CN202881181U - Used in coke oven riser waste gas waste heat recovery system - Google Patents

Used in coke oven riser waste gas waste heat recovery system Download PDF

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CN202881181U
CN202881181U CN2012206013887U CN201220601388U CN202881181U CN 202881181 U CN202881181 U CN 202881181U CN 2012206013887 U CN2012206013887 U CN 2012206013887U CN 201220601388 U CN201220601388 U CN 201220601388U CN 202881181 U CN202881181 U CN 202881181U
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coke oven
gas
heat exchanger
waste heat
water
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郁鸿凌
沈丹丹
杨东伟
王美清
林友斌
陈梦洁
惠建明
惠文博
李�杰
余晖
张丕祥
张昆钢
尹思聪
何正祥
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WUXI YIEN TECHNOLOGY Co Ltd
YUNNAN KUNGANG COAL COKING CO Ltd
University of Shanghai for Science and Technology
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WUXI YIEN TECHNOLOGY Co Ltd
YUNNAN KUNGANG COAL COKING CO Ltd
University of Shanghai for Science and Technology
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    • Y02P20/129Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines

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Abstract

本实用新型涉及一种用于用于焦炉上升管荒煤气余热回收系统,由上升管换热器、主集气管、水/汽换热器组成,上升管换热器进气口连接焦炉的工质气体出口,上升管换热器的热气体出口连接主集气管,主集气管连接水/汽换热器,用于产生蒸汽或热水。该系统在保证焦炉安全运行和不影响荒煤气的其他工艺要求的前提下,利用上升管换热器能有效回收荒煤气的50%以上的余热量,并且减少了用于荒煤气减温的氨水用量,同时也减少了荒煤气净化工艺流程中产生的有毒有害废水。

Figure 201220601388

The utility model relates to a waste heat recovery system for coke oven ascending pipe waste gas waste heat, which is composed of ascending pipe heat exchanger, main gas collecting pipe and water/steam heat exchanger, and the air inlet of the ascending pipe heat exchanger is connected with coke oven The working medium gas outlet, the hot gas outlet of the riser heat exchanger is connected to the main gas collector, and the main gas collector is connected to the water/steam heat exchanger for generating steam or hot water. Under the premise of ensuring the safe operation of the coke oven and not affecting other process requirements of the raw gas, the system can effectively recover more than 50% of the waste heat of the raw gas by using the riser heat exchanger, and reduce the waste gas used for cooling the raw gas. The amount of ammonia water is reduced, and the toxic and harmful wastewater generated in the crude gas purification process is also reduced.

Figure 201220601388

Description

用于焦炉上升管荒煤气余热回收系统Used in coke oven riser waste gas waste heat recovery system

技术领域 technical field

本实用新型涉及一种用于焦炉上升管荒煤气余热回收系统,尤其是一种采用氮气或(空气)作为冷却介质的焦炉上升管荒煤气余热回收利用系统。 The utility model relates to a waste heat recovery system for coke oven rising pipe raw gas, in particular to a coke oven rising pipe waste heat recovery system using nitrogen or (air) as a cooling medium.

背景技术 Background technique

炼焦工艺流程中产生的余热资源的高效回收利用,是建立资源节约、环境友好的绿色焦化厂节能的主要方向,也是降低焦炉能耗的主要途径之一。其中,从炭化室经上升管逸出的650℃~700℃荒煤气带出热占焦炉输出总热量的36%。为了冷却高温的荒煤气必须喷洒大量70℃~75℃循环氨水,高温荒煤气因循环氨水的大量蒸发而被冷却至82℃~85℃,再经初冷器冷却至22℃~35℃,荒煤气带出热被白白浪费。目前荒煤气的余热回收还处于研发阶段,如用导热油夹套管、热管、锅炉、半导体温差发电和水套管等技术来回收荒煤气带出热。但是有些方法和方式还达不到工业生产应用。 The efficient recovery and utilization of waste heat resources generated in the coking process is the main direction of building a resource-saving and environmentally friendly green coking plant for energy conservation, and it is also one of the main ways to reduce coke oven energy consumption. Among them, the 650°C-700°C raw coal gas that escapes from the carbonization chamber through the riser accounts for 36% of the total output heat of the coke oven. In order to cool the high-temperature raw gas, it is necessary to spray a large amount of circulating ammonia water at 70°C to 75°C. The high-temperature raw gas is cooled to 82°C to 85°C due to the evaporation of a large amount of circulating ammonia water, and then cooled to 22°C to 35°C through the primary cooler. The heat brought out by the gas is wasted. At present, the waste heat recovery of raw gas is still in the research and development stage, such as heat transfer oil jacketed pipes, heat pipes, boilers, semiconductor thermoelectric power generation and water jackets to recover raw gas to bring out heat. However, some methods and methods have not yet reached industrial production applications.

发明内容 Contents of the invention

本实用新型是要解决现有焦炉碳化室通过上升管溢出的荒煤气的余热回收的技术问题,而提供一种焦炉上升管荒煤气余热回收利用系统,该系统在保证焦炉安全运行和不影响荒煤气的其他工艺要求的前提下,利用上升管换热器能有效回收荒煤气的50%以上的余热量,并且减少了用于荒煤气减温的氨水用量,同时也减少了荒煤气净化工艺流程中产生的有毒有害废水。 The utility model aims to solve the technical problem of recovering the waste heat of the raw coal gas overflowing through the rising pipe in the existing coke oven carbonization chamber, and provides a coke oven rising pipe waste gas waste heat recovery and utilization system. The system can ensure the safe operation of the coke oven and Under the premise of not affecting other process requirements of raw gas, the use of riser heat exchangers can effectively recover more than 50% of the waste heat of raw gas, and reduce the amount of ammonia water used for cooling raw gas, and also reduce the waste of raw gas. Toxic and harmful wastewater generated in the purification process.

为实现上述目的,本实用新型采用的技术方案如下: In order to achieve the above object, the technical scheme adopted by the utility model is as follows:

一种用于焦炉上升管荒煤气余热回收利用系统,由上升管换热器、主集气管、水/汽换热器组成,其特点是:上升管换热器进气口连接焦炉的工质气体出口,上升管换热器的热气体出口连接主集气管,主集气管连接水/汽换热器,用于产生蒸汽或热水。 A waste heat recovery and utilization system for waste gas in the riser tube of coke oven, which is composed of a riser heat exchanger, a main gas collector, and a water/steam heat exchanger. Its characteristics are: the air inlet of the riser heat exchanger is connected to the coke oven Working medium gas outlet, the hot gas outlet of the riser heat exchanger is connected to the main gas collection pipe, and the main gas collection pipe is connected to the water/steam heat exchanger for generating steam or hot water.

上升管换热器的回流通道中流动惰性气体。 Inert gas flows in the return channel of the riser heat exchanger.

上升管换热器的内壁底部设置一焦油导出管,用于防止从荒煤气析出的焦油回流到焦炉上升管底端与焦炉连接处,使得焦炉煤气析出口处结焦形成石墨。 A tar outlet pipe is installed at the bottom of the inner wall of the riser heat exchanger to prevent the tar precipitated from the raw coal gas from flowing back to the connection between the bottom end of the riser pipe of the coke oven and the coke oven, so that the outlet of the coke oven gas is coked to form graphite.

本实用新型的有益效果是: The beneficial effects of the utility model are:

本实用新型与其它形式的焦炉上升管荒煤气余热回收利用系统(装置)相比较,适合焦化工艺荒煤气余热回收利用,并且运行安全性高。上升管换热器的结构尺寸能与原有的上升管外形结构尺寸相同,便于更换维修;并且其受热面面积布置更为合理,在荒煤气高温段最大程度地利用内设多股螺旋回流通道的上升管换热器受热面,提高荒煤气与空气或(氮气)之间的换热效果,空气或(氮气)能有效地获取荒煤气的热量,同时可以通过改变空气或(氮气)流量能控制荒煤气的出口温度,避免了荒煤气在急剧降温的状态下,荒煤气中焦油析出造成上升管管壁结焦,影响焦炉安全运行。采用气体作为热交换器的介质,在事故状态下可以确保焦炉的安全运行,假如采用氮气作为传热介质也可以作为干熄焦余热锅炉的补充烟气,可以提高干熄焦余热锅炉的运行效率和出力。 Compared with other forms of waste heat recovery and utilization system (device) of raw gas in coke oven rising pipe, the utility model is suitable for recovery and utilization of waste heat of waste gas in coking process, and has high operation safety. The structural size of the riser heat exchanger can be the same as that of the original riser, which is convenient for replacement and maintenance; and the area of the heating surface is more reasonable, and the multi-strand spiral return channel is set up in the high temperature section of the raw gas to the greatest extent. The heating surface of the rising tube heat exchanger improves the heat exchange effect between the raw gas and the air or (nitrogen), the air or (nitrogen) can effectively obtain the heat of the raw gas, and at the same time, it can change the flow energy of the air or (nitrogen) Controlling the outlet temperature of the raw gas prevents the coking of the wall of the ascending pipe caused by the precipitation of tar in the raw gas when the temperature of the raw gas drops sharply, which affects the safe operation of the coke oven. Using gas as the medium of the heat exchanger can ensure the safe operation of the coke oven in an accident state. If nitrogen is used as the heat transfer medium, it can also be used as supplementary flue gas for the CDQ waste heat boiler, which can improve the operation of the CDQ waste heat boiler. efficiency and output.

附图说明 Description of drawings

图1是本实用新型的结构原理图; Fig. 1 is a structural principle diagram of the utility model;

图2是上升管换热器结构主视图; Figure 2 is a front view of the riser heat exchanger structure;

图3是图2中沿A-A的剖视图; Fig. 3 is a sectional view along A-A in Fig. 2;

图4是图2中沿B-B的剖视图。 Fig. 4 is a sectional view along B-B in Fig. 2 .

具体实施方式 Detailed ways

下面结合附图与实施例对本实用新型作进一步说明。 Below in conjunction with accompanying drawing and embodiment the utility model is further described.

如图1所示,本实用新型的用于焦炉上升管荒煤气余热回收利用系统,包括上升管换热器1、主集气管2、水/汽换热器3等。 As shown in FIG. 1 , the waste heat recovery system for coke oven riser waste gas of the present invention includes riser heat exchanger 1 , main gas collector 2 , water/steam heat exchanger 3 and so on.

上升管换热器1进气口连接焦炉的工质气体出口,上升管换热器1的热气体出口连接主集气管2,主集气管2连接水/汽换热器3,用于产生蒸汽或热水。 The air inlet of riser heat exchanger 1 is connected to the working gas outlet of the coke oven, the hot gas outlet of riser heat exchanger 1 is connected to the main gas collector 2, and the main gas collector 2 is connected to the water/steam heat exchanger 3 for generating steam or hot water.

如图2,3,4所示,上升管换热器1由内、外套管5,4构成,内、外套管5,4之间设多股螺旋回流通道6,内、外套管5,4两端各设一个汇流集箱。上升管换热器的内、外套管的多股螺旋回流通道6中流动惰性气体。上升管换热器的内套管5内壁底部设置一焦油导出管7,用于防止从荒煤气析出的焦油回流到焦炉上升管底端与焦炉连接处,使得焦炉煤气析出口处结焦形成石墨。 As shown in Figures 2, 3, and 4, the riser heat exchanger 1 is composed of inner and outer casings 5, 4, and a multi-strand spiral return channel 6 is set between the inner and outer casings 5, 4, and the inner and outer casings 5, 4 There is a confluence header box at each end. The inert gas flows in the multi-strand spiral return channels 6 of the inner and outer casings of the riser heat exchanger. A tar outlet pipe 7 is arranged at the bottom of the inner wall of the inner casing 5 of the riser heat exchanger to prevent the tar precipitated from the raw gas from flowing back to the connection between the bottom end of the riser pipe of the coke oven and the coke oven, so that coking occurs at the exit of the coke oven gas. Graphite is formed.

本实用新型利用焦炉中荒煤气通过焦炉炉顶的上升管换热器,将荒煤气的热量传递给在上升管换热器套管内设多股螺旋回流通道中流动空气或惰性气体(氮气),受热后的空气(氮气)通过上升管换热器的上部汇流集箱后流入到主集气管。主集气管把焦炉的多个上升管换热器产生的热空气(或氮气)汇集在一起,通过鳍片管式水/汽换热器产生微过热饱和水或者过热蒸汽,用于生产工艺或生活,或者过热蒸汽用于发电。 The utility model uses the raw gas in the coke oven to pass through the heat exchanger of the rising tube on the top of the coke oven, and transfers the heat of the raw gas to the flowing air or inert gas (nitrogen ), the heated air (nitrogen) flows into the main header after passing through the upper header of the riser heat exchanger. The main gas header gathers the hot air (or nitrogen) generated by multiple riser heat exchangers of the coke oven together, and generates slightly superheated saturated water or superheated steam through the finned tube water/steam heat exchanger for the production process Or life, or superheated steam for power generation.

Claims (3)

1. one kind is used for coke oven coke oven uprising tube raw gas waste heat recycling system, formed by upcast interchanger (1), main effuser (2), water/vapour interchanger (3), it is characterized in that: described upcast interchanger (1) inlet mouth connects the Working medium gas outlet of coke oven, the hot gas outlet of upcast interchanger (1) connects main effuser (2), main effuser (2) connects water/vapour interchanger (3), for generation of steam or hot water.
2. according to claim 1ly it is characterized in that slumpability gas in the return flow line (6) of described upcast interchanger (1) for coke oven coke oven uprising tube raw gas waste heat recycling system.
3. according to claim 1 for coke oven coke oven uprising tube raw gas waste heat recycling system, it is characterized in that, described upcast interchanger (1) inwall bottom arranges a tar delivery line (7), be used for preventing from being back to coke oven coke oven uprising tube bottom and coke oven junction from the tar that raw gas is separated out, form graphite so that coke-oven gas is analysed the exit coking.
CN2012206013887U 2012-11-15 2012-11-15 Used in coke oven riser waste gas waste heat recovery system Expired - Fee Related CN202881181U (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102925165A (en) * 2012-11-15 2013-02-13 上海理工大学 Afterheat recovery system for raw coke oven gas of coke oven ascension pipe
CN111849564A (en) * 2019-04-25 2020-10-30 北京凯德恒源科技发展有限公司 Deep recovery method of coke oven crude gas heat energy

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102925165A (en) * 2012-11-15 2013-02-13 上海理工大学 Afterheat recovery system for raw coke oven gas of coke oven ascension pipe
CN111849564A (en) * 2019-04-25 2020-10-30 北京凯德恒源科技发展有限公司 Deep recovery method of coke oven crude gas heat energy

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Granted publication date: 20130417

Termination date: 20131115