CN202808537U - Town sewage deep treatment system - Google Patents
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- 239000010865 sewage Substances 0.000 title claims abstract description 140
- 238000001179 sorption measurement Methods 0.000 claims abstract description 34
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims abstract description 33
- 239000010802 sludge Substances 0.000 claims abstract description 33
- 238000004659 sterilization and disinfection Methods 0.000 claims abstract description 24
- 239000003463 adsorbent Substances 0.000 claims abstract description 14
- 239000012528 membrane Substances 0.000 claims abstract description 11
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 24
- 239000002131 composite material Substances 0.000 claims description 13
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 10
- 238000005273 aeration Methods 0.000 claims description 8
- 239000010954 inorganic particle Substances 0.000 claims description 8
- 239000007787 solid Substances 0.000 claims description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 5
- 239000003957 anion exchange resin Substances 0.000 claims description 5
- 230000005484 gravity Effects 0.000 claims description 5
- 239000007864 aqueous solution Substances 0.000 claims description 4
- 239000003245 coal Substances 0.000 claims description 4
- 239000005909 Kieselgur Substances 0.000 claims description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 2
- 229910052757 nitrogen Inorganic materials 0.000 claims 1
- 230000001376 precipitating effect Effects 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 10
- 206010021143 Hypoxia Diseases 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 238000007599 discharging Methods 0.000 abstract 1
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 abstract 1
- 238000012554 master batch record Methods 0.000 description 29
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 29
- 238000000034 method Methods 0.000 description 19
- 230000014759 maintenance of location Effects 0.000 description 11
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 7
- 238000006703 hydration reaction Methods 0.000 description 7
- 229910052760 oxygen Inorganic materials 0.000 description 7
- 239000001301 oxygen Substances 0.000 description 7
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 5
- 239000003344 environmental pollutant Substances 0.000 description 5
- 229910052698 phosphorus Inorganic materials 0.000 description 5
- 239000011574 phosphorus Substances 0.000 description 5
- 231100000719 pollutant Toxicity 0.000 description 5
- 238000010992 reflux Methods 0.000 description 5
- 230000008929 regeneration Effects 0.000 description 5
- 238000011069 regeneration method Methods 0.000 description 5
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- 239000000969 carrier Substances 0.000 description 3
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- 230000001954 sterilising effect Effects 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 230000018044 dehydration Effects 0.000 description 2
- 238000006297 dehydration reaction Methods 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
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- 238000004062 sedimentation Methods 0.000 description 2
- 238000012163 sequencing technique Methods 0.000 description 2
- 239000003643 water by type Substances 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 1
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000006065 biodegradation reaction Methods 0.000 description 1
- 230000031018 biological processes and functions Effects 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
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- 238000012851 eutrophication Methods 0.000 description 1
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- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
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- 239000004576 sand Substances 0.000 description 1
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- 238000004065 wastewater treatment Methods 0.000 description 1
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/10—Biological treatment of water, waste water, or sewage
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- Activated Sludge Processes (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Water Treatment By Sorption (AREA)
Abstract
Description
技术领域 technical field
本实用新型涉及一种城镇污水的处理系统,尤其涉及一种城镇污水的深度处理系统。The utility model relates to a treatment system for urban sewage, in particular to an advanced treatment system for urban sewage.
背景技术 Background technique
随着我国人口的不断增长和经济的飞速发展,用水量及排水量正在逐年增加,而有限的水资源又不断的被污染,水环境状况正在不断的恶化。同时,我国大量污水处理厂是在“九五”、“十五”期间建成的,排放标准相对较低,已经不能满足总量控制的要求。国家环境保护总局环发[2005]110号“关于严格执行《城镇污水处理厂污染物排放标准》的通知”中第一次提出,“为防止水域发生富营养化,城镇生活污水处理厂出水排入国家和省确定的重点流域及湖泊、水库等封闭式、半封闭水域时,应执行《标准》中一级标准的A标准”。2006年第21号公告提出再次重申了这个问题,这实际上在法规层面上将GB18918-2002中一级标准A标准的适用范围直接扩大到绝大多数城镇污水处理厂,城镇污水处理厂一级A标准的污水处理系统的改造将在许多流域和省市大量实施。此外我国虽然水资源总量较大,居世界第六,但由于人口众多,人均水资源占有量仅有世界的四分之一,同时我国水资源还存在着分布不均匀,南方多北方少的现象,所以我国一个水资源非常匮乏的国家。而污水循环再利用可以节约大量的新鲜水,补充水资源的不足,并且城镇污水具有就地可取、稳定可靠、保证率高等优点,对缓解我国水资源的不足有重要的意义。因此,开发出一种适用于城镇污水深度处理及再生的工艺是迫在眉睫的。With the continuous growth of my country's population and rapid economic development, water consumption and drainage are increasing year by year, while limited water resources are constantly being polluted, and the water environment is constantly deteriorating. At the same time, a large number of sewage treatment plants in our country were built during the "Ninth Five-Year Plan" and "Tenth Five-Year Plan", and the discharge standards are relatively low, which can no longer meet the requirements of total volume control. State Environmental Protection Administration Huanfa [2005] No. 110 "Notice on Strictly Implementing Pollutant Discharge Standards for Urban Sewage Treatment Plants" stated for the first time that "in order to prevent eutrophication of waters, the effluent of urban domestic sewage treatment plants When entering the key river basins determined by the country and the province, lakes, reservoirs and other closed and semi-closed waters, the standard A of the first-level standard in the "Standard" should be implemented. Announcement No. 21 in 2006 reiterated this issue again, which actually directly expanded the scope of application of the first-level standard A in GB18918-2002 to the vast majority of urban sewage treatment plants at the regulatory level. The renovation of standard A sewage treatment systems will be implemented in large numbers in many river basins and provinces. In addition, although my country's total water resources are relatively large, ranking sixth in the world, due to its large population, the per capita water resources are only a quarter of the world's. At the same time, my country's water resources are still unevenly distributed, with more in the south and less in the north. Phenomenon, so my country is a country with very scarce water resources. The recycling and reuse of sewage can save a lot of fresh water and supplement the shortage of water resources, and urban sewage has the advantages of local availability, stability and reliability, and high guarantee rate, which is of great significance to alleviate the shortage of water resources in our country. Therefore, it is imminent to develop a process suitable for advanced treatment and regeneration of urban sewage.
目前我国城市污水处理广泛使用的是二级生物处理工艺包括:传统活性污泥法,延时曝气活性污泥法,SBR(Sequencing Batch Reactor Activated SludgeProcess)序批式活性污泥法,AB,UNITANK和氧化沟工艺,A/O和A2/O等,污水经处理后出水一般能达到GB18918-2002一级B标准。为了进一步提高处理效果,使其出水达到一级A标准以及回用标准,往往在后续耦合混凝沉淀、过滤、活性炭吸附等三级处理工艺进行深度处理。但这种城镇污水深度处理工艺,具有流程长,投资高,运行成本高、稳定性差等缺点。At present, secondary biological treatment processes are widely used in China's urban sewage treatment, including: traditional activated sludge process, delayed aeration activated sludge process, SBR (Sequencing Batch Reactor Activated Sludge Process) sequencing batch activated sludge process, AB, UNITANK And oxidation ditch process, A/O and A 2 /O, etc. After the sewage is treated, the effluent can generally meet the GB18918-2002 Class B standard. In order to further improve the treatment effect and make the effluent meet the first-class A standard and the reuse standard, advanced treatment is often carried out in the subsequent three-stage treatment process coupled with coagulation sedimentation, filtration, and activated carbon adsorption. However, this urban sewage advanced treatment process has the disadvantages of long process, high investment, high operating cost and poor stability.
MBR又称膜生物反应器,是一种由膜处理单元和生物处理单元相结合的新型水处理技术,它将生物降解、沉淀、过滤集为一体,减少了设备的需求,目前正在受到逐渐的重视。MBR具有出水水质稳定、处理能力高、工艺流程短、占地面积小、运行管理方便等特点,其对COD、NH3-N以及SS悬浮物的去除效果明显好于传统的二级生物工艺。但,MBR一般具有很长的污泥龄,这样使得磷酸盐在系统内长期富集,导致系统对磷的去除效果较差。从大多数MBR的运行结果来看,出水磷的浓度并不理想,很难降至1mg/L以下,从而严重的制约了该工艺在污水深度处理以及回用领域的应用。MBR, also known as membrane bioreactor, is a new type of water treatment technology that combines membrane treatment unit and biological treatment unit. It integrates biodegradation, sedimentation and filtration, reduces the demand for equipment, and is currently being gradually accepted. Pay attention to. MBR has the characteristics of stable effluent quality, high treatment capacity, short process flow, small footprint, and convenient operation and management. Its removal effect on COD, NH 3 -N and SS suspended matter is significantly better than traditional secondary biological processes. However, MBR generally has a very long sludge age, which makes phosphate enriched in the system for a long time, resulting in poor phosphorus removal effect of the system. Judging from the operation results of most MBRs, the concentration of phosphorus in the effluent is not ideal, and it is difficult to reduce it to below 1mg/L, which seriously restricts the application of this process in the field of advanced sewage treatment and reuse.
吸附法被认为是处理水体中磷污染最为有效的方法之一。近二十年的研究结果表明,水合氧化铁具有较高的比表面积和表面羟基密度,对磷具有高度的选择吸附性,并且可以通过调节pH实现再生和反复使用。该铁氧化物颗粒尺寸极细,若直接运用在吸附滤池中,会产生较高的压力损失,并致使吸附系统无法稳定运行。目前,为了解决这一工程难题,多将水合氧化铁固载在多孔大颗粒载体内制备成复合吸附剂。Adsorption is considered to be one of the most effective methods for treating phosphorus pollution in water bodies. Research results in the past two decades have shown that hydrated iron oxide has a high specific surface area and surface hydroxyl density, has a high degree of selective adsorption of phosphorus, and can be regenerated and reused by adjusting the pH. The particle size of the iron oxide is extremely fine. If it is directly used in the adsorption filter, it will cause a high pressure loss and make the adsorption system unable to operate stably. At present, in order to solve this engineering problem, hydrated iron oxide is often immobilized in porous large particle carriers to prepare composite adsorbents.
综合上述可知,目前城镇污水的处理存在以下几个问题:Based on the above, we can see that the current treatment of urban sewage has the following problems:
1:城镇污水处理急需达到国家一级A标准与现有的城镇污水处理的效果不佳存在急待解决的矛盾;1: There is an urgent contradiction between the urgent need to meet the national first-class A standard for urban sewage treatment and the poor effect of existing urban sewage treatment;
2:现有的城镇污水处理系统和方法存在处理和回用的工艺流程长、投资高、运行成本高且稳定性差。2: The existing urban sewage treatment systems and methods have long processing and reuse processes, high investment, high operating costs and poor stability.
实用新型内容 Utility model content
为克服上述问题,本实用新型提供一种流程短、成本低、运行费用低且稳定性高的城镇污水处理系统。In order to overcome the above problems, the utility model provides an urban sewage treatment system with short flow, low cost, low operating cost and high stability.
为达上述目的,本实用新型城镇污水深度处理系统包括依次相连通的用以去除悬浮物的栅格污水处理装置、沉淀无机颗粒物的沉砂池、进行反硝化脱氮处理的缺氧池、MBR好氧池、吸附滤池以及消毒池;In order to achieve the above purpose, the urban sewage advanced treatment system of the present utility model includes a grid sewage treatment device for removing suspended solids, a grit chamber for depositing inorganic particles, an anoxic pool for denitrification and denitrification treatment, and an MBR that are connected in sequence. Aerobic pools, adsorption filters and disinfection pools;
其中,in,
所述MBR好氧池底部设有污泥出口;The bottom of the MBR aerobic tank is provided with a sludge outlet;
所述吸附滤池内填充有纳米水合氧化铁的复合吸附剂,用以进一步对污水进行脱磷处理。The adsorption filter tank is filled with a composite adsorbent of nanometer hydrated iron oxide for further dephosphorization of sewage.
进一步地,所述栅格污水处理装置包括粗栅格污水处理机和细栅格污水处理机;所述粗栅格污水处理机栅条间隙为20-30mm;所述细栅格污水处理机栅条间隙为5-10mm。Further, the grid sewage treatment device includes a coarse grid sewage treatment machine and a fine grid sewage treatment machine; the grid gap of the coarse grid sewage treatment machine is 20-30mm; the fine grid sewage treatment machine grid The strip gap is 5-10mm.
进一步地,所述沉砂池为平流式沉砂池、旋流式沉砂池或曝气式沉砂池。Further, the grit chamber is an advection type grit chamber, a swirl type grit chamber or an aeration type grit chamber.
进一步地,所述MBR好氧池包括平板式MBR膜组件。Further, the MBR aerobic pool includes a flat MBR membrane module.
进一步地,所述MBR好氧池的污泥出口还通过管道与所述缺氧池相连通;所述管道用以将部分污泥回流至所述缺氧池中,且回流比为30%-60%。Further, the sludge outlet of the MBR aerobic tank is also communicated with the anoxic tank through a pipeline; the pipeline is used to return part of the sludge to the anoxic tank, and the return ratio is 30%- 60%.
进一步地,所述负载纳米水合氧化铁包括载体,所述载体为大孔阴离子交换树脂、活性碳、硅藻土或粉煤粉。Further, the loaded nanometer hydrated iron oxide includes a carrier, and the carrier is a macroporous anion exchange resin, activated carbon, diatomaceous earth or pulverized coal.
进一步地,所述吸附滤池还包括一用以输入比重为2%-5%的氢氧化钠水溶液的输入管。Further, the adsorption filter tank also includes an input pipe for inputting a sodium hydroxide aqueous solution with a specific gravity of 2%-5%.
进一步地,所述消毒池为紫外线消毒池。Further, the disinfection pool is an ultraviolet disinfection pool.
进一步地,所述污泥出口后端连接有污泥脱水设备。Further, sludge dewatering equipment is connected to the rear end of the sludge outlet.
本实用新型城镇污水深度处理系统的有益效果:The beneficial effects of the utility model urban sewage advanced treatment system:
1、本实用新型城镇污水深度处理系统,采用MBR膜技术与纳米水合氧化铁的复合吸附剂的吸附相结合,利用水合氧化铁复合吸附剂进行去磷的深度处理,从而弥补了MBR去磷效果差的不足。1. The urban sewage advanced treatment system of this utility model adopts the combination of MBR membrane technology and the adsorption of nanometer hydrated iron oxide composite adsorbent, and uses the hydrated iron oxide composite adsorbent to carry out the advanced treatment of dephosphorization, thereby making up for the dephosphorization effect of MBR Bad enough.
2、本实用新型城镇污水深度处理系统,纳米水合氧化铁复合吸附剂吸附饱和后,利用氢氧化钠水溶液进行再生,且再生性能良好、机械强度高、可重复使用。2. The urban sewage advanced treatment system of this utility model, after the nano-hydration iron oxide composite adsorbent is saturated, is regenerated by sodium hydroxide aqueous solution, and has good regeneration performance, high mechanical strength, and can be reused.
3、本实用新型城镇污水深度处理系统,污水处理后的效果佳,处理后出水中,COD<50mg/L,BOD<10mg/L,SS<10mg/L,TP<0.2mg/L,NH3-N<3mg/L,出水的水质优于GB18918-2002一级标准中的A标准。3. The urban sewage advanced treatment system of this utility model has good effect after sewage treatment. After treatment, COD<50mg/L, BOD<10mg/L, SS<10mg/L, TP<0.2mg/L, NH 3 -N<3mg/L, the water quality of the effluent is better than the A standard in the first grade standard of GB18918-2002.
4、本实用新型城镇污水深度处理系统,具有流程短、投资少、占地面积小以及运行效果稳定等特点。4. The urban sewage advanced treatment system of the utility model has the characteristics of short process, low investment, small floor area and stable operation effect.
附图说明 Description of drawings
图1是本实用新型实施例一中所述的城镇污水处理系统的结构示意图。Fig. 1 is a schematic structural view of the urban sewage treatment system described in the first embodiment of the utility model.
具体实施方式 Detailed ways
下面结合说明书附图对本实用新型做进一步的描述。Below in conjunction with accompanying drawing, the utility model is described further.
实施例一:Embodiment one:
如图1所示,本实例城镇污水深度处理系统包括依次相连通的栅格污水处理装置、平流式沉砂池、缺氧池、MBR好氧池、内部填充有以大孔阴离子交换树脂为载体的纳米水合氧化铁复合吸附剂的吸附滤池以及消毒池,污水处理规模为5.0万m3/d,进水为城镇生活污水。As shown in Figure 1, the urban sewage advanced treatment system in this example includes grid sewage treatment devices connected in sequence, advection grit chambers, anoxic tanks, and MBR aerobic tanks, which are filled with macroporous anion exchange resins as carriers. The adsorption filter and disinfection pool of the nano-hydration iron oxide composite adsorbent, the sewage treatment scale is 50,000 m3/d, and the influent is urban domestic sewage.
所述栅格污水处理装置,包括粗栅格污水处理机和细栅格污水处理机;所述粗栅格污水处理机栅条间隙为30mm;所述细栅格污水处理机的栅条间隙为8mm;栅格污水处理装置用以去除污水中的悬浮物;The grid sewage treatment device includes a coarse grid sewage treatment machine and a fine grid sewage treatment machine; the grid gap of the coarse grid sewage treatment machine is 30mm; the grid gap of the fine grid sewage treatment machine is 8mm; grid sewage treatment device is used to remove suspended solids in sewage;
所述平流式沉砂池用以沉淀污水中的无机物颗粒;The advection grit chamber is used for settling inorganic particles in sewage;
所述缺氧池用以对污水进行反硝化脱氮处理;The anoxic pool is used for denitrification and denitrification treatment of sewage;
所述MBR好氧池用以对污水进行深度净化处理,底部设有污泥出口;The MBR aerobic pool is used for deep purification treatment of sewage, and a sludge outlet is provided at the bottom;
特别是,所述污泥出口后端连接有污泥脱水设备;In particular, sludge dehydration equipment is connected to the rear end of the sludge outlet;
所述吸附滤池用以进一步对污水进行脱磷处理;The adsorption filter is used to further dephosphorize the sewage;
所述消毒池用以对污水进行消毒杀菌。The disinfection tank is used for disinfection and sterilization of sewage.
进一步地,所述MBR好氧池的污泥出口还通过管道与所述缺氧池相连通,所述管道用以将部分污泥回流至所述缺氧池中,通常回流比为30%-60%。Further, the sludge outlet of the MBR aerobic tank is also communicated with the anoxic tank through a pipeline, and the pipeline is used to return part of the sludge to the anoxic tank, usually with a return ratio of 30%- 60%.
本实例所述的城镇污水深度处理系统进行污水处理时包括以下步骤:The urban sewage advanced treatment system described in this example includes the following steps when performing sewage treatment:
1)待处理污水先后经过栅条间隙为30mm的粗格栅污水处理机和栅条间隙为8mm的细格栅污水处理机,以拦截水中较大的悬浮物;1) The sewage to be treated passes through the coarse grid sewage treatment machine with a grid gap of 30mm and the fine grid sewage treatment machine with a grid gap of 8mm to intercept larger suspended solids in the water;
2)然后该水进入平流式沉砂池,以去除水中的无机颗粒,水力停留时间为60s;2) Then the water enters the advection grit chamber to remove inorganic particles in the water, and the hydraulic retention time is 60s;
3)平流式沉砂池出水进入缺氧池,在搅拌的条件下进行反硝化脱氮处理,池内水力停留时间为2.5h,混合液悬浮固体浓度(MLSS)为3-4g/L,溶解氧浓度1.0mg/L;3) The effluent of the flat-flow grit chamber enters the anoxic tank, and the denitrification and denitrification treatment is carried out under the condition of stirring. Concentration 1.0mg/L;
4)厌氧池出水进入内置MBR平板膜的好氧池,池内水力停留时间为4h,MLSS为10-12g/L,通过鼓风曝气,维持的溶解氧在3.0mg/L;4) The effluent from the anaerobic pool enters the aerobic pool with a built-in MBR flat membrane. The hydraulic retention time in the pool is 4 hours, the MLSS is 10-12g/L, and the dissolved oxygen maintained at 3.0mg/L is maintained through blast aeration;
在步骤4)中还包括将产生的至少部分污泥经板框压滤机脱水后外运,处理后的污泥营养丰富可填埋或用作农肥;In step 4), at least part of the generated sludge is dehydrated by a plate-and-frame filter press and transported outside, and the treated sludge is rich in nutrients and can be landfilled or used as agricultural fertilizer;
5)MBR好氧池出水进入吸附滤池,池中装填有以大孔阴离子交换树脂为载体的纳米水合氧化铁复合吸附剂,吸附流速为每小时40床体积,吸附饱和后的材料,采用比重为2%的NaOH溶液,在温度20摄氏度下,以每小时1床体积进行再生。5) The effluent from the MBR aerobic tank enters the adsorption filter tank, which is filled with nano-hydration iron oxide composite adsorbent with macroporous anion exchange resin as the carrier, and the adsorption flow rate is 40 bed volume per hour. It is 2% NaOH solution, at a temperature of 20 degrees Celsius, the regeneration is carried out at a bed volume per hour.
6)吸附滤池出水进行杀菌消毒处理。6) The effluent of the adsorption filter is sterilized and disinfected.
此外,MBR好氧池还通过管道以回流比30%-60%的比例将污泥部分回流至缺氧池中。而本实施例中所述回流比为50%。In addition, the MBR aerobic tank also returns part of the sludge to the anoxic tank through the pipeline at a ratio of 30%-60%. However, the reflux ratio in this embodiment is 50%.
本实施例城镇污水深度处理系统运行后,得到了很好的运行效果,出水浊度<5NTU、COD<50mg/L,BOD<10mg/L,SS悬浮物<10mg/L,TP磷含量<0.2mg/L,NH3-N氨氮含量<5mg/L,满足《城市杂用水质标准》GB/T 18920-2002以及《城镇污水处理厂污染物排放标准》GB18918-2002中的一级A标准。此外,本实施例所述的城镇污水深度处理系统还具有处理流程短、投资少,运行成本低、占地面积小,运行稳定等优点。After the operation of the urban sewage advanced treatment system in this embodiment, a good operation effect has been obtained, the effluent turbidity <5NTU, COD <50mg/L, BOD <10mg/L, SS suspended solids <10mg/L, TP phosphorus content <0.2 mg/L, NH3-N ammonia nitrogen content <5mg/L, meeting the Grade A standard in the "Urban Miscellaneous Water Quality Standard" GB/T 18920-2002 and "Urban Sewage Treatment Plant Pollutant Discharge Standard" GB18918-2002. In addition, the urban sewage advanced treatment system described in this embodiment also has the advantages of short treatment process, low investment, low operating cost, small footprint, and stable operation.
实施例二:Embodiment two:
本实例城镇污水深度处理系统,包括依次相连通的栅格污水处理装置、旋流式沉砂池、缺氧池、MBR好氧池、吸附滤池以及消毒池;其中所述栅格污水处理装置包括两级,第一级为粗格栅污水处理机且栅条间隙为25mm,第二级为细栅格污水处理机且栅条间隙为5mm。在具体的应用过程中,所述栅格污水处理装置可以为一级也可以为多级。当所述栅格污水处理装置仅有一级时,栅条间隔优选为6-12mm,也能达到污水深度处理一级A标准。但是存在一个问题,及一级栅极污水处理机拦截需要频繁的清理,否则将造成出水难等问题。当所述栅格污水处理装置采用3级或4级或更多级的时候,增加了系统的硬件投资成本,且提高了结构的复杂度。故采用粗栅格污水处理机以及细栅格污水处理机的两级结构为优选结构。所述MBR好氧池内设置有平板式MBR膜组件。所述消毒池为内置有紫外线消毒装置的紫外线消毒池。The urban sewage advanced treatment system in this example includes a grid sewage treatment device, a swirl type grit chamber, an anoxic tank, an MBR aerobic tank, an adsorption filter and a disinfection tank connected in sequence; the grid sewage treatment device It includes two stages, the first stage is a coarse grid sewage treatment machine with a grid gap of 25mm, and the second level is a fine grid sewage treatment machine with a grid gap of 5mm. In a specific application process, the grid sewage treatment device can be one-stage or multi-stage. When the grid sewage treatment device has only one stage, the interval between the grid bars is preferably 6-12 mm, which can also meet the first-level A standard of advanced sewage treatment. But there is a problem, and the interception of the first-level gate sewage treatment machine needs frequent cleaning, otherwise it will cause problems such as difficulty in water discharge. When the grid sewage treatment device adopts 3 or 4 or more stages, the hardware investment cost of the system is increased, and the complexity of the structure is increased. Therefore, the two-stage structure of the coarse grid sewage treatment machine and the fine grid sewage treatment machine is the preferred structure. The MBR aerobic pool is provided with a flat MBR membrane module. The disinfection pool is an ultraviolet disinfection pool with a built-in ultraviolet disinfection device.
本实施例所述的城镇污水深度处理系统的污水处理规模为2.0万m3/d,进水为城镇生活污水。The sewage treatment scale of the urban sewage advanced treatment system described in this embodiment is 20,000 m3/d, and the influent is urban domestic sewage.
本实例所述城镇污水深度处理系统在具体的城镇污水深度处理中包括以下步骤:The urban sewage advanced treatment system described in this example includes the following steps in the specific urban sewage advanced treatment:
1)待处理污水先后经过栅条间隙为25mm的粗格栅污水处理机和栅条间隙为5mm的细格栅污水处理机,以拦截水中较大的悬浮物;1) The sewage to be treated passes through the coarse grid sewage treatment machine with a grid gap of 25mm and the fine grid sewage treatment machine with a grid gap of 5mm to intercept larger suspended solids in the water;
2)然后该水进入旋流式沉砂池,以去除水中的无机颗粒,水力停留时间为40s;2) Then the water enters the cyclone grit chamber to remove inorganic particles in the water, and the hydraulic retention time is 40s;
3)旋流式沉砂池的出水与好氧池的回流液一同进入缺氧池,在搅拌的条件下进行反硝化脱氮处理,池内水力停留时间为2h,MLSS为2-3g/L,溶解氧浓度1.5mg/L;3) The effluent of the swirling grit chamber and the reflux liquid of the aerobic tank enter the anoxic tank together, and carry out denitrification and denitrification treatment under the condition of stirring. The hydraulic retention time in the tank is 2h, and the MLSS is 2-3g/L. Dissolved oxygen concentration 1.5mg/L;
4)厌氧池出水进入内置MBR平板膜的好氧池,池内水力停留时间为6h,MLSS为8-10g/L,通过鼓风曝气,维持的溶解氧在3.0mg/L;4) The effluent from the anaerobic pool enters the aerobic pool with a built-in MBR flat membrane. The hydraulic retention time in the pool is 6 hours, the MLSS is 8-10g/L, and the dissolved oxygen is maintained at 3.0mg/L through blast aeration;
在步骤4)中还包括将产生的部分污泥通过好氧池底部的污泥管回流至厌氧池,回流比为40%,剩余污泥经板框压滤机脱水后外运,可填埋或用作农肥;In step 4), it also includes returning part of the generated sludge to the anaerobic tank through the sludge pipe at the bottom of the aerobic tank. The reflux ratio is 40%. buried or used as fertilizer;
5)MBR好氧池的出水进入吸附滤池,池中装填有以活性炭为载体的纳米水合氧化铁复合吸附剂,吸附流速为每小时50床体积,吸附饱和后的材料,采用比重为2%的NaOH溶液,在温度25摄氏度下,以每小时2床体积进行再生;5) The effluent of the MBR aerobic tank enters the adsorption filter tank, which is filled with nano-hydration iron oxide composite adsorbent with activated carbon as the carrier, the adsorption flow rate is 50 bed volume per hour, and the material after adsorption saturation is used with a specific gravity of 2%. NaOH solution, at a temperature of 25 degrees Celsius, regenerates at 2 bed volumes per hour;
6)吸附滤池出水进入紫外消毒池,进行杀菌消毒。6) The effluent from the adsorption filter enters the ultraviolet disinfection pool for sterilization.
本实施例所述的城镇污水深度处理系统运行后,得到了很好的运行效果,出水浊度<3NTU、COD<50mg/L,BOD<10mg/L,SS<10mg/L,TP<0.1mg/L,NH3-N<3mg/L,满足《城市杂用水质标准》GB/T 18920-2002以及《城镇污水处理厂污染物排放标准》GB18918-2002中的一级A标准。After the operation of the urban sewage advanced treatment system described in this embodiment, good operation results have been obtained, effluent turbidity <3NTU, COD<50mg/L, BOD<10mg/L, SS<10mg/L, TP<0.1mg /L, NH3-N<3mg/L, meeting the Class A standard in the "Urban Miscellaneous Water Quality Standard" GB/T 18920-2002 and "Pollutant Discharge Standard for Urban Sewage Treatment Plant" GB18918-2002.
实施例三:Embodiment three:
本实例城镇污水深度处理系统规模为1.0万m3/d,主要包括栅格污水处理装置、曝气式沉砂池、缺氧池、MBR好氧池、吸附滤池以及消毒池。所述栅格污水处理装置包括粗栅格污水处理机以及细栅格污水处理机。The urban sewage advanced treatment system in this example has a scale of 10,000 m3/d, mainly including grid sewage treatment devices, aerated grit chambers, anoxic ponds, MBR aerobic ponds, adsorption filters and disinfection ponds. The grid sewage treatment device includes a coarse grid sewage treatment machine and a fine grid sewage treatment machine.
本实例城镇污水深度处理系统污水处理包括以下步骤:The sewage treatment of the urban sewage advanced treatment system in this example includes the following steps:
1)待处理污水先后经过栅条间隙为20mm的粗格栅污水处理机和栅条间隙为3mm的细格栅污水处理机,以拦截水中较大的悬浮物;1) The sewage to be treated passes through the coarse grid sewage treatment machine with a grid gap of 20mm and the fine grid sewage treatment machine with a grid gap of 3mm to intercept larger suspended solids in the water;
2)然后该水进入曝气式沉砂池,以去除水中的无机颗粒,水力停留时间为30s;2) Then the water enters the aerated grit chamber to remove inorganic particles in the water, and the hydraulic retention time is 30s;
3)曝气式沉砂池的出水与好氧池的回流液一同进入缺氧池,在搅拌的条件下进行反硝化脱氮处理,池内水力停留时间为1h,MLSS为3-4g/L,溶解氧浓度1.0mg/L;3) The effluent of the aerated grit chamber and the reflux liquid of the aerobic tank enter the anoxic tank together, and carry out denitrification and denitrification treatment under the condition of stirring. The hydraulic retention time in the tank is 1h, and the MLSS is 3-4g/L. Dissolved oxygen concentration 1.0mg/L;
4)厌氧池出水进入内置MBR平板膜的好氧池,池内水力停留时间为4h,MLSS为8-10g/L,通过鼓风曝气,维持的溶解氧在3.0mg/L;4) The effluent from the anaerobic pool enters the aerobic pool with built-in MBR flat membrane, the hydraulic retention time in the pool is 4 hours, the MLSS is 8-10g/L, and the dissolved oxygen is maintained at 3.0mg/L through blast aeration;
在步骤4)中还包括将产生的部分污泥通过MBR好氧池底部的管道回流至厌氧池,回流比为60%,剩余污泥经带式浓缩一体污泥脱水设备处理后,可外运用于填埋或用作农肥;In step 4), it also includes returning part of the generated sludge to the anaerobic tank through the pipeline at the bottom of the MBR aerobic tank. The return ratio is 60%. Used in landfill or as agricultural fertilizer;
5)MBR好氧池的出水进入吸附滤池,池中装填有硅藻土为载体的纳米水合氧化铁复合吸附剂,吸附流速为每小时50床体积,吸附饱和后的材料,采用比重为2.5%的NaOH溶液,在温度20摄氏度下,以每小时2床体积进行再生。5) The effluent of the MBR aerobic tank enters the adsorption filter tank, which is filled with nano-hydration iron oxide composite adsorbent with diatomite as the carrier, the adsorption flow rate is 50 bed volume per hour, and the material after adsorption saturation is used with a specific gravity of 2.5 % NaOH solution at a temperature of 20 degrees Celsius for regeneration at 2 bed volumes per hour.
6)吸附滤池出水进入内置紫外设备的紫外消毒池,经杀菌消毒。6) The effluent from the adsorption filter enters the ultraviolet disinfection pool with built-in ultraviolet equipment, and is sterilized.
本实施例所述的城镇污水深度处理系统处理后的污水,洁净效果良好,满足《城市杂用水质标准》GB/T 18920-2002以及《城镇污水处理厂污染物排放标准》GB18918-2002中的一级A标准。具体的洁净的参数如下:The sewage treated by the urban sewage advanced treatment system described in this embodiment has a good cleaning effect and meets the requirements in the "Urban Miscellaneous Water Quality Standard" GB/T 18920-2002 and "Urban Wastewater Treatment Plant Pollutant Discharge Standard" GB18918-2002 Grade A standard. The specific cleaning parameters are as follows:
出水浊度<5NTU、COD<50mg/L,BOD<10mg/L,SS<10mg/L,TP<0.2mg/L,NH3-N<5mg/L。Effluent turbidity<5NTU, COD<50mg/L, BOD<10mg/L, SS<10mg/L, TP<0.2mg/L, NH3-N<5mg/L.
实施例四:Embodiment four:
本实例城镇污水深度处理系统的污水处理规模为6000m3/d,进水为城镇生活污水。所述城镇污水深度处理系统包括依次相连通的由栅条间隔为25mm的粗栅格污水处理机和栅条间隔为3mm的细栅格污水处理机的组成栅格污水处理装置、旋流式沉砂池、缺氧池、MBR好氧池、内部填充有以煤炭分为载体的纳米水合样化铁复合吸附剂的吸附滤池以及消毒池;The sewage treatment scale of the urban sewage advanced treatment system in this example is 6000m3/d, and the influent is urban domestic sewage. The urban sewage advanced treatment system includes a grid sewage treatment device, a swirl type sink, and a coarse grid sewage treatment machine with a grid interval of 25 mm and a fine grid sewage treatment machine with a grid interval of 3 mm, which are connected in sequence. Sand pool, anoxic pool, MBR aerobic pool, adsorption filter filled with nano-hydration iron composite adsorbent with coal as carrier, and disinfection pool;
所述栅格污水处理装置用以去除污水中的悬浮物;The grid sewage treatment device is used to remove suspended solids in sewage;
所述旋流式沉砂池用以沉淀污水中的无机物颗粒;The cyclone grit chamber is used to settle inorganic particles in sewage;
所述缺氧池用以对污水进行硝化脱氮处理;The anoxic pool is used for nitrification and denitrification treatment of sewage;
所述MBR好氧池用以对污水进行深度净化处理,底部设有污泥出口;所述污泥出口后端连接有污泥脱水设备;The MBR aerobic pool is used for deep purification treatment of sewage, and the bottom is provided with a sludge outlet; the rear end of the sludge outlet is connected with sludge dehydration equipment;
所述吸附滤池,设有用于输入NaOH水溶液的输入管,用以进一步对污水进行脱磷处理;The adsorption filter tank is provided with an input pipe for inputting NaOH aqueous solution to further dephosphorize the sewage;
所述消毒池用以对污水进行消毒杀菌。The disinfection tank is used for disinfection and sterilization of sewage.
本实例城镇污水深度处理系统进行污水处理时包括以下步骤:In this example, the urban sewage advanced treatment system includes the following steps for sewage treatment:
1)待处理污水先后经过栅条间隙为25mm的粗格栅和栅条间隙为3mm的细格栅,以拦截水中较大的悬浮物;1) The sewage to be treated passes through the coarse grid with a grid gap of 25mm and the fine grid with a grid gap of 3mm to intercept larger suspended matter in the water;
2)然后该水进入旋流式沉砂池,以去除水中的无机颗粒,水力停留时间为60s;2) Then the water enters the cyclone grit chamber to remove inorganic particles in the water, and the hydraulic retention time is 60s;
3)旋流式沉砂池的出水与好氧池的回流液一同进入缺氧池,在搅拌的条件下进行反硝化脱氮处理,池内水力停留时间为1h,MLSS为2-3g/L,溶解氧浓度1.5mg/L;3) The effluent of the swirling grit chamber and the reflux liquid of the aerobic tank enter the anoxic tank together, and carry out denitrification and denitrification treatment under the condition of stirring. The hydraulic retention time in the tank is 1h, and the MLSS is 2-3g/L. Dissolved oxygen concentration 1.5mg/L;
4)厌氧池出水进入内置平板式MBR膜组件的好氧池,池内水力停留时间为2h,MLSS为10-12g/L,通过鼓风曝气,维持的溶解氧在3.0mg/L;4) The effluent from the anaerobic tank enters the aerobic tank with a built-in flat MBR membrane module. The hydraulic retention time in the tank is 2 hours, the MLSS is 10-12g/L, and the dissolved oxygen maintained at 3.0mg/L is maintained through blast aeration;
在步骤4)中还包括将产生的部分污泥通过好氧池底部的污泥管回流至厌氧池,回流比为30%,剩余污泥经带式浓缩一体脱水机处理后外运,可填埋或用作农肥;In step 4), it also includes returning part of the generated sludge to the anaerobic tank through the sludge pipe at the bottom of the aerobic tank. Landfill or use as agricultural fertilizer;
5)MBR好氧池的出水进入吸附滤池,吸附流速为每小时50床体积,纳米水合氧化铁复合吸附剂吸附饱和后的材料,采用比重为2.5%的NaOH溶液,在温度25摄氏度下,以每小时2床体积进行再生。5) The effluent of the MBR aerobic tank enters the adsorption filter tank, and the adsorption flow rate is 50 bed volumes per hour. The nano-hydration iron oxide composite adsorbent absorbs the saturated material, and the NaOH solution with a specific gravity of 2.5% is used. At a temperature of 25 degrees Celsius, Regeneration was performed at 2 bed volumes per hour.
6)吸附滤池出水进入内置紫外设备的紫外消毒池,经杀菌消毒。6) The effluent from the adsorption filter enters the ultraviolet disinfection pool with built-in ultraviolet equipment, and is sterilized.
本工程运行后,得到了很好的运行效果,出水浊度<5NTU、COD<40mg/L,BOD<10mg/L,SS<5mg/L,TP<0.1mg/L,NH3-N<3mg/L,满足《城市杂用水质标准》GB/T 18920-2002以及《城镇污水处理厂污染物排放标准》GB18918-2002中的一级A标准。After the operation of this project, good operation results have been obtained, effluent turbidity <5NTU, COD<40mg/L, BOD<10mg/L, SS<5mg/L, TP<0.1mg/L, NH3-N<3mg/L L, meeting the Grade A standard in the "Urban Miscellaneous Water Quality Standard" GB/T 18920-2002 and "Pollutant Discharge Standard for Urban Sewage Treatment Plant" GB18918-2002.
综合实施例一至实施例四可知:本实用新型所述的城镇污水深度处理系统中所述栅格污水处理装置可以为一级也可以为多级,优选为两级的粗栅格污水处理机以及细栅格污水处理机;所述粗栅格污水处理机的栅条间隙为20-30mm;所述细栅格污水处理机的栅条间隙为5-10mm。所述沉砂池可选用的种类至少包括三种,平流式沉砂池、旋流式沉砂池以及曝气式沉砂池。所述纳米水合氧化铁的复合吸附剂的载体可选用的种类至少包括大孔阴离子交换树脂、活性碳、硅藻土以及粉煤粉。Comprehensive embodiment 1 to embodiment 4 shows that: the grid sewage treatment device in the urban sewage advanced treatment system described in the utility model can be one-stage or multi-stage, preferably two-stage coarse grid sewage treatment machine and Fine grid sewage treatment machine; the grid gap of the coarse grid sewage treatment machine is 20-30mm; the grid gap of the fine grid sewage treatment machine is 5-10mm. There are at least three types of grit chambers that can be selected, advection type grit chambers, swirl type grit chambers and aeration type grit chambers. The types of carriers that can be selected for the composite adsorbent of nanometer hydrated iron oxide include at least macroporous anion exchange resin, activated carbon, diatomaceous earth and pulverized coal.
以上,仅为本实用新型的较佳实施例,但本实用新型的保护范围并不局限于此,任何熟悉本技术领域的技术人员在本实用新型揭露的技术范围内,可轻易想到的变化或替换,都应涵盖在本实用新型的保护范围之内。因此,本实用新型的保护范围应该以权利要求所界定的保护范围为准。The above are only preferred embodiments of the present utility model, but the scope of protection of the present utility model is not limited thereto. Any skilled person familiar with the art within the technical scope disclosed by the utility model can easily think of changes or Replacement should be covered within the protection scope of the present utility model. Therefore, the protection scope of the present utility model should be determined by the protection scope defined in the claims.
Claims (9)
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102775029A (en) * | 2012-08-23 | 2012-11-14 | 中冶华天工程技术有限公司 | Advanced municipal wastewater treatment system and method |
| CN103449687A (en) * | 2013-09-30 | 2013-12-18 | 山西科元晟地科技有限公司 | Method for processing domestic sewage through diatomite biological system |
| CN106145510A (en) * | 2015-04-14 | 2016-11-23 | 上海子征环保科技有限公司 | A kind of method using water supply plant dewatered sludge reinforced film biological reactor phosphor-removing effect |
| CN108816178A (en) * | 2018-06-07 | 2018-11-16 | 暨南大学 | A kind of porous ceramic grain and preparation method loading nano-iron oxide |
-
2012
- 2012-08-23 CN CN201220421518.9U patent/CN202808537U/en not_active Expired - Lifetime
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102775029A (en) * | 2012-08-23 | 2012-11-14 | 中冶华天工程技术有限公司 | Advanced municipal wastewater treatment system and method |
| CN103449687A (en) * | 2013-09-30 | 2013-12-18 | 山西科元晟地科技有限公司 | Method for processing domestic sewage through diatomite biological system |
| CN106145510A (en) * | 2015-04-14 | 2016-11-23 | 上海子征环保科技有限公司 | A kind of method using water supply plant dewatered sludge reinforced film biological reactor phosphor-removing effect |
| CN108816178A (en) * | 2018-06-07 | 2018-11-16 | 暨南大学 | A kind of porous ceramic grain and preparation method loading nano-iron oxide |
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