CN202729939U - Zero emission special system for photovoltaic industrial nitrogenous waste water - Google Patents
Zero emission special system for photovoltaic industrial nitrogenous waste water Download PDFInfo
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- CN202729939U CN202729939U CN2012201641964U CN201220164196U CN202729939U CN 202729939 U CN202729939 U CN 202729939U CN 2012201641964 U CN2012201641964 U CN 2012201641964U CN 201220164196 U CN201220164196 U CN 201220164196U CN 202729939 U CN202729939 U CN 202729939U
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/30—Wastewater or sewage treatment systems using renewable energies
- Y02W10/37—Wastewater or sewage treatment systems using renewable energies using solar energy
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Abstract
Provided is a zero emission special system for photovoltaic industrial nitrogenous waste water. Firstly, collected nitrogenous waste water is subjected to preprocessing, namely, the collected nitrogenous waste water is uniformed in quality and quantity of water so as to enable the nitrogenous waste water to be uniform in water quality. Potential hydrogen (PH) value of the nitrogenous waste water is regulated to be within 6-8. Meanwhile, suspended matters (SS), macromolecule organic matters and parts of colloid of the nitrogenous waste water are filtered and eliminated. Then the nitrogenous waste water which is regulated in the PH value and filtered is subjected to membrane separation processing to obtain contributing water and thick water. Next, the contributing water after the membrane separation is reused and evaporated through the thick water. The contributing water through the photovoltaic industrial nitrogenous waste water processing is reused in high-powered mode, and the thick water is treated in three-functional evaporated mode. The zero emission special system reduces operation cost, and enables the nitrogenous waste water to be in zero exhausting, and simultaneously enables photovoltaic industrial waste water to be reused, saves water, protects environment, is cheap in cost of an integrated device and facilitates popularization.
Description
Technical field
The utility model belongs to environmental technology field, specifically just relates to photovoltaic industry nitrogenous effluent zero release dedicated system.
Background technology
China is a poor-water country, is listed in one of country of poor-water in the world.Particularly the north, western wide geographic area lack of water especially severe.China southeast is because surface water resource pollution causes that water quality lack of water situation is also very serious.In the face of severe lack of water situation, China's industrial water consumption is but wasted surprising.Mainly being that recycling rate of water used by the industries is low, only having 20-28%, only is 1/3rd of developed country.Water saving has become the task of top priority of our country, water shortage problem also will seriously restrict China's sustainable economic development in this century, and will cause environmental degradation, human settlement worsen, for water saving country is formulating and is implementing some concrete behave and policies, the water that encourages frugality, improve repeating utilization factor, the waste water treating and reutilizing of water.
In this case, sewage is back to production after advanced treatment, has become that enterprise increases the benefit, the megatrend of cleaner production, energy-saving and cost-reducing and environmental contamination reduction.The waste water that enterprise's production produces is different varied because of production technique, needs owing to production in photovoltaic industry can discharge the more waste water of a kind of nitrogen content, this sewage is discharged in the physical environment can cause water eutrophication, affect the water quality of water body, cause the transparency of water to reduce, so that sunlight is difficult to penetrate water layer, thereby affect the photosynthesis of aquatic plant, cause the hypersaturated state of dissolved oxygen.Supersaturation and the oxygen in water of oxygen in water are on the low side, and be all harmful to hydrocoles; Simultaneously, because body eutrophication, water surface can grow a large amount of algaes, forms one deck " green scum silica frost ", causes organic substance that bottom piles up to decompose at anaerobic condition and produces the biotoxin that obnoxious flavour and some planktonic organisms produce with this understanding and also can injure animal in the water.These material nitrogen contents of people and animals' long-term drinking surpass the water of certain standard, also can poison pathogenic, in the past since people that the understanding deficiency of nitrogenous effluent often directly is discharged into the river, rivers and lakes is marine, cause several large-scale pollution incidents to occur, even nitrogenous effluent is processed rear discharging, also just utilize simple ion exchange method that the nitrogen in the waste water is removed, and waste water is not recycled, do not meet now water-saving environmental requirement.
The utility model content
The purpose of this utility model provides a kind of photovoltaic industry nitrogenous effluent zero release dedicated system, serious for current China photovoltaic industry water waste, the repeating utilization factor of water is low, direct discharging of waste water causes the serious drawback of body eutrophication phenomenon, and the product water high power reuse after the photovoltaic industry nitrogenous effluent treatment, dense water triple effect evaporation are processed.Reduce working cost, make the nitrogenous effluent zero release, make simultaneously the photovoltaic industry waste water circulation use the water saving protection of the environment.
Technical scheme
In order to realize above-mentioned technical purpose, the utility model designs a kind of photovoltaic industry nitrogenous effluent technique of zero discharge, it comprises following step: at first the nitrogenous effluent of collecting is carried out pre-treatment, namely to the even water yield of nitrogenous effluent, make nitrogenous effluent water quality even, it is carried out potential of hydrogen regulate, pH value filters SS, larger molecular organics and the part colloid of getting rid of wherein simultaneously between 6～8; Then the nitrogenous effluent of regulating and filtering through potential of hydrogen is carried out flash trapping stage, during flash trapping stage, the nitrogenous effluent temperature is between 15～28 ℃, pressure is between 1.5～2.0MPa, and PH is that ORP is less than 220mv between 6～8, electricity is led between 2000～4000 μ s/cm, NO
3 -Content is between 200～400ppm; Then will carry out the second-order separation from the dense water of flash trapping stage, during the second-order separation, the nitrogenous effluent temperature is between 15～28 ℃, and pressure is between 3.0～6.0MPa, and PH is between 7～8, and ORP is less than 220mv, and electricity is led between 8000～16000 μ s/cm, NO
3 -Content is at 800～1600ppm; Then will carry out from the dense water of the second-order separation high pressure again and separate, when high pressure separated, the nitrogenous effluent temperature was between 15～35 ℃, and pressure is between 6.0～6.5MPa, and PH is between 7～9, and ORP is less than 220mv, and electricity is led between 28000～50000 μ s/cm, NO
3 -Content is at 3200～6400ppm; The product water reuse that will obtain through membrane sepn at last, dense water evaporation, when reuse, the nitrogenous effluent temperature is between 15～35 ℃, and pressure is between 1.0～1.5MPa, and PH is between 6～7, and ORP is less than 220mv, and electricity is led between 120～240 μ s/cm, NO
3 -Content is at 12～24ppm.
A kind of photovoltaic industry nitrogenous effluent zero release dedicated system by above-mentioned processing method design, it comprises collecting tank, the collecting tank water side is connected to acid-base reaction pond feed-water end, on collecting tank and the acid-base reaction pond connecting pipeline the first topping-up pump is housed, the first medicine system is housed on the acid-base reaction pond, water side, acid-base reaction pond is connected to intermediate pool, the intermediate pool water side is connected to the sand-bed filter feed-water end, the sand-bed filter water side is connected with char filter, the second topping-up pump and first is housed on intermediate pool and the sand-bed filter connecting pipeline successively adds the Scale inhibitors device; Interchanger is received in described char filter water side, the special separation membrane system of one-level is received in the interchanger water side, on the special separation membrane system connecting pipeline of interchanger and one-level the 3rd topping-up pump is installed successively, the second medicine system, the special separation membrane system of one-level is produced water out and is received the first product water intermediate water tank, the dense water out of the special separation membrane system of one-level is received the first dense water intermediate water tank, the special separation membrane system feed-water end of secondary is received in the first dense water intermediate water tank water side, on the first dense water intermediate water tank and the special separation membrane system connecting pipeline of secondary the Scale inhibitors medicine system is housed, the special separation membrane system of secondary is produced water out and is received the first product water intermediate water tank, and dense water enters the second dense water intermediate water tank; Described first produces water intermediate water tank water outlet is connected with reuse film system, on the first product water intermediate water tank and the reuse film system connecting pipeline sterilization medicine system is installed, and reuse film system produces water out and is connected to reuse pool, and dense water out connects back intermediate pool; The described second dense water intermediate water tank water outlet is connected to the high-pressure membrane system, the high-pressure membrane system produces water out and connects back intermediate pool, dense water out is received the triple effect evaporation feed chute, triple effect evaporation feed chute water outlet is received the triple effect evaporation system, on triple effect evaporation feed chute and the triple effect evaporation system connecting pipeline the 4th topping-up pump is housed, triple effect evaporation system condensing water out is connected to intermediate pool.
Further, the applicable PH of the filtering membrane that the special separation membrane system of described one-level, the special separation membrane system of secondary, reuse film system 21 and high-pressure membrane system adopt is 2～12, tolerates 50 ℃ of temperature.
Further, be connected to the first film on the pipeline between described interchanger and the 3rd topping-up pump and clean the water tank water side, described the first film cleans the water tank feed-water end and receives the dense water of the special separation membrane system of one-level water side and produce the water water side.
Further, be connected to the second film on the described first dense water intermediate water tank and the second high-pressure pump connecting pipeline and clean the water tank water side, described the second film cleans the water tank feed-water end and receives the dense water of the special separation membrane system of secondary water side and produce the water water side.
Further, be connected to tertiary membrane on described the first product water intermediate water tank and the third high press pump connecting pipeline and clean the water tank water side, described tertiary membrane cleans the water tank feed-water end and receives reuse film system dense water water side and produce the water water side.
Further, be connected to the 4th film on the described second dense water intermediate water tank and the 4th high-pressure pump connecting pipeline and clean the water tank water side, described tertiary membrane cleans the water tank feed-water end and receives high-pressure membrane system dense water water side and produce the water water side.
Beneficial effect
The photovoltaic industry nitrogenous effluent technique of zero discharge that the utility model is designed is processed the product water high power reuse after the photovoltaic industry nitrogenous effluent treatment, dense water triple effect evaporation.Reduce working cost, make the nitrogenous effluent zero release, the photovoltaic industry waste water circulation is used, the water saving protection of the environment, the whole plant low cost is beneficial to popularization.
Description of drawings
Accompanying drawing 1 is process flow sheet of the present utility model.
Accompanying drawing 2 is first to produce the anterior annexation schematic diagram of water intermediate water tank among special-purpose the first embodiment of system in the utility model.
Accompanying drawing 3 is first to produce water intermediate water tank rear portion annexation diagram among special-purpose the first embodiment of system in the utility model.
Accompanying drawing 4 be in the utility model among special-purpose the second embodiment of system the first film clean water tank annexation structural representation.
Accompanying drawing 5 be in the utility model among special-purpose the second embodiment of system the second film clean water tank annexation structural representation.
Accompanying drawing 6 be in the utility model among special-purpose the second embodiment of system tertiary membrane clean water tank annexation structural representation.
Accompanying drawing 7 be in the utility model among special-purpose the second embodiment of system the 4th film clean water tank annexation structural representation.
Embodiment
Below in conjunction with drawings and Examples, the utility model is described further.
Shown in attached Fig. 1 and 2, a kind of photovoltaic industry nitrogenous effluent zero release dedicated system, it comprises collecting tank 1, collecting tank 1 water side is connected to acid-base reaction pond 2 feed-water ends, on collecting tank 1 and acid-base reaction pond 2 connecting pipelines the first topping-up pump 3 is housed, the first medicine system 4 is housed on the acid- base reaction pond 2,2 water sides, acid-base reaction pond are connected to intermediate pool 5, intermediate pool 5 water sides are connected to sand-bed filter 6 feed-water ends, connection is connected in sand-bed filter 6 water sides with char filter, on intermediate pool 5 and sand-bed filter 6 connecting pipelines the second topping-up pump 8 and first is housed successively and adds Scale inhibitors device 9.
Interchanger 12 is received in described char filter 7 water sides, the special separation membrane system 13 of one-level is received in interchanger 12 water sides, on special separation membrane system 13 connecting pipelines of interchanger 12 and one-level the 3rd topping-up pump 10 and the second medicine system 11 are installed successively, the special separation membrane system 13 of one-level is produced water out and is received the first product water intermediate water tank 14, the special separation membrane system 13 dense water outs of one-level are received the first dense water intermediate water tank 15, special separation membrane system 16 feed-water ends of secondary are received in the first dense water intermediate water tank 15 water sides, on special separation membrane system 16 connecting pipelines of the first dense water intermediate water tank 15 and secondary Scale inhibitors medicine system 18 is housed, the special separation membrane system 16 of secondary is produced water out and is received the first product water intermediate water tank 14, and dense water enters the second dense water intermediate water tank 20.
Described first produces water intermediate water tank 14 water outlets is connected with reuse film system 21, on the first product water intermediate water tank 14 and reuse film system 21 connecting pipelines sterilization medicine system 23 is installed, reuse film system 21 produces water out and is connected to reuse pool 25, and dense water out connects back intermediate pool 5.
The described second dense water intermediate water tank 20 water outlets are connected to high-pressure membrane system 26, high-pressure membrane system 26 produces water out and connects back intermediate pool 5, dense water out is received triple effect evaporation feed chute 27, triple effect evaporation feed chute 27 water outlets are received triple effect evaporation system 28, on triple effect evaporation feed chute 27 and triple effect evaporation system 28 connecting pipelines the 4th topping-up pump 29 is housed, triple effect evaporation system 28 condensation-water drains are connected to intermediate pool 5.
The applicable PH of filtering membrane that the special separation membrane system 13 of described one-level, the special separation membrane system 16 of secondary, reuse film system 21 and high-pressure membrane system 26 adopt is 2～12, tolerates 50 ℃ of temperature.
As shown in Figure 3, the working process of the utility model the first embodiment is achieved in that the nitrogenous effluent of at first collecting tank 1 being collected carries out pre-treatment, namely to the even water quality and quantity of nitrogenous effluent, make nitrogenous effluent water quality even, by acid-base reaction pond 2 it being carried out potential of hydrogen simultaneously regulates, pH value will filter SS, larger molecular organics and the part colloid of getting rid of wherein by sand-bed filter 6 and char filter 7 through the nitrogenous effluent that water amount is regulated simultaneously between 6～8; Then the nitrogenous effluent of regulating and filtering through potential of hydrogen is passed into the special separation membrane system 13 of one-level and carry out flash trapping stage, during flash trapping stage, the nitrogenous effluent temperature is between 15～28 ℃, pressure is between 1.5～2.0MPa, PH is between 6～8, ORP is less than 220mv, and electricity is led between 2000～4000 μ s/cm, NO
3 -Content is between 200～400ppm; Then will pass into from the dense water of flash trapping stage the special separation membrane system 16 of secondary and carry out the second-order separation, during the second-order separation, the nitrogenous effluent temperature is between 15～28 ℃, pressure is between 3.0～6.0MPa, and PH is that ORP is less than 220mv between 7～8, electricity is led between 8000～16000 μ s/cm, NO
3 -Content is at 800～1600ppm; Then will pass into from the dense water of the second-order separation high-pressure membrane system 26 again and carry out the high pressure separation, when high pressure separated, the nitrogenous effluent temperature was between 15～35 ℃, pressure is between 6.0～6.5MPa, and PH is that ORP is less than 220mv between 7～9, electricity is led between 28000～50000 μ s/cm, NO
3 -Content is at 3200～6400ppm; To pass into through the product water that membrane sepn obtains 21 reuses of reuse film system at last, dense water is through 28 evaporations of triple effect evaporation system, when reuse, the nitrogenous effluent temperature is between 15～35 ℃, pressure is between 1.0～1.5MPa, and PH is that ORP is less than 220mv between 6～7, electricity is led between 120～240 μ s/cm, NO
3 -Content is at 12～24ppm.
The second embodiment of the present utility model, in order to prolong the work-ing life of whole system, as shown in Figure 4, be connected to the first film on the pipeline between described interchanger 12 and the 3rd topping-up pump 10 and clean water tank 17 water sides, described the first film cleans water tank 17 feed-water ends and receives the special separation membrane system of one-level 13 dense water water sides and produce the water water side.
As shown in Figure 5, be connected to the second film on the described first dense water intermediate water tank 15 and Scale inhibitors medicine system 18 connecting pipelines and clean water tank 19 water sides, described the second film cleans water tank 19 feed-water ends and receives the special separation membrane system of secondary 16 dense water water sides and produce the water water side.
As shown in Figure 6, be connected to tertiary membrane on described the first product water intermediate water tank 14 and sterilization medicine system 23 connecting pipelines and clean water tank 22 water sides, described tertiary membrane cleans water tank 22 feed-water ends and receives reuse film system 21 dense water water sides and produce the water water side.
As shown in Figure 7, be connected to the 4th film on the described second dense water intermediate water tank 20 outlet pipelines and clean water tank 24 water sides, described the 4th film cleans water tank 24 feed-water ends and receives high-pressure membrane system 26 dense water water sides and produce the water water side.
The photovoltaic industry nitrogenous effluent technique of zero discharge that the utility model is designed is processed the product water high power reuse after the photovoltaic industry nitrogenous effluent treatment, dense water triple effect evaporation.Reduce working cost, make the nitrogenous effluent zero release, the photovoltaic industry waste water circulation is used, the water saving protection of the environment, the whole plant low cost is beneficial to popularization.
Claims (6)
1. photovoltaic industry nitrogenous effluent zero release dedicated system, it is characterized in that: it comprises collecting tank (1), collecting tank (1) water side is connected to acid-base reaction pond (2) feed-water end, on collecting tank (1) and acid-base reaction pond (2) connecting pipeline the first topping-up pump (3) is housed, the first medicine system (4) is housed on the soda acid Ying Chi (2), soda acid Ying Chi (2) water side is connected to intermediate pool (5), intermediate pool (5) water side is connected to sand-bed filter (6) feed-water end, sand-bed filter (6) water side is connected 7 with char filter) connect, on intermediate pool (5) and sand-bed filter (6) connecting pipeline the second topping-up pump (8) and first is housed successively and adds Scale inhibitors device (9);
Interchanger (12) is received in described char filter (7) water side, the special separation membrane system of one-level (13) is received in interchanger (12) water side, on interchanger (12) and the special separation membrane system of one-level (13) connecting pipeline the 3rd topping-up pump (10) and the second medicine system (11) are installed successively, the special separation membrane system of one-level (13) is produced water out and is received the first product water intermediate water tank (14), the dense water out of the special separation membrane system of one-level (13) is received the first dense water intermediate water tank (15), the special separation membrane system of secondary (16) feed-water end is received in the first dense water intermediate water tank (15) water side, on the first dense water intermediate water tank (15) and the special separation membrane system of secondary (16) connecting pipeline Scale inhibitors medicine system (18) is housed, the special separation membrane system of secondary (16) is produced water out and is received the first product water intermediate water tank (14), and dense water enters the second dense water intermediate water tank (20);
Described first produces water intermediate water tank (14) water outlet is connected with reuse film system (21), on the first product water intermediate water tank (14) and reuse film system (21) connecting pipeline sterilization medicine system (23) is installed, reuse film system (21) produces water out and is connected to reuse pool (25), and dense water out connects back intermediate pool (5);
The described second dense water intermediate water tank (20) water outlet is connected to high-pressure membrane system (26), high-pressure membrane system (26) produces water out and connects back intermediate pool (5), dense water out is received triple effect evaporation feed chute (27), triple effect evaporation feed chute (27) water outlet is received triple effect evaporation system (28), on triple effect evaporation feed chute (27) and triple effect evaporation system (28) connecting pipeline the 4th topping-up pump (29) is housed, triple effect evaporation system (28) condensation-water drain is connected to intermediate pool (5).
2. a kind of photovoltaic industry nitrogenous effluent zero release dedicated system as claimed in claim 1, it is characterized in that: the applicable PH of the filtering membrane that the special separation membrane system of described one-level (13), the special separation membrane system of secondary (16), reuse film system (21) and high-pressure membrane system (26) adopt is 2～12, tolerates 50 ℃ of temperature.
3. a kind of photovoltaic industry nitrogenous effluent zero release dedicated system as claimed in claim 1, it is characterized in that: be connected to the first film on the pipeline between described interchanger (12) and the 3rd topping-up pump (10) and clean water tank (17) water side, described the first film cleans water tank (17) feed-water end and receives the dense water of the special separation membrane system of one-level (13) water side and produce the water water side.
4. a kind of photovoltaic industry nitrogenous effluent zero release dedicated system as claimed in claim 1, it is characterized in that: be connected to the second film on the described first dense water intermediate water tank (15) and Scale inhibitors medicine system (18) connecting pipeline and clean water tank (19) water side, described the second film cleans water tank (19) feed-water end and receives the dense water of the special separation membrane system of secondary (16) water side and produce the water water side.
5. a kind of photovoltaic industry nitrogenous effluent zero release dedicated system as claimed in claim 1, it is characterized in that: be connected to tertiary membrane on described the first product water intermediate water tank (14) and sterilization medicine system (23) connecting pipeline and clean water tank (22) water side, described tertiary membrane cleans water tank (22) feed-water end and receives reuse film system (21) dense water water side and produce the water water side.
6. a kind of photovoltaic industry nitrogenous effluent zero release dedicated system as claimed in claim 1, it is characterized in that: be connected to the 4th film on the described second dense water intermediate water tank (20) water side pipeline and clean water tank (24) water side, described the 4th film cleans water tank (24) feed-water end and receives high-pressure membrane system (26) dense water water side and produce the water water side.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012201641964U CN202729939U (en) | 2012-04-17 | 2012-04-17 | Zero emission special system for photovoltaic industrial nitrogenous waste water |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012201641964U CN202729939U (en) | 2012-04-17 | 2012-04-17 | Zero emission special system for photovoltaic industrial nitrogenous waste water |
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| Publication Number | Publication Date |
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| CN202729939U true CN202729939U (en) | 2013-02-13 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN2012201641964U Withdrawn - After Issue CN202729939U (en) | 2012-04-17 | 2012-04-17 | Zero emission special system for photovoltaic industrial nitrogenous waste water |
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| CN (1) | CN202729939U (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104355431A (en) * | 2014-11-12 | 2015-02-18 | 湖北加德科技股份有限公司 | Device capable of efficiently treating and recycling reverse osmosis concentrated water and high-salt wastewater |
-
2012
- 2012-04-17 CN CN2012201641964U patent/CN202729939U/en not_active Withdrawn - After Issue
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104355431A (en) * | 2014-11-12 | 2015-02-18 | 湖北加德科技股份有限公司 | Device capable of efficiently treating and recycling reverse osmosis concentrated water and high-salt wastewater |
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| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| AV01 | Patent right actively abandoned |
Granted publication date: 20130213 Effective date of abandoning: 20150722 |
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| RGAV | Abandon patent right to avoid regrant |