CN203007033U - Novel partial-nitrosation anaerobic ammonia oxidation integral reactor - Google Patents

Novel partial-nitrosation anaerobic ammonia oxidation integral reactor Download PDF

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Publication number
CN203007033U
CN203007033U CN2012207311968U CN201220731196U CN203007033U CN 203007033 U CN203007033 U CN 203007033U CN 2012207311968 U CN2012207311968 U CN 2012207311968U CN 201220731196 U CN201220731196 U CN 201220731196U CN 203007033 U CN203007033 U CN 203007033U
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China
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anammox
microbial film
district
reactor
film district
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CN2012207311968U
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黄勇
李祥
袁怡
李勇
潘杨
李大鹏
李雪艳
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Suzhou University of Science and Technology
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Suzhou University of Science and Technology
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Abstract

The utility model discloses a novel partial-nitrosation anaerobic ammonia oxidation integral reactor which comprises a main reaction area, an upper three-phase separator and an air ascending chamber, wherein the main reaction area is internally sequentially provided with a sludge fluidization area, a middle biomembrane area and an upper biomembrane area from bottom to top, and the main reaction area is externally sequentially provided with a bottom water inlet, an air inlet and an upper water outlet from bottom to top; a three-phase separator area internally sequentially comprises a biomembrane area and an air collecting chamber from bottom to top; and the three-phase separator is externally provided with a sediment area. The novel partially-nitrosation anaerobic ammonia oxidation integral reactor disclosed by the utility model can realize the subarea culture of nitrosation and anaerobic ammonia oxidation in a single reactor, thereby preventing the influence of certain environment factors on anaerobic ammonia oxidation bacteria and nitrosation bacteria; and the novel partially-nitrosation anaerobic ammonia oxidation integral reactor disclosed by the utility model realizes the combination of various areas through a self-reflux function, thereby realizing the denitrification of wastewater autotrophs.

Description

A kind of Anammox integrated reactor of novel partial nitrification
Technical field
The utility model relates to a kind of Anammox integrated reactor of novel partial nitrification.
Background technology
In recent years, Anammox is as a kind of novel bio-denitrification technology, because having high nitric efficiency, and the reduction process cost, and be subject to numerous investigators' favor.Anammox refers to that anaerobic ammonia oxidizing bacteria utilizes ammonia nitrogen as electron donor under the condition of anaerobism, and nitrite nitrogen carries out biological respinse as electron acceptor(EA), and is translated into the process of nitrogen.This process need not oxygen and organic carbon source, has greatly reduced the consumption of power and energy.But Anammox needs nitrite as matrix, needs the ammonia nitrogen in waste water is carried out partial nitrification before carrying out the Anammox reaction.Yet there are some Intraspecific differences in physiologicals in nitrite bacteria and anaerobic ammonia oxidizing bacteria, when therefore adopting process integration to process high ammonia-nitrogen wastewater, how to realize that nitrosification and being connected of Anammox become extremely important.
Some parts nitrosification, the Anammox process integration reported at present mainly contain two kinds of forms: a kind of is with two kinds of microorganism single culture, realize waste water semi-hitrosation-Anammox by connection, for example: SBR+ anaerobism class reactor, SHARON+ anaerobism class reactor; Another kind is to realize two kinds of microorganisms mixed culture in same reactor, for example CANON reactor by limiting some control factors.It is used in mainly outstanding following problem of nitrosation-anaerobic ammoxidation aspect: (1) is stronger adaptability because nitrobacteria has, nitrococcus is placed on separately in reactor to cultivate easily causes the nitrobacteria growth, thereby affect the stable operation for a long time of nitrosification effect; (2) because anaerobic ammonia oxidizing bacteria is strictly anaerobic bacterium, and nitrococcus is aerobic bacteria, places it in single reaction vessel, if do not carry out subregion, in any case limit oxygen, dissolved oxygen all can exert an influence to the denitrification functions of anaerobic ammonia oxidizing bacteria; (3) no matter adopt two reactor isolate forsters, still adopt single reaction vessel to cultivate, its water outlet dissolved oxygen is lower, need to carry out reoxygenation to water outlet; (4) Anammox is the reaction that a pH value increases, and nitrosification is a reaction that the pH value reduces, and need to add respectively soda acid when adopting two reactors and regulate the pH value.
The characteristic that has for the existing defective of present nitrosation-anaerobic ammoxidation process integration and nitrococcus and anaerobic ammonia oxidizing bacteria, the design attempts subregion in single reaction vessel, guarantee that mutual growing environment is unaffected, realize again the integrated of nitrosification and Anammox simultaneously.The tail gas of nitrosification process is used for gas lift, realizes nitrosification district and the backflow certainly of Anammox district.Experiment showed, that accordingly the reactor of utility model is conducive to high ammonia-nitrogen wastewater and realizes denitrification of autotrophic organism, can avoid the pH value to the impact of reactor; Avoid the impact of high nitrogen concentration.
The utility model content
The purpose of this utility model is to overcome the above problem that prior art exists, and a kind of Anammox integrated reactor of novel partial nitrification is provided.
For realizing above-mentioned technical purpose, reach above-mentioned technique effect, the utility model is achieved through the following technical solutions:
A kind of Anammox integrated reactor of novel partial nitrification, comprise main reaction region, top triphase separator and gas lift chamber, main reaction region inside is mud fluidization regions, microbial film district, middle part, microbial film district, top from below to up successively, and the main reaction region outside is bottom water-in, inlet mouth, top water outlet from below to up successively; Inside, triphase separator district comprises microbial film district and collection chamber from below to up successively, and described triphase separator outside is the settling region; The built-in drive unit of described reactor mud fluidization regions; The described reactor body outside is provided with the gas lift chamber, return line is set in it is connected with described reactor bottom mud fluidization regions, nitrosification liquid thrust-augmenting nozzle is set is connected with microbial film district, described top, airway is set is connected with described collection chamber.
Further, the drive unit size of described mud fluidization regions installation is relevant by the intensity of the mud needed fluidized state of district's mud and stirring.
Further, described gas lift chamber arranges described airway, described thrust-augmenting nozzle and described return line.
Further, microbial film district, described top is aerobic nitrosated, microbial film district, described middle part is set to Anammox, described bottom mud fluidization regions comprises nitrosification and Anammox, microbial film district, described top volume has been contained in described collection chamber liquid level with down to the aerator inlet part, described part is placed filler, and described mud fluidization regions, microbial film district, middle part and microbial film district, top volume ratio are determined according to the nitrosification ability of Anammox ability and the required nitrite of Anammox.
The beneficial effects of the utility model are:
The utility model has been avoided the impact of the unfavorable factors such as dissolved oxygen on the Anammox sludge activity; Utilize simultaneously gas lift to realize nitrosification district and Anammox district UNICOM, realize mutually replenishing and high ammonia-nitrogen wastewater denitrification of autotrophic organism process of two district's potential of hydrogen; Because the nitrosification district is arranged on the reactor top, satisfy the requirement of wastewater effluent dissolved oxygen in addition.
Principle of the present utility model is:
Enter air by the reactor inlet mouth, realize top microbial film district nitrosification, simultaneously remaining exhaust collection is entered the collection chamber of triphase separator, import the gas lift chamber by airway and form gas lift, inferior Digestive system is back to reactor bottom mud fluidization regions, mix with influent ammonia nitrogen, satisfy the demand of microbial film district, middle part anaerobic ammonia oxidation microbiological.Water inlet simultaneously can be utilized by the partial nitrification bacterium in the mud fluidization regions with the entrained dissolved oxygen that refluxes.Thereby avoid dissolved oxygen on the impact of anaerobic ammonia oxidizing bacteria.
Above-mentioned explanation is only the general introduction of technical solutions of the utility model, for can clearer understanding technique means of the present utility model, and can be implemented according to the content of specification sheets, below with preferred embodiment of the present utility model and coordinate accompanying drawing to be described in detail as follows.Embodiment of the present utility model is provided in detail by following examples and accompanying drawing thereof.
Description of drawings
Accompanying drawing described herein is used to provide further understanding of the present utility model, consists of the application's a part, and illustrative examples of the present utility model and explanation thereof are used for explaining the utility model, do not consist of improper restriction of the present utility model.In the accompanying drawings:
Fig. 1 is one-piece construction schematic diagram of the present utility model.
Number in the figure explanation: 1, drive unit, 2, water-in, 3, the mud fluidization regions, 4, middle part microbial film district, 5, nitrosification film district, 6, triphase separator, 7, collection chamber, 8, settling region, 9, airway, 10, thrust-augmenting nozzle, 11, gas lift chamber, 12, inlet mouth, 13, return line, 14, water outlet.
Embodiment
Below with reference to the accompanying drawings and in conjunction with the embodiments, further illustrate the utility model.
The utility model proposes a kind of Anammox integrated reactor of novel partial nitrification.With reference to shown in Figure 1, a kind of anaerobic ammonia oxidation reactor of novel partial nitrification, comprise main reaction region, top triphase separator 6 and gas lift chamber 11, main reaction region inside is mud fluidization regions 3, microbial film district, middle part 4, microbial film district, top 5 from below to up successively, and the main reaction region outside is bottom water-in 2, inlet mouth 12, top water outlet 14 from below to up successively; Triphase separator 6 inside, district comprise microbial film 5th district and collection chamber 7 from below to up successively, and described triphase separator 6 outsides, district are settling regions; Described reactor mud fluidization regions arranges drive unit 1; The described reactor body outside is provided with gas lift chamber 11, return line 13 is set in it is connected with described reactor bottom mud fluidization regions 3, nitrosification liquid thrust-augmenting nozzle 10 is set is connected with microbial film district, described top 5, airway 9 is set is connected with described collection chamber 7.
Further, the size of described mud fluidization regions 3 drive units installations is relevant by the intensity of the mud needed fluidized state of district's mud and stirring.
Further, described gas lift chamber 11 arranges described airway 9, described thrust-augmenting nozzle 10 and described return line 13.
Further, microbial film district, described top 5 is aerobic nitrosated, microbial film district, described middle part 4 is set to Anammox, described bottom mud fluidization regions 3 comprises nitrosification and Anammox, microbial film district, described top 5 volumes have been contained the interior liquid level of described collection chamber 7 with down to the aerator part, described part is placed filler, and described mud fluidization regions 3, microbial film district, middle part 4 and microbial film district, top 5 volume ratios are determined according to the nitrosification ability of Anammox ability and the required nitrite of Anammox.
Optimize, on the basis of principle of peactor described above, according to the laboratory small testing device, sketch the realization of nitrosifying Anammox integrated reactor; At first microbial film district, described reactor top 5 adds polyethylene carrier, described reactor middle part employing tunica fibrosa, and the inoculation ordinary activated sludge is controlled the needed control parameter of biochemical reaction; Guarantee that by mechanical stirring film mixes with mud, is conducive to microbial film and forms fast; After biofilm success, according to the growth conditions of anaerobic ammonia oxidizing bacteria and nitrite bacteria, regulate the air input of inlet mouth, keep nitrosification district dissolved oxygen concentration at optimal level; Control simultaneously the amount of phegma by controlling air input, to satisfy Anammox to the matrix biological need; Influent ammonium concentration progressively improves with microorganism enrichment degree in reactor
The above is only preferred embodiment of the present utility model, is not limited to the utility model, and for a person skilled in the art, the utility model can have various modifications and variations.All within spirit of the present utility model and principle, any modification of doing, be equal to replacement, improvement etc., within all should being included in protection domain of the present utility model.

Claims (4)

1. the Anammox integrated reactor of a novel partial nitrification, comprise main reaction region, top triphase separator (6) and gas lift chamber (11), it is characterized in that, main reaction region inside is mud fluidization regions (3), microbial film district, middle part (4), microbial film district, top (5) from below to up successively, and the main reaction region outside is bottom water-in (2), inlet mouth (12), top water outlet (14) from below to up successively; Inside, triphase separator (6) district comprises microbial film district (5) and collection chamber (7) from below to up successively, and outside, described triphase separator (6) district is settling region (8); The built-in drive unit of described reactor mud fluidization regions (3) (1); The described reactor body outside is provided with gas lift chamber (11), return line (13) is set in it to be connected with described reactor bottom mud fluidization regions (3), nitrosification liquid thrust-augmenting nozzle (10) is set is connected with microbial film district, described top (5), airway (9) is set is connected with described collection chamber (7).
2. the Anammox integrated reactor of novel partial nitrification according to claim 1, is characterized in that, the drive unit size that described mud fluidization regions (3) is installed is relevant by the intensity of the mud needed fluidized state of district's mud and stirring.
3. the Anammox integrated reactor of novel partial nitrification according to claim 1, is characterized in that, described gas lift chamber (11) arranges described airway (9), described thrust-augmenting nozzle (10) and described return line (13).
4. the Anammox integrated reactor of novel partial nitrification according to claim 1, it is characterized in that, microbial film district, described top (5) is aerobic nitrosated, microbial film district, described middle part (4) is set to Anammox, described bottom mud fluidization regions (3) comprises nitrosification and Anammox, microbial film district, described top (5) volume has been contained the interior liquid level of described collection chamber (7) with down to the aerator part, described part is placed filler, and described mud fluidization regions (3), microbial film district (4), middle part and microbial film district, top (5) volume ratio are determined according to the nitrosification ability of Anammox ability and the required nitrite of Anammox.
CN2012207311968U 2012-12-27 2012-12-27 Novel partial-nitrosation anaerobic ammonia oxidation integral reactor Expired - Fee Related CN203007033U (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103508562A (en) * 2013-09-29 2014-01-15 浙江大学 Integrated swimming self-circulation denitrification reactor
CN103896395A (en) * 2012-12-27 2014-07-02 苏州科技学院 Novel partial-nitrosation anaerobic ammoxidation integrated reactor
CN104710018A (en) * 2015-02-26 2015-06-17 中国环境科学研究院 Submerged device and method for rapid multiplication culture by jetting and backflow for anaerobic ammonia oxidizing bacteria multi-phase mixed culture
CN114436397A (en) * 2022-01-14 2022-05-06 南京大学 A processing apparatus for high concentration organic, difficult biochemical waste water

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103896395A (en) * 2012-12-27 2014-07-02 苏州科技学院 Novel partial-nitrosation anaerobic ammoxidation integrated reactor
CN103508562A (en) * 2013-09-29 2014-01-15 浙江大学 Integrated swimming self-circulation denitrification reactor
CN104710018A (en) * 2015-02-26 2015-06-17 中国环境科学研究院 Submerged device and method for rapid multiplication culture by jetting and backflow for anaerobic ammonia oxidizing bacteria multi-phase mixed culture
CN104710018B (en) * 2015-02-26 2018-03-16 中国环境科学研究院 The submerged spray back rapid amplifying culture apparatus and method of a kind of mixed training thing of anaerobic ammonium oxidizing bacteria multiphase
CN114436397A (en) * 2022-01-14 2022-05-06 南京大学 A processing apparatus for high concentration organic, difficult biochemical waste water

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