CN103234189B - The steam generation device of the water gas reaction of gangue pyrolytic gasification - Google Patents

The steam generation device of the water gas reaction of gangue pyrolytic gasification Download PDF

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CN103234189B
CN103234189B CN201310132836.2A CN201310132836A CN103234189B CN 103234189 B CN103234189 B CN 103234189B CN 201310132836 A CN201310132836 A CN 201310132836A CN 103234189 B CN103234189 B CN 103234189B
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gas
water
heater
air
gangue
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CN103234189A (en
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王新民
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Shanxi Xinli Energy Technology Co Ltd
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Shanxi Xinli Energy Technology Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONAGEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • C10B53/04Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of powdered coal
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONAGEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B3/00Coke ovens with vertical chambers
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONAGEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B3/00Coke ovens with vertical chambers
    • C10B3/02Coke ovens with vertical chambers with heat-exchange devices
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/58Production of combustible gases containing carbon monoxide from solid carbonaceous fuels combined with pre-distillation of the fuel
    • C10J3/60Processes
    • C10J3/62Processes with separate withdrawal of the distillation products
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency
    • Y02P20/129Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines

Abstract

The steam generation device of the water gas reaction of the open gangue pyrolytic gasification of the present invention, comprise annular hollow metal box body, steamdrum and drum input pipe, drum efferent duct, annular hollow metal box body is arranged on bottom of furnace body, the inner ring cavity of annular hollow metal box body is connected to the low temperature cooling chamber bottom of material heat sink, the body of heater water bag that opposing seal is used for storage of water is formed in annular hollow metal box body case, body of heater water bag is connected to water inlet pipe and drum input pipe, water inlet pipe communicates with storage tank, drum input pipe and steamdrum are connected, drum efferent duct and the steam of material heat sink of steamdrum enter the siphunculus other end and communicate.The present invention utilizes the waste heat of the solid product after gangue pyrolytic gasification to produce water vapour, saves energy consumption, can reduce solid product temperature again, the discharge of convenient solid product simultaneously.

Description

The steam generation device of the water gas reaction of gangue pyrolytic gasification
Technical field
The present invention relates to the technology of gangue pyrolytic gasification, particularly the steam generation device of the water gas reaction of gangue pyrolytic gasification.
Background technology
Gangue---the stone selected from raw coal is the waste residue of coal preparation plant, bad process, China has the gangue of more than one hundred million tons not utilize every year, and still continues to discharge about 100Mt every year, not only piles up occupation of land, and can also spontaneous combustion contaminated air or cause fire, cause serious environmental pollution.
Due to the incoalation of 1 years, carbon, oil, gas material containing 20-30% in gangue, wherein oil gas accounted for 11-15%, carbon accounts for 7-15%.Gangue pyrolytic gasification, (composition is the compositions such as silica, alundum (Al2O3), di-iron trioxide, titanium dioxide, calcium oxide, magnesia, potassium oxide, sodium oxide molybdena, phosphorus pentoxide, manganese oxide, sulfur trioxide to obtain the solid product of oil gas product and 70-80%, the grog of sa refractory material), there is economic worth, more have social benefit.
The present inventor to the physical characteristic of gangue and the research of high-temperature coal pyrolytic gasification technique, innovates a set of brand-new gangue high temperature pyrolysis and gasification composite technology and device for a long time.
Summary of the invention
The invention provides the steam generation device of the water gas reaction of gangue pyrolytic gasification, this device utilizes the waste heat of the solid product after gangue pyrolytic gasification to produce water vapour, saves energy consumption, can reduce solid product temperature again, the discharge of convenient solid product simultaneously.
Realizing the technical scheme that above-mentioned purpose takes is:
The steam generation device of the water gas reaction of gangue pyrolytic gasification, comprise annular hollow metal box body, steamdrum and drum input pipe, drum efferent duct, annular hollow metal box body is arranged on bottom of furnace body, the inner ring cavity of annular hollow metal box body is connected to the low temperature cooling chamber bottom of material heat sink, the body of heater water bag that opposing seal is used for storage of water is formed in annular hollow metal box body case, body of heater water bag is connected to water inlet pipe and drum input pipe, water inlet pipe communicates with storage tank, drum input pipe and steamdrum are connected, drum efferent duct and the steam of material heat sink of steamdrum enter the siphunculus other end and communicate.
The big up and small down funnel-form of inner ring cavity of the annular hollow metal box body of described steam generation device.
The present invention utilizes solid product waste heat in low temperature cooling chamber to add thermosetting water vapour to the water in body of heater water bag, do not need extra heating power consumption, water vapour enters in steamdrum by drum input pipe, in steamdrum, water vapour passes into water vapour by drum input pipe to the low temperature cooling chamber of material heat sink, and water gas reaction can uninterruptedly successfully be carried out continuously.
Accompanying drawing explanation
Below in conjunction with accompanying drawing, the specific embodiment of the present invention is described in further detail.
Fig. 1 is gangue pyrolysis gasification furnace schematic diagram of the present invention;
Fig. 2 is gas diverter schematic diagram of the present invention;
Gas diverter of the present invention coils schematic diagram to Fig. 3;
Fig. 4 is gas diverter lower wall schematic diagram of the present invention;
Fig. 5 is c-c place cross-sectional schematic in Fig. 3;
Fig. 6 is gas diverter of the present invention and combustion heater pipe network connection diagram;
Fig. 7 is t-t place schematic cross-section in Fig. 1;
Fig. 8 is u-u place schematic cross-section in Fig. 1;
Fig. 9 is v-v place schematic cross-section in Fig. 1;
Figure 10 is central supported of the present invention bow schematic diagram (in Fig. 1 x-x place schematic cross-section);
Figure 11 is steam channel of the present invention intention (in Fig. 1 y-y place schematic cross-section);
Figure 12 is steamdrum pipeline schematic diagram of the present invention (in Fig. 1 z-z place schematic cross-section);
Figure 13 is industry control central electrical connection diagram of the present invention.
Detailed description of the invention
The specific embodiment of the comprehensive utilization of gangue pyrolytic gasification of the present invention is mainly introduced in detail following.
Part I gangue Task-size Controlling
Gangue processing is broken into 0 ~ 20mm granularity, dehydrates in this particle size range to gangue particle, fully dry, dewatering efficiency is high, but this is not formed the restriction of the present invention to required gangue.
The damping of Part II gangue is dewatered
The hot waste gas produced after purified gas burning after raw coke oven gas recovery of chemical products purification gangue high temperature pyrolysis and water gas reaction produced is used for the gangue pellet after fragmentation entering stokehold and carries out damping dehydration.
In order to keep the neat and tidy of environment, after damping dehydration, tail gas washes one's hair the rear qualified discharge of purification by water.
Part III gangue high temperature pyrolysis and gasification (pyrolysis heating, water-gas are sent out and answered)
The high temperature pyrolysis heating of first segment gangue
As shown in Figure 1, gangue pyrolysis installation 6 is arranged in the middle part of body of heater 91, mainly comprises pyrolysis vaporizer 61, outer gas-operated thermal bath facility 64, interior gas-operated thermal bath facility 67, gas reversing arrangement 66, central supported bow 65 formation, as Fig. 8, shown in Fig. 9: pyrolysis vaporizer 61 is by fire-resistant Heat Conduction Material, outer ring wall 612, 611 form an annulus, being centered around pyrolysis vaporizer's exterior wall 611 ring periphery is outer gas-operated thermal bath facility 64, be interior gas-operated thermal bath facility 67 in ringwall 612 ring in pyrolysis vaporizer, wherein outer gas-operated thermal bath facility 64 is mainly first combustion heater 62 of some groups of (this example 9 groups) identical associations of structure, second combustion heater 60 forms (see Fig. 1, Fig. 2), as Fig. 1, Fig. 8, shown in Fig. 9: because pyrolysis vaporizer 61 is highly higher, wherein outer gas-operated thermal bath facility 64 is mainly divided into, in, lower Three-section type heating, every section of first combustion heater 62 having 9 groups of identical associations of structure, second combustion heater 60 is formed, interior gas-operated thermal bath facility 67 is mainly divided into, lower two-period form heating, every section has 6 groups of identical 3rd combustion heaters 68 mutually of structure, 4th combustion heater 69 is formed.
As Fig. 1, Fig. 9 show, the first described combustion heater 62 mainly comprises the first combustion chamber 621, first coal gas and enters arm 622 and the first regenerative heat exchanger 624, first coal gas and enter arm 622 and lead in the first combustion chamber 621 through body of heater 91 exterior wall.
As shown in Fig. 1, Fig. 9: body of heater 91 exterior wall that the first combustion chamber 621 is made up of refractory material and fire-resistant Heat Conduction Material make the gas-fired quirk that pyrolysis vaporizer's outer ring wall 611 and outer quirk partition wall 625 surround a relative closure.
As shown in Fig. 1, Fig. 9, the first regenerative heat exchanger 624 comprises the first thermal 626, first heat storage 623, first air and enters arm 627 and the first burnt gas exhaust outlet 628; First thermal 626 is arranged in body of heater 91 exterior wall, first heat storage 623 arranges in the first thermal 626, first thermal 626 one end is led to bottom the first combustion chamber 621, and the other end is connected to the first air respectively and enters arm 627 and the first burnt gas exhaust outlet 628.
As shown in Figure 9, enter at the first air and to be provided with the first one-way air valve 629, first one-way air valve 629 between arm 627 and the first thermal 626 and to allow air to enter pipe 627 from the first air and the first thermal 626 flows into the first combustion chamber 621; The first unidirectional waste gas valve 620 is provided with between the first burnt gas exhaust outlet 628 and the first thermal 626, first unidirectional waste gas valve 620 allows gas-fired waste gas to flow through the first thermal 626 from the first combustion chamber 621, finally discharge (certainly from the first burnt gas exhaust outlet 628, adopt gas reversing arrangement 66 as described below, when air supervisor 667 and the first air are in charge of 6671 connections, air supervisor 667 and the second air are in charge of 6673 and are in cut-out; Meanwhile, burnt gas supervisor 669 is in charge of 6691 with the first burnt gas and also cuts off mutually, and corresponding burnt gas supervisor 669 and the second burnt gas are in charge of 6693 and are in and are connected, the effect of replacement first one-way air valve 629 and the first unidirectional waste gas valve 620 can be played).
In like manner, as shown in Figure 9: identical second combustion heater 60 of structure mainly comprises the second combustion chamber 601, second coal gas and enters arm 602 and the second regenerative heat exchanger 604.
As shown in Figure 9: body of heater 91 exterior wall that the second combustion chamber 601 is made up of refractory material and fire-resistant Heat Conduction Material make the gas-fired quirk that pyrolysis vaporizer's outer ring wall 611 and outer quirk partition wall 625 surround a relative closure.
As shown in Fig. 1, Fig. 9: the second coal gas enters arm 602 and leads in the first combustion chamber 601 through body of heater 91 exterior wall.
As shown in Figure 9: the second regenerative heat exchanger 604 comprises the second thermal 606, second heat storage 603, second air enters arm 607 and the second burnt gas exhaust outlet 608, second thermal 606 is arranged in body of heater 91 exterior wall, second heat storage 603 arranges in the second thermal 606, second thermal 606 one end is led to bottom the second combustion chamber 601, the other end is connected to the second air respectively and enters arm 607 and the second burnt gas exhaust outlet 608, enter between arm 607 and the second thermal 606 at the second air and be provided with the second one-way air valve 609, second one-way air valve 609 allows air to enter pipe 607 from the second air and the second thermal 606 flows into the second combustion chamber 601, the second unidirectional waste gas valve 600 is provided with between the second burnt gas exhaust outlet 608 and the second thermal 606, second unidirectional waste gas valve 600 allows gas-fired waste gas to flow through the second thermal 606 from the second combustion chamber 601, finally discharge (certainly from the second burnt gas exhaust outlet 608, adopt gas reversing arrangement 66 as described below, when air supervisor 667 and the first air are in charge of 6671 cut-outs, air supervisor 667 and the second air are in charge of 6673 and are in connection, meanwhile, burnt gas supervisor 669 and the first burnt gas are in charge of 6691 and are also connected, and corresponding burnt gas supervisor 669 is in charge of 6693 with the second burnt gas and also cuts off mutually, the effect of replacement second one-way air valve 609 and the second unidirectional waste gas valve 600 can be played).
As shown in Fig. 1, Fig. 8, between second combustion chamber 601 of the first combustion chamber 621 and next-door neighbour, the top of outer quirk partition wall 625 is provided with combustion chamber through hole 6251, first combustion chamber 621 and second combustion chamber 601 of next-door neighbour are connected to form and are associated one group by combustion chamber through hole 6251, in this example, outer gas-operated thermal bath facility 64 is provided with quirk partition wall 625 partition wall outside 18 roads altogether, forms 9 groups of association burning groups; In addition, as shown in Figure 1; Because pyrolysis vaporizer 61 is highly higher, wherein outer gas-operated thermal bath facility 64 is mainly divided into the heating of upper, middle and lower segment formula, and every section has 9 groups of structures identical and associates the first combustion heater 62, second combustion heater 60 and forms.
As shown in Figure 1: on body of heater 91 exterior wall, each combustion chamber is also provided with chamber temperature monitoring holes 6201 and combustion chamber peephole 6202, combustion chamber peephole 6202 is convenient to the gas-fired situation of each combustion chamber of technical staff's direct vision, chamber temperature table 6203 is provided with for the temperature monitoring to combustion chamber, so that the assessment to pyrolysis of coal process in chamber temperature monitoring holes 6201.
As shown in figure 13: chamber temperature table 6203 and industry control center 90 are connected, the temperature data of chamber temperature table 6203 is automatically gathered by industry control center 90.
As Fig. 2, Fig. 3, Fig. 4, Fig. 5, Fig. 6, gas reversing arrangement 66 comprises dish 661, lower wall 662, rotate reversing motor 663, air blower 664, gas fan 665, exhaust gas fan 666, lower wall 662 is connected to an air supervisor 667 respectively and the first air is in charge of 6671, second air is in charge of 6673, a coal gas supervisor 668 and the first gas manifold 6681, second gas manifold 6683, a burnt gas supervisor 669 and the second burnt gas are in charge of 6693, first burnt gas is in charge of 6691, wherein, second burnt gas be in charge of 6693 and first burnt gas be in charge of 6691 and first air be in charge of 6671 and second air be in charge of 6673 and first the setting of gas manifold 6681 and the second gas manifold 6683 just exchange (Fig. 3, Fig. 4, shown in Fig. 6).
As Fig. 3, Fig. 4, Fig. 5, shown in Fig. 6: upper dish 661 is fitted in above lower wall 662, upper dish 661 respectively correspondence is provided with air tube connector 6672, gas connection pipes 6682, burnt gas tube connector 6692, rotate reversing motor 663 drive upper dish 661 on lower wall 662 reciprocating rotation thus realize air supervisor 667 be constantly in charge of with the first air 6671 and second air be in charge of 6673 and carry out connecting and cutting off conversion, coal gas supervisor 668 constantly carries out connecting and cutting off conversion with the first gas manifold 6681 and the second gas manifold 6683, burnt gas supervisor 669 be constantly in charge of with the second burnt gas 6693 and first burnt gas be in charge of and 6691 carry out connecting and cut off and change (with the first air be in charge of 6671 and second air be in charge of 6673 and first the switching of gas manifold 6681 and the second gas manifold 6683 just contrary).
As shown in Fig. 1, Fig. 6, be also provided with two groups of bustle pipes in the periphery of body of heater 91, comprise the first air bustle pipe 6674, first coal gas bustle pipe 6684, first burnt gas bustle pipe 6694; Second air bustle pipe 6675, second coal gas bustle pipe 6685, second burnt gas bustle pipe 6695.
As shown in Fig. 1, Fig. 6, first air bustle pipe 6,674 first air is in charge of 6671 and first air enter arm 627 and link up, the first air is in charge of the 6671, first air bustle pipe 6674, first air and enters arm 627, first thermal 626 and the first combustion chamber 621 forms same path;
Meanwhile, the first gas manifold 6681 and the first coal gas are entered arm 622 and link up by the first coal gas bustle pipe 6684, the first gas manifold 6681, first coal gas bustle pipe 6684, first coal gas are entered arm 622 and the first combustion chamber 621 forms same path;
Simultaneously now, first burnt gas bustle pipe 6694 be the first burnt gas is in charge of 6691 and first burnt gas exhaust outlet 628 link up, the first burnt gas is in charge of the 6691, first burnt gas bustle pipe 6694, first burnt gas exhaust outlet 628, first thermal 626 and forms same path with combustion chamber 621.
In like manner, second air bustle pipe 6,675 second air is in charge of 6673 and second air enter arm 607 and link up, the second air is in charge of the 6673, second air bustle pipe 6675, second air and enters arm 607, second thermal 606 and the second combustion chamber 601 forms same path;
Meanwhile, the second gas manifold 6683 and the second coal gas are entered arm 602 and link up by the second coal gas bustle pipe 6685, the second gas manifold 6683, second coal gas bustle pipe 6685, second coal gas are entered arm 602 and the second combustion chamber 601 forms same path;
Meanwhile, second burnt gas bustle pipe 6,695 second combustion gas is in charge of 6693 and second burnt gas exhaust outlet 608 link up, the second burnt gas is in charge of the 6693, second burnt gas bustle pipe 6695, second burnt gas exhaust outlet 608, second thermal 606 and the second combustion chamber 601 forms same path.
In addition; as shown in figure 13; this example also comprises gas reversing arrangement controller 906 for controlling rotation reversing motor 663, air blower 664, gas fan 665, exhaust gas fan 666; gas reversing arrangement electric controller 906 is connected with upper industry control center 90 again; certainly from electric control theory; rotate reversing motor 663, air blower 664, gas fan 665, exhaust gas fan 666 in this example also can directly control by industry control center 90, so arrange gas reversing arrangement controller 906 herein do not form restriction to this routine protection domain.
Shown in as shown in Figure 1, Figure 2 ~ Fig. 5, Fig. 6, Figure 13: the heating means of this outer gas-operated thermal bath facility 64 are:
(1) industry control center 90 starts and rotates reversing motor 663 and drive upper dish 661 to rotate on lower wall 662, and air supervisor 667 and the first air are in charge of 6671 connections, air be responsible for 667 and second air be in charge of 6673 and be in dissengaged positions; Meanwhile, coal gas supervisor 668 and the first gas manifold 6681 are also connected, and coal gas supervisor 668 and the second gas manifold 6683 are in dissengaged positions; Meanwhile, burnt gas supervisor 669 is in charge of 6691 with the first burnt gas and also cuts off mutually, and corresponding burnt gas be responsible for 669 and second burnt gas be in charge of 6693 and be in the state of being connected;
(2) industry control center 90 starts air blower 664, gas fan 665, exhaust gas fan 666, air is blasted air supervisor 667 by air blower 664, air passes into air tube connector 6672, first air successively and is in charge of the 6671, first air bustle pipe 6674, first air and enters arm 627 and enter into the first thermal 626, enters in the first combustion chamber 621 after the heat utilizing the first heat storage 623 to discharge heats air, simultaneously, raw coke oven gas is obtained purified gas and blasts coal gas supervisor 668 by gas fan 665 after recovery of chemical products purification, coal gas enters gas connection pipes 6682 successively, first gas manifold 6681, first coal gas bustle pipe 6684, first coal gas enters arm 622 and enters in the first combustion chamber 621 and burn, meanwhile, because burnt gas supervisor 669 is in charge of 6691 with the first burnt gas and is in phase dissengaged positions, and corresponding burnt gas supervisor 669 and the second burnt gas are in charge of 6693 and are in the state of being connected, so the waste gas in the first combustion chamber 621 after gas-fired can only enter into the second combustion chamber 601 by the combustion chamber through hole 6251 on outer quirk partition wall 625 top, again in the second thermal 606, carry out after absorbing and cooling temperature from the second burnt gas exhaust outlet 608 through the second heat storage 603 in the second thermal 606, second burnt gas bustle pipe 6695, second burnt gas is in charge of 6693, burnt gas supervisor 669 is discharged by exhaust gas fan 666,
(3) reach setting burning time, industry control center 90 starts rotation reversing motor 663 and drives upper dish 661 to rotate backward on lower wall 662, air supervisor 667 and the first air are in charge of 6671 cut-outs, air supervisor 667 and the second air are in charge of 6673 and are in on-state, simultaneously, coal gas supervisor 668 also cuts off mutually with the first gas manifold 6681, coal gas supervisor 668 and the second gas manifold 6683 on-state, meanwhile, burnt gas supervisor 669 and the first burnt gas are in charge of 6691 and are also connected, and corresponding burnt gas supervisor 669 and the second burnt gas are in charge of 6693 also phase dissengaged positions,
(4) air is blasted air supervisor 667 by air blower 664, air passes into air tube connector 6672, second air successively and be in charge of the 6673, second air bustle pipe 6675, second air and enter arm 607 and enter into the second thermal 606, enters in the second combustion chamber 601 after the heat utilizing the second heat storage 603 in the second thermal 606 to discharge heats air, simultaneously, gas fan 665 by raw coke oven gas through recovery clean after obtain purified gas and blast coal gas supervisor 668, coal gas enters gas connection pipes 6682 successively, second gas manifold 6683, second coal gas bustle pipe 6685, second coal gas enters arm 602 and enters in the second combustion chamber 601 and burn, meanwhile, because burnt gas supervisor 669 and the first burnt gas are in charge of 6691 and are connected, and corresponding burnt gas supervisor 669 and the second burnt gas are in charge of 6693 and are in phase dissengaged positions, so the waste gas in the second combustion chamber 601 after gas-fired can only enter in the first combustion chamber 621 by the combustion chamber through hole 6251 on outer quirk partition wall 625 top, again through the first thermal 626, after the first heat storage 603 in the first thermal 626 carries out absorbing and cooling temperature, last from the first burnt gas exhaust outlet 628, first burnt gas bustle pipe 6694, first burnt gas is in charge of 6691, burnt gas supervisor 669 is discharged by exhaust gas fan 666, so outer gas-operated thermal bath facility 64 theory of combustion is when the waste gas generated after gas-fired in the first combustion chamber 621 enters the second combustion chamber 601 from combustion chamber through hole 6251, discharge after the cooling of its exhaust-heat absorption through the second heat storage 603 in the second combustion chamber 601 and the second thermal 606, otherwise, when the waste gas generated after gas-fired in the second combustion chamber 601 enters the first combustion chamber 621 from combustion chamber through hole 6251, discharge after the cooling of its exhaust-heat absorption through the first heat storage 603 in the first combustion chamber 621 and the first thermal 606.
In sum, this gas two by gas reversing arrangement enters the working method of the regenerative heat exchange of a working method out and regenerative heat exchanger, realize the combustion heater alternate combustion of two groups of associations, namely gas reversing arrangement sends into air, purified gas burning to the combustion chamber of the first combustion heater, hot waste gas simultaneously from the combustion chamber of the second combustion heater after sucking-off burning, the second heat storage absorbing and cooling temperature of hot waste gas in the second regenerative heat exchanger of the second combustion heater becomes the relatively low low temperature waste gas of temperature and discharges; In like manner, gas reversing arrangement sends into air, purified gas burning to the combustion chamber of the second combustion heater, hot waste gas simultaneously from the combustion chamber of the first combustion heater after sucking-off burning, the first heat storage absorbing and cooling temperature of hot waste gas in the first regenerative heat exchanger of the first combustion heater becomes the relatively low low temperature waste gas of temperature and discharges; This mutually utilize gas-fired after waste gas residual heat carry out adding the method for hot-air, both served the waste gas residual heat after to gas-fired to make full use of, improve the efficiency of combustion of the coal gas in combustion chamber, the cooling carrying out to a certain degree to the waste gas after gas-fired again, the external energy need not be consumed, play energy-saving and cost-reducing object, save gangue pyrolytic gasification cost.
Automatically controlled by the heating of external gas-operated thermal bath facility 64, reduce human cost, improve the control accuracy to pyrolysis of coal process, realize automation.
As Fig. 1, shown in Figure 10, interior gas-operated thermal bath facility 67 is primarily of some groups of (this example 6 groups) combustion heaters 68 that structure is identical, 69, because the highly higher interior gas-operated thermal bath facility 67 of pyrolysis vaporizer 61 is primarily of being mainly divided into, lower two-period form heating, every section has association the 3rd combustion heater 68 that 6 groups of structures are identical, 4th combustion heater 69, its composition structure and theory of combustion associate the first burning heater 62 with above introduction, second burning heater 60 is almost identical, 3rd combustion heater 68 also comprises the 3rd combustion chamber 681, 3rd coal gas enters arm 682, 3rd thermal 686, 3rd heat storage 683, 3rd air enters arm 687 and the 3rd burnt gas exhaust outlet 688.
As shown in Fig. 1, Fig. 9, Figure 10, the 3rd combustion chamber 681 is made ringwall 612 and internal-quirk partition wall 635 in pyrolysis vaporizer by fire-resistant Heat Conduction Material and is surrounded the gas-fired quirk of a relative closure.
As shown in Figure 1, Figure 10 shows, 3rd coal gas of hypomere enters arm 682 and upwards leads to the 3rd combustion chamber 681 from article passing beneath of bow 651 for central supported bow 65,3rd thermal 686 is arranged on the body of heater 91 below article bow 651,3rd heat storage 683 is placed in the 3rd thermal 686,3rd thermal 686 one end is led to bottom the 3rd combustion chamber 681 by extending passage 6861 from the upwards extension that passes beneath of article bow 651 of central supported bow 65, and the 3rd thermal 686 other end is connected to the 3rd air respectively and enters arm 687 and the 3rd burnt gas exhaust outlet 688.
As Fig. 1, Fig. 9, shown in Figure 10, 3rd coal gas of epimere enters arm 682 and upwards leads to the 3rd combustion chamber 681 through quirk partition wall 635 from article passing beneath of bow 651 for central supported bow 65, 3rd thermal 686 is arranged on the body of heater 91 below article bow 651, 3rd heat storage 683 is placed in the 3rd thermal 686, 3rd thermal 686 one end is upwards led to bottom the 3rd combustion chamber 681 through quirk partition wall 635 extension by extending passage 6861 from the passing beneath of article bow 651 of central supported bow 65, 3rd thermal 686 other end is connected to the 3rd air respectively and enters arm 687 and the 3rd burnt gas exhaust outlet 688.
In like manner, as shown in Figure 9, Figure 10,4th combustion heater 69 structure is complete identical with the 3rd combustion heater 68, repeats no more here, and wherein the 4th combustion chamber 691 and the 3rd combustion chamber 681 are connected to form by chamber passage 6305 and associated one group (shown in Fig. 1, Fig. 8).
Wherein, as shown in Figure 6,3rd coal gas of the 3rd combustion chamber 681 of the 3rd burning heater 68 enters arm 682, the 3rd air enters arm 687 and the 3rd burnt gas exhaust outlet 688 is in charge of the 6671, first burnt gas respectively by the first coal gas bustle pipe 6684, first air bustle pipe 6674, first burnt gas bustle pipe 6694 and the first gas manifold 6681, first air and is in charge of 6691 and communicates.
As shown in Fig. 1, Fig. 6, Figure 10, the 4th coal gas of the 4th combustion chamber 691 of the 4th burning heater 69 enters arm 692, the 4th air enters arm 697 and the 4th burnt gas exhaust outlet 698 is in charge of the 6673, second burnt gas respectively by the second coal gas bustle pipe 6685, second air bustle pipe 6675, second burnt gas bustle pipe 6695 and the second gas manifold 6683, second air and is in charge of 6693 and communicates.
In sum, the 3rd burning heater 68, the 4th combustion heater 69 theory of combustion are almost identical with above first burning heater 62, second burning heater 60, repeat no more here.
As shown in Figure 1, Figure 10 shows, central supported bow 65, because the quirk partition wall 635 of ringwall 612 and combustion heater 67 is all arranged in furnace chamber in pyrolysis vaporizer, needs central supported to bend 65 and provide support for it, provide the laying of various pipeline to again combustion heater 67 simultaneously.
As shown in Figure 1, Figure 10 shows, central supported bow 65 is arranged in the furnace chamber below pyrolysis vaporizer 61, combustion heater 67, mainly comprise bar bow 651, the Huo Gong center ringwall 652 of some, bar bends 651 one end and is fixed on Huo Gong center ringwall 652, the other end is fixed on body of heater 91, bar bow 651 around ringwall 652 center, Huo Gong center at a certain angle spaced radiation shape to scatter layout, fire bow 651 in this example is 12 bows, and quantity is consistent with the 3rd burning heater 68 the 4th burning heater 69 sum that is mutually related of combustion heater 67.
As shown in Figure 1, Figure 10 shows, article one, fiery bow in the body of wall of 651 arranges the extension passage 6861 that the 3rd coal gas enters arm 682 and the 3rd thermal 686, tightly adjacent another bar fire bends the extension passage 6961 that the 4th coal gas arranged in the body of wall of 651 enters arm 692 and the 4th thermal 696, provide convenience to the pipe laying of combustion heater 67, make the various conduit arrangements of combustion heater 67 orderly, be unlikely to interfere.
Second section water gas reaction
Because gangue temperature in pyrolysis vaporizer is higher, then pass into water vapour to gangue, the charcoal in gangue pyrolysis afterproduct and superheated vapour meet and carry out water gas reaction and generate water-gas (carbon monoxide and hydrogen).
As shown in Fig. 1, Figure 10, Figure 11, water gas reaction device 7 comprises pyrolysis vaporizer 61, material heat sink 70, steam generation device 75.
As shown in Figure 1, pyrolysis vaporizer 61 is positioned at above central supported bow 65, and material heat sink 70, steam generation device 75 are positioned at below central supported bow 65.
As shown in Figure 1, shown in Figure 11, material heat sink 70 is arranged on and stretches out body of heater 91 bottom, comprises high temperature reduction chamber 701, low temperature cooling chamber 702, reduction chamber bridge arch 703; The top of high temperature reduction chamber 701 communicates with bottom pyrolysis vaporizer 61; High temperature reduction chamber 701 is setting up and down with low temperature cooling chamber 702, and reduction chamber bridge arch 703 is arranged between high temperature reduction chamber 701 and low temperature cooling chamber 702, and reduction chamber bridge arch 703 comprises bridge bow 7031, steam chest 704, steam enter siphunculus 707; Article 4, bridge bow 7031 is partitioned into spoke shape layout at an angle with high temperature reduction chamber 701 and low temperature cooling chamber 702 axle center, steam chest 704 is formed in the middle part of bridge bow 7031, steam chest 704 is a cylindrical chamber, the top of steam chest 704 is provided with hemispherical blast cap 708, and the lower openings of steam chest 704 is towards low temperature cooling chamber 702; Steam enters siphunculus 707 and is arranged in bridge bow 7031, and steam enters siphunculus 707 one end and leads to steam chest 704, and the other end stretches out outside body of heater 91.
As Fig. 1, shown in Figure 12, steam generation device 75 comprises annular hollow metal box body 755, steamdrum 754 and drum input pipe 751, drum efferent duct 752, annular hollow metal box body 755 is arranged on bottom body of heater 91, the inner ring cavity 758 of annular hollow metal box body 755 is connected to low temperature cooling chamber 702 bottom of material heat sink 70, the big up and small down funnel-form of inner ring cavity 758 toroidal cavity, the body of heater water bag 753 that opposing seal is used for storage of water is formed in annular hollow metal box body 755 casees, body of heater water bag 753 is connected to water inlet pipe 756 and drum input pipe 751, water inlet pipe 756 communicates with storage tank 757, drum input pipe 751 and steamdrum 754 are connected, drum efferent duct 752 and the steam of material heat sink 70 of steamdrum 754 enter siphunculus 707 other end and communicate.
Water gas reaction Principle Method of the present invention is:
(1), in steamdrum 754, water vapour enters siphunculus 707 by drum input pipe 752 and steam and passes into water vapour to the low temperature cooling chamber 702 of material heat sink 70, water vapour blows to low temperature cooling chamber 702, except lowering the temperature to the solid product after pyrolytic gasification in low temperature cooling chamber 702, water vapour upwards seals in high temperature reduction chamber 701, give and fall into the cooling of the high-temp solid product after a large amount of pyrolytic gasification of high temperature reduction chamber 701 from pyrolysis vaporizer 61, while the solid of water vapour after giving pyrolytic gasification carries out lowering the temperature, improve vapor (steam) temperature and form superheated vapour;
(2), superheated vapour enters pyrolysis vaporizer 61 through central supported bow 65, and contact with the high-temperature coal spoil pyrolysis material of pyrolysis vaporizer 61, the charcoal after gangue pyrolysis in solid product and superheated vapour meet and carry out water gas reaction and generate water-gas (carbon monoxide and hydrogen);
(3), solid product after gangue pyrolytic gasification falls into high temperature reduction chamber 701 and the low temperature cooling chamber 702 of material heat sink 70 from pyrolysis vaporizer 61, overheated high-temperature water vapor is heated as again to the water vapour upwards entering pyrolysis vaporizer 61 through low temperature cooling chamber 702 and high temperature reduction chamber 701, again the solid product after gangue pyrolytic gasification is lowered the temperature simultaneously, in recycling low temperature cooling chamber 702, solid product waste heat adds thermosetting water vapour to the water in body of heater water bag 753, water vapour enters in steamdrum 754 by drum input pipe 751, to supplementing a large amount of water vapours consumed because of water gas reaction in steamdrum 754, water gas reaction can uninterruptedly be carried out continuously.
It is carry out in pyrolysis vaporizer 61 middle and lower part that water gas reaction of the present invention generates in a large number, this is because the gangue pyrolysis in this section of pyrolysis vaporizer is relatively abundant, temperature is also relatively high, now pass into the water vapour of hyperthermia and superheating from the bottom of pyrolysis vaporizer 61, the charcoal in the solid product after overheated water vapour and gangue pyrolysis swashs mutually will produce a large amount of water-gas; Certainly, water vapour is being given in the solid product temperature-fall period in high temperature reduction chamber 701 and low temperature cooling chamber 702 after gangue pyrolytic gasification, also water-gas can be produced with charcoal remaining in the solid product after gangue pyrolytic gasification, but the amount produced is relatively little, this height of charcoal remaining in solid product after this and gangue pyrolytic gasification is few, and steam temperature neither be too high relevant.
The present invention utilizes the waste heat of the relatively low solid product of the temperature after gangue pyrolytic gasification to carry out heat trnasfer and produces water vapour, the solid product that recycling water vapour is higher with temperature directly contacts generation superheated vapour, reach the temperature required of water gas reaction, promote that water gas reaction fills part more, both while reduction solid product temperature, produce water vapour and superheated steam again, thisly do not need to consume that the technical method of additional energy source meets that we advocate today is energy-saving and cost-reducing, the theory of sustainable development.
Section three, raw coke oven gas let-off gear(stand)
Gangue produces the gas containing a lot of useful composition in high temperature pyrolysis and gasification process, charcoal in gangue pyrolysis afterproduct and superheated vapour carry out water gas reaction and generate water-gas (carbon monoxide and hydrogen), more than be referred to as raw coke oven gas, need to derive to utilize raw coke oven gas.
As shown in Fig. 1, Fig. 8, Fig. 9, raw coke oven gas let-off gear(stand) 8, comprises raw coke oven gas concentration chamber 81, interior derivation passage 82, and outer derivation passage 83, derivation main channel 84, derive circuit 85; Raw coke oven gas concentration chamber 81 be arranged on the top of pyrolysis vaporizer 61 and pyrolysis vaporizer 61 integrally formed; As shown in Fig. 1, Fig. 8, article 6, deriving passage 82 in arranges in quirk partition wall 635, interior derivation feeder connection 821 leads to pyrolysis vaporizer 61 through in the middle part of interior ringwall 612, and interior derivation channel outlet 822 leads to the raw coke oven gas concentration chamber 81 at pyrolysis vaporizer top through interior ringwall 612; As shown in Fig. 1, Fig. 8, article 6, outer passage 83 of deriving arranges in the exterior wall of body of heater 91, lower outside derivation feeder connection 831, upper outside derivation feeder connection 834 lead to pyrolysis vaporizer 61 through in the middle part of outer ring wall 611, and outer derivation channel outlet 832 leads to the raw coke oven gas concentration chamber 81 at pyrolysis vaporizer top through outer ring wall 611.
As shown in Figure 1, Figure 7 shows, deriving main channel 84 is arranged in the exterior wall of body of heater 91 of coal heat decomposition stove, derive main channel inlets 841 to communicate with raw coke oven gas concentration chamber 81 and extend up to the exterior wall top arranging body of heater 91 again and derive in circuit 85, derivation circuit 85 is provided with raw coke oven gas export mouth 851, raw coke oven gas export mouth 852.
As Fig. 1, Fig. 7, Fig. 8, shown in Fig. 9, because pyrolysis vaporizer 61 annular chamber in this example, so raw coke oven gas concentration chamber 81 also corresponding annular chamber, article 6, deriving passage 82 in is separately positioned in 6 road quirk partition walls 635, pyrolysis vaporizer 61 is led to through interior ringwall 612, article 6, outer derivation passage 83 is separately positioned in the middle of body of heater 91 exterior wall and leads to pyrolysis vaporizer 61 through with outer quirk partition wall 625 and outer ring wall 611, wherein, because the circumference of pyrolysis vaporizer 61 is longer, so in pyrolysis vaporizer 61 ringwall 612, outer ring wall 611 is respectively arranged with in 6 and derives feeder connection 821 and lower outside derivation feeder connection 831, upper outside derivation feeder connection 834, again because the height of pyrolysis vaporizer 61 is high, interior derivation feeder connection 821 and lower outside derivation feeder connection 831, upper outside derivation feeder connection about 834 staggers setting, as shown in Figure 1, interior derivation feeder connection 821 is higher than lower outside derivation feeder connection 831, but lower than upper outside derivation feeder connection 834 place, this example adopts this structure can better can derive the raw coke oven gas that section different in pyrolysis vaporizer 61 produces, also be provided with 6 larger raw coke oven gas main channels 84 of sectional area around raw coke oven gas concentration chamber 81 in addition and lead to derivation circuit 85, the object of such setting conveniently can derive a large amount of raw coke oven gas in raw coke oven gas concentration chamber 81.
As shown in Figure 1, the exterior wall of body of heater 91 is provided with the raw gas temperature monitoring holes 811 leading to raw coke oven gas concentration chamber 81, in raw gas temperature monitoring holes 811, places raw gas temperature table 812.
As shown in figure 13, raw gas temperature table 812 and industry control center 90 are electrically connected, and temperature in raw coke oven gas concentration chamber 81 is monitored by raw gas temperature table 812 in industry control center 90.
The raw coke oven gas that section different in pyrolysis vaporizer 61 produces enters interior derivation passage 82 from interior derivation feeder connection 821 by this routine feature respectively, enter outer derivation passage with lower outside derivation feeder connection 831, upper outside derivation feeder connection 834 to go out in 83 to collect in raw coke oven gas concentration chamber 81 again, a large amount of raw coke oven gas in certain pyrolysis vaporizer 61 directly rise up in raw coke oven gas concentration chamber 81, entering derivation circuit 85 by deriving main channel 84, finally discharging from raw coke oven gas export mouth 851.
Section four, continuous pyrolysis gasification
Comprehensively above-mentioned, this routine feature is that gangue pyrolysis, gasification (water gas reaction), steam generation, raw coke oven gas are derived process integration in same body of heater, makes gangue pyrolysis, gasification (water gas reaction), steam generation, raw coke oven gas be able to continuous realization.
As shown in Figure 1, gangue pyrolysis gasification furnace 9 comprise body of heater 91, enter furnace charge storehouse 92, gangue pyrolysis gasifying device 93, raw coke oven gas let-off gear(stand) 8, hinge cage sealing discharging device 96, product feed bin 94, gangue pyrolysis gasifying device 93 comprises gangue pyrolysis installation 6, water gas reaction device 7, and the concrete structure of gangue pyrolysis installation 6, water gas reaction device 7, raw coke oven gas let-off gear(stand) 8 is shown in the above, enter furnace charge storehouse 92 and be arranged on body of heater 91 top, body of heater 91 top is provided with into stove cloth passage 921, enter stove cloth passage 921 upper end and enter furnace charge storehouse 92 and communicate, enter stove cloth passage 921 lower end to communicate with pyrolysis vaporizer 61 top of gangue pyrolysis installation 6, hinge cage sealing discharging device 96 is arranged on bottom the inner ring cavity 758 of the annular hollow metal box body 755 of the steam generation device 75 of water gas reaction device 7, product feed bin 94 is placed in bottom body of heater 91, product feed bin 94 connects hinge cage sealing discharging device 96, hinge cage sealing discharging device 96 belongs to prior art, as the sealing discharging device on market, sealing material returning device, sealing blanking device etc.
The method of this routine continuous pyrolysis gasification is:
(1), by the as-fired coal spoil pellet after controlling as-fired coal spoil belt conveyor 95 damping being dewatered send in furnace charge storehouse 92, then pass through stove cloth passage 921 and enter in the pyrolysis vaporizer 61 of gangue pyrolysis installation 6;
(2), by gas-fired after purification in the outer gas-operated thermal bath facility 64 of gangue pyrolysis installation 6, interior gas-operated thermal bath facility 67 provide thermal source to pyrolysis vaporizer 61, gangue carries out pyrolysis under hot environment in pyrolysis vaporizer 61;
(3), high-temperature water vapor is passed into by water gas reaction device 7 from pyrolysis vaporizer 61 bottom, and the gangue pyrolysis material hot with the high temperature of pyrolysis vaporizer 61 contacts, the charcoal in the solid product after gangue pyrolysis and superheated vapour meet and carry out water gas reaction and generate water-gas;
(4), solid product after gangue pyrolytic gasification falls into high temperature reduction chamber 701 and the low temperature cooling chamber 702 of material heat sink 70 from pyrolysis vaporizer 61, overheated high-temperature water vapor is heated as again to the water vapour upwards entering pyrolysis vaporizer 61 through low temperature cooling chamber 702 and high temperature reduction chamber 701, again the solid product after gangue pyrolytic gasification is lowered the temperature simultaneously, in recycling low temperature cooling chamber 702, solid product waste heat adds thermosetting water vapour to the water in the body of heater water bag 753 of the annular hollow metal box body 755 of steam generation device 75, water vapour enters in steamdrum 754 by drum input pipe 751, to supplementing a large amount of water vapours consumed because of water gas reaction in steamdrum 754,
(5), steamdrum 754 enters siphunculus 707 by drum input pipe 752 and steam and passes into water vapour to the low temperature cooling chamber 702 of material heat sink 70 again, and water gas reaction can uninterruptedly be carried out continuously;
(6), the gas that produces in high temperature pyrolysis process of gangue and carry out water gas reaction and generate water-gas (carbon monoxide and hydrogen), be referred to as raw coke oven gas, raw coke oven gas is derived by the raw coke oven gas let-off gear(stand) 8 that body of heater is arranged, to carry out recovery of chemical products and utilization, derivation main channel 84 process that simultaneously raw coke oven gas of higher temperature enters raw coke oven gas let-off gear(stand) from pyrolysis vaporizer 61 top carries out preheating to from the gangue pellet just entering stove entering pyrolysis vaporizer 61 top that stove cloth passage 921 enters again;
(7) according to gangue pyrolytic gasification degree, reed time controll hinge cage sealing discharging device 96 opens or cuts out, and is entered in product feed bin by the solid product after gangue high temperature pyrolysis and gasification cooling in low temperature cooling chamber 702 and inner ring cavity 758.
This example by gangue pyrolytic gasification process integration at the hot body of heater of same coal, realize continuous gangue pyrolytic gasification, production efficiency is high, needed for equipment, factory building face is little, human cost is low, utilize waste heat in the solid product after pyrolytic gasification to produce water vapour, the high humidity superheated vapour utilizing again water vapour to carry out lowering the temperature simultaneously required for generation water gas reaction to the solid product after high temperature pyrolysis and gasification, has the feature of low consumption, environmental protection simultaneously.
The comprehensive cyclic utilization of Part IV, pyrolysis of coal gas
Chapter 1, the reclaiming clean of raw coke oven gas utilizes (change and produce)
First segment raw coke oven gas condensing unit
Gangue pyrolytic gasification discharge raw gas temperature is higher, carries before recovery of chemical products for the ease of high temperature raw coke oven gas, sprays ammoniacal liquor cool high temperature raw coke oven gas.
The reclaiming clean of second section raw coke oven gas
Raw coke oven gas after ammoniacal liquor sprays carries out gas-liquid separation, other auxiliary product is refined containing multiple useful organic component such as carbolic oil, naphtalene oil, washing oil, carbolineum etc. for industry in mixed liquor after gas-liquid separation, coal gas after gas-liquid separation is after air cooling cooling, after Dry recovery Recovery Purifying, become purified gas, purified gas can store for burning.
Chapter 2, raw coke oven gas reclaiming clean after-combustion utilizes
Purified gas burning after first segment raw coke oven gas reclaiming clean
Purified gas after absorption is used for burning provides thermal source to gangue pyrolytic gasification.
Second section utilizes purified gas exhaust gases after combustion to saturated active coke regeneration heating
Hot waste gas after purified gas burning is used for because adsorption cleaning raw coke oven gas forms saturated active coke that to carry out evaporation thermal regeneration be unsaturated activated coke.
Section three, utilize purified gas to burn rear hot waste gas to the damping of as-fired coal spoil pellet
Hot waste gas after purified gas burning is used for carrying out damping dehydration to the gangue pellet entering stokehold.
Chapter 3, thermal cycle continuous gangue pyrolytic gasification is comprehensive
The continuous gangue pyrolytic gasification of first segment thermal cycle and damping and tail gas clean-up
Hot waste gas after purified gas burning is used for carrying out damping dehydration to the gangue pellet entering stokehold, carries out water again and washes one's hair purification and cooling, finally reach clean discharged at lower temperature after hot waste gas dehydration.
Second section thermal cycle continuous gangue pyrolytic gasification composite technology
Comprehensive above content draws the composite technology that a kind of thermal cycle continuous gangue pyrolytic gasification is complete, includes stove gangue hot waste gas damping dehydration, gangue pyrolytic gasification, raw coke oven gas condensation, raw coke oven gas reclaiming clean, tail gas water washes one's hair purification etc.
Section three, the control of thermal cycle continuous gangue pyrolytic gasification composite technology
The various electric equipments used in the technique such as UTILIZATION OF VESIDUAL HEAT IN of the present invention by the hot waste gas after gangue pyrolytic gasification, raw coke oven gas reclaiming clean, purified gas burning, burning are controlled, and make thermal cycle continuous gangue pyrolytic gasification smooth.
Above content introduction just exemplifies a tool embodiment of thermal cycle continuous gangue pyrolytic gasification integration unit and technique, does not form the restriction to this case thermal cycle continuous gangue pyrolytic gasification integration unit and technique protection domain.

Claims (2)

1. the steam generation device of the water gas reaction of gangue pyrolytic gasification, it is characterized in that: comprise annular hollow metal box body, steamdrum and drum input pipe, drum efferent duct, annular hollow metal box body is arranged on bottom of furnace body, the inner ring cavity of annular hollow metal box body is connected to the low temperature cooling chamber bottom of material heat sink, the body of heater water bag that opposing seal is used for storage of water is formed in annular hollow metal box body case, body of heater water bag is connected to water inlet pipe and drum input pipe, water inlet pipe communicates with storage tank, drum input pipe and steamdrum are connected, one end that drum efferent duct and the steam of material heat sink of steamdrum enter outside siphunculus body of heater communicates.
2. the steam generation device of the water gas reaction of gangue pyrolytic gasification as claimed in claim 1, is characterized in that: the big up and small down funnel-form of inner ring cavity of the annular hollow metal box body of described steam generation device.
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