CN203108413U - Oxynitride absorption device - Google Patents
Oxynitride absorption device Download PDFInfo
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- CN203108413U CN203108413U CN201220526388.5U CN201220526388U CN203108413U CN 203108413 U CN203108413 U CN 203108413U CN 201220526388 U CN201220526388 U CN 201220526388U CN 203108413 U CN203108413 U CN 203108413U
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- 238000010521 absorption reaction Methods 0.000 title claims abstract description 33
- 239000007788 liquid Substances 0.000 claims abstract description 36
- 239000000945 filler Substances 0.000 claims abstract description 11
- 230000000694 effects Effects 0.000 claims abstract description 6
- 238000006243 chemical reaction Methods 0.000 claims abstract description 5
- 239000007789 gas Substances 0.000 claims description 33
- 239000012530 fluid Substances 0.000 claims description 12
- 238000002347 injection Methods 0.000 claims description 12
- 239000007924 injection Substances 0.000 claims description 12
- 239000007921 spray Substances 0.000 claims description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 3
- 241000521257 Hydrops Species 0.000 claims 4
- 206010030113 Oedema Diseases 0.000 claims 4
- 229910001873 dinitrogen Inorganic materials 0.000 claims 1
- 238000007599 discharging Methods 0.000 claims 1
- 230000008676 import Effects 0.000 claims 1
- 238000001179 sorption measurement Methods 0.000 claims 1
- 239000003595 mist Substances 0.000 abstract description 11
- 238000012423 maintenance Methods 0.000 abstract description 2
- 230000002378 acidificating effect Effects 0.000 abstract 1
- 238000005507 spraying Methods 0.000 abstract 1
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 61
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 12
- 238000009825 accumulation Methods 0.000 description 12
- 229910017604 nitric acid Inorganic materials 0.000 description 12
- 239000002253 acid Substances 0.000 description 9
- 238000004519 manufacturing process Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 238000009776 industrial production Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- MGWGWNFMUOTEHG-UHFFFAOYSA-N 4-(3,5-dimethylphenyl)-1,3-thiazol-2-amine Chemical compound CC1=CC(C)=CC(C=2N=C(N)SC=2)=C1 MGWGWNFMUOTEHG-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 238000010531 catalytic reduction reaction Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 2
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000000779 smoke Substances 0.000 description 2
- 238000003916 acid precipitation Methods 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Images
Classifications
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
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- Treating Waste Gases (AREA)
- Gas Separation By Absorption (AREA)
Abstract
Description
技术领域 technical field
本实用新型属于氮氧化物吸收处理的技术领域,适用于硝酸工业生产、硝酸装车系统、硝基为原料的生产行业进行氮氧化物吸收处理的一种氮氧化物吸收装置,特别是在对人体危害比较大的场合以及对环境等大气污染严重的行业。 The utility model belongs to the technical field of nitrogen oxide absorption and treatment, and is suitable for nitric acid industrial production, nitric acid loading system, and production industries where nitro is a raw material for nitrogen oxide absorption treatment, especially for nitrogen oxide absorption. Occasions with relatively large human hazards and industries with serious air pollution such as the environment. the
背景技术 Background technique
如今的硝酸工业生产、硝酸装车系统、硝基为原料的生产行业。在生产工艺环节中及浓硝酸储运中极不稳定,在常温下极易分解,分解后的氮氧化物在空气中迅速冷凝形成极其微小的颗粒物,表现为产生大量的可视黄烟。这些有机烟排放到空气中,不但损腐蚀厂房,并可直接形成酸雨,水体的氨氮含量超标等对环境造成严重的污染,人体吸入后对职业健康造成很大影响。 Today's nitric acid industrial production, nitric acid loading system, and nitro as raw material production industry. It is extremely unstable in the production process and in the storage and transportation of concentrated nitric acid, and it is easy to decompose at room temperature. The decomposed nitrogen oxides condense rapidly in the air to form extremely small particles, which is manifested as a large amount of visible yellow smoke. These organic fumes are discharged into the air, which not only damages and corrodes the factory buildings, but also directly forms acid rain, and the ammonia nitrogen content in the water body exceeds the standard, causing serious pollution to the environment, and the human body has a great impact on occupational health after inhalation. the
现有技术大多都是针对大型工业锅炉及硝酸装置尾气等的脱硝治理,但对零星的微量的氮氧化物排放无从下手。催化还原的方法都投资过大而且能耗极高,不利于中小排放点的治理推广。 Most of the existing technologies are aimed at the denitrification treatment of tail gas from large industrial boilers and nitric acid plants, etc., but there is no way to deal with sporadic and trace nitrogen oxide emissions. Catalytic reduction methods are all over-invested and extremely energy-consuming, which is not conducive to the promotion of treatment of small and medium-sized emission points. the
实用新型内容 Utility model content
本实用新型的目的在于对硝酸挥发烟雾存在的问题加以解决,进而提供一种设计结构合理、操作方便、节能环保效果好的氮氧化物吸收装置。 The purpose of the utility model is to solve the problem of nitric acid volatilization smoke, and further provide a nitrogen oxide absorption device with reasonable design structure, convenient operation, and good energy saving and environmental protection effect. the
为实现上述目的,本实用新型采用的技术解决方案是这样的:氮氧化物吸收装置,其特征在于,是由气体喷射装置、积液装置、反应吸收装置三部分组成的,根据各自特征依次把设备分为气体喷射室、积液室、吸收反应室、除雾室四个工作单元,气体喷射室和吸收反应室均与积液室连接, 除雾室安装在吸收反应室上端,其中,气体喷射室设有进气口及循环液进口;积液室内设有循环液液位控制口、循环泵接口、排液口和排净口;在吸收反应室中设有填料支撑架、填料、循环液喷淋口和喷头,填料的作用是延长氮氧化物气体在塔体内的停留时间;在除雾室中设有除雾装置丝网垫及出气口。 In order to achieve the above object, the technical solution adopted by the utility model is as follows: the nitrogen oxide absorption device is characterized in that it is composed of three parts: a gas injection device, a liquid accumulation device, and a reaction absorption device, and according to their respective characteristics, the The equipment is divided into four working units: gas injection chamber, liquid accumulation chamber, absorption reaction chamber and demisting chamber. Both the gas injection chamber and the absorption reaction chamber are connected with the liquid accumulation chamber. The injection chamber is provided with an air inlet and a circulating fluid inlet; a circulating fluid liquid level control port, a circulating pump interface, a liquid discharge port and a clean discharge port are provided in the effusion chamber; a packing support frame, packing, and circulating fluid are provided in the absorption reaction chamber. The function of the filler is to prolong the residence time of the nitrogen oxide gas in the tower body; the demisting device wire mesh pad and the gas outlet are arranged in the demisting chamber. the
其工作方式:依靠文丘里管瞬间压差将外界挥发性酸雾气体由进气口吸入塔体内,一部分凝结的酸雾雾滴靠自身重量沉积到积液室中另一部分氮氧化物气体中的一氧化氮被循环液喷淋口喷淋来的过氧化氢水溶液氧化为二氧化氮与水反应后生成硝酸溶液进入积液室,气体由下而上进入反吸收应室,在吸收反应室中未被氧化的氮氧化物酸性气体与喷淋水雾(过氧化氢水溶液)形成逆向接触使大部分的氮氧化物中一氧化氮完全被氧化成二氧化氮被水吸收后变成稀硝酸溶液进入积液室,经吸收后的气体进入除雾装置(丝网垫),经过除雾(丝网垫)分离,把气体中所夹带的液体酸雾分离出来,分离后的洁净气体通过出去口排出塔体外部,吸收完的液体靠自身重力作用进入积液室中。 Its working method: relying on the instantaneous pressure difference of the Venturi tube, the external volatile acid mist gas is sucked into the tower body from the air inlet, and a part of the condensed acid mist droplets are deposited into the other part of the nitrogen oxide gas in the effusion chamber by their own weight. Nitric oxide is oxidized to nitrogen dioxide by the hydrogen peroxide solution sprayed from the spray port of the circulating fluid, and reacts with water to form nitric acid solution, which enters the liquid accumulation chamber, and the gas enters the reaction chamber from bottom to top, and in the absorption reaction chamber The unoxidized nitrogen oxide acid gas forms a reverse contact with the spray water mist (hydrogen peroxide solution), so that the nitrogen monoxide in most of the nitrogen oxides is completely oxidized to nitrogen dioxide, which is absorbed by water and then becomes a dilute nitric acid solution After entering the effusion chamber, the absorbed gas enters the demisting device (wire mesh pad), and is separated by the demisting (wire mesh pad) to separate the liquid acid mist entrained in the gas, and the separated clean gas passes through the outlet It is discharged from the outside of the tower body, and the absorbed liquid enters the liquid accumulation chamber by its own gravity. the
与现有催化还原技术相比,本实用新型硝酸雾吸收处理装置在硝酸工业生产、硝酸装车系统、化肥生产等行业实际应用中具有吸收效果好、过滤精度高、去除气体中夹带酸烟雾效果好、投资维护费用低、占地面积小、节约能耗、保护生态环境等优点,而且使用寿命长、性能稳定、适用性强。主要针对中小排放点及无组织排放点的氮氧化物治理。 Compared with the existing catalytic reduction technology, the nitric acid mist absorption and treatment device of the utility model has good absorption effect, high filtration precision, and the effect of removing acid mist entrained in the gas in the practical application of nitric acid industrial production, nitric acid loading system, chemical fertilizer production and other industries. Good, low investment and maintenance costs, small footprint, energy saving, ecological environment protection, etc., and long service life, stable performance, and strong applicability. It is mainly aimed at the control of nitrogen oxides at small and medium-sized emission points and unorganized emission points. the
附图说明 Description of drawings
图1为本实用新型氮氧化物吸收装置的结构示意图。 Fig. 1 is a structural schematic diagram of a nitrogen oxide absorption device of the present invention. the
具体实施方式 Detailed ways
参见图1,本实用新型氮氧化物吸收装置,是由气体喷射装置、积液装置、反应吸收装置三部分组成的,根据各自特征依次把设备分为气体喷 射室B、积液室A、吸收反应室C、除雾室D四个工作单元,气体喷射室B和吸收反应室C均与积液室A连接,除雾室D安装在吸收反应室C上端,其中,气体喷射室B设有文丘里喷射装置、进气口N1及循环液进口N8,文丘里喷射装置的作用是:1、对气体酸雾和污染物进行洗涤。2、利用文丘里喉颈变化所产生的瞬间压差形成负压,将外界氮氧化物吸入塔体内,从而保证污染气体不从其它开口处冒出;进气口的作用是将气体送入塔体的流通通道,循环液进口是将积液室中的循环液由循环泵打入喷射室内对含有氮氧化物的酸雾气体进行初步氧化吸收;在积液室A内设有循环液液位控制口N3、循环泵接口N4、排液口N5及排净口N6,其中,循环液液位控制的作用是显示积液室内循环液位的高低从而控制排液口在什么状况开启,循环泵接口的作用是将积液室中的循环液用泵分别送入N7、N8循环液入口对含有氮氧化物的酸雾气体进行氧化吸收,排液口的作用是当液位控制超出范围后将积液室中的部分循环液排出塔体外从而使积液室内的液位保持恒定状态,排净口的作用是在停车检修时将塔体内的杂质、废液排出;在吸收反应室C中设有填料支撑架、填料3、循环液喷淋口N7及喷头2,填料支架的作用是支撑铺放在上的填料,填料3的作用是延长氮氧化物气体在塔体内的停留时间以保证氮氧化物在塔体内能充分氧化吸收,循环液喷淋口N7的作用是由循环泵送来的循环液由喷头2喷入塔体内与所含氮氧化物的气体进行逆向接触;在除雾室D中设有除雾装置丝网垫1及出气口N2。除雾装置丝网垫1的作用是将氧化吸收后的气体中所夹带的酸雾液滴分离出来,出气口N2的作用是经过除雾装置分离净化后的气体通过此口排出塔体之外。 Referring to Fig. 1, the nitrogen oxide absorption device of the present utility model is composed of three parts: a gas injection device, a liquid accumulation device, and a reaction absorption device, and the equipment is divided into a gas injection chamber B, a liquid accumulation chamber A, Absorption reaction chamber C, demister D four working units, gas injection chamber B and absorption reaction chamber C are connected to liquid accumulation chamber A, demist chamber D is installed on the upper end of absorption reaction chamber C, and gas injection chamber B is set There are Venturi injection device, air inlet N1 and circulating fluid inlet N8. The function of Venturi injection device is: 1. Wash gas acid mist and pollutants. 2. Utilize the instantaneous pressure difference generated by the change of Venturi throat to form a negative pressure, suck the nitrogen oxides from the outside into the tower body, so as to ensure that the polluted gas does not emerge from other openings; the function of the air inlet is to send the gas into the tower The circulation channel of the body, the inlet of the circulating fluid is to pump the circulating fluid in the liquid accumulation chamber into the injection chamber from the circulating pump to carry out preliminary oxidation and absorption of the acid mist gas containing nitrogen oxides; Control port N3, circulating pump interface N4, drain port N5 and drain port N6, among which, the function of circulating liquid level control is to display the level of circulating liquid in the effusion chamber so as to control when the drain port is opened, and the circulating pump The function of the interface is to send the circulating liquid in the liquid accumulation chamber into the N7 and N8 circulating liquid inlets to oxidize and absorb the acid mist gas containing nitrogen oxides, and the function of the liquid discharge port is to discharge the liquid when the liquid level control exceeds the range. Part of the circulating liquid in the liquid accumulation chamber is discharged out of the tower to keep the liquid level in the liquid accumulation chamber in a constant state. There are filler support frame, filler 3, circulating fluid spray port N7 and nozzle 2. The function of the filler bracket is to support the filler placed on it. The function of the filler 3 is to prolong the residence time of nitrogen oxide gas in the tower to ensure nitrogen The oxides can be fully oxidized and absorbed in the tower body. The function of the circulating liquid spray port N7 is that the circulating liquid sent by the circulating pump is sprayed into the tower body from the nozzle 2 to make reverse contact with the gas containing nitrogen oxides; D is equipped with demisting device wire mesh pad 1 and air outlet N2. The function of the wire mesh pad 1 of the demister device is to separate the acid mist droplets entrained in the gas after oxidation and absorption, and the function of the gas outlet N2 is to discharge the gas separated and purified by the demist device out of the tower body through this port . the
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201220526388.5U CN203108413U (en) | 2012-10-15 | 2012-10-15 | Oxynitride absorption device |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201220526388.5U CN203108413U (en) | 2012-10-15 | 2012-10-15 | Oxynitride absorption device |
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| CN203108413U true CN203108413U (en) | 2013-08-07 |
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| CN201220526388.5U Expired - Fee Related CN203108413U (en) | 2012-10-15 | 2012-10-15 | Oxynitride absorption device |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108744896A (en) * | 2018-07-20 | 2018-11-06 | 四川思达能环保科技有限公司 | A kind of nitrogen oxide containing gas absorption acid making system |
| CN109718635A (en) * | 2017-10-31 | 2019-05-07 | 中国石油化工股份有限公司 | A kind of process of flue gas desulfurization and denitrification |
-
2012
- 2012-10-15 CN CN201220526388.5U patent/CN203108413U/en not_active Expired - Fee Related
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109718635A (en) * | 2017-10-31 | 2019-05-07 | 中国石油化工股份有限公司 | A kind of process of flue gas desulfurization and denitrification |
| CN108744896A (en) * | 2018-07-20 | 2018-11-06 | 四川思达能环保科技有限公司 | A kind of nitrogen oxide containing gas absorption acid making system |
| CN108744896B (en) * | 2018-07-20 | 2023-12-15 | 四川思达能环保科技有限公司 | Nitrogen oxide flue gas absorption system for preparing acid |
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| Date | Code | Title | Description |
|---|---|---|---|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20130807 Termination date: 20141015 |
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| EXPY | Termination of patent right or utility model |