CN202678471U - Lithium iron phosphate battery - Google Patents

Lithium iron phosphate battery Download PDF

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Publication number
CN202678471U
CN202678471U CN2012202603616U CN201220260361U CN202678471U CN 202678471 U CN202678471 U CN 202678471U CN 2012202603616 U CN2012202603616 U CN 2012202603616U CN 201220260361 U CN201220260361 U CN 201220260361U CN 202678471 U CN202678471 U CN 202678471U
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CN
China
Prior art keywords
battery
lithium cell
ferric phosphate
phosphate lithium
battery core
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Expired - Fee Related
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CN2012202603616U
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Chinese (zh)
Inventor
李瑶
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Shenzhen OptimumNano Energy Co Ltd
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Shenzhen OptimumNano Energy Co Ltd
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Priority to CN2012202603616U priority Critical patent/CN202678471U/en
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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  • Primary Cells (AREA)

Abstract

The utility model discloses a lithium iron phosphate battery. The battery comprises a cylinder-shaped housing, a cap and a cylindrical battery cell accommodated in the hosing, wherein the height of the battery cell is L; the battery cell comprises a first end part electrically connected to the bottom of the hosing, a second end part electrically connected to the cap and a channel penetrating the first end part and the second end part; a hollow pipeline extending from the first end part to the second end part is formed in the channel; and the length of the pipeline is H, and H is smaller than or equal to 4L/5 and larger than or equal to 1L/2. Compared with the prior art, the lithium iron phosphate battery has the advantages that as the steel pipeline is arranged in the battery cell of the lithium iron phosphate battery, excellent heat conduction between the two ends of the battery can still be guaranteed when the battery is in an abnormal working state, and if the electrolyte vaporization caused by overtemperature of the bottom of the battery occurs, the vaporized objects can enter the top of the battery cell through the pipeline to ensure the pressure equalization at the two ends of the battery cell, thereby ensuring security work of the battery.

Description

Ferric phosphate lithium cell
[technical field]
The utility model relates to new energy field, relates in particular to a kind of ferric phosphate lithium cell of electric vehicle.
[background technology]
Energy crisis, shortage of resources, environmental pollution are the three large severe challenges that human survival faces, and seeking secondary resource clean, renewable, resource-conserving is the vital task that realizes that human social will solve.
Raising along with expanding economy and living standards of the people, people are more and more strong to the battery requirements of high-energy-density, lithium ion battery have operating voltage height, energy density large, have extended cycle life, the advantages such as self-discharge rate is little, environmental protection, become the trend of secondary cell.Now be widely used in the portable electricity consuming productses such as wireless telecommunications, digital camera, and tentatively in special dimension extensive uses such as aviation, national defence.
LiFePO4 is a kind of positive electrode of making lithium battery, and not only specific capacity is high, and particularly the outstanding feature of superior, the good cycle of its Heat stability is good, security performance is considered to the desirable making material of lithium battery anode.
Although ferric phosphate lithium cell has the unrivaled series of advantages of other materials, its part that also comes with some shortcomings, these weak points mainly are relevant with the structure of traditional lithium battery.Although traditional lithium battery is equipped with safety valve at the block place, if but battery bottom is short-circuited, the passage that the heat when then thereby the bottom can produce a large amount of heats and cause the battery core at place, bottom to expand rapidly initial conditions when high temperature between battery core bottom and the top is transmitted stops up, like this, the heat of battery bottom just can not in time pass, finally cause over-heat at the bottom sharply to expand, pressure sharply raises even blasts.
In view of above drawback, be necessary to provide a kind of new ferric phosphate lithium cell to overcome defects in fact.
[utility model content]
The purpose of this utility model is to overcome above-mentioned defective, and a kind of ferric phosphate lithium cell simple, that security performance is high of making is provided.
To achieve these goals, the utility model provides a kind of ferric phosphate lithium cell, comprise cylindrical shape housing, block a shot and be contained in cylinder battery core in the housing, the height of described battery core is L, it comprises the first end that is electrically connected to housing bottom and the second end that is electrically connected to block, described battery core also is provided with through the passage of first end and the second end, in described passage, be provided with the hollow pipe that extends to the second end from first end, the length of described pipeline is H, and 1L/2≤H≤4L/5.
As a kind of improvement of the utility model ferric phosphate lithium cell, described battery core is that the positive and negative plate of mutual insulating isolation twines formation.
As a kind of improvement of the utility model ferric phosphate lithium cell, described hollow pipe is hollow cylindrical, and its external diameter is consistent with the passage internal diameter.
As a kind of improvement of the utility model ferric phosphate lithium cell, a port of described hollow pipe shrinks gradually, and it is horn-like that the another port is.
As a kind of improvement of the utility model ferric phosphate lithium cell, described positive plate has plus plate current-collecting body and the positive electrode active material that is coated on the plus plate current-collecting body; Described negative plate has negative current collector and the negative electrode active material that is coated on the negative current collector.
As a kind of improvement of the utility model ferric phosphate lithium cell, described plus plate current-collecting body adopts aluminium foil to make, and negative current collector adopts Copper Foil to make.
As a kind of improvement of the utility model ferric phosphate lithium cell, be welded with respectively lug on the described positive and negative plate, described lug welds together with housing bottom and block respectively.
As a kind of improvement of the utility model ferric phosphate lithium cell, described block is provided with safety valve.
As a kind of improvement of the utility model ferric phosphate lithium cell, described pipeline is that steel material is made.
Compared to prior art, the utlity model has following advantage: be installed on a steel pipe in the battery core of the utility model ferric phosphate lithium cell, this pipeline can guarantee that battery is when operation irregularity, can also keep good heat conduction between the two ends of battery core, if and because of the excess Temperature of battery core bottom, caused the electrolyte vaporization, then described vaporizer also could enter by pipeline the top of battery core, guarantee place, the two ends isostasy of battery core, thereby guarantee the trouble free service of battery.
[description of drawings]
Fig. 1 is the three-dimensional exploded view (battery core is not installed) of the utility model ferric phosphate lithium cell;
Fig. 2 is the structural representation of the plus plate current-collecting body of the utility model ferric phosphate lithium cell;
Fig. 3 is the battery core generalized section of the utility model ferric phosphate lithium cell;
Fig. 4 is the pipeline configuration schematic diagram that relates to of the utility model ferric phosphate lithium cell.
[embodiment]
Please refer to Fig. 1 to shown in Figure 4, the utility model is described in further detail below in conjunction with the accompanying drawing illustrated embodiment.
The manufacture craft of the utility model ferric phosphate lithium cell 100 may further comprise the steps: 1) batching, 2) coating, 3) roll-in, 4) the battery pole piece making, 5) baking, 6) reel 7) the tubulature road, and 8) Laser Welding, 9) fluid injection, 10) change into 11) partial volume;
1) batching:
The anode sizing agent of preparation take water as medium, material requested has: water system glue, LiFePO4, the superconduction carbon black, electrically conductive graphite, lithium salts, water system glue is added to the water carries out agitation and dilution, add superconduction carbon black and electrically conductive graphite and stir, add LiFePO4 at last and lithium salts stirs into slurry;
The cathode size of preparation take water as medium, material requested has: graphite, sodium carboxymethylcellulose, the superconduction carbon black, water system glue is added to the water stirring with sodium carboxymethylcellulose, after staticly settling, adds water system glue, superconduction carbon black, and graphite stirs into slurry;
2) coating
Positive pole after filtering and cathode size are coated in respectively on the corresponding plus plate current-collecting body 21 and negative current collector equably, and reserve uncoated zone, as the lug district, then put into the coating machine oven baking, the linear velocity plus plate current-collecting body of coating is 4.5 meters of per minutes, negative current collector is 5 meters of per minutes, after the coating baking is finished, each pole piece is cut into slices; In the utility model, described plus plate current-collecting body adopts aluminium foil to make, and negative current collector adopts Copper Foil to make, and the slurry that coating is adopted is respectively positive electrode active material and negative electrode active material.
3) roll-in
Roll process, with the positive plate roll-in to thickness at 115 μ m-140 μ m, compacted density is at 1.9g/cm 3-2.3g/cm 3; With the negative plate roll-in to thickness at 75 μ m-90 μ m, compacted density is at 1.3g/cm 3-1.6g/cm 3
4) battery pole piece is made;
Positive plate is cut into the rectangular sheet with three lugs, and negative pole is cut into the rectangular sheet with three lugs;
5) baking
Section is toasted, baking is 24 hours in vacuum oven, vacuum degree is not less than-0.08Mpa, and baking temperature is 100 degree, every ventilation in 2-4 hour once, kept 30 minutes after the ventilation, and then vacuumize, stoving time finishes, and temperature is reduced to below 45 degree, baking box is taken out in section, then changed over to subsequent processing.
6) reel
Positive/negative plate is placed in the groove of up-coiler, reels, the coiling height of formation is the cylindrical shape of L.In winding process, must guarantee that the two is that insulation is isolated.The battery core 20 of described cylindrical shape can be divided into first end 23 and the second end 24, and it also is provided with the passage 22 through first end and the second end, with adhesive tape battery core is twined a circle afterwards.
7) tubulature road
Get the hollow pipe 40 that is hollow cylindrical, the length of described hollow pipe 40 is H, and 1L/2≤H≤4L/5.The passage of described pipeline 40 from battery core first end 23 inserted until get final product in the passage 22 that all submerges.
Certainly, in Practical manufacturing, in order to prevent to slide up and down after hollow cylindrical from inserting passage, so, in when design, not only can require the external diameter of hollow pipe 40 and passage 22 internal diameters are designed to consistent, the end port 41 of hollow pipe 40 can also be designed and be horn-like.For the convenience in tubulature road, the shape that usually also the port 42 of the insertion end of hollow pipe is designed to shrink gradually.
8) Laser Welding
Battery core 20 is packed in the aluminium casing 10, then use ultrasonic welding machine with the bottom of negative pole lug welding to housing 10, with electric resistance welding positive pole is soldered to again the safety valve position of block 30.In welding process, guarantee to weld smooth, without trachoma, rosin joint.
9) fluid injection
Battery liquid-filling adopts semi-automatic vacuum liquid injecting machine fluid injection, passes into high-purity argon gas in the time of fluid injection, and the reservoir quantity of lithium ion battery needs according to its calculation of capacity, and its reservoir quantity is about 7g/Ah; The electrolyte that adopts is LiPF6/EC, DMC, the EMC of 1M, and the environment control of fluid injection is extremely important, so need to finish fluid injection in glove box, fluid injection is injected from the fluid injection of battery container usually.
10) change into
Formation process must disposablely be finished incessantly, and changing into curve should be smoothly connected, and Current Control is at 0.1A/30min, 0.25A/120min, 0.35A/300min.
11) partial volume
The battery that the electrical property indices is all met technological requirement separates with the battery that every electrical performance indexes does not reach technological requirement, inserts in the storehouse respectively.
The distinguishing feature that the utility model adopts ferric phosphate lithium cell 100 that above-mentioned technique makes and traditional lithium battery to have is: although traditional lithium battery also is to cover block after the cylinder battery core is housed in housing again, but, traditional lithium battery only relies on the path that runs through battery core bottom and top when forming battery core to guarantee bottom the battery core and the thermal cycle between the top, yet, in actual use, if the battery core short circuit of bottom occurs, then the battery core of bottom just can expand rapidly and stop up any path that leads to the battery core top, causing the bottom to gather a large amount of heats can't discharge, electrolyte liquefies rapidly, even the accident of can blasting.But owing in battery core 20 of the present utility model, inserted the pipeline 40 of a steel, thereby the first end 23 that can guarantee battery core 20 is formed through thermal cycle all the time with the second end 24, even and because the temperature of battery core 20 bottoms acutely rises, cause the electrolyte of battery core 20 bottoms to liquefy rapidly, so aforesaid liquefied substance also can enter the top of battery core and finally wash safety valve open by pipeline 40, has guaranteed the fail safe that battery uses.
A kind of ferric phosphate lithium cell of the utility model, be not restricted to described in specification and the execution mode, therefore for the personnel of familiar field, can easily realize additional advantage and modification, so in the situation of the spirit and scope that do not deviate from the universal that claim and equivalency range limit, the utility model is not limited to specific details, representational equipment and illustrates here and the examples shown of describing.

Claims (9)

1. ferric phosphate lithium cell, it is characterized in that: it comprise cylindrical shape housing, block a shot and be contained in cylinder battery core in the housing, the height of described battery core is L, it comprises the first end that is electrically connected to housing bottom and the second end that is electrically connected to block, described battery core also is provided with through the passage of first end and the second end, be provided with the hollow pipe that extends to the second end from first end in described passage, the length of described pipeline is H, and 1L/2≤H≤4L/5.
2. ferric phosphate lithium cell as claimed in claim 1 is characterized in that: described battery core is that the positive and negative plate of mutual insulating isolation twines and forms.
3. ferric phosphate lithium cell as claimed in claim 1, it is characterized in that: described hollow pipe is hollow cylindrical, and its external diameter is consistent with the passage internal diameter of battery core.
4. ferric phosphate lithium cell as claimed in claim 3, it is characterized in that: a port of described hollow pipe shrinks gradually, and it is horn-like that the another port is.
5. ferric phosphate lithium cell as claimed in claim 2 is characterized in that: described positive plate has plus plate current-collecting body and is coated on positive electrode active material on the plus plate current-collecting body; Described negative plate has negative current collector and the negative electrode active material that is coated on the negative current collector.
6. ferric phosphate lithium cell as claimed in claim 5 is characterized in that: described plus plate current-collecting body adopts aluminium foil to make, and negative current collector adopts Copper Foil to make.
7. ferric phosphate lithium cell as claimed in claim 2, it is characterized in that: be welded with respectively lug on the described positive and negative plate, described lug welds together with housing bottom and block respectively.
8. ferric phosphate lithium cell as claimed in claim 1, it is characterized in that: described block is provided with safety valve.
9. such as the described arbitrary ferric phosphate lithium cell of claim 1 to 8, it is characterized in that: described pipeline is that steel material is made.
CN2012202603616U 2012-06-04 2012-06-04 Lithium iron phosphate battery Expired - Fee Related CN202678471U (en)

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Application Number Priority Date Filing Date Title
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103456979A (en) * 2012-06-04 2013-12-18 深圳市沃特玛电池有限公司 Lithium iron phosphate battery
CN108666631A (en) * 2017-03-28 2018-10-16 三洋电机株式会社 The manufacturing method of secondary cell

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103456979A (en) * 2012-06-04 2013-12-18 深圳市沃特玛电池有限公司 Lithium iron phosphate battery
CN103456979B (en) * 2012-06-04 2017-07-07 深圳市沃特玛电池有限公司 Ferric phosphate lithium cell
CN108666631A (en) * 2017-03-28 2018-10-16 三洋电机株式会社 The manufacturing method of secondary cell

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Legal Events

Date Code Title Description
C14 Grant of patent or utility model
GR01 Patent grant
PE01 Entry into force of the registration of the contract for pledge of patent right

Denomination of utility model: Electromobile with lithium ferric phosphate cell

Effective date of registration: 20141218

Granted publication date: 20130116

Pledgee: Export Import Bank of China

Pledgor: Shenzhen Optimum Battery Co.,Ltd.|Zhao Bing

Registration number: 2014990001097

PLDC Enforcement, change and cancellation of contracts on pledge of patent right or utility model
PC01 Cancellation of the registration of the contract for pledge of patent right

Date of cancellation: 20171025

Granted publication date: 20130116

Pledgee: Export Import Bank of China

Pledgor: Shenzhen Optimum Battery Co.,Ltd.|Zhao Bing

Registration number: 2014990001097

PC01 Cancellation of the registration of the contract for pledge of patent right
PP01 Preservation of patent right

Effective date of registration: 20180428

Granted publication date: 20130116

PP01 Preservation of patent right
PD01 Discharge of preservation of patent

Date of cancellation: 20210428

Granted publication date: 20130116

PD01 Discharge of preservation of patent
PP01 Preservation of patent right

Effective date of registration: 20210428

Granted publication date: 20130116

PP01 Preservation of patent right
PD01 Discharge of preservation of patent

Date of cancellation: 20220604

Granted publication date: 20130116

PD01 Discharge of preservation of patent
DD01 Delivery of document by public notice

Addressee: Ke Hongtao

Document name: Notice of End of Suspension Proceedings

DD01 Delivery of document by public notice
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20130116

Termination date: 20180604

CF01 Termination of patent right due to non-payment of annual fee