Micro-etched waste liquid regeneration recovery system
Technical field
The utility model relates to recovery system, especially relates to micro-etched waste liquid regeneration recovery system, the micro-etched waste liquid that discharges for the treatment of (PCB) printed circuit board factory.
Background technology
The typical process of printed circuit board (pcb) processing adopts " graphic plating method ".Namely then elder generation's (being the visuals of circuit) preplating one deck slicker solder resist layer on the outer Copper Foil part that needs to keep of plate erodes remaining Copper Foil with chemical mode, is called etching.The PCB etching is divided into alkalescence and two kinds of acidity, and one is hydrochloric acid hydrogen peroxide system (acidity); Two is ammonium chloride ammoniacal liquor system (alkalescence).Alkaline etching liquid mainly is applicable to graphic plating metal resist layer, such as plated with gold, nickel, tinsel, the etching of the printed board of tin-nickel alloy and tin, its characteristics are that etch-rate is fast, and lateral erosion is little, molten copper ability is high, etch-rate is controlled easily, and in the printed circuit board production process, etching is a very important technological process, needing to use a large amount of etching solutions, therefore also is an operation that produces the severe contamination source.Traditional governance approach is: specify the company that qualification is arranged to reclaim by environmental administration, adopt simple way, wherein contained copper is processed into copper sulfate, then process slightly discharging.This significant wastage that has not only caused resource is (in every kilolitre alkaline etching liquid except cupric, also have the ammonium chloride more than 240 kilograms, about 30 kilograms the chemical substances such as liquefied ammonia), and waste liquid does not obtain real radical cure, has therefore formed the transfer of source of pollution.
Micro-etching solution content of copper ion after etching increases, and peroxide concentrations reduces, and loses etch capabilities.Low (the micro-etched waste liquid copper content is 15-35g/L to this type of micro-etched waste liquid with respect to the etching waste liquor copper content, the etching waste liquor copper content is 150g/L), it is little to recycle value, there is not special company to reclaim, the small-sized PCB enterprise that has is with its direct discharging, severe contamination environment, larger PCB enterprise includes it in waste water system, use conventional methods such as neutralisation, substitution method, directly discharging after disposing, but these class methods can consume a large amount of industrial chemicals such as soda acid, often cause secondary pollution, and are incomplete to the recovery of copper utilization simultaneously, wasted the metallic copper that has in a large number high economic worth, and PCB enterprise has a strong impact on production schedule when changing cylinder, waste of manpower and material resources, and this does not all meet the circular economy industrial policy of resource-conserving.
The utility model content
The purpose of this utility model is to overcome the shortcoming and defect of above-mentioned prior art, micro-etched waste liquid regeneration recovery system is provided, and the principle of this recovery system is easy, has brought direct economic benefit, high to recovery of copper efficient, recycle micro-etching solution, saved cost, reduced production line and changed the cylinder time, improved production efficiency, allow enterprise accomplish that fundamentally cleaner production is pollution-free, reduce factory's environmental protection pressure, promoted the social image of enterprise.
The purpose of this utility model is achieved through the following technical solutions: micro-etched waste liquid regeneration recovery system, the waste liquid hold-up vessel that comprises etching bath and be communicated with etching bath, described waste liquid hold-up vessel is connected with the center two-stage system, the center two-stage system is connected with the regenerated liquid regulating tank, described regenerated liquid regulating tank is connected with the regenerated liquid hold-up vessel, regenerated liquid hold-up vessel and etching bath are communicated with, between described etching bath and the waste liquid hold-up vessel, between waste liquid hold-up vessel and the center two-stage system, between center two-stage system and the regenerated liquid regulating tank, between regenerated liquid regulating tank and the regenerated liquid hold-up vessel, be provided with water pump between regenerated liquid hold-up vessel and the etching bath, described water pump is connected with the PLC Controlling System simultaneously, and etching bath, center two-stage system and regenerated liquid regulating tank are connected with the PLC Controlling System simultaneously.
Further, described water pump comprises water pump one, water pump two, water pump three, water pump four and water pump five, and water pump one, water pump two, water pump three, water pump four and water pump five are connected with the PLC Controlling System simultaneously, water pump one is arranged between etching bath and the waste liquid hold-up vessel, and is communicated with etching bath and waste liquid hold-up vessel respectively; Water pump two is arranged between waste liquid hold-up vessel and the center two-stage system, and is communicated with waste liquid hold-up vessel and center two-stage system respectively; Water pump three is arranged between center two-stage system and the regenerated liquid regulating tank, and is communicated with center two-stage system and regenerated liquid regulating tank respectively; Water pump four is arranged between regenerated liquid regulating tank and the regenerated liquid hold-up vessel, and is communicated with regenerated liquid regulating tank and regenerated liquid hold-up vessel respectively; Water pump five is arranged between regenerated liquid hold-up vessel and the etching bath, and is communicated with regenerated liquid hold-up vessel and etching bath respectively.
Further, described water pump one is connected the top with the bottom of etching bath respectively and is connected with the waste liquid hold-up vessel.
Further, described water pump two is connected the top with the bottom of waste liquid hold-up vessel respectively and is connected with the center two-stage system.
Further, described water pump three is connected the top with the bottom of center two-stage system respectively and is connected with the regenerated liquid regulating tank.
Further, described water pump four is connected the top with the bottom of regenerated liquid regulating tank respectively and is connected with the regenerated liquid hold-up vessel.
Further, described water pump five is connected the bottom with the bottom of regenerated liquid hold-up vessel respectively and is connected with etching bath.
In sum, the beneficial effects of the utility model are: the principle of this recovery system is easy, brought direct economic benefit, high to recovery of copper efficient, recycle micro-etching solution, saved cost, reduced production line and changed the cylinder time, improved production efficiency, allowed enterprise accomplish that fundamentally cleaner production is pollution-free, reduce factory's environmental protection pressure, promoted the social image of enterprise.
Description of drawings
Fig. 1 is synoptic diagram of the present utility model.
Mark and corresponding component title in the accompanying drawing: 1-etching bath; 2-water pump one; 3-waste liquid hold-up vessel; 4-water pump two; 5-center two-stage system; 6-water pump three; 7-regenerated liquid regulating tank; 8-PLC Controlling System; 9-water pump four; 10-regenerated liquid hold-up vessel; 11-water pump five; 12-pipeline.
Embodiment
Below in conjunction with embodiment and accompanying drawing, the utility model is described in further detail, but embodiment of the present utility model is not limited only to this.
Embodiment:
As shown in Figure 1, micro-etched waste liquid regeneration recovery system, comprise etching bath 1 and the waste liquid hold-up vessel 3 that is communicated with etching bath 1, described waste liquid hold-up vessel 3 is connected with center two-stage system 5, center two-stage system 5 is connected with regenerated liquid regulating tank 7, described regenerated liquid regulating tank 7 is connected with regenerated liquid hold-up vessel 10, regenerated liquid hold-up vessel 10 and etching bath 1 are communicated with, between described etching bath 1 and the waste liquid hold-up vessel 3, between waste liquid hold-up vessel 3 and the center two-stage system 5, between center two-stage system 5 and the regenerated liquid regulating tank 7, between regenerated liquid regulating tank 7 and the regenerated liquid hold-up vessel 10, be provided with water pump between regenerated liquid hold-up vessel 10 and the etching bath 1, described water pump is connected with PLC Controlling System 8 simultaneously, and etching bath 1, center two-stage system 5 and regenerated liquid regulating tank 7 are connected with PLC Controlling System 8 simultaneously.Utilize PLC control, the reaction times is fast, controls easier.
Described water pump comprises water pump 1, water pump 24, water pump 36, water pump 49 and water pump 5 11, and water pump 1, water pump 24, water pump 36, water pump 49 and water pump 5 11 are connected with PLC Controlling System 8 simultaneously, water pump 1 is arranged between etching bath 1 and the waste liquid hold-up vessel 3, and is communicated with etching bath 1 and waste liquid hold-up vessel 3 respectively; Water pump 24 is arranged between waste liquid hold-up vessel 3 and the center two-stage system 5, and is communicated with waste liquid hold-up vessel 3 and center two-stage system 5 respectively; Water pump 36 is arranged between center two-stage system 5 and the regenerated liquid regulating tank 7, and is communicated with center two-stage system 5 and regenerated liquid regulating tank 7 respectively; Water pump 49 is arranged between regenerated liquid regulating tank 7 and the regenerated liquid hold-up vessel 10, and is communicated with regenerated liquid regulating tank 7 and regenerated liquid hold-up vessel 10 respectively; Water pump 5 11 is arranged between regenerated liquid hold-up vessel 10 and the etching bath 1, and is communicated with regenerated liquid hold-up vessel 10 and etching bath 1 respectively.
Described water pump 1 is connected with the top of being connected with the waste liquid hold-up vessel in the bottom of etching bath 1 respectively; Described water pump 24 is connected with the top of being connected with the center two-stage system in the bottom of waste liquid hold-up vessel 3 respectively; Described water pump 36 is connected with the top of being connected with the regenerated liquid regulating tank in the bottom of center two-stage system 5 respectively.The top that is arranged on equipment is the conveniently interference of pressure when adding, and being arranged on the bottom is to utilize action of gravitation the liquid in the equipment can be emitted fully.
Described water pump 49 is connected with the top of being connected with the regenerated liquid hold-up vessel in the bottom of regenerated liquid regulating tank 7 respectively.The convenient regenerated liquid that regulates in the regenerated liquid regulating tank 7 is drawn in the regenerated liquid hold-up vessel 10 stores, be provided with pharmacy jar on the regenerated liquid regulating tank 7, after adding the loss medicament in the micro etching solution after the electrolysis, adjust to suitable concentration and content, arrive the etchant concentration of need of production.
Described water pump 5 11 is connected with the bottom of being connected with etching bath in the bottom of regenerated liquid hold-up vessel 10 respectively.Conveniently the regenerated liquid in the regenerated liquid hold-up vessel 10 is drawn in the etching bath 1.
Principle of work: the useless pipeline that connects by liquid water pump 1 of the microetch of producing in factory's etching bath 1 is transported to waste liquid hold-up vessel 3 and stores, after the waste liquid that stores reaches certain volume, be drawn into by water pump 24 and carry out electrolysis in the center two-stage system 5, cupric ion in the waste liquid is discharged center two-stage system 5 after by electrowinning, the treatment solution that obtains in the center two-stage system 5 is drawn into by water pump 36 and carries out chemicals addition control in the regenerated liquid regulating tank 7, reaching regenerated liquid recycling water pump 49 after the concentration of micro-etching solution is drawn in the regenerated liquid hold-up vessel 10 and stores, volume according to etching bath 1 internal solution utilizes water pump 5 11 to extract, so that the production of system can continue, operational process all is to finish under the control of PLC Controlling System 8.
Copper loss electricity of every product is less than 4000 degree, and current consumption is lower than traditional electrolysis mode, has saved production cost, and the ability that this system processes micro-etched waste liquid per month is 10 tons to 50 tons, and efficient is high.
Take aforesaid way, just can realize preferably the utility model.