The double light path spectral detection system
Technical field
The utility model relates to field of spectral analysis technology, especially relates to a kind of spectrophotometer, particularly a kind of double light path spectral detection system.
Background technology
Spectrophotometric method is by measuring measured matter Optical Absorption degree in certain wave strong point or certain wavelength coverage, this material being carried out the method for qualitative and quantitative analysis.
In spectrophotometer, when different wave length is shone certain density sample solution continuously, just can obtain the corresponding absorption intensity of unusual wavelength.As take wavelength (λ) as horizontal ordinate, absorption intensity (A) is ordinate, just can draw the absorption spectrum curve of this material.Utilize this curve to carry out qualitative, the quantitative analytical approach of material, be called spectrophotometric method, be also referred to as absorption spectroscopy.Method with ultraviolet source mensuration colourless substance is called ultraviolet spectrophotometry; Method with visible light source mensuration coloring matter is called the visible light photometry.They are the same with colourimetry, all take the Beer-Lambert law as the basis.Above-mentioned ultraviolet region and visible region are commonly used.But the district that should use up of spectrophotometric method comprises ultraviolet region, visible region, infrared light district.
According to lambert (Lambert)-Bill (Beer) law: A=abc, when a beam intensity be the solution of monochromatic light vertical irradiation something of I0 after because a part of light absorbed by system, so the transmission light intensity is down to I, then the transmittance T of solution is:
A is absorbance in the formula, and b is solution layer thickness (cm), and c is the concentration (g/dm^3) of solution, and a is absorptivity.Wherein absorptivity is relevant with the factors such as person's character, temperature and wavelength of solution.Other components in the solution (such as solvent etc.) can be deducted with blank solution Optical Absorption.
By following formula as can be known, when fixed solution layer thickness l and absorptivity, the concentration of absorbance A and solution is linear.When quantitative test, at first need to measure solution to the absorbing state (absorption spectrum) of different wavelengths of light, therefrom determine maximum absorption wavelength, then take the light of this wavelength as light source, measure the absorbance A of a series of concentration known c solution, make A ~ c working curve.When analyzing unknown solution, according to the absorbance A of measuring, look into working curve and can determine corresponding concentration.This is the ultimate principle of metric measurement concentration.
The detecting instrument of existing employing spectrophotometric method, mostly adopt single light source list receiving light path, the advantage of this kind equipment is: principle is clear, light path is succinct, is classical pipeline analytic system, but this system to the inhibition of temperature drift, power-supply fluctuation equal error control ability a little less than.
Summary of the invention
Technical problem to be solved in the utility model is to overcome existing spectrophotometric instrument and has temperature drift, power-supply fluctuation equal error defective, and a kind of double light path spectral detection system that can overcome temperature drift, power-supply fluctuation equal error is provided.
In order to solve the problems of the technologies described above, the technical solution of the utility model is: a kind of double light path spectral detection system, comprise led light source, colorimetric pool and place the first receiver after the described colorimetric pool, it is characterized in that, between described led light source and colorimetric pool, be provided with half anti-semi-permeable mirror, and be provided with the second receiver at the reflected light path of described half-reflecting half mirror.
Preferably, described half-reflecting half mirror and lED light source optical path are 45 degree angles.
Double light path spectral detection system of the present utility model: the light that same light source is launched, a branch of by half-reflecting half mirror, arrive the first receiver through colorimetric pool, another bundle is arrived the second receiver by the half-reflecting half mirror reflection, form two photodetections, the data-signal synchronous acquisition is processed.Half-reflecting half mirror becomes a branch of light source into the two-beam that luminous flux equates, along with the intensity variation of light source, this two-beam Strength Changes is consistent.It sees through light beam I
1
By reaction reagent as measurement light source I
1-1
, its folded light beam I
2
Do not pass through as a setting light value I of reagent
2-2
And reaction finishes, calculate solution reaction absorbance be A=LOG (I
1-1
/ I
2-2
).Because I
1
=I
2
So,, when temperature drift or power supply shakiness cause light source fluctuation, I
1-1
With I
2-2
Change in proportion, so absorbance A is constant.Thereby reach the impact that suppresses temperature drift and power-supply fluctuation.
The utility model has the advantages that:
Double light path spectral detection system of the present utility model: form two photodetections, the data-signal synchronous acquisition is processed, and can well suppress the systematic errors such as temperature drift, power-supply fluctuation.
Description of drawings
Below in conjunction with drawings and Examples the utility model is further described:
Fig. 1 is the utility model double light path spectral detection system one structural representation.
Wherein, 1 is led light source, and 2 is colorimetric pool, and 3 is the first receiver, and 4 is the second receiver, and 5 is half-reflecting half mirror.
Embodiment
Embodiment:
Double light path spectral detection system structural representation of the present utility model comprises led light source as shown in Figure 1, colorimetric pool and place the first receiver after the described colorimetric pool, between described led light source and colorimetric pool, be provided with half anti-semi-permeable mirror, and the reflected light path at described half-reflecting half mirror is provided with the second receiver, and described half-reflecting half mirror and lED light source optical path are 45 degree angles.
The half-reflecting half mirror that uses in the utility model is common commercially available prod.
With the electro-optical system rectification of company's existing CODcr on-line monitoring instrument, by end, with the optical axis miter angle half anti-semi-permeable mirror is installed in original LED light source light path.Transmitted light arrives the first receiver through cuvette, and reflected light directly arrives the second receiver, mode and the computing method of change software reading out data, thus realize the more stable analysis to measure of instrument.
Certainly, above-described embodiment only is explanation technical conceive of the present invention and characteristics, and its purpose is to allow people can understand content of the present invention and implements according to this, can not limit protection scope of the present invention with this.The all Spirit Essence of main technical schemes is done according to the present invention equivalent transformation or modification all should be encompassed within protection scope of the present invention.