CN203118523U - Graphical transparent conductive film - Google Patents

Graphical transparent conductive film Download PDF

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Publication number
CN203118523U
CN203118523U CN2013200672279U CN201320067227U CN203118523U CN 203118523 U CN203118523 U CN 203118523U CN 2013200672279 U CN2013200672279 U CN 2013200672279U CN 201320067227 U CN201320067227 U CN 201320067227U CN 203118523 U CN203118523 U CN 203118523U
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conduction region
insulation layer
metal wire
conductive layer
metal
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CN2013200672279U
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Chinese (zh)
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周菲
曹淼倩
高育龙
方运
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Nanchang OFilm Tech Co Ltd
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Nanchang OFilm Tech Co Ltd
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Abstract

The utility model relates to a graphical transparent conductive film, which comprises a substrate, a first conductive layer and a second conductive layer. The first conductive layer comprises a first conductive region and a first insulating region, and the second conductive layer comprises a second conductive region and a second insulating region, wherein both the first and second conductive regions comprise multiple metal grids formed by metal lines, and the multiple metal grids are embedded metal grids and are random-shaped; the probability density that the gradient of the metal lines of the first conductive region is close to transverse direction is greater than the probability density that the gradient is close to the vertical direction, and the probability density that the gradient of the metal lines of the second conductive region is close to vertical direction is greater than the probability density that the gradient is close to the transverse direction; and the first and second conductive layers are superposed and are mutually separated and insulated in the thickness direction of the substrate, and superposed metal grids are uniformly distributed in different angles. Thus, light transmittance is increased and conductivity is maintained; and after superposition, the metal grids of the two layers of the conductive film are uniformly distributed in different angles, thereby completely eliminating phenomenon of moire fringes.

Description

Graphical nesa coating
Technical field
The utility model relates to the conducting film technical field, particularly relates to a kind of graphical nesa coating.
Background technology
Nesa coating is a kind of conductive film that has satisfactory electrical conductivity and have high transmission rate at visible light wave range.Nesa coating has been widely used in fields such as flat panel display, photovoltaic device, contact panel and electromagnetic shielding at present, has extremely vast market space.
In traditional handset touch panel, for thickness and the weight that alleviates mobile phone, be the graphical nesa coating of the flexibility of usefulness mostly; General Touch Screen needs to adopt two nesa coatings to form upper/lower electrode to finish touch controllable function mostly.Yet when two nesa coatings make up up and down, its light transmittance will further reduce.The conductive region of two traditional transparent conducting films is the grid of regular shape mostly, because the pixel cell of LCD is the rectangular element of regular shape, be regular shape and the black lines that becomes periodic distribution between the pixel, and the light tight lines of the periodicity of conductive film will periodically cover with the black line formation of LCD, comparatively significantly Moire fringe can occur when therefore this transparent conductive film being attached at the LCD surface.Identical principle in addition is when the applying of two regular grid conducting films also can produce tangible Moire fringe.This phenomenon has had a strong impact on the application based on the graphical nesa coating of metal grill undoubtedly.
The utility model content
Based on this, be necessary at the problems referred to above, a kind of graphical nesa coating that can either eliminate the Moire fringe phenomenon fully is provided.
A kind of graphical nesa coating comprises:
Substrate comprises first surface and second surface, and described first surface and described second surface are oppositely arranged;
First conductive layer is located at the first surface of described substrate, and described first conductive layer comprises first conduction region and first insulation layer, and described first conduction region comprises by the formed some metal grills of metal wire; And
Second conductive layer comprises second conduction region and second insulation layer, and described second conduction region comprises by the formed some metal grills of metal wire;
Wherein said some metal grills are the flush type metal grill and are random grid in irregular shape, the metal wire slope of described first conduction region near horizontal probability density greater than near probability density longitudinally, the close probability density longitudinally of the metal wire slope of described second conduction region is greater than close horizontal probability density, described second conductive layer and the stack of described first conductive layer and space and insulation on the thickness direction of described substrate, the stack metal grill that the stack back forms evenly distributes in all angles.
Therein among embodiment, meet the following conditions after the random grid stack in irregular shape of described first conductive layer and described second conductive layer: the metal wire in the described stack metal grill is straightway, and is evenly distributed with dextrad horizontal direction X-axis angulation θ; Wherein, described even distribution refers to the θ value of each metal line of statistics, and according to 5 ° step pitch, statistics drops on the Probability p of metal wire in each angular interval then i, obtain p at 0 ~ 180 ° with 36 interior angular interval thus 1, p 2... to p 36p iSatisfy standard deviation less than 20% of arithmetic equal value.
Therein among embodiment, the slope K of the metal wire of described first conduction region 1Probability density maximum in (1,1) scope, the slope K of the metal wire of described second conduction region 2Probability density maximum in (﹣ ∞, ﹣ 1) ∪ (1, ﹢ ∞) scope.
Among embodiment, described second conductive layer is arranged at the second surface of described substrate, is oppositely arranged with described first conductive layer therein.
Among embodiment, described second conductive layer is arranged at the surface of described first conductive layer therein, is positioned at the homonymy of described substrate with described first conductive layer.
Therein among embodiment, described first insulation layer and described second insulation layer comprise by the formed metal grill of metal wire, insulate between described first insulation layer and described first conduction region, insulate between described second insulation layer and described second conduction region, the metal grill of described first insulation layer and described second insulation layer is random grid in irregular shape.
Among embodiment, the metal grill of described first insulation layer and described second insulation layer evenly distributes on all angles therein.
Therein among embodiment, described first insulation layer and described first conduction region, the insulation mode of described second insulation layer and described second conduction region is: interconnect between the metal wire of described first insulation layer, and and the metal wire of described first conduction region between be provided with at interval; Interconnect between the metal wire of described second insulation layer, and and the metal wire of described first conduction region between be provided with at interval.
Therein among embodiment, described first insulation layer and described first conduction region, the insulation mode of described second insulation layer and described second conduction region is: the metal grill of described first insulation layer and described second insulation layer is made of the metal wire that does not have node and disconnect each other.
Among embodiment, the minimum range of per two metal wires head and the tail end points that disconnect mutually is less than 30 μ m in the described metal wire that does not have node and disconnect each other therein.
Among embodiment, the difference of the transmitance of described first conduction region and described first insulation layer is less than 2% therein, and the difference of the transmitance of described second conduction region and described second insulation layer is less than 2%.
Above-mentioned graphical nesa coating, by the metal grill of first conductive layer being done in a lateral direction the intercepting that stretches, the metal grill of second conductive layer is done the intercepting that stretches in a longitudinal direction, the metal wire slope that makes the conduction region of winning near horizontal probability density greater than near probability density longitudinally, the close probability density longitudinally of the metal wire slope of second conduction region is greater than close horizontal probability density, guaranteed that simultaneously the metal grill area is the increase of transmission region, make the light transmittance of whole nesa coating increase, again because unidirectional stretching and intercepting can to guarantee to be partial to the probability density of the metal wire on this direction constant, therefore the electric conductivity of nesa coating on this direction can keep constant substantially, and because first conductive layer is different with the metal wire probability density of second conductive layer on same direction, so after first conductive layer and the stack of second conductive layer, the stack metal grill of whole conducting film evenly distributes in all angles, has eliminated the Moire fringe phenomenon fully.
Description of drawings
Fig. 1 is the structural representation of graphical nesa coating;
Fig. 2 is the random grid part schematic diagram of first conductive layer of graphical nesa coating;
Fig. 3 is the random grid part schematic diagram of second conductive layer of graphical nesa coating;
Fig. 4 is the part-structure schematic diagram after Fig. 2 and Fig. 3 stack;
Fig. 5 is the probability distribution schematic diagram after Fig. 2 and Fig. 3 stack;
Fig. 6 is the Probability p of every line segment and X-axis angle in the random grid of graphical transparent conductive film iDistribute;
Fig. 7 is the enlarged diagram of the random grid of Fig. 2 and Fig. 3;
Fig. 7 A is the partial enlarged drawing of A among Fig. 7;
Fig. 7 B is the partial enlarged drawing of B among Fig. 7.
Embodiment
The utility model is described in further detail to reach embodiment below with reference to the accompanying drawings.
See also Fig. 1 to Fig. 5, a kind of graphical nesa coating 100 comprises substrate 110, first conductive layer 120 and second conductive layer 130, and substrate 110 comprises first surface 112 and second surface 114, and first surface 112 and second surface 114 are oppositely arranged.First conductive layer 120 is located at the first surface 112 of substrate, comprise first conduction region 122 and first insulation layer 124, first conduction region 122 comprises by the formed some metal grills of metal wire, and the metal wire slope of first conduction region 122 near horizontal probability density greater than near probability density longitudinally.Second conductive layer 130 comprises second conduction region 132 and second insulation layer 134, second conduction region 132 comprises by the formed some metal grills of metal wire, second conductive layer 130 and 120 stacks of first conductive layer and space and mutual insulating on the thickness direction of substrate 110, formed stack metal grill after the stack evenly distributes in all angles, and the close probability density longitudinally of metal wire slope is greater than close horizontal probability density.Wherein, metal grill is the flush type metal grill, by offering groove or offer groove on the hypothallus surface on substrate 110 surfaces, filling metal material again in groove forms, perhaps directly at substrate 110 metal wire that the surface is coated with, oven dry obtains being interspersed, carry out compacting again, obtain the flush type metal grill.
Above-mentioned graphical nesa coating is coordinate plane with the plane at substrate 110 places, laterally is X-axis, vertically is Y-axis.Metal wire slope in the metal grill of first conduction region 122 that obtains near horizontal probability density greater than near probability density longitudinally, that is to say first conduction region 122 near the quantity of the metal wire of X-axis greater than the quantity near Y-axis.Metal wire slope in the metal grill of second conduction region 132 near probability density longitudinally greater than near horizontal probability density, that is to say second conduction region 132 near the quantity of the metal wire of Y-axis greater than the quantity near X-axis.And because first conductive layer 120 is different with the metal wire probability density of second conductive layer 130 on same direction, after first conductive layer 120 and 130 stacks of second conductive layer, the stack metal grill distribution probability of whole conducting film becomes evenly to distribute, avoid grid and the repetition of LCD meshing rule, eliminated Moire fringe.The said random grid of present embodiment can be alveolate texture.
Seeing also Fig. 5, is first conductive layer 120 and second conductive layer, 130 stacks probability distribution schematic diagram afterwards.As shown in the figure, because the metal wire slope of first conduction region 122 near horizontal probability density greater than near probability density longitudinally, the close probability density longitudinally of the metal wire slope of second conduction region 132 is greater than close horizontal probability density, so when the slope of the metal wire in the metal grill of first conduction region 122 is in rising trend, the slope of the metal wire in the metal grill of second conduction region 132 is on a declining curve, after first conductive layer 120 and second conductive layer 130 superposeed, the slope integral body of the metal wire after the stack is the level of state, and namely the stack metal grill distribution probability of whole conductive layer is evenly distributed.
See also Fig. 4 and Fig. 6, in the present embodiment, the type of random grid is the irregular polygon random grid of isotropic, will be the angular distribution that example is analyzed the metal wire of its stack metal grill below with the random grid of 5mm*5mm area.
Among the embodiment as shown in Figure 4, random grid comprises 4257 line segments altogether.That adds up every line segment obtains one-dimension array θ (1) ~ θ (4257) with X-axis angle θ; And then with 5 ° be interval layout, be divided into 36 angular interval with 0 ~ 180 °; Drop on each interval interior probability in the statistics line segment, obtain one group of array p (1) ~ p (36), as shown in Figure 6; Subsequently according to the standard deviation computing formula:
s = ( p 1 - p ) 2 + ( p 2 - p ) 2 + · · · ( p n - p ) 2 n
N is 36 in the formula, and can obtain standard deviation s is 0.26%, and average probability p is 2.78%.Thus
Figure BDA00002823474700052
As seen the grid line of above-mentioned random grid is very even in angular distribution, can effectively avoid the generation of Moire fringe.When being attached at the LCD surface, will can not produce Moire fringe by the described graphical nesa coating of present embodiment.
See also Fig. 1, in present embodiment, second conductive layer 130 is arranged at the second surface 114 of substrate 110, is oppositely arranged with first conductive layer 120.By carry out the groove impression at hypothallus, filled conductive material in groove then, form first conductive layer 120 and second conductive layer 130, first conductive layer 120 that to make at last and second conductive layer 130 are fabricated into first surface 112 and the second surface 114 of substrate respectively, form after the stack the graphical nesa coating that grid immediately is evenly distributed on all angles.Wherein, hypothallus is the thermoplastic polymer layer.The visible light transmissivity of first conductive layer 120 and second conductive layer 130 is all greater than 88.6%.Certainly, in other embodiment, also first conductive layer 120 and second conductive layer 130 can be superimposed upon the same side of substrate 110, and the each interval insulation, satisfying the conducting film of different types of structure, thereby be applied to the touch-screen of different types of structure.
When planning grid, by intercepting after will stretching in a lateral direction for the grid of making first conductive layer, intercepting after will stretching in a longitudinal direction for the grid of making second conductive layer, the equal grid of preceding area obtains and stretches; According to the grid photoetching that designs; Again according to the figure mfg. moulding die of photoetching; Impress with mould again, obtain groove; Filled conductive material in groove obtains some flush type metal grills.Behind the stretching grid, the area of single metal grid has increased, so first conductive layer that obtains and the second conductive layer transmitance have increased.And the metal wire of the metal grill of first conductive layer that obtains is more near the quantity of X-axis, and the metal wire of the metal grill of second conductive layer is more near the quantity of Y-axis.Because the metal wire near a certain direction is more many, the unilateal conduction performance on this direction is more good, so the X-axis of first conductive layer conducts electricity very well, the Y-axis of second conductive layer conducts electricity very well.
In present embodiment, the slope K of the metal wire of first conduction region 122 1Probability density maximum in (1,1) scope, the slope K of the metal wire of second conduction region 132 2Probability density maximum in (﹣ ∞, ﹣ 1) ∪ (1, ﹢ ∞) scope.Slope K=tan θ, θ is the angle of metal wire and abscissa.By tan fixed as can be known, tan45 °=1, tan-45 °=-1, so the metal wire of first conduction region 122 and the angle of the X-axis quantity in (45 °, 45 °) or (225 °, 315 °) scope is maximum, wherein do not comprise endpoint value, namely the quantity of the metal wire of close X-axis is maximum.The metal wire of second conduction region 132 and the angle of the X-axis quantity in (45 °, 135 °) or (45 ° ,-135 °) scope is maximum, does not wherein comprise endpoint value, and namely the quantity of the metal wire of close Y-axis is maximum.
See also Fig. 3, the slope K of the metal wire in the metal grill of first conduction region 122 1The probability density that is distributed within the scope of (1,1) is more big, and namely the quantity near the metal wire of X-axis is just more many, thereby the electric conductivity on the X-direction is just more good.So in the present embodiment, when the slope K of the metal wire of first conduction region 122 1Be distributed in probability in the scope of (1,1) when maximum, graphical nesa coating is best at the electric conductivity of X-direction.Similarly, see also Fig. 4, when the slope K of the metal wire of second conduction region 132 2When the probability density in (﹣ ∞, ﹣ 1) ∪ (1, ﹢ ∞) scope was maximum, graphical nesa coating was best at the electric conductivity of Y direction.The visible light transmissivity of first conductive layer 120 and second conductive layer 130 is 89.86%, and corresponding X-axis and the resistance on the Y direction are 58 ohm, and the visible light transmissivity after the two conductive layers stack is 87.6%, has improved visible light transmissivity.
See also Fig. 7, Fig. 7 A and Fig. 7 B, expression be the metal wire of the metal grill of first insulation layer 124 and second insulation layer 134, be example explanation with first insulation layer 124, second insulation layer 134 and first insulation layer 124 are similar, repeat no more here.First insulation layer 124 comprises by the formed metal grill of metal wire, and metal grill is grid immediately in irregular shape, and the density of metal grill is identical with first conduction region 122, and the average diameter R of metal grill all can be conducive to reduce the Moire fringe phenomenon for 120 μ m.And first insulation layer 124 and 122 insulation of first conduction region, in present embodiment, insulation mode can for: interconnect between the metal wire of first insulation layer 124, and white space is set with spaced apart first conduction region 122 and first insulation layer 124 at first conduction region 122 and first insulation layer 124, the width d of this white space can be 3 μ m, after tested after, these width naked eyes are invisible, the transparence of naked eyes can be satisfied, therefore intensity contrast can be do not produced.
In other embodiment, the metal grill of described first insulation layer 124 and described second insulation layer 134 evenly distributes on all angles.And the difference of the transmitance of described first conduction region 122 and described first insulation layer 124 is less than 2%, and the difference of the transmitance of described second conduction region 132 and described second insulation layer 134 is less than 2%.Therefore, the conduction region and the insulation layer that are positioned at same conductive layer can not produce macroscopic gray difference, have improved the customer experience sense.
In other embodiment, insulation mode also can be made of the metal wire that does not have node and disconnect each other for: the metal grill of first insulation layer 124.Being specially will be centered by each node, and radius r is the groove structure cancellation in the 3 μ m.Because first insulation layer 124 is to be made of the isolated metal wire that disconnects each other, therefore can realize thoroughly non-conductively, first conduction region 122 is identical with the transmitance of first insulation layer 124, so can not produce intensity contrast.In present embodiment, simultaneously above-mentioned two kinds of insulation modes all are applied to the insulating regions of first conductive layer 120 and second conductive layer 130.First conduction region 122 and second conduction region 132 will use the silver-colored line of silk-screen fabrication techniques to draw, so that when being applied to touch-screen, constitute drive electrode and induction electrode.
In present embodiment, the minimum range of per two metal wire head and the tail end points that disconnect mutually is less than 30 μ m in the described metal wire that does not have node and disconnect each other.Can guarantee that conduction region and insulation layer are non-conductive mutually, simultaneously, have the white space that can guarantee insulation layer to be unlikely to produce grey scale change, avoid influencing operator's experience sense.
Among the above embodiment, the material of substrate 110 can be glass, quartz, polymethyl methacrylate, Merlon etc., and said electric conducting material is not limited to silver, also can be graphite, macromolecule conducting material etc.
The above embodiment has only expressed several execution mode of the present utility model, and it describes comparatively concrete and detailed, but can not therefore be interpreted as the restriction to the utility model claim.Should be pointed out that for the person of ordinary skill of the art under the prerequisite that does not break away from the utility model design, can also make some distortion and improvement, these all belong to protection range of the present utility model.Therefore, the protection range of the utility model patent should be as the criterion with claims.

Claims (11)

1. a graphical nesa coating is characterized in that, comprising:
Substrate comprises first surface and second surface, and described first surface and described second surface are oppositely arranged;
First conductive layer is located at the first surface of described substrate, and described first conductive layer comprises first conduction region and first insulation layer, and described first conduction region comprises by the formed some metal grills of metal wire; And
Second conductive layer comprises second conduction region and second insulation layer, and described second conduction region comprises by the formed some metal grills of metal wire;
Wherein said some metal grills are the flush type metal grill and are random grid in irregular shape, the metal wire slope of described first conduction region near horizontal probability density greater than near probability density longitudinally, the close probability density longitudinally of the metal wire slope of described second conduction region is greater than close horizontal probability density, described second conductive layer and the stack of described first conductive layer and space and insulation on the thickness direction of described substrate, the stack metal grill that the stack back forms evenly distributes in all angles.
2. graphical nesa coating according to claim 1, it is characterized in that, meet the following conditions after the random grid stack in irregular shape of described first conductive layer and described second conductive layer: the metal wire in the described stack metal grill is straightway, and is evenly distributed with dextrad horizontal direction X-axis angulation θ;
Wherein, described even distribution refers to: add up the θ value of each metal line, according to 5 ° step pitch, statistics drops on the Probability p of metal wire in each angular interval then i, obtain p at 0 ~ 180 ° with 36 interior angular interval thus 1, p 2... to p 36p iSatisfy standard deviation less than 20% of arithmetic equal value.
3. graphical nesa coating according to claim 1 is characterized in that, the slope K of the metal wire of described first conduction region 1Probability density maximum in (1,1) scope, the slope K of the metal wire of described second conduction region 2Probability density maximum in (﹣ ∞, ﹣ 1) ∪ (1, ﹢ ∞) scope.
4. graphical nesa coating according to claim 1 is characterized in that, described second conductive layer is arranged at the second surface of described substrate, is oppositely arranged with described first conductive layer.
5. graphical nesa coating according to claim 4 is characterized in that, described second conductive layer is arranged at the surface of described first conductive layer, is positioned at the homonymy of described substrate with described first conductive layer.
6. according to any described graphical nesa coating in the claim 1 to 5, it is characterized in that, described first insulation layer and described second insulation layer comprise by the formed metal grill of metal wire, insulate between described first insulation layer and described first conduction region, insulate between described second insulation layer and described second conduction region, the metal grill of described first insulation layer and described second insulation layer is random grid in irregular shape.
7. graphical nesa coating according to claim 6 is characterized in that, the metal grill of described first insulation layer and described second insulation layer evenly distributes on all angles.
8. graphical nesa coating according to claim 7, it is characterized in that, described first insulation layer and described first conduction region, the insulation mode of described second insulation layer and described second conduction region is: interconnect between the metal wire of described first insulation layer, and and the metal wire of described first conduction region between be provided with at interval; Interconnect between the metal wire of described second insulation layer, and and the metal wire of described first conduction region between be provided with at interval.
9. graphical nesa coating according to claim 7, it is characterized in that, described first insulation layer and described first conduction region, the insulation mode of described second insulation layer and described second conduction region is: the metal grill of described first insulation layer and described second insulation layer is made of the metal wire that does not have node and disconnect each other.
10. graphical nesa coating according to claim 9 is characterized in that, the minimum range of per two metal wire head and the tail end points that disconnect mutually is less than 30 μ m in the described metal wire that does not have node and disconnect each other.
11. graphical nesa coating according to claim 10 is characterized in that, the difference of the transmitance of described first conduction region and described first insulation layer is less than 2%, and the difference of the transmitance of described second conduction region and described second insulation layer is less than 2%.
CN2013200672279U 2013-02-05 2013-02-05 Graphical transparent conductive film Withdrawn - After Issue CN203118523U (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103426502A (en) * 2013-02-05 2013-12-04 南昌欧菲光科技有限公司 Patterned transparent conductive film

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103426502A (en) * 2013-02-05 2013-12-04 南昌欧菲光科技有限公司 Patterned transparent conductive film
WO2014121581A1 (en) * 2013-02-05 2014-08-14 南昌欧菲光科技有限公司 Patterned transparent conductive film
CN103426502B (en) * 2013-02-05 2016-08-03 南昌欧菲光科技有限公司 Patterned transparent conducting film

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