CN202666618U - Compound air purifying device - Google Patents
Compound air purifying device Download PDFInfo
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- CN202666618U CN202666618U CN201220112056.2U CN201220112056U CN202666618U CN 202666618 U CN202666618 U CN 202666618U CN 201220112056 U CN201220112056 U CN 201220112056U CN 202666618 U CN202666618 U CN 202666618U
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- 150000001875 compounds Chemical class 0.000 title abstract 6
- 239000002131 composite material Substances 0.000 claims abstract description 36
- 238000004887 air purification Methods 0.000 claims abstract description 22
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- 230000003197 catalytic effect Effects 0.000 claims abstract description 15
- 230000009290 primary effect Effects 0.000 claims abstract description 4
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims description 26
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 14
- 238000000746 purification Methods 0.000 claims description 13
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- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 3
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- 229910052751 metal Inorganic materials 0.000 claims 1
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- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 10
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- OLAPPGSPBNVTRF-UHFFFAOYSA-N naphthalene-1,4,5,8-tetracarboxylic acid Chemical compound C1=CC(C(O)=O)=C2C(C(=O)O)=CC=C(C(O)=O)C2=C1C(O)=O OLAPPGSPBNVTRF-UHFFFAOYSA-N 0.000 description 1
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
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- Exhaust Gas Treatment By Means Of Catalyst (AREA)
Abstract
Description
技术领域 technical field
本实用新型属于空气净化技术领域,尤其涉及焊接厂房空气净化技术,是一种复合空气净化装置。 The utility model belongs to the technical field of air purification, in particular to the air purification technology of welding workshops, and is a composite air purification device. the
背景技术 Background technique
焊接厂房中大量排放的挥发性有机污染物(VOCs)和无机污染物如SO 2、NOx、焊接烟尘等,威胁着人类自身健康和赖以生存的环境。传统的空气净化技术如热力/催化燃烧法、生物过滤法、膜分离和选择性还原技术等,存在投资大、周期长、运行费用高等缺点。为此需要寻找创新性的复合空气净化方法和途径。 A large amount of volatile organic pollutants (VOCs) and inorganic pollutants such as SO 2 , NOx, welding fumes, etc. are emitted in welding workshops, threatening human health and the environment on which we live. Traditional air purification technologies such as thermal/catalytic combustion, biological filtration, membrane separation, and selective reduction technologies have disadvantages such as large investment, long cycle time, and high operating costs. For this reason, it is necessary to find innovative composite air purification methods and approaches.
紫外氧化法:工艺简单,可分解VOCs,处理流程短,效率高,能耗低,适用范围广;缺点是紫外光发射管效率低及停留时间长,紫外光对人体有损伤作用。 UV oxidation method: the process is simple, can decompose VOCs, the treatment process is short, the efficiency is high, the energy consumption is low, and the scope of application is wide; the disadvantage is that the efficiency of the ultraviolet light emitting tube is low and the residence time is long, and the ultraviolet light can damage the human body. the
纳米光催化法:利用催化剂将有害物氧化分解成无害物质,能延长净化器的使用寿命;能耗低、操作简单、无二次污染。缺点是降解的效率比较低,某些情况生成的二次产物后期处理比较复杂;活性随时间降低,需进行后续处理;使用的紫外光源有生物损伤作用。 Nano-photocatalysis method: using catalysts to oxidize and decompose harmful substances into harmless substances, which can prolong the service life of the purifier; low energy consumption, simple operation, and no secondary pollution. The disadvantage is that the degradation efficiency is relatively low, and the post-processing of the secondary products generated in some cases is more complicated; the activity decreases with time, and subsequent processing is required; the ultraviolet light source used has biological damage. the
纳米二氧化钛:纳米二氧化钛在等离子体放电的催化下可产生大量的羟基自由基,在羟基自由基、等离子体、紫外辐射、强电场等效应联合作用下,降解空气中的有害有机物(例如甲醛、甲苯等)和杀灭病菌病毒。 Nano-titanium dioxide: Nano-titanium dioxide can generate a large number of hydroxyl radicals under the catalysis of plasma discharge. Under the combined effects of hydroxyl radicals, plasma, ultraviolet radiation, and strong electric field, it can degrade harmful organic substances in the air (such as formaldehyde, toluene, etc.) etc.) and kill germs and viruses. the
低温等离子体净化法:可利用高频、高压电流产生离子碎片,在常温、常压下分解有害物,提高净化效率;缺点是易产生二次污染,对二次污染物的后期处理复杂昂贵;能量利用的效率比较低。 Low-temperature plasma purification method: high-frequency and high-voltage current can be used to generate ion fragments, decompose harmful substances under normal temperature and pressure, and improve purification efficiency; the disadvantage is that secondary pollution is easy to occur, and the post-treatment of secondary pollutants is complicated and expensive; The efficiency of energy utilization is relatively low. the
由于各种技术尤其各自的局限性,要达到高效去除污染物的目的,目前还没有最行之有效的方法。 Due to the respective limitations of various technologies, there is currently no most effective method to achieve the purpose of efficiently removing pollutants. the
发明内容 Contents of the invention
本实用新型的目的在于提供一种集低温等离子、纳米二氧化钛和双波段紫外光催化触媒协同作用的净化技术,集合了各自的优点,弥补了各者的不足,是一种全新的空气污染控制技术。该装置可同时实现对颗粒灰尘及各种悬浮物的高效过滤、污染有毒气体的高效去除及细菌、病毒的杀灭目的,提高室内空气品质,改善生活环境。 The purpose of this utility model is to provide a purification technology that integrates low-temperature plasma, nano-titanium dioxide and dual-band ultraviolet photocatalyst synergistically. It combines the advantages of each and makes up for the shortcomings of each. It is a brand-new air pollution control technology. . The device can realize the efficient filtration of particulate dust and various suspended solids, the efficient removal of polluted and toxic gases, and the killing of bacteria and viruses at the same time, so as to improve indoor air quality and improve the living environment. the
为了达到上述目的,本实用新型技术解决方案是:提供了一种集低温等离子、纳米二氧化钛和双波段紫外光催化触媒协同作用的净化技术于一体及多级过滤的空气复合净化装 置。它包括初效过滤器(1)、针板式低温等离子体发生器(2)、双波段紫外光灯(3)、高效过滤器(4)、风机(5)、变压器(6)、镇流器(7)、底座(8)。该装置为风道结构,出风口处设引气风机(5),风道内设置空气净化器件,空气复合净化装置分为三级过滤,第一级为初效过滤器(1),初效过滤器(1)为6个圆柱型初效过滤器组合而成;第二级为低温等离子、纳米二氧化钛和双波段紫外光催化触媒协同作用过滤(2和3);第三级为高效过滤器(4)。第二级过滤分别为低温等离子体结构、聚合高分子复合膜及纳米二氧化钛催化膜(15)、双波段紫外光灯(3)。其中,低温等离子体电极结构、聚合高分子复合膜及纳米二氧化钛催化膜(15)的结构为针板式结构,针板式电极之间是具有强氧化性的纳米二氧化钛催化膜(15),纳米二氧化钛催化膜(15)为负载在活性炭网上的纳米二氧化钛膜,纳米二氧化钛催化膜厚度为2-5mm。针型电极(10)放电端加工成针尖状,采用金属镍制成。低温等离子结构中的负极板为透明的无机玻璃做成的孔状电极。低温等离子体电极结构、聚合高分子复合膜及纳米二氧化钛催化膜结构板,两块结构板块平行放置,且与水平风道轴线的夹角为45°。两个电极板接3kV-5kV的高压电源和地,低温等离子体电极结构、聚合高分子复合膜及纳米二氧化钛催化膜(2)通过固定框架(14)安装在风道四壁上;双波段紫外光灯(3)为长波UVA加短波UVC,安装在风道中间;镇流器(7)和变压器(6)安置在装置的外壁上。针板结构的电极,其中正极板为在绝缘线(12)上均匀布置的平行针,针尖指向负极板,负极板前有一层聚合高分子复合膜,聚合高分子复合膜是由聚氟乙烯、芳香族四酸二酐、有机硅、芳族二氨聚合成膜与云母复合而成的。通过引线(18)接高压电源的正极;正极板利用针的尖端进行放电,采用绝缘线上布置放电针,是为了充分利用正极侧的双波段紫外光源的能量。负极板为孔板结构,通过引线(17)接高压电源的负极(地)。 In order to achieve the above purpose, the technical solution of the utility model is to provide a composite air purification device that integrates low-temperature plasma, nano-titanium dioxide and dual-band ultraviolet photocatalyst synergistic purification technology and multi-stage filtration. It includes primary filter (1), pin-plate low-temperature plasma generator (2), dual-band ultraviolet lamp (3), high-efficiency filter (4), fan (5), transformer (6), and ballast (7), base (8). The device has an air duct structure, an air-inducing fan (5) is installed at the air outlet, and an air purification device is installed in the air duct. The air composite purification device is divided into three stages of filtration. The device (1) is a combination of six cylindrical primary filters; the second stage is low-temperature plasma, nano-titanium dioxide and dual-band ultraviolet photocatalyst synergistic filtration (2 and 3); the third stage is a high-efficiency filter ( 4). The second-stage filtration is a low-temperature plasma structure, a polymer composite membrane, a nano-titanium dioxide catalytic membrane (15), and a dual-band ultraviolet light lamp (3). Among them, the structure of the low-temperature plasma electrode structure, polymer composite film and nano-titanium dioxide catalytic film (15) is a pin-plate structure, and between the pin-plate electrodes is a nano-titanium dioxide catalytic film (15) with strong oxidative properties. The film (15) is a nano-titanium dioxide film supported on an activated carbon net, and the thickness of the nano-titanium dioxide catalytic film is 2-5 mm. The discharge end of the needle electrode (10) is processed into a needle-point shape and is made of metallic nickel. The negative plate in the low-temperature plasma structure is a hole-shaped electrode made of transparent inorganic glass. Low-temperature plasma electrode structure, polymer composite film and nano-titanium dioxide catalytic membrane structural plate, two structural plates are placed in parallel, and the included angle with the axis of the horizontal air duct is 45°. The two electrode plates are connected to 3kV-5kV high-voltage power supply and ground, and the low-temperature plasma electrode structure, polymer composite film and nano-titanium dioxide catalytic film (2) are installed on the four walls of the air duct through the fixed frame (14); the dual-band ultraviolet The light lamp (3) is long-wave UVA plus short-wave UVC, and is installed in the middle of the air duct; the ballast (7) and transformer (6) are arranged on the outer wall of the device. An electrode with a needle-plate structure, wherein the positive plate is parallel needles evenly arranged on the insulating wire (12), and the needle points point to the negative plate. There is a layer of polymer composite film in front of the negative plate. The polymer composite film is made of polyvinyl fluoride, aromatic It is compounded by polymerizing film of tetra-acid dianhydride, organic silicon and aromatic diamine and mica. The positive pole of the high-voltage power supply is connected through the lead wire (18); the positive plate uses the tip of the needle to discharge, and the discharge needle is arranged on an insulated wire in order to fully utilize the energy of the dual-band ultraviolet light source on the positive side. The negative plate is a hole plate structure, and is connected to the negative pole (ground) of the high-voltage power supply through the lead wire (17). the
本实用新型的原理是:污染有害气体通过针型结构电极时,针型电极进行低温等离子放电,气体分子在低温等离子体中的高能电子碰撞作用下,被打碎形成碎片小分子,紧接着被吸附在光催化材料上,为光催化过程提供一个预富集过程;同时,纳米二氧化钛在低温等离子体放电作用下,可产生大量的氧化能力极强的羟基自由基,它可以快速有效分解空气中的各种有害物质。双波段紫外光透过透明的无机玻璃照射到光催化材料上,发生催化反应,这样就避免了在单纯使用低温等离子体进行净化时容易产生比原分子更大的中间产物的可能,通过低温等离子体激发的光催化作用产生电子-孔穴对气体分子进行氧化还原净化,使得气体分子得到完全降解破坏,同时也使得光催化材料的活性吸附位点实现了原位再生。这样就实现了一个低温等离子体净化-光催化材料吸附和光催化降解-光催化材料活性位点的原位再生。 The principle of the utility model is: when the polluted and harmful gas passes through the needle-shaped structure electrode, the needle-shaped electrode performs low-temperature plasma discharge, and the gas molecules are broken into fragments and small molecules under the impact of high-energy electrons in the low-temperature plasma, and then are Adsorbed on the photocatalytic material to provide a pre-enrichment process for the photocatalytic process; at the same time, under the action of low-temperature plasma discharge, nano-titanium dioxide can generate a large number of hydroxyl radicals with strong oxidation ability, which can quickly and effectively decompose of various harmful substances. The dual-band ultraviolet light shines on the photocatalytic material through transparent inorganic glass, and a catalytic reaction occurs, which avoids the possibility of easily producing intermediate products larger than the original molecule when purely using low-temperature plasma for purification. The bulk-induced photocatalysis generates electron-holes to redox and purify the gas molecules, so that the gas molecules are completely degraded and destroyed, and at the same time, the active adsorption sites of the photocatalytic materials are regenerated in situ. In this way, a low-temperature plasma purification-photocatalytic material adsorption and photocatalytic degradation-photocatalytic material active site regeneration in situ are realized. the
本实用新型的有益效果是:将低温等离子、纳米二氧化钛和双波段紫外光催化触媒协同作用的净化技术相结合,利用活性炭的吸附作用可以使有害气体在催化剂表面浓集到某一特定高浓度,这样就提高了污染物的光催化氧化反应速率,同时活性炭还可以吸附中间副产物使其进一步被光催化氧化,这样可以使吸附在活性炭表面的污染物氧化分解,从而使活性炭达到活性吸附再生的目的。这样既提高了有害气体的去除效率,又延长了活性炭的使用寿命。将低温等离子体技术与纳米二氧化钛和双波段紫外光催化触媒协同技术相结合,高能等离子体除了可以将有害气体氧化分解外,还可以进一步激发催化剂表面产生羟基官能团,彻底提高有害气体的氧化分解能力。 The beneficial effects of the utility model are: combining low-temperature plasma, nano-titanium dioxide and dual-band ultraviolet photocatalyst synergistic purification technology, using the adsorption of activated carbon to concentrate harmful gases on the surface of the catalyst to a specific high concentration, In this way, the photocatalytic oxidation reaction rate of pollutants is improved, and at the same time, activated carbon can also adsorb intermediate by-products to be further photocatalytically oxidized, so that the pollutants adsorbed on the surface of activated carbon can be oxidized and decomposed, so that activated carbon can achieve active adsorption regeneration. Purpose. This not only improves the removal efficiency of harmful gases, but also prolongs the service life of activated carbon. Combining low-temperature plasma technology with nano-titanium dioxide and dual-band ultraviolet photocatalyst synergistic technology, high-energy plasma can not only oxidize and decompose harmful gases, but also further stimulate the surface of the catalyst to generate hydroxyl functional groups, completely improving the ability of oxidative decomposition of harmful gases . the
附图说明 Description of drawings
图1、初效过滤器结构示意图; Figure 1. Schematic diagram of the primary filter structure;
图2、针板式低温等离子体电极结构与催化剂膜侧面的结构示意图; Figure 2. Schematic diagram of the structure of the pin-plate low-temperature plasma electrode and the side of the catalyst membrane;
图3、针板式低温等离子体电极结构与催化剂膜正面的结构示意图; Figure 3. Schematic diagram of the structure of the pin-plate low-temperature plasma electrode and the front of the catalyst membrane;
图4、针板式低温等离子体电极结构与催化剂膜中气流走向示意图; Figure 4. Schematic diagram of the structure of the pin-plate low-temperature plasma electrode and the gas flow in the catalyst film;
图5、复合空气净化装置结构示意图。 Figure 5. Schematic diagram of the composite air purification device.
图5中,1、初效过滤器,2、针板式等温等离子发生器,3、双波段紫外光,4、高效过滤器, 5、引风风机,6、变压器,7、镇流器,8、底座。 In Fig. 5, 1. Primary effect filter, 2. Needle-plate type isothermal plasma generator, 3. Dual-band ultraviolet light, 4. High-efficiency filter, 5. Induced draft fan, 6. Transformer, 7. Ballast, 8 , base. the
图2中,9、固定螺栓,10、针型电极,11、聚合高分子复合膜,12、低温等离子体电极结构中的正极板,13、绝缘线,14、固定框架,15、催化剂膜,16、低温等离子体电极结构中的负极板 17、负极引线、18、正极引线。 In Fig. 2, 9, fixing bolt, 10, needle-shaped electrode, 11, polymer composite film, 12, positive plate in the low-temperature plasma electrode structure, 13, insulating wire, 14, fixed frame, 15, catalyst film, 16. Negative plate in low temperature plasma electrode structure 17. Negative lead wire, 18. Positive lead wire. the
具体实施方式 Detailed ways
如图一所示为复合空气净化装置,风道为矩形风道,污染有害气体经引风风机(5)引入复合净化单元(复合净化单元1为初效过滤器,复合净化单元2为低温等离子、纳米二氧化钛和双波段紫外光催化触媒协同作用的净化结构,复合净化单元3为高效过滤器。)。首先,污染有害气体通过第一级过滤可以去除5μm以上的PM10、大部分焊接粉尘。接着,经过一次过滤的污染有害气体引入第二级过滤,先是在高频脉冲放电条件下,基态气体得到足够大的能量,电离氧化空气中的细菌、病毒、TVOC物质;再接着在光触媒受紫外光波的辐射,被激活产生游离子、电子及空穴,从而分解空气中的一氧化碳、氮氧化物、碳氢化物、醛类、苯及各种有害物质,将它们催化分解还原成环保型无污染的H2O和CO2。最后进入第三级过滤, 此级主要是去除空气0.3μm以上的颗粒灰尘、微生物及各种悬浮物,同时对前几级空气净化装置处理后的副产物进行进一步净化处理。 As shown in Figure 1, it is a composite air purification device, the air duct is a rectangular air duct, and the polluted and harmful gases are introduced into the composite purification unit through the induced draft fan (5) (the composite purification unit 1 is the primary filter, and the composite purification unit 2 is the low-temperature plasma , nano-titanium dioxide and dual-band ultraviolet photocatalyst synergistic purification structure, the composite purification unit 3 is a high-efficiency filter.). First of all, PM10 above 5 μm and most of welding dust can be removed by the first-stage filtration of polluted and harmful gases. Then, the polluted and harmful gases that have been filtered once are introduced into the second stage of filtration. First, under the condition of high-frequency pulse discharge, the ground state gas obtains enough energy to ionize and oxidize bacteria, viruses, and TVOC substances in the air; The radiation of light waves is activated to generate free ions, electrons and holes, thereby decomposing carbon monoxide, nitrogen oxides, hydrocarbons, aldehydes, benzene and various harmful substances in the air, and catalytically decomposing and reducing them into environmentally friendly pollution-free H 2 O and CO 2 . Finally, it enters the third stage of filtration. This stage is mainly to remove particulate dust, microorganisms and various suspended solids above 0.3μm in the air, and at the same time, further purify the by-products after the previous stages of air purification devices.
Claims (10)
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104478034A (en) * | 2014-11-10 | 2015-04-01 | 大连海事大学 | Dual Wave UV-Photocatalytic Treatment Method |
| CN104955258A (en) * | 2014-03-25 | 2015-09-30 | Lg电子株式会社 | Plasma electrode device and method for manufacturing the same |
| CN105042699A (en) * | 2015-08-27 | 2015-11-11 | 成都成实塑胶建材有限公司 | Air supply system for dust-free room |
| CN110793227A (en) * | 2019-04-09 | 2020-02-14 | 山东大学 | A refrigeration system for deep well mining |
| CN115335144A (en) * | 2020-03-24 | 2022-11-11 | 埃芬科有限公司 | Nanoscale ceramic plasma catalysts for stable and assisted plasma combustion |
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2012
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104955258A (en) * | 2014-03-25 | 2015-09-30 | Lg电子株式会社 | Plasma electrode device and method for manufacturing the same |
| US9646806B2 (en) | 2014-03-25 | 2017-05-09 | Lg Electronics Inc. | Plasma electrode device and method for manufacturing the same |
| CN104955258B (en) * | 2014-03-25 | 2017-07-21 | Lg电子株式会社 | Plasma electrode device and its manufacture method |
| CN104478034A (en) * | 2014-11-10 | 2015-04-01 | 大连海事大学 | Dual Wave UV-Photocatalytic Treatment Method |
| CN105042699A (en) * | 2015-08-27 | 2015-11-11 | 成都成实塑胶建材有限公司 | Air supply system for dust-free room |
| CN105042699B (en) * | 2015-08-27 | 2017-07-14 | 成都成实塑胶建材有限公司 | A kind of clean room air supply system |
| CN110793227A (en) * | 2019-04-09 | 2020-02-14 | 山东大学 | A refrigeration system for deep well mining |
| CN115335144A (en) * | 2020-03-24 | 2022-11-11 | 埃芬科有限公司 | Nanoscale ceramic plasma catalysts for stable and assisted plasma combustion |
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