CN203288661U - Cylindrical steel shell lithium ion battery - Google Patents

Cylindrical steel shell lithium ion battery Download PDF

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CN203288661U
CN203288661U CN2013202788994U CN201320278899U CN203288661U CN 203288661 U CN203288661 U CN 203288661U CN 2013202788994 U CN2013202788994 U CN 2013202788994U CN 201320278899 U CN201320278899 U CN 201320278899U CN 203288661 U CN203288661 U CN 203288661U
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battery
battery core
material layer
polymer material
soft polymer
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王景芳
余红明
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Ningde Amperex Technology Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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Abstract

本实用新型涉及锂离子电池技术领域,特指一种圆柱型钢壳锂离子电池,包括电池钢壳,收容于电池钢壳内的电池芯和填充于其中的电解液,电池芯表面均匀涂刷有软质聚合物材料层,采用本技术方案可以很好固定电池芯,使得电池芯在实际循环过程,有效抑制阳极膨胀,从而保持很好的电化学界面。同时可以吸收电池在使用过程中振动能量,有利于缓解电池芯在实际运输,振动过程内部由于晃动而引起的短路和极耳扭断隐患。而且软质聚合物材料层可以减少钢壳刚性强度和硬度对电池芯的压力和破坏。

Figure 201320278899

The utility model relates to the technical field of lithium-ion batteries, in particular to a cylindrical steel-cased lithium-ion battery, comprising a battery steel case, a battery core housed in the battery steel case and an electrolyte filled therein, and the surface of the battery core is uniformly coated with The soft polymer material layer adopts this technical solution to fix the battery core well, so that the battery core can effectively inhibit the expansion of the anode during the actual cycle process, thereby maintaining a good electrochemical interface. At the same time, it can absorb the vibration energy of the battery during use, which is beneficial to alleviate the hidden dangers of short circuit and tab twisting caused by shaking inside the battery core during actual transportation and vibration. Moreover, the soft polymer material layer can reduce the pressure and damage of the rigidity and hardness of the steel shell to the battery core.

Figure 201320278899

Description

一种圆柱型钢壳锂离子电池A cylindrical steel case lithium-ion battery

技术领域 technical field

本实用新型涉及锂离子电池技术领域,特指一种圆柱型钢壳锂离子电池。 The utility model relates to the technical field of lithium ion batteries, in particular to a cylindrical steel shell lithium ion battery.

背景技术 Background technique

锂离子电池作为一种绿色的环保电池,具有高能量密度,高工作电压和长使用寿命的优点,在移动电动工具中应用广泛。圆柱型锂离子电池通常包括电池壳体,收容于电池壳体内的电池芯和填充于其中的电解液,电池芯包括一个阴极极片,阳极极片和隔离膜。 As a green and environmentally friendly battery, lithium-ion batteries have the advantages of high energy density, high operating voltage and long service life, and are widely used in mobile power tools. Cylindrical lithium-ion batteries generally include a battery case, a battery core accommodated in the battery case and an electrolyte filled therein, and the battery core includes a cathode pole piece, an anode pole piece and a separator.

电动工具用锂离子电池市场广泛,它具有自身特殊的特点,要求放电电流大,功率性能高。同时电动工具实际使用的环境比较苛刻,电池芯在高温,高倍率充放电循环后,阴阳极极片由于结构的变化,出现较大的膨胀,极片中活性物质容易剥落,导致电池芯界面不够好。电动工具实际运用中,振动强度大,对电池芯的机械力学和可靠性的要求非常高,故电动工具用锂离子电池往往采用刚性强度和机械强度较高的钢壳作为电池芯外壳。但是在实际运输或使用过程,刚性强度大的钢壳对电池芯会产生不同程度压力和破坏。而且追求功率密度提升的电动工具用锂离子电池,能量密度要求不算高,因此其电池芯通常会比较小,而钢壳的规格是固定,如18650,26650等,那么电池芯在钢壳壳体会出现上下左右晃动,导致电池芯在运输,振动过程内部由于晃动而引起的极耳端或者极片出现短路隐患。 Lithium-ion batteries for power tools have a wide market, and they have their own special characteristics, requiring large discharge current and high power performance. At the same time, the actual use environment of electric tools is relatively harsh. After the battery core is charged and discharged at high temperature and at a high rate, the cathode and anode sheets will expand due to structural changes, and the active material in the electrode sheet is easy to peel off, resulting in insufficient battery core interface. good. In the actual use of power tools, the vibration intensity is high, and the mechanical mechanics and reliability requirements of the battery core are very high. Therefore, lithium-ion batteries for power tools often use steel shells with high rigidity and mechanical strength as the battery core shell. However, during actual transportation or use, the steel shell with high rigidity and strength will exert different degrees of pressure and damage on the battery core. Moreover, lithium-ion batteries for power tools that seek to increase power density do not require high energy density, so the battery core is usually relatively small, and the specifications of the steel shell are fixed, such as 18650, 26650, etc., then the battery core in the steel shell Experience the shaking up and down, left and right, resulting in the potential short circuit of the battery core or the pole piece due to the shaking inside the battery cell during transportation.

综上所述,确有必要提供一种既可以保证机械强度,又可以兼顾吸收电池在运输与使用过程中振动能量和保持循环过程界面优越的电池芯结构,以顺应电动工具用锂离子电池发展的需求。 To sum up, it is indeed necessary to provide a battery core structure that can not only ensure the mechanical strength, but also absorb the vibration energy of the battery during transportation and use and maintain a superior interface during the cycle process, so as to comply with the development of lithium-ion batteries for electric tools. demand.

实用新型内容 Utility model content

本实用新型的目的在于克服现有技术的不足,而提供一种既可以保证机械强度,又可以兼顾吸收电池芯在运输与使用过程中的振动能量,同时也可以在电池芯充放电循环过程中,保持界面良好。 The purpose of the utility model is to overcome the deficiencies of the prior art, and provide a device that can not only ensure the mechanical strength, but also absorb the vibration energy of the battery core during transportation and use, and can also be used during the charging and discharging cycle of the battery core. , keep the interface nice.

为了解决上述的技术问题,本实用新型所提供的圆柱电池,包括电池钢壳,收容于电池钢壳内的电池芯和填充于其中的电解液,电池芯表面均匀涂刷有软质聚合物材料层。所述的软质聚合物材料层为本身容易被压缩,可以减少钢壳刚性强度对电池芯的压力和破坏。软质聚合物材料可以吸收电池在使用和振动过程中的能量,可以有助缓解电池芯在运输,振动过程的隐患,解决电池芯内部由于晃动而引起的短路隐患。所述的软质聚合物材料层的材料可以为丁苯橡胶,聚偏氟乙烯,α-氰基丙稀酸酯等聚合物胶,该材质要求具有耐高温、抗冲击、抗震动、柔软等的特点,且所述的软质聚合物材料层为电子绝缘层。  In order to solve the above-mentioned technical problems, the cylindrical battery provided by the utility model includes a battery steel case, a battery core contained in the battery steel case and an electrolyte filled therein, and the surface of the battery core is uniformly coated with a soft polymer material layer. The soft polymer material layer itself is easy to be compressed, which can reduce the pressure and damage of the rigidity of the steel case to the battery core. The soft polymer material can absorb the energy of the battery during use and vibration, which can help alleviate the hidden dangers of the battery core during transportation and vibration, and solve the hidden danger of short circuit caused by shaking inside the battery core. The material of the soft polymer material layer can be polymer glue such as styrene-butadiene rubber, polyvinylidene fluoride, α-cyanoacrylate, etc., and the material is required to have high temperature resistance, impact resistance, vibration resistance, softness, etc. characteristics, and the soft polymer material layer is an electronic insulating layer. the

所述的软质聚合物材料层的厚度为0.5-5.0mm。软质聚合物材料层厚度可以根据电池芯积与钢壳内部体积的实际比例调整,以保证电池芯能顺利套入钢壳为前提。这样的电池芯表面处理,由于软质聚合物材料层具有较好的弹性,改善了电池芯膨胀收缩的能力,有效抑制在高温,高倍率循环过程阴阳极的膨胀,从而始终保持很好的电化学界面,提高了电池循环性能。 The thickness of the soft polymer material layer is 0.5-5.0mm. The thickness of the soft polymer material layer can be adjusted according to the actual ratio of the battery core volume to the internal volume of the steel case, so as to ensure that the battery core can be inserted into the steel case smoothly. Such surface treatment of the battery core, due to the good elasticity of the soft polymer material layer, improves the expansion and contraction capacity of the battery core, and effectively inhibits the expansion of the cathode and anode during high-temperature, high-rate cycles, thereby maintaining a good battery life. The chemical interface improves the battery cycle performance.

所述的软质聚合物材料层为一层或者多层。 The soft polymer material layer is one or more layers.

所述的软质聚合物材料层为电子绝缘层。 The soft polymer material layer is an electronic insulating layer.

附图说明 Description of drawings

图1为本实用新型电池芯结构示意图。 Fig. 1 is a schematic diagram of the structure of the battery core of the present invention.

图2为本实用新型电池芯结构涂有均匀软质聚合物材料层示意图。 Fig. 2 is a schematic diagram of a battery core structure coated with a uniform soft polymer material layer in the present invention.

图3为本实用新型电池芯结构涂有均匀软质聚合物材料层俯视图。 Fig. 3 is a top view of a battery core structure coated with a uniform soft polymer material layer in the present invention.

图4 为本实用新型钢壳锂离子电池剖视图。 Figure 4 is a cross-sectional view of the utility model steel case lithium-ion battery.

具体实施方式 Detailed ways

为了使本实用新型的目的,技术方案及优点更加清晰明了,下面结合附图和具体实施方式,对其进行进一步详细说明。 In order to make the purpose, technical solution and advantages of the present utility model clearer, it will be further described in detail below in conjunction with the accompanying drawings and specific implementation methods.

附图1所示,通过卷绕方式,把阴阳极极片空金属箔面上焊接好电流输出端子2,后续将焊接好极耳的阴,阳极与隔离膜卷绕成裸电池芯1。 As shown in Figure 1, the current output terminal 2 is welded on the empty metal foil surface of the cathode and anode by winding, and then the cathode, anode and separator with the tabs welded are wound into a bare battery core 1.

附图2所示,在裸电池芯1表面均匀涂刷软质聚合物材料层3,软质聚合物材料层3厚度可以根据电池实际能量密度和电池芯1的直径做出调整,软质聚合物材料层3可以为一层或者以上,厚度为0.5-5.0mm。以保证电池芯1顺利套入钢壳4,尽可能使得电池芯1与钢壳4之间的空隙空间较小。 As shown in Figure 2, a soft polymer material layer 3 is uniformly painted on the surface of the bare battery core 1, and the thickness of the soft polymer material layer 3 can be adjusted according to the actual energy density of the battery and the diameter of the battery core 1. The object material layer 3 can be one or more layers, and the thickness is 0.5-5.0mm. In order to ensure that the battery core 1 is inserted into the steel case 4 smoothly, the gap space between the battery core 1 and the steel case 4 is as small as possible.

见图3,考虑软质聚合物材料层3的实用目的,软质聚合物材料层3的材料可以为丁苯橡胶,聚偏氟乙烯,α-氰基丙稀酸酯等聚合物胶,选择的材质要求具有耐高温、高强度、抗冲击、抗震动、柔软等特点等。 See Fig. 3, considering the practical purpose of the soft polymer material layer 3, the material of the soft polymer material layer 3 can be polymer glues such as styrene-butadiene rubber, polyvinylidene fluoride, α-cyanoacrylate, etc., select The material requirements have the characteristics of high temperature resistance, high strength, impact resistance, vibration resistance, softness and so on.

如附图4所示,完成卷绕和表面涂刷软质聚合物材料层3的电池芯1,通过人工或者机器的方式,置入钢壳4壳体内。通过后续的阴阳极耳与相应的正负极焊接,并向钢壳4注入电解液,经过抽真空,密封即可以得到所需的圆柱型锂离子电池。 As shown in FIG. 4 , the battery core 1 that has been wound and coated with the soft polymer material layer 3 is put into the steel shell 4 by manual or machine means. The subsequent cathode and anode lugs are welded to the corresponding positive and negative electrodes, and the electrolyte solution is injected into the steel shell 4. After vacuuming and sealing, the desired cylindrical lithium ion battery can be obtained.

本实用新型涂刷一定厚度的软质聚合物材料层3可以占据电池芯与钢壳4中间的空余空间,很好固定电池芯1,有效抑制阴阳极膨胀,从而始终保持很好的电化学界面。同时可以吸收电池在使用过程中振动的能量,避免电池芯1在运输和实际振动使用过程中出现晃动所引起的极耳折断或者其他可能的短路隐患。减少钢壳4刚性强度对电池芯的压力和破坏,提高电池的安全性。 The utility model paints a certain thickness of the soft polymer material layer 3 to occupy the empty space between the battery core and the steel shell 4, and fixes the battery core 1 well, effectively inhibiting the expansion of the cathode and anode, thereby maintaining a good electrochemical interface all the time. . At the same time, it can absorb the vibration energy of the battery during use, and avoid tab breakage or other possible short circuit hazards caused by shaking of the battery core 1 during transportation and actual vibration use. Reduce the pressure and damage of the rigidity of the steel shell 4 on the battery core, and improve the safety of the battery.

根据上述说明书的揭示,本实用新型所属领域的技术人员还可以对上述实施方式进行适当的变更和修改。因此,本实用新型并不局限于上面揭示和描述的具体实施方式,对本实用新型的一些修改和变更也应当落入本实用新型的权利要求的保护范围内。此外,尽管本实用新型书中使用了一些特定的术语,但这些术语只是为了方便说明,并不对本实用新型专利成任何限制。 According to the disclosure of the above specification, those skilled in the art to which the present utility model belongs can also make appropriate changes and modifications to the above embodiment. Therefore, the utility model is not limited to the specific implementation manners disclosed and described above, and some modifications and changes to the utility model should also fall within the scope of protection of the claims of the utility model. In addition, although some specific terms are used in this utility model, these terms are only for convenience of description and do not limit the utility model patent in any way.

Claims (4)

1. a cylinder type steel case lithium ion battery, comprise battery steel shell, is contained in battery and the electrolyte that is filled in wherein in battery steel shell, and it is characterized in that: the battery surface uniform is coated with and is brushed with the soft polymeric material layer.
2. a kind of cylinder type steel case lithium ion battery as claimed in claim 1, it is characterized in that: the thickness of described soft polymeric material layer is 0.5-5.0mm.
3. a kind of cylinder type steel case lithium ion battery as claimed in claim 2, it is characterized in that: described soft polymeric material layer is one deck or multilayer.
4. a kind of cylinder type steel case lithium ion battery as claimed in claim 3, it is characterized in that: described soft polymeric material layer is the electronic isolation layer.
CN2013202788994U 2013-05-21 2013-05-21 Cylindrical steel shell lithium ion battery Expired - Lifetime CN203288661U (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105261715A (en) * 2015-11-07 2016-01-20 合肥国轩高科动力能源有限公司 Cylindrical battery shell
CN105552252A (en) * 2015-12-11 2016-05-04 中国电子科技集团公司第十八研究所 Long-storage lifetime lithium-ion battery and treatment method therefor
CN110661009A (en) * 2019-10-08 2020-01-07 中国电子科技集团公司第十八研究所 A Self-Limited Swelling Suppression Structure for Cylindrical Lithium Carbon Fluoride Batteries
CN112133956A (en) * 2020-11-03 2020-12-25 江西力能新能源科技有限公司 A new type of lithium battery and its manufacturing process and application

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105261715A (en) * 2015-11-07 2016-01-20 合肥国轩高科动力能源有限公司 Cylindrical battery shell
CN105552252A (en) * 2015-12-11 2016-05-04 中国电子科技集团公司第十八研究所 Long-storage lifetime lithium-ion battery and treatment method therefor
CN110661009A (en) * 2019-10-08 2020-01-07 中国电子科技集团公司第十八研究所 A Self-Limited Swelling Suppression Structure for Cylindrical Lithium Carbon Fluoride Batteries
CN112133956A (en) * 2020-11-03 2020-12-25 江西力能新能源科技有限公司 A new type of lithium battery and its manufacturing process and application

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