heat exchange of a mode of operation out and regenerative heat exchanger, realize the combustion heater alternate combustion of two groups of associations, be that the gas reversing system is sent into air, purified gas burning to the combustion chamber of the first combustion heater, while is the hot waste gas after the sucking-off burning from the combustion chamber of the second combustion heater, and the second heat storage absorbing and cooling temperature of hot waste gas in the second regenerative heat exchanger of the second combustion heater becomes the relatively low low temperature waste gas of temperature and discharge; In like manner, the gas reversing system is sent into air, purified gas burning to the combustion chamber of the second combustion heater, while is the hot waste gas after the sucking-off burning from the combustion chamber of the first combustion heater, and the first heat storage absorbing and cooling temperature of hot waste gas in the first regenerative heat exchanger of the first combustion heater becomes the relatively low low temperature waste gas of temperature and discharge; This method of mutually utilizing waste gas residual heat after gas-fired to be added warm air, both played the waste gas residual heat after gas-fired had been taken full advantage of, improve the efficiency of combustion of the coal gas in combustion chamber, can carry out cooling to a certain degree to the waste gas after gas-fired again, need not consume the external energy, play energy-saving and cost-reducing purpose, save coal gangue pyrolytic gasification cost.
Heating by external gas-operated thermal bath facility 64 is controlled automatically, reduces human cost, has improved the control accuracy to the pyrolysis of coal process, realizes automatization.
As Fig. 1, shown in Figure 10, interior gas-operated thermal bath facility 67 is mainly by some groups of (6 groups of this examples) combustion heaters 68 that structure is identical, 69, because the highly higher interior gas-operated thermal bath facility 67 of pyrolysis vaporizer 61 is mainly by mainly being divided into, lower two-section type heating, every section has 6 groups of association the 3rd combustion heaters 68 that structure is identical, the 4th combustion heater 69, it forms structure and associated first burning heater 62 of combustion principle with above introduction, the second burning heater 60 is almost completely identical, the 3rd combustion heater 68 also comprises the 3rd combustion chamber 681, the 3rd coal gas enters arm 682, the 3rd accumulation of heat chamber 686, the 3rd heat storage 683, the 3rd air enters arm 687 and the 3rd combustion exhaust exhaust outlet 688.
As shown in Fig. 1, Fig. 9, Figure 10, the gas-fired quirk that the indoor ringwall 612 of pyrolytic gasification and internal-quirk partition wall 635 surround a relative closure is made by fire-resistant thermally conductive material in the 3rd combustion chamber 681.
As shown in Figure 1, Figure 10 shows, the 3rd coal gas of hypomere enter arm 682 below the bar bow 651 of center support bow 65 through upwards leading to the 3rd combustion chamber 681, the 3rd accumulation of heat chamber 686 is arranged on the body of heater 91 that bar bends 651 belows, the 3rd heat storage 683 is placed in the 3rd accumulation of heat chamber 686, the 3rd accumulation of heat chamber 686 1 ends lead to three combustion chamber 681 bottoms through extending upward by extending passage 6861 below the bar bow 651 of center support bow 65, and the 3rd accumulation of heat chamber 686 the other ends are connected to respectively the 3rd air and enter arm 687 and the 3rd combustion exhaust exhaust outlet 688.
As Fig. 1, Fig. 9, shown in Figure 10, the 3rd coal gas of epimere enter arm 682 below the bar bow 651 of center support bow 65 through upwards through quirk partition wall 635, leading to the 3rd combustion chamber 681, the 3rd accumulation of heat chamber 686 is arranged on the body of heater 91 that bar bends 651 belows, the 3rd heat storage 683 is placed in the 3rd accumulation of heat chamber 686, the 3rd accumulation of heat chamber 686 1 ends by extend passage 6861 below the bar bow 651 of center support bow 65 through upwards through quirk partition wall 635, extending and lead to 681 bottoms, the 3rd combustion chamber, the 3rd accumulation of heat chamber 686 the other ends are connected to respectively the 3rd air and enter arm 687 and the 3rd combustion exhaust exhaust outlet 688.
In like manner, as shown in Figure 9, Figure 10, the 4th combustion heater 69 structures are complete identical with the 3rd combustion heater 68, repeat no more here, and wherein the 4th combustion chamber 691 is connected and formed associated one group (shown in Fig. 1, Fig. 8) by chamber passage 6305 with the 3rd combustion chamber 681.
Wherein, as shown in Figure 6, the 3rd coal gas of the 3rd combustion chamber 681 of the 3rd burning heater 68 enters arm 682, the 3rd air and enters arm 687 and the 3rd combustion exhaust exhaust outlet 688 and be in charge of the 6671, first combustion exhaust by the first coal gas bustle pipe 6684, the first air bustle pipe 6674, the first combustion exhaust bustle pipes 6694 and the first gas manifold 6681, the first air respectively and be in charge of 6691 and communicate.
As shown in Fig. 1, Fig. 6, Figure 10, the 4th coal gas of the 4th combustion chamber 691 of the 4th burning heater 69 enters arm 692, the 4th air and enters arm 697 and the 4th combustion exhaust exhaust outlet 698 and be in charge of the 6673, second combustion exhaust by the second coal gas bustle pipe 6685, the second air bustle pipe 6675, the second combustion exhaust bustle pipe 6695 and the second gas manifold 6683, the second air respectively and be in charge of 6693 and communicate.
In sum, the 3rd burning heater 68, the 4th combustion heater 69 combustion principle and above the first burning heater 62, the second burning heater 60 are almost completely identical, repeat no more here.
As shown in Figure 1, Figure 10 shows, center support bow 65, because the quirk partition wall 635 of the indoor ringwall 612 of pyrolytic gasification and internal combustion heating unit 67 all is arranged in furnace chamber, need center support bow 65 for it provides support, the laying of various pipelines is provided to again internal combustion heating unit 67 simultaneously.
As shown in Figure 1, Figure 10 shows, center support bow 65 is arranged in the furnace chamber of pyrolysis vaporizer 61, internal combustion heating unit 67 belows, the bar that mainly comprises some bends 651 ,Huo Gong center ringwalls 652, bar bow 651 1 ends are fixed on Huo Gong center ringwall 652, the other end is fixed on body of heater 91, bar bow 651 is the radial layout of scattering in interval at a certain angle around ringwall 652 centers, Huo Gong center, fire bow 651 in this example is 12 bows, and quantity is consistent with the 3rd burning heater 68 the 4th burning heater 69 sums that are mutually related of internal combustion heating unit 67.
As shown in Figure 1, Figure 10 shows, article one, in the body of wall of fire bow 651, the extension passage 6861 that the 3rd coal gas enters arm 682 and the 3rd accumulation of heat chamber 686 is set, the 4th coal gas tightly arranged in the body of wall of another adjacent fire bow 651 enters the extension passage 6961 in arm 692 and the 4th accumulation of heat chamber 696, provide convenience to the pipeline laying of internal combustion heating unit 67, make the various conduit arrangements of internal combustion heating unit 67 orderly, be unlikely to interfere.
The second section water-gas reaction
Because coal gangue temperature in pyrolysis vaporizer is higher, then pass into water vapor to coal gangue, the charcoal in coal gangue pyrolysis after product and superheated vapour meet and carry out water-gas reaction generation water-gas (carbon monoxide and hydrogen).
As shown in Fig. 1, Figure 10, Fig. 1, water-gas reaction device 7 comprises pyrolysis vaporizer 61, material heat sink 70, steam generation device 75.
As shown in Figure 1, pyrolysis vaporizer 61 is positioned at center support and bends 65 tops, and material heat sink 70, steam generation device 75 are positioned at center support and bend 65 belows.
As shown in Fig. 1, Fig. 1, material heat sink 70 is arranged on and stretches out body of heater 91 bottoms, comprises high temperature cooling chamber 701, low temperature cooling chamber 702, cooling chamber's bridge bow 703; The top of high temperature cooling chamber 701 communicates with pyrolysis vaporizer 61 bottoms; High temperature cooling chamber 701 and low temperature cooling chamber 702 are setting up and down, and cooling chamber's bridge bow 703 is arranged between high temperature cooling chamber 701 and low temperature cooling chamber 702, and cooling chamber's bridge bow 703 comprises that bridge bow 7031, steam chest 704, steam enter siphunculus 707; Article 4, bridge bow 7031 is partitioned into spoke shape layout at an angle with high temperature cooling chamber 701 and the 702Zhou of low temperature cooling chamber center, bridge bends 7031 middle parts and forms steam chest 704, steam chest 704 is a cylindrical chamber, the top of steam chest 704 is provided with semisphere blast cap 708, and the lower openings of steam chest 704 is towards low temperature cooling chamber 702; Steam enters siphunculus 707 and is arranged in bridge bow 7031, and steam enters siphunculus 707 1 ends and leads to steam chest 704, and the other end stretches out outside body of heater 91.
As Fig. 1, shown in Fig. 2, steam generation device 75 comprises annular hollow metal casing 755, steam pockets 754 and drum input tube 751, drum output tube 752, annular hollow metal casing 755 is arranged on body of heater 91 bottoms, the interior annular space chamber 758 of annular hollow metal casing 755 is connected to low temperature cooling chamber 702 bottoms of material heat sink 70, the big up and small down funnel-form of interior annular space chamber 758 annular cavity, 755 casees interior formation of annular hollow metal casing seal the body of heater water bag 753 for storage of water relatively, body of heater water bag 753 is connected to water inlet pipe 756 and drum input tube 751, water inlet pipe 756 communicates with water tank 757, drum input tube 751 is connected with steam pockets 754, the drum output tube 752 of steam pockets 754 enters siphunculus 707 the other ends with the steam of material heat sink 70 and communicates.
Water-gas reaction Principle Method of the present utility model is:
(1), in steam pockets 754, water vapor enters siphunculus 707 by drum input tube 752 and steam and passes into water vapor to the low temperature cooling chamber 702 of material heat sink 70, water vapor blows to low temperature cooling chamber 702, except the cooling of the solid product to after pyrolytic gasification in low temperature cooling chamber 702, water vapor upwards seals in high temperature cooling chamber 701, give the cooling of the high-temp solid product after pyrolysis vaporizer 61 falls into a large amount of pyrolytic gasification of high temperature cooling chamber 701, when the solid of water vapor after giving pyrolytic gasification lowered the temperature, improve vapor temperature and form superheated vapour;
(2), superheated vapour enters pyrolysis vaporizer 61 through center support bow 65, and contact with the high-temperature coal spoil pyrolysis material of pyrolysis vaporizer 61, the charcoal after the coal gangue pyrolysis in solid product and superheated vapour meet and carry out water-gas reaction generation water-gas (carbon monoxide and hydrogen);
(3), solid product after the coal gangue pyrolytic gasification falls into high temperature cooling chamber 701 and the low temperature cooling chamber 702 of material heat sink 70 from pyrolysis vaporizer 61, the water vapor that upwards enters pyrolysis vaporizer 61 to passing through low temperature cooling chamber 702 and high temperature cooling chamber 701 is heated as overheated high-temperature water vapor again, again the solid product after the coal gangue pyrolytic gasification is lowered the temperature simultaneously, in recycling low temperature cooling chamber 702, the solid product waste heat adds the thermosetting water vapor to the water in body of heater water bag 753, water vapor enters in steam pockets 754 by drum input tube 751, give in steam pockets 754 and supplement a large amount of water vapors that consume because of water-gas reaction, make water-gas reaction uninterruptedly to carry out continuously.
The a large amount of generation of water-gas reaction of the present utility model is to carry out in pyrolysis vaporizer 61 middle and lower parts, this is because the pyrolysis of coal gangue in this section pyrolysis vaporizer is relatively abundant, temperature is also relatively high, now from the bottom of pyrolysis vaporizer 61, pass into the water vapor of hyperthermia and superheating, the charcoal in the solid product after overheated water vapor and coal gangue pyrolysis swashs and will produce a large amount of water-gas mutually; Certainly, water vapor is in giving high temperature cooling chamber 701 and low temperature cooling chamber 702 in the solid product temperature-fall period after the coal gangue pyrolytic gasification, also can produce water-gas with charcoal remaining in solid product after the coal gangue pyrolytic gasification, but the amount less produced, this height of charcoal remaining in solid product after this and coal gangue pyrolytic gasification is few, and steam temperature neither be too high relevant.
The waste heat of the solid product that the temperature of the utility model utilization after the coal gangue pyrolytic gasification is relatively low carries out heat transmission and produces water vapor, the recycling water vapor solid product higher with temperature directly contacts the generation superheated vapour, reach the temperature required of water-gas reaction, promote water-gas reaction more to fill part, both when reducing the solid product temperature, produce again water vapor and superheated vapour, this technological method that consumes additional energy source that do not need meets energy-saving and cost-reducing that we advocate today, the theory of Sustainable development.
The 3rd joint raw gas take-up gear
Coal gangue produces the gas containing a lot of useful compositions in the high temperature pyrolysis and gasification process, charcoal in coal gangue pyrolysis after product and superheated vapour carry out water-gas reaction and generate water-gas (carbon monoxide and hydrogen), above general designation raw gas, need to derive in order to utilize raw gas.
As shown in Fig. 1, Fig. 8, Fig. 9, raw gas take-up gear 8, comprise raw gas concentration chamber 81, interior derivation passage 82, and outer derivation passage 83, derivation main channel 84, derive circuit 85; It is integrally formed that raw gas concentration chamber 81 is arranged on top and the pyrolysis vaporizer 61 of pyrolysis vaporizer 61; As shown in Fig. 1, Fig. 8, article 6, deriving passage 82 in arranges in quirk partition wall 635, interior derivation feeder connection 821 leads to pyrolysis vaporizer 61 through interior ringwall 612 middle parts, the raw gas concentration chamber 81 that interior derivation channel outlet 822 is led to the pyrolysis vaporizer top through interior ringwall 612; As shown in Fig. 1, Fig. 8, article 6, the outer passage 83 of deriving arranges in the exterior wall of body of heater 91, lower outside derivation feeder connection 831, upper outside derivation feeder connection 834 lead to pyrolysis vaporizer 61 through outer ring wall 611 middle parts, the raw gas concentration chamber 81 that outer derivation channel outlet 832 is led to the pyrolysis vaporizer top through outer ring wall 611.
As shown in Figure 1, Figure 7 shows, deriving main channel 84 is arranged in the exterior wall of body of heater 91 of coal heat decomposition stove, derivation main channel entrance 841 communicates with raw gas concentration chamber 81 and extends up in the exterior wall top derivation circuit 85 that body of heater 91 is set again, and derives circuit 85 and is provided with raw gas export mouth 851, raw gas export mouth 852.
As Fig. 1, Fig. 7, Fig. 8, shown in Fig. 9, in this example because pyrolysis vaporizer's 61 annular chamber, so raw gas concentration chamber 81 is corresponding annular chamber also, article 6, deriving passage 82 in is separately positioned in 6 road quirk partition walls 635, lead to pyrolysis vaporizer 61 through interior ringwall 612, article 6, outer derive passage 83 be separately positioned in the middle of body of heater 91 exterior walls through and outer quirk partition wall 625 and outer ring wall 611 lead to pyrolysis vaporizer 61, wherein, because the circumference of pyrolysis vaporizer 61 is longer, so interior ringwall 612 in pyrolysis vaporizer 61, be respectively arranged with on outer ring wall 611 in 6 and derive feeder connection 821 and lower outside derivation feeder connection 831, upper outside derivation feeder connection 834, again because the height of pyrolysis vaporizer 61 is high, interior derivation feeder connection 821 and lower outside derivation feeder connection 831, the setting of staggering up and down of upper outside derivation feeder connection 834, as shown in Figure 1, interior derivation feeder connection 821 is higher than lower outside derivation feeder connection 831, but lower than upper outside derivation feeder connection 834 places, this example adopts this structure can better derive the raw gas that in pyrolysis vaporizer 61, different sections produce, also be provided with 6 the larger raw gas of sectional area main channels 84 around raw gas concentration chamber 81 in addition and lead to derivation circuit 85, the purpose arranged like this can conveniently derive a large amount of raw gas in raw gas concentration chamber 81.
As shown in Figure 1, be provided with the raw gas temperature monitoring holes 811 that leads to raw gas concentration chamber 81 on the exterior wall of body of heater 91, place raw gas temperature table 812 in raw gas temperature monitoring holes 811.
As shown in Figure 3, raw gas temperature table 812 and 90 electrical connections of industry control center, industry control center 90 is by temperature in raw gas temperature table 812 monitoring raw gas concentration chamber 81.
These routine characteristics will enter interior derivation passage 82 from interior derivation feeder connection 821 respectively by the different sections raw gas that produce in pyrolysis vaporizer 61, entering outer derivation passage with lower outside derivation feeder connection 831, upper outside derivation feeder connection 834 goes out in 83 to collect in raw gas concentration chamber 81 again, certainly a large amount of raw gas in pyrolysis vaporizer 61 are directly to rise up in raw gas concentration chamber 81, enter derivation circuit 85 by deriving main channel 84, finally discharge from raw gas export mouth 851.
The 4th joint continuous pyrolysis gasification
Comprehensively above-mentioned, these routine characteristics are that coal gangue pyrolysis, gasification (water-gas reaction), steam generation, raw gas are derived to process integration in same body of heater, make coal gangue pyrolysis, gasification (water-gas reaction), steam generation, raw gas be able to continuous realization.
As shown in Figure 1, coal gangue pyrolytic gasification stove 9 comprise body of heater 91, enter furnace charge storehouse 92, coal gangue pyrolysis gasifying device 93, raw gas take-up gear 8, hinge cage sealing discharging device 96, product feed bin 94, coal gangue pyrolysis gasifying device 93 comprises coal gangue pyrolysis installation 6, water-gas reaction device 7, and the concrete structure of coal gangue pyrolysis installation 6, water-gas reaction device 7, raw gas take-up gear 8 is shown in the above, enter furnace charge storehouse 92 and be arranged on body of heater 91 tops, body of heater 91 tops are provided with into stove cloth passage 921, enter stove cloth passage 921 upper ends and enter furnace charge storehouse 92 and communicate, entering stove cloth passage 921 lower ends communicates with pyrolysis vaporizer 61 tops of coal gangue pyrolysis installation 6, hinge cage sealing discharging device 96 is arranged on 758 bottoms, interior annular space chamber of annular hollow metal casing 755 of the steam generation device 75 of water-gas reaction device 7, product feed bin 94 is placed in body of heater 91 bottoms, connect hinge cage sealing discharging device 96 on product feed bin 94, hinge cage sealing discharging device 96 belongs to prior art, as the sealing discharging device on market, the sealing material returning device, sealing blanking device etc.
The method of this routine continuous pyrolysis gasification is:
(1), by controlling stove coal gangue rotary conveyor 95, the stove coal gangue pellet that enters after damping dehydration is sent in furnace charge storehouse 92, then by entering stove cloth passage 921, enter in the pyrolysis vaporizer 61 of coal gangue pyrolysis installation 6;
(2), purify in the outer combustion gas heating unit 64 by coal gangue pyrolysis installation 6, interior gas-operated thermal bath facility 67 after gas-fired provide thermal source to pyrolysis vaporizer 61, coal gangue carries out pyrolysis in pyrolysis vaporizer 61 under hot environment;
(3), by water-gas reaction device 7, from pyrolysis vaporizer 61 bottoms, pass into high-temperature water vapor, and the coal gangue pyrolysis material hot with the high temperature of pyrolysis vaporizer 61 contact, the charcoal in the solid product after the coal gangue pyrolysis and superheated vapour meet and carry out water-gas reaction and generate water-gas;
(4), solid product after the coal gangue pyrolytic gasification falls into high temperature cooling chamber 701 and the low temperature cooling chamber 702 of material heat sink 70 from pyrolysis vaporizer 61, the water vapor that upwards enters pyrolysis vaporizer 61 to passing through low temperature cooling chamber 702 and high temperature cooling chamber 701 is heated as overheated high-temperature water vapor again, again the solid product after the coal gangue pyrolytic gasification is lowered the temperature simultaneously, in recycling low temperature cooling chamber 702, the solid product waste heat adds the thermosetting water vapor to the water in the body of heater water bag 753 of the annular hollow metal casing 755 of steam generation device 75, water vapor enters in steam pockets 754 by drum input tube 751, give in steam pockets 754 and supplement a large amount of water vapors that consume because of water-gas reaction,
(5), steam pockets 754 enters siphunculus 707 by drum input tube 752 and steam and passes into water vapor to the low temperature cooling chamber 702 of material heat sink 70 again, makes water-gas reaction uninterruptedly to carry out continuously;
(6) gas that, coal gangue produces in the high temperature pyrolysis process and carry out water-gas reaction and generate water-gas (carbon monoxide and hydrogen), be referred to as raw gas, raw gas is derived by the raw gas take-up gear 8 arranged on body of heater, in order to carry out recovery of chemical products and utilization, derivation main channel 84 processes that simultaneously raw gas of comparatively high temps enters the raw gas take-up gear from pyrolysis vaporizer 61 tops are carried out preheating to the coal gangue pellet that just enters stove from entering pyrolysis vaporizer 61 tops that stove cloth passage 921 enters again;
(7) according to coal gangue pyrolytic gasification degree, control hinge cage sealing discharging device 96 in good time and open or close, the solid product after coal gangue high temperature pyrolysis and gasification cooling in low temperature cooling chamber 702 and interior annular space chamber 758 is entered in the product feed bin.
This example by coal gangue pyrolytic gasification process integration at the hot body of heater of same coal, realize continuous coal gangue pyrolytic gasification, production efficiency is high, the required factory building face of equipment is little, human cost is low, utilize waste heat in the solid product after pyrolytic gasification to produce water vapor, the solid product after utilizing again water vapor to high temperature pyrolysis and gasification is lowered the temperature produces the needed high humidity superheated vapour of water-gas reaction simultaneously, has the characteristics of low consumption, environmental protection simultaneously.
The comprehensive cyclic utilization of the 4th part, pyrolysis of coal gas
Chapter 1, the reclaiming clean utilization of raw gas (change product)
First segment raw gas condensing works
As shown in Figure 1, higher from raw gas export mouth 851 discharge raw gas temperatures, for the ease of the high temperature raw gas, before recovery of chemical products, carried, need to use 86 pairs of high temperature raw gas of raw gas condensing works and carry out cooling.
As shown in Figure 1, raw gas condensing works 86 comprises, condensation housing 861, regulating wheel 862, threaded adjusting bar 863, valve gap 864, valve seat 865, effuser 867, ammoniacal liquor shower nozzle 868, condensation housing 861 is relative sealing long barrel shape, its side wall upper part offers raw gas admission port 869, ammoniacal liquor shower nozzle 868 is arranged on the top in condensation housing 861, threaded adjusting bar 863 1 ends stretch out and regulating wheel 862 thread connection from condensation housing 861 tops, threaded adjusting bar 863 the other ends and valve gap 864 are connected to a fixed, valve seat 865 is arranged on the interior middle and lower part of condensation housing 861 by 861 minutes upper and lower two portions of condensation housing, valve seat 865 middle parts are formation like funnelform annular cavity, valve gap 864 is back taper, valve gap 864 is placed in annular cavity, the control to the uninterrupted of raw gas is realized in the gap of the inner ring surface of the male cone (strobilus masculinus) of threaded adjusting bar 863 by driving valve gap 864 and annular cavity, effuser 867 is arranged on condensation housing 861 bottoms.
In addition, regulating wheel 862 can manual adjustment wheel, can also be the automatic regulating wheel with stepper-motor, and 90 pairs, industry control center regulating wheel 862 rotates and automatically controls as shown in figure 13.
These routine characteristics are: when raw gas is discharged and entered condensation housing 861 by raw gas admission port 869 from raw gas export mouth 851, run into raw gas that the ammoniacal liquor of ammoniacal liquor shower nozzle 868 ejection the lowered the temperature mixed solution together with coal tar and ammoniacal liquor, flow through and enter condensation housing 861 bottoms from the gap of the inner ring surface of the annular cavity of the male cone (strobilus masculinus) of valve gap 864 and valve seat 865, finally by effuser 867, carry and carry out follow-up purification recovery, this example moves up and down by the rotation drive threaded adjusting bar 863 of regulating wheel 862, thereby the gap length of the inner ring surface of the male cone (strobilus masculinus) of adjustment valve gap 864 and the annular cavity of valve seat 865 plays the control of the raw gas pressure of controlling raw gas concentration chamber 81, booster action is played in control to the coal gangue pyrolysis gas process of pyrolysis vaporizer 61.
The reclaiming clean of second section raw gas
Raw gas after ammoniacal liquor sprays carries out gas-liquid separation together with the mixed solution of coal tar process ammoniacal liquor through effuser, contain multiple useful organic component in mixed solution after gas-liquid separation and refine other auxiliary product as carbolic oil, naphtalene oil, washing oil, carbolineum etc. for industry, coal gas after gas-liquid separation is after the air cooling cooling, become purified gas after the dry back receiving apparatus purifies recovery, purified gas can store for burning.
As shown in Figure 14, Figure 15, raw gas reclaiming clean device 4 comprises coal tar and ammoniacal liquor gas-liquid mixture transfer lime 410, coal tar ammonia precipitation process groove 42, air cooler 43, gas fan group 44, activated coke dry method withdrawer 45, activated coke bucket elevator 46, activated coke revivifier 47, cut tower 48, oil gas air cooler 49.
As shown in Figure 14, Figure 15, raw gas and coal tar are divided into and enter in two branch roads through coal tar and ammoniacal liquor gas-liquid mixture transfer lime 410, raw gas upwards leads to air cooler 43 through a road heating gas transfer lime 412, coal tar and ammonia water mixture lead to coal tar ammonia precipitation process groove 42 downwards through another road mixed solution pipe 413, coal tar ammonia precipitation process groove is common tank body in industry, and coal tar ammonia precipitation process groove 42 separates coal tar with ammonia precipitation process, air cooler 43 comprises air cooling housing 431, coal gas cooling pipe network 435, the inner air cooling chamber 436 that forms of air cooling housing 431, coal gas cooling pipe network 435 is grid by a fairly large number of stainless steel tube by certain rule and forms, coal gas cooling pipe network 435 independent loops are placed in air cooling chamber 436, coal gas cooling pipe network 435 entrances link with heating gas transfer lime 412 by the first air cooling gate valve 432, coal gas cooling pipe network outlet 433 also is provided with the second air cooling gate valve 434, gas fan group 44 links by the first air cooling gas conveying tube 414 and the second air cooling gate valve 434, activated coke dry method withdrawer 45 communicates with gas fan group 44 by the second gas conveying tube 415.
As shown in figure 13, gas fan group 44 links with industry control center 90, by industry control center 90, automatically controls the work of gas fan group 44.
As shown in figure 15, activated coke dry method withdrawer 45 comprises that recycling shell collector 453, absorption storehouse 458, unsaturated activated coke enter storehouse 454, saturated active coke storage silo 456, recycling shell collector 453 is a cavity container, recycling shell collector 453 top purified gas output tubes 416, recycling shell collector 453 bottoms and the second gas conveying tube 415 link; Absorption storehouse 458 is arranged in sky recycling shell collector 453 between purified gas output tube 416 and the second gas conveying tube 415, absorption 458 top, storehouse 4581, bottom 4582 are the filtration net structure, absorption top, storehouse 4581 enters storehouse 454 with the unsaturated activated coke that is arranged on recycling shell collector 453 tops and links, and absorption top, storehouse 4581 and unsaturated activated coke enter between storehouse 454 the first recovery gate valve 455 is set; Absorption storehouse bottom 4582 be arranged on recycling shell collector 453 bottoms with saturated active coke storage silo 456 links, bottom the absorption storehouse 4582 and saturated active coke storage silo 456 between be provided with the second recovery gate valve 457.
As shown in figure 15, activated coke revivifier 47 comprises revivifier housing 471, hot waste gas evaporation pipe network 472, unsaturated activated coke recovery bin 476, revivifier housing 471 is a cavity container, revivifier housing 471 tops are provided with saturated active coke and enter gate valve 475, bottom is provided with unsaturated activated coke discharge gate valve 474, unsaturated activated coke discharge gate valve 474 belows are provided with unsaturated activated coke recovery bin 476, also are provided with evaporation exhaust of oil pipe 473 on revivifier housing 471; 472 one-tenth independent loops of waste gas evaporation pipe network are arranged in revivifier housing 471 chambeies, the bottom of waste gas evaporation pipe network 472 is provided with hot waste gas and enters pipe 477, top is provided with hot waste gas delivery pipe 479, in order to increase the flow velocity of hot waste gas at waste gas evaporation pipe network 472, be provided with waste gas circulation pipeline 478 at waste gas evaporation pipe network 472 middle parts, waste gas circulation pipeline 478 stretch out revivifier housing 471 outer and hot waste gas recirculation blower (figure does not look out) link.
As shown in figure 15, activated coke bucket elevator 46 comprises saturated active coke bucket elevator 461, unsaturated activated coke bucket elevator 462, saturated active coke bucket elevator 461 1 ends are arranged in the saturated active coke storage silo 456 of activated coke dry method withdrawer 45 belows, and the saturated active coke that the other end leads to activated coke revivifier 47 tops enters gate valve 475; Unsaturated activated coke bucket elevator 462 1 ends are arranged in unsaturated activated coke recovery bin 476, and the unsaturated activated coke that the other end leads to activated coke dry method withdrawer 45 enters in storehouse 454.
As shown in figure 13, saturated active coke bucket elevator 461, unsaturated activated coke bucket elevator 462 link with industry control center 90, by industry control center 90, automatically control the work of saturated active coke bucket elevator 461, unsaturated activated coke bucket elevator 462.
As shown in figure 15, cut tower 48 comprises cut tower shell 481, crude benzol return channel 482, cut net 483, mixed triolein oil trap 484, carbolineum medial launder 485, cut tower shell 481 is a cavity container, the top of cut tower shell 481 is provided with light oil crude benzene vapor vent pipe 417, and cut tower shell 481 bottoms are carbolineum medial launder 485, cut net 483 is arranged in cut tower shell 481 and is positioned at the top of carbolineum medial launder 485, cut net 483 comprises lower cut net 4831, middle cut net 4832, upper cut net 4833, wherein descend cut net 4831, middle cut net 4832, upper cut net 4833 is disposed in cut tower shell 481 successively from top to bottom, lower cut net 4831, between middle cut net 4832, the evaporation exhaust of oil pipe 473 of cavity and activated coke revivifier 47 links, middle cut net 4832, upper cut net 4833 is provided with mixed triolein oil trap 484, between the top of upper cut net 4833 and cut tower shell 481, crude benzol return channel 482 is set.
As shown in figure 15, carbolineum medial launder 485 is mainly used to deposit carbolineum, and it is the common cooling structure of an industry (referring to the structrual description of following mixed triolein water cooler 487) that carbolineum medial launder 485 connects a carbolineum water cooler 486 with circulation pipe network.
As shown in figure 15, mixed triolein oil trap 484 comprises oil trap dividing plate 4841, oil trap is every cap 4842, raise up a split ring along 4843 in the middle of oil trap dividing plate 4841, oil trap every cap 4842 cover put split ring along 4843 on, split ring along 4843 and cut tower shell 481 between form oil-collecting tank 4844, oil-collecting tank 4844 slot parts are provided with the mixed triolein transfer lime 418 that passes cut tower shell 481, mixed triolein transfer lime 418 communicates with mixed triolein water cooler 487, mixed triolein water cooler 487 is common cooling structure, comprise in cooler casing 4871 and form waterway 4872, contaminated product cooling pipe network 4873 forms independent loop and is placed in waterway 4872, the entrance of contaminated product cooling pipe network 4873 communicates with mixed triolein transfer lime 418, the outlet of contaminated product cooling pipe network 4873 communicates with mixed triolein medial launder 488, mixed triolein medial launder 488 is mainly used to deposit mixed triolein.
As shown in figure 15, oil gas air cooler 49 comprises air cooler support body 491, air cooler pipe network 492, air cooling blower fan 493, air cooler support body 491 upper and lower parts form respectively airtight upper chamber 497, lower chamber 498, between upper chamber 497 and lower chamber 498, by air cooler pipe network 492, communicate, upper chamber 497 communicates with light oil crude benzene vapor vent pipe 417, lower chamber 498 is led in water-and-oil separator 495 and crude benzol backflash 496, water-and-oil separator 495 is the industry common structure, repeats no more.
Comprehensively go out a kind of coal gangue pyrolytic gasification raw gas by upper third part, the described content of the 4th part and derive condensation and reclaiming clean device and method, this device comprises coal gangue pyrolysis gasifying device 93, raw gas take-up gear 8, raw gas condensing works 86, raw gas reclaiming clean device 4, concrete structure and annexation are shown in the above, here repeat no more, only their annexation is explained here.
As shown in Fig. 1, Figure 14, Figure 15, the raw gas export mouth 851 of raw gas take-up gear 8 passes through pipeline communication with the raw gas admission port 869 of raw gas condensing works 86, the effuser 867 of raw gas condensing works 86 is connected by pipeline with coal tar and the ammoniacal liquor gas-liquid mixture transfer lime 410 of raw gas reclaiming clean device 4, and the step that present method realizes is:
(1), purify in the outer combustion gas heating unit 64 by coal gangue pyrolysis installation 6, interior gas-operated thermal bath facility 67 after gas-fired provide thermal source to pyrolysis vaporizer 61, coal gangue carries out pyrolysis in pyrolysis vaporizer 61 under hot environment;
(2), by water-gas reaction device 7, from pyrolysis vaporizer 61 bottoms, pass into high-temperature water vapor, and the coal gangue pyrolysis material hot with the high temperature of pyrolysis vaporizer 61 contact, the charcoal in the solid product after the coal gangue pyrolysis and superheated vapour meet and carry out water-gas reaction and generate water-gas;
(3), the gas that produces in the high temperature pyrolysis process of coal gangue and carry out water-gas reaction and generate water-gas (carbon monoxide and hydrogen), be referred to as raw gas, raw gas is derived by the raw gas take-up gear 8 arranged on body of heater;
(4), the raw gas of derivation is passed into to raw gas condensing works 86 and carry out the mixed solution of ammoniacal liquor sprinkling cooling formation raw gas together with coal tar and ammoniacal liquor;
(5), raw gas is divided into two-way together with coal tar and ammonia water mixture through raw gas reclaiming clean device 4 coal tar and ammoniacal liquor gas-liquid mixture transfer lime 410, one road heating gas transfer lime 412 upwards leads to air cooler 43 and carries out coolingly, and the coal tar ammonia water mixture flows to tar ammonia settling bath 42 downwards through another road mixed solution pipe 413 of raw gas reclaiming clean device 4 and carries out precipitate and separate;
(6), cooling raw gas is delivered to through gas fan group 44 in the activated coke dry method withdrawer 45 of raw gas reclaiming clean device 4 and is carried out activated coke absorption (also can be referred to as activated coke absorption in industry), saturated activated coke falls into saturated active coke storage silo 456, send into activated coke revivifier 47 through saturated active coke bucket elevator 462 and evaporate regeneration, unsaturated activated coke after evaporation falls into unsaturated activated coke recovery bin 476, again send in activated coke dry method withdrawer 45 and enter absorption through unsaturated activated coke bucket elevator 46, so repeatedly carry out, purified gas after absorption is for storage or burning,
(7), evaporate the light oil that contains of regeneration through the activated coke revivifier 47 of raw gas reclaiming clean device 4, crude benzol, mixed triolein, the compositions such as carbolineum enter cut tower 48 by evaporation exhaust of oil pipe 473 and carry out cut, the carbolineum that proportion is larger flows in the carbolineum medial launder by lower cut net 4833, the slightly heavy mixed triolein of proportion flows in the oil-collecting tank 4844 of mixed triolein oil trap 484, by mixed triolein transfer lime 418, enter in mixed triolein water cooler 487 cooling, finally store in mixed triolein medial launder 488, the light oil that proportion is lighter and crude benzol steam enter oil gas air cooler 49 and carry out condensation from light oil crude benzene vapor vent pipe 417, phlegma enters water-and-oil separator 495 and carries out oily water separation, light oil and crude benzol solution enter in crude benzol backflash 496, wherein a part is for returning stream, part overflow is to light oil crude benzol medial launder.
Wherein between the 4th step and the 5th step, increasing by a step is, by the regulating wheel 83 of raw gas condensing works 86, thereby regulate raw gas together with the circulation realization of the mixed solution of coal tar and ammoniacal liquor the pressure-controlling to the raw gas in coking chamber 61.
Chapter 2, raw gas reclaiming clean afterfire utilizes
Purified gas burning after first segment raw gas reclaiming clean
Comprehensive above content draws a kind of coal gangue pyrolytic gasification raw gas purification of combustion recycling device and method, this device mainly comprises coal gangue pyrolysis gasifying device 93, raw gas take-up gear 8, activated coke dry method withdrawer 45, also comprises raw gas condensing works 86, concrete structure is shown in the above, here repeat no more, at this moment only explain with regard to its annexation.
As shown in Figure 15, Fig. 1, the gas fan 665 of gas reversing system 66 in the coal gangue pyrolysis installation 6 of the purified gas output tube on activated coke dry method withdrawer 45 tops of raw gas reclaiming clean device 4 416 and coal gangue pyrolysis gasifying device 93 is connected by pipeline.
Wherein above the 6th step is further supplemented and is, outer combustion gas heating unit 64, interior gas-operated thermal bath facility 67 that purified gas after absorption is transported to coal gangue pyrolysis installation 6 by purified gas output tube 416 are burnt, and its combustion principle method mainly is shown in that the 3rd first segment is described.
After second section utilizes the purified gas burning, waste gas is to saturated active coke regeneration heating
Comprehensive above content draws a kind of coal gangue pyrolytic gasification raw gas purification of combustion hot waste gas active coke regeneration device and method, this device mainly comprises coal gangue pyrolysis gasifying device 93, raw gas take-up gear 8, activated coke revivifier 47, also comprises raw gas condensing works 86, concrete structure is shown in the above, here repeat no more, at this moment only explain with regard to its annexation.
As shown in Fig. 1, Figure 15, the exhaust gas fan 666 that the hot waste gas of activated coke revivifier 47 bottoms of raw gas reclaiming clean device 4 is entered to gas reversing system 66 in pipe 477 and the coal gangue pyrolysis installation 6 of coal gangue pyrolysis gasifying device 93 is connected by pipeline.
Increase again by a step after the 6th step after above-mentioned supplementing, the hot waste gas that the exhaust gas fan 666 of rear waste gas by gas reversing system 66 that burn in the outer combustion gas heating unit 64 of coal gangue pyrolysis installation 6, interior gas-operated thermal bath facility 67 is entered to activated coke revivifier 47 bottoms of raw gas reclaiming clean device 4 enters pipe 477, in the hot waste gas evaporation pipe network 472 that heat is useless, gas enters activated coke revivifier 47, it is unsaturated activated coke that the saturated active coke in revivifier housing 471 is evaporated to thermal regeneration.
After the 3rd joint utilizes the purified gas burning, hot waste gas carries out the damping dehydration to the hot waste gas entered after stove coal gangue pellet damping purified gas burns for the coal gangue pellet to entering stokehold.
Chapter 3, the continuous coal gangue pyrolytic gasification of thermal cycling is comprehensive
The continuous coal gangue pyrolytic gasification of first segment thermal cycling and damping and tail gas clean-up
Hot waste gas after the purified gas burning, for the coal gangue pellet that enters stokehold is carried out to the damping dehydration, carries out water again and washes one's hair purification and cooling after the hot waste gas dehydration, finally reach clean discharged at lower temperature.
The continuous coal gangue pyrolytic gasification of second section thermal cycling composite technology
Comprehensive above content draws the complete composite technology of the continuous coal gangue pyrolytic gasification of a kind of thermal cycling, includes stove coal gangue hot waste gas damping dehydration, coal gangue pyrolytic gasification, raw gas condensation, raw gas reclaiming clean, tail gas water and washes one's hair purification etc.
The control of the continuous coal gangue pyrolytic gasification of the 3rd joint thermal cycling composite technology
The various electrical equipments that use in the techniques such as UTILIZATION OF VESIDUAL HEAT IN of the hot waste gas after the utility model burns, burns by coal gangue pyrolytic gasification, raw gas reclaiming clean, purified gas are controlled, and make the continuous coal gangue pyrolytic gasification of thermal cycling smooth.
Above content introduction just exemplifies a tool embodiment of thermal cycling continuous coal gangue pyrolytic gasification integration unit and technique, does not form the restriction to this case thermal cycling continuous coal gangue pyrolytic gasification integration unit and technique protection domain.
Claims (6)
1. coal gangue pyrolytic gasification raw gas purification of combustion recycling device, is characterized in that: mainly comprise coal gangue pyrolysis gasifying device, raw gas take-up gear, activated coke dry method withdrawer, described coal gangue pyrolysis gasifying device, mainly comprise coal gangue pyrolysis installation and water-gas reaction device, described coal gangue pyrolysis installation is arranged on the body of heater middle part, mainly by pyrolysis vaporizer, outer combustion gas heating unit, interior gas-operated thermal bath facility, gas reversing system, center support bow, formed, described pyrolysis vaporizer forms an annulus by the inside and outside ringwall of fire-resistant thermally conductive material, being centered around pyrolysis vaporizer's exterior wall ring periphery is outer combustion gas heating unit, in the indoor ringwall ring of pyrolytic gasification, is interior gas-operated thermal bath facility, described outer combustion gas heating unit is mainly some groups of identical associated the first combustion heaters of structure, the second combustion heater forms, described the first combustion heater mainly comprises the first combustion chamber, the first coal gas enters arm and the first regenerative heat exchanger, the first coal gas enters arm and leads in the first combustion chamber through the body of heater exterior wall, the body of heater exterior wall that the first combustion chamber is made by refractory materials and fire-resistant thermally conductive material are made the gas-fired quirk that pyrolysis vaporizer's outer ring wall and outer quirk partition wall surround a relative closure, described the first regenerative heat exchanger comprises the first accumulation of heat chamber, the first heat storage, the first air enters arm and the first combustion exhaust exhaust outlet, the first accumulation of heat chamber is arranged in the body of heater exterior wall, the first heat storage arranges in the first accumulation of heat chamber, the first accumulation of heat chamber one end leads to the first bottom, combustion chamber, the other end is connected to respectively the first air and enters arm and the first combustion exhaust exhaust outlet, in like manner identical the second combustion heater of structure also mainly comprises the second combustion chamber, the second coal gas enters arm and the second regenerative heat exchanger, between the second combustion chamber of described the first combustion chamber and next-door neighbour, the top of outer quirk partition wall is provided with the combustion chamber through hole, the combustion chamber through hole is connected the second combustion chamber of the first combustion chamber and next-door neighbour to form associated one group, described interior gas-operated thermal bath facility is mainly by some groups of association the 3rd combustion heaters that structure is identical, the 4th combustion heater, its structure and associated the first burning heater, the second burning heater forms almost completely identical, the gas-fired quirk that the indoor ringwall of pyrolytic gasification and internal-quirk partition wall surround a relative closure is made by fire-resistant thermally conductive material in the 3rd combustion chamber of different is the 3rd combustion heater, the 3rd coal gas enter arm below the bar bow of center support bow through upwards leading to the 3rd combustion chamber, the 3rd accumulation of heat chamber is arranged on the body of heater of bar bow below, the 3rd heat storage is placed in the 3rd accumulation of heat chamber, lead to the 3rd bottom, combustion chamber through extending upward below the bar bow that the 3rd accumulation of heat chamber one end bends from center support by the extension passage, the 3rd accumulation of heat chamber the other end is connected to respectively the 3rd air and enters arm and the 3rd combustion exhaust exhaust outlet, between described the 3rd combustion chamber and next-door neighbour's the 4th combustion chamber, the top of internal-quirk partition wall is provided with chamber passage, chamber passage is connected the 3rd combustion chamber and next-door neighbour's the 4th combustion chamber to form associated one group, described gas reversing system comprises dish, lower wall, the rotation reversing motor, air blower, gas fan, exhaust gas fan, lower wall is connected to respectively an air supervisor and the first air is in charge of, the second air is in charge of, a coal gas is responsible for and the first gas manifold, the second gas manifold, combustion exhaust supervisor and the second combustion exhaust are in charge of, the first combustion exhaust is in charge of, wherein the second combustion exhaust is in charge of with the first combustion exhaust and is in charge of with the first air and is in charge of and is in charge of with the second air and the setting of the first gas manifold and the second gas manifold is just exchanged, upper dish is fitted in the lower wall top, upper dish correspondence respectively is provided with the air pipe connecting, the coal gas pipe connecting, the combustion exhaust pipe connecting, thereby the rotation reversing motor drives upper dish reciprocating rotation on lower wall and realizes that the air supervisor constantly is in charge of with the second air and is in charge of and is connected and cut off conversion with the first air, the coal gas supervisor is constantly connected and is cut off conversion with the first gas manifold and the second gas manifold, combustion exhaust supervisor constantly be in charge of with the first combustion exhaust and be in charge of and connected and cut off conversion with the second combustion exhaust, wherein, described the first air is in charge of and is entered arm, the 3rd air with the first air and enter arm and connect, simultaneously, described the first gas manifold and the first coal gas enter arm, the 3rd coal gas enters arm and connects, now simultaneously, described the first combustion exhaust is in charge of with the first combustion exhaust exhaust outlet, the 3rd combustion exhaust exhaust outlet and is connected, in like manner, the second air is in charge of and is entered arm, the 4th air with the second air and enter arm and connect, simultaneously, the second gas manifold and the second coal gas enter arm, the 4th coal gas enters arm and connects, meanwhile, the second burning gas is in charge of with the second combustion exhaust exhaust outlet, the 4th combustion exhaust exhaust outlet and is connected, described water-gas reaction device comprises pyrolysis vaporizer, the material heat sink, steam generation device, the pyrolysis vaporizer of described pyrolysis vaporizer and coal gangue pyrolysis installation is same chamber, pyrolysis vaporizer is positioned at center support bow top, described material heat sink, steam generation device is positioned at center support bow below, described material heat sink comprises high temperature cooling chamber, low temperature cooling chamber, cooling chamber's bridge bow, the top of high temperature cooling chamber communicates bottom pyrolysis vaporizer, high temperature cooling chamber and low temperature cooling chamber are setting up and down, cooling chamber's bridge bow is arranged between high temperature cooling chamber and low temperature cooling chamber, described cooling chamber bridge bow comprises the bridge bow, steam chest, steam enters siphunculus, bridge bow middle part forms steam chest, the lower openings of steam chest is towards low temperature cooling chamber, steam enters siphunculus and is arranged in the bridge bow, steam enters siphunculus one end and leads to steam chest, the other end stretches out outside stove, described steam generation device comprises annular hollow metal casing, steam pockets and drum input tube, the drum output tube, annular hollow metal casing is arranged on bottom of furnace body, the interior annular space chamber of annular hollow metal casing is connected to the low temperature cooling chamber bottom of material heat sink, form sealing relatively for the body of heater water bag of storage of water in annular hollow metal casing case, body of heater water bag is connected to water inlet pipe and drum input tube, water inlet pipe communicates with water tank, drum input tube and steam pockets are connected, the drum output tube of steam pockets enters the siphunculus the other end with the steam of material heat sink and communicates, described raw gas take-up gear comprises the raw gas concentration chamber, interior derivation passage, outer derivation passage, derive main channel, derive circuit, it is integrally formed that described raw gas concentration chamber is arranged on top and the pyrolysis vaporizer of pyrolysis vaporizer, in interior derivation channel setting quirk partition wall, interior derivation feeder connection leads to pyrolysis vaporizer through interior ringwall middle part, the raw gas concentration chamber that interior derivation channel outlet is led to the pyrolysis vaporizer top through interior ringwall, in the exterior wall of described outer derivation channel setting body of heater, lower outside derivation feeder connection, upper outside derivation feeder connection leads to pyrolysis vaporizer through the outer ring wall middle part, the raw gas concentration chamber that outer derivation channel outlet is led to the pyrolysis vaporizer top through outer ring wall, described derivation main channel is arranged in the exterior wall of body of heater of coal heat decomposition stove, derivation main channel entrance communicates with the raw gas concentration chamber and extends up in the exterior wall top derivation circuit that body of heater is set again, derive circuit and be provided with the raw gas export mouth, described activated coke dry method withdrawer comprises that recycling shell collector, absorption storehouse, unsaturated activated coke enter storehouse, saturated active coke storage silo, recycling shell collector is a cavity container, recycling shell collector top purified gas output tube, recycling shell collector bottom and the second gas conveying tube link, the absorption storehouse is arranged in the sky recycling shell collector between purified gas output tube and the second gas conveying tube, top, the bottom in absorption storehouse are the filtration net structure, absorption top, storehouse enters storehouse with the unsaturated activated coke that is arranged on the recycling shell collector top and links, absorption top, storehouse and unsaturated activated coke enter between storehouse the first recovery gate valve are set, bottom, absorption storehouse links with the saturated active coke storage silo with being arranged on the recycling shell collector bottom, between bottom, absorption storehouse and saturated active coke storage silo, is provided with the second recovery gate valve, the second gas conveying tube of described activated coke dry method withdrawer communicates with the raw gas export mouth of raw gas take-up gear, and in the purified gas output tube on activated coke dry method withdrawer top and the coal gangue pyrolysis installation of coal gangue pyrolysis gasifying device, the gas fan of gas reversing system is connected by pipeline.
2. coal gangue pyrolytic gasification raw gas purification of combustion recycling device as claimed in claim 1, it is characterized in that: described coal gangue pyrolytic gasification raw gas purification of combustion recycling device also comprises the raw gas condensing works, and described raw gas condensing works comprises condensation housing, regulating wheel, threaded adjusting bar, valve gap, valve seat, effuser, ammoniacal liquor shower nozzle, the condensation housing is relative sealing long barrel shape, its side wall upper part offers the raw gas admission port, the ammoniacal liquor shower nozzle is arranged on the top in the condensation housing, threaded adjusting bar one end stretches out and the regulating wheel thread connection from the condensation case top, the threaded adjusting bar the other end and valve gap are connected to a fixed, valve seat is arranged on middle and lower part in the condensation housing and divides upper and lower two portions by the condensation housing, the valve seat middle part is formation like funnelform annular cavity, valve gap is back taper, valve gap is placed in annular cavity, the control to the uninterrupted of raw gas is realized in the gap of the inner ring surface of the male cone (strobilus masculinus) of threaded adjusting bar by driving valve gap and annular cavity, effuser is arranged on the condensation housing bottom, described raw gas condensing works is arranged between described raw gas take-up gear and activated coke dry method withdrawer, the raw gas export mouth of described raw gas take-up gear first communicates with the raw gas admission port of raw gas condensing works, and the effuser of raw gas condensing works communicates with the second gas conveying tube of described activated coke dry method withdrawer again.
3. coal gangue pyrolytic gasification raw gas purification of combustion recycling device as claimed in claim 1, it is characterized in that: described coal gangue pyrolysis installation also comprises that two groups of bustle pipes are arranged on the periphery of body of heater, comprise the first air bustle pipe, the first coal gas bustle pipe, the first combustion exhaust bustle pipe; The second air bustle pipe, the second coal gas bustle pipe, the second combustion exhaust bustle pipe; Wherein said the first air is in charge of and is entered arm, the 3rd air by the first air bustle pipe and the first air and enter arm and connect, simultaneously, described the first gas manifold enters arm, the 3rd coal gas by the first coal gas bustle pipe and the first coal gas and enters arm and connect, now simultaneously, described the first combustion exhaust is in charge of by the first combustion exhaust bustle pipe and is connected with the first combustion exhaust exhaust outlet, the 3rd combustion exhaust exhaust outlet; In like manner, the second air is in charge of and is entered arm, the 4th air by the second air bustle pipe and the second air and enter arm and connect, simultaneously, the second gas manifold enters arm, the 4th coal gas by the second coal gas bustle pipe and the second coal gas and enters arm and connect, meanwhile, the second burning gas is in charge of by the second combustion exhaust bustle pipe and is connected with the second combustion exhaust exhaust outlet, the 4th combustion exhaust exhaust outlet.
4. coal gangue pyrolytic gasification raw gas purification of combustion recycling device as claimed in claim 1, it is characterized in that: the first air of described the first combustion heater enters between arm and the first accumulation of heat chamber and is provided with the first one-way air valve, and the first one-way air valve allows air to enter pipe and the first accumulation of heat chamber flows into the first combustion chamber from the first air; Be provided with the first unidirectional waste gas valve between the first combustion exhaust exhaust outlet and the first accumulation of heat chamber, the first unidirectional waste gas valve allows the gas-fired waste gas first accumulation of heat chamber of flowing through from the first combustion chamber, finally from the first combustion exhaust exhaust outlet, discharges; The second air of described the second combustion heater enters between arm and the second accumulation of heat chamber and is provided with the second one-way air valve, and the second one-way air valve allows air to enter pipe and the second accumulation of heat chamber flows into the second combustion chamber from the second air; Be provided with the second unidirectional waste gas valve between the second combustion exhaust exhaust outlet and the second accumulation of heat chamber, the second unidirectional waste gas valve allows the gas-fired waste gas second accumulation of heat chamber of flowing through from the second combustion chamber, finally from the second combustion exhaust exhaust outlet, discharges; In like manner the 3rd combustion heater, the 4th combustion heater also comprise one-way air valve, unidirectional waste gas valve, arrange identical with the first combustion heater, the second combustion heater.
5. coal gangue pyrolytic gasification raw gas purification of combustion recycling device as claimed in claim 1, it is characterized in that: described outer combustion gas heating unit mainly is divided into the heating of upper, middle and lower segment formula, and every section consists of 9 groups of identical first combustion heaters of structure and the second combustion heater.
6. coal gangue pyrolytic gasification raw gas purification of combustion recycling device as claimed in claim 1, it is characterized in that: described interior gas-operated thermal bath facility mainly is divided into upper and lower two-section type heating, and every section consists of 6 groups of identical the 3rd combustion heaters of structure and the 4th combustion heater.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103194272A (en) * | 2013-04-10 | 2013-07-10 | 山西鑫立能源科技有限公司 | Coal gangue pyrolysis gasification crude gas purified combustion recycling device |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103194272A (en) * | 2013-04-10 | 2013-07-10 | 山西鑫立能源科技有限公司 | Coal gangue pyrolysis gasification crude gas purified combustion recycling device |
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