CN103499391A - Spectrum measuring system - Google Patents
Spectrum measuring system Download PDFInfo
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- CN103499391A CN103499391A CN201310401610.8A CN201310401610A CN103499391A CN 103499391 A CN103499391 A CN 103499391A CN 201310401610 A CN201310401610 A CN 201310401610A CN 103499391 A CN103499391 A CN 103499391A
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N2201/00—Features of devices classified in G01N21/00
- G01N2201/06—Illumination; Optics
- G01N2201/065—Integrating spheres
Abstract
The invention provides a spectrum measuring system which mainly comprises a power source module, a light chopper, a reference sample module, a reflection module, a sample pool and a photoelectric detecting and processing unit. The power source module is used for generating monochromatic light. The light chopper is used for dividing the monochromatic light produced by the power source module into a path of reference light beam and a path of measuring light. The reference sample module comprises a reference sample pool and an attenuation slice which are arranged on the light path of the reference light in sequence. The reflection module is arranged on the light path of the measuring light so as to change the direction in which the measuring light is irradiated to a sample to be measured, and an included angle is formed between the measuring light irradiated to the sample to be measured and measuring light scattered by the sample to be measured. The sample pool is arranged on the light path of the measuring light emitted from the reflection module and used for bearing the sample to be measured. The photoelectric detecting and processing unit is used for processing the two light beams, and then an extinction spectrum and a scattered spectrum are obtained.
Description
Technical field
The present invention relates to the spectral information fields of measurement, relate in particular to a kind of twin-beam spectral measurement system that is applied to extinction spectra, scattering spectrum and absorption spectrum information measurement.
Background technology
Along with the continuous progress of technology, people improve day by day to the measuring requirement of material extinction spectra information.In many decades in the past, as the spectral measurement field, important scientific research apparatus is widely used spectrophotometer.Existing spectrophotometer mainly contains: single beam, twin-beam and dual wavelength three types.They are widely used in many industries, comprise semiconductor, laser and optics manufacture, and printing and forensic medical examination, and the research of the chemical substance of carrying out in laboratory etc.
Extinction spectra comprises scattering spectrum and absorption spectrum, along with the mankind constantly deepen the research of substance characteristics, it is found that in extinction spectra, scattering spectrum and the absorption spectrum of material and contain a large amount of different information, these information can help people to carry out quantitative test to the composition such as material, and the form of material is carried out to quantitatively calibrating etc.The Multifunctional double-light bundle spectroscopic system of quantitative measurment is carried out respectively in research and development to extinction spectra, scattering spectrum and the absorption spectrum of material, can effectively improve measuring accuracy and resolution, for scientific and technical development and application provide reliable technical guarantee, there is important scientific research and be worth and huge economic worth.
Yet, existing spectrophotometer only can directly be measured reflection, transmission and the fluorescence spectrum of material, therefore only can indirectly obtain the extinction spectra of material, and, existing spectrophotometer can't separate substance absorption spectrum and scattering spectrum, therefore can't carry out the quantitative measurment of absorption spectrum and scattering spectrum.
Summary of the invention
In sum, necessaryly provide a kind of and can measure the especially twin-beam spectral measurement system of scattering spectrum information measurement of extinction spectra.
A kind of spectral measurement system mainly comprises: the light source module, in order to produce monochromatic light; Chopper, be divided into a reference light and in order to the monochromatic light that the light source module is produced and measure light two-way light beam; The reference sample module, comprise that a reference sample pond and an attenuator are set in turn on the light path of described reference light, and described reference sample pond is in order to carry reference sample, and described attenuator is in order to weaken from the reference light of reference sample pond outgoing; The reflection module, be arranged on the light path of described measurement light, to change, measures the direction that light incides testing sample, makes incide the measurement light of testing sample and form an angle from the measurement light of testing sample scattering; Sample cell, be arranged at the light path of the measurement light of described reflection module outgoing, in order to carry testing sample; And photodetection and processing unit, for surveying from the measurement light of sample cell outgoing and from the measurement light of attenuator outgoing, and two-beam is processed, obtain extinction spectra and scattering spectrum.
Compared with prior art, spectral measurement system provided by the invention, utilize reference light and measure the light twin-beam testing sample is measured, and measure by change the direction that light incides testing sample, extinction spectra, scattering spectrum have been realized directly obtaining, and then can derive absorption spectrum, and make measuring result error very little.
The accompanying drawing explanation
The structural representation of the spectral measurement system that Fig. 1 provides for first embodiment of the invention.
The structural representation of the spectral measurement system that Fig. 2 provides for second embodiment of the invention.
The structural representation of the spectral measurement system that Fig. 3 provides for third embodiment of the invention.
The structural representation of the spectral measurement system that Fig. 4 provides for fourth embodiment of the invention.
The main element symbol description
| Spectral measurement system | 100，200，300，400 |
| The light source module | 20 |
| The reference sample module | 30 |
| The reflection module | 40 |
| |
1 |
| |
2 |
| |
3 |
| The reference sample pond | 4 |
| Photodetection and |
5 |
| |
6 |
| The |
7 |
| The second catoptron | 8 |
| Absorption layer | 9 |
| The 3rd catoptron | 10 |
| Polaroid | 11 |
| |
12 |
| |
13 |
| The first fibre- |
14 |
| The second fibre- |
15 |
| |
16 |
| |
17 |
| The first through |
171 |
| The second through |
173 |
| Third through- |
172 |
Following specific embodiment further illustrates the present invention in connection with above-mentioned accompanying drawing.
Embodiment
Describe spectral measurement system provided by the invention in detail below with reference to accompanying drawing.
Refer to Fig. 1, first embodiment of the invention provides a kind of spectral measurement system 100, and described spectral measurement system 100 comprises a light source module 20, chopper 6, reference sample module 30, reflection module 40, sample cell 3 and a photodetection and processing unit 5.The light that described light source module 20 sends, after chopper 6 light splitting, forms two light beams.Wherein a branch of light beam enters photodetection and processing unit 5 through reference sample module 30 is laggard; Another light beam, after 40 reflections of reflection module, enters sample cell 3, through sample cell 3 is laggard, enters photodetection and processing unit 5.
Described light source module 20 is in order to produce monochromatic light, and in the present embodiment, described light source module 20 comprises a light source 1 and a monochromator 2, and the light produced by light source 1 produces monochromatic light through monochromator 2.Described light source module 20 also can be a laser instrument, to produce monochromatic light.
Described chopper 6 is divided into the two-way light beam for the monochromatic light by 20 outputs of light source module, comprises and measures light and reference light.Described two-way light beam can form an angle.In the present embodiment, the direction of propagation of described measurement light is vertical with the direction of propagation of described reference light.The direction of propagation that defines described reference light is directions X, and the direction of propagation of measuring light is Y-direction.
Described reference sample module 30 is arranged on the propagation light path of described reference light, and described reference sample module 30 comprises that a reference sample pond 4 and an attenuator 13 set gradually along the propagation light path of described reference light.Can comprise in described reference sample pond 4 that a cuvette (not shown) is in order to carry reference sample, its concrete shape can be selected according to the concrete form of reference sample.Described attenuator 13, in order to weaken from the reference light of reference sample pond outgoing, its role is to, due to from the testing sample surface scattering scattered light light intensity out very weak, at the same order of magnitude, (approximately do not differ 10 with the light intensity of outgoing reference light from reference sample pond 4
4).Therefore for guarantee that photodetection and processing unit 5 can detect measurement light and the reference light light intensity of input simultaneously, need to increase described attenuator 13, make the reference light that incides photodetection and processing unit 5 and the light intensity of measuring light at the same order of magnitude, when the measurement light received in detection with assurance photodetection and processing unit 5 and reference light light intensity, be operated in same state, i.e. same response time, same gain.
Described reflection module 40 is arranged on the propagation light path of described measurement light, incide the incident direction of sample cell 3 in order to change described measurement light, and in the process of measuring scattering spectrum, make from described sample cell 3 measurement light out form certain angle with the measurement direction of light that incides sample cell 3 and enter into photodetection and processing unit 5, to avoid in the process of measuring scattering spectrum, be directly incident on photodetection and processing unit 5 from the measurement light of chopper 6 outputs, and then affect result of detection.In the present embodiment, described measurement light incides described sample cell 3 along Y-direction, from the scattered light of described sample cell 3 outgoing, along directions X, incide described photodetection and processing unit 5, the angle formed from the described scattered light of described sample cell 3 outgoing and the described measurement direction of light that incides sample cell 3 is 90 °, and resulting scattering spectrum is near the scattering spectrum 90 ° of testing samples.Concrete, described reflection module 40 comprises one first catoptron 7, the second catoptron 8, the 3rd catoptron 10.Described the first catoptron 7, the second catoptron 8 and the 3rd catoptron 10 can all adopt level crossing.From the measurement light of described chopper 6 outgoing after the first catoptron 7, the second catoptron 8 and the 3rd catoptron 10 reflections, along perpendicular to described, with reference to direction of light, entering to inject described sample cell 3.Further, because the light from described monochromator outgoing in described light source module 20 is not proper directional light, the light that therefore incides sample cell 3 has started to disperse and has caused intensity very weak.Therefore described the first catoptron 7, the second catoptron 8 can adopt level crossing, and described the 3rd catoptron 10 can adopt a concave mirror, so that incide the light of sample cell 3, is focused on and strengthens, and then strengthen the light intensity from described sample cell 3 scattered light out.
Described sample cell 3 is in order to carry testing sample, concrete, and described sample cell 3 inside are provided with a cuvette (not shown) with the carrying testing sample.The measurement light of exporting from chopper 6, after 40 reflections of reflection module, incides the testing sample in described sample cell 3.The concrete shape of described sample cell 3 and described cuvette can be selected according to testing sample.
Described photodetection and processing unit 5 are for surveying the measurement light from described sample cell 3 outgoing, and the reference light after 4 outgoing of described reference sample pond process attenuator 13, and are treated to spectral information.The measurement light that final photodetection and processing unit 5 obtain and reference light be output data and collection of illustrative plates through the amplification of oversampling circuit and computer with after processing, and then obtains extinction spectra and scattering spectrum.
Further, owing to measuring light, incide in described sample cell 3 after testing sample, part is measured light and is reflected, and transmits described sample cell 3.For preventing again being reflected back described sample cell 3 from the transmitted light of sample cell 3 outgoing and the scattered light of other directions, described testing sample is formed to rescattering, sample cell 3 surfaces of other directions that can be the direction to be measured of the incident direction except described measurement light, scattered light, absorption layer 9 all is set, to absorb through the transmitted light of sample cell 3 and the unnecessary scattered light of other directions.
Further, for measuring the response of testing sample to different polarization light, can between described the 3rd catoptron 10 and described sample cell 3, a polaroid 11 be set, between described sample cell 3 and described photodetection and processing unit 5, an analyzer 12 be set.Described polaroid 11 is arranged on the light path of the measurement light that incides described sample cell 3, and the light that makes to incide institute's testing sample is polarized light.Described analyzer 12 is arranged at the light path of the measurement light of described sample cell 3 outgoing, and described measurement light light, after analyzer 12, incides in described photodetection and processing unit 50 and analyzed.
The present invention further provides a kind of measuring method of utilizing described spectral measurement system 100 measurement extinction spectras and scattering spectrum, comprise the following steps:
Step S10, calibration spectrum measuring system 100, obtain reference light and measure the light intensity ratio, as benchmark
.
Concrete, the calibration of described spectral measurement system 100 comprises the second catoptron 8, absorption layer 9 analyzers 12 and attenuator 13 is removed, and do not put into any testing sample; Reference light after chopper 6 light splitting and measurement light are directly received by photodetection and processing unit 5.Can directly measure by this method the strength ratio of described reference light and measurement light twin-beam, as benchmark.The expression formula of described benchmark is as follows:
Wherein, I
m0for the measured light intensity that described photodetection and processing unit 5 detect, I
r0the reference light intensity detected for described photodetection and processing unit 5.
Step S20, the transmitance of measurement testing sample
, the extinction spectra of calculating testing sample.
In step S20, because testing sample self can't disperse at sample cell 3 and reference sample pond 4, therefore can be scattered in a solvent by described testing sample or be suspended in a gas.In the present embodiment, described testing sample is distributed in a solvent, and substantially is insoluble to described solvent, forms mixed liquor.Further polaroid 11 is removed, the mixed liquor that will contain testing sample is put into sample cell 3, and described solvent is put into reference sample pond 4 as the reference sample, is measured.The transmitance T of described testing sample (λ) can be expressed as follows:
Wherein, I
m1for the measured light intensity that described photodetection and processing unit 5 detect, I
r1the reference light intensity detected for described photodetection and processing unit 5, and
.The recycling formula
calculate extinction spectra.
Step S30, the mixed liquor that will contain testing sample is arranged in reference sample pond 4 and sample cell 3, and photodetection and processing unit 5 are surveyed and are measured the light light intensity
and reference light light intensity
.
By the second catoptron 8, absorption layer 9, and attenuator 13 be arranged in light path, make after measuring 90 ° of light deflections and enter to inject sample cell 3.Concrete, the mixed liquor that will contain testing sample is placed on respectively in sample cell 3 and reference sample pond 4.Now, the measurement light light intensity that described photodetection and processing unit 5 detect and the strength ratio of described reference light light intensity are:
Wherein,
for the measurement light light intensity that photodetection and processing unit 5 detect, scattered light intensity, described
the reference light light intensity detected for photodetection and processing unit 5.
Wherein, described scattered light intensity
expression formula as follows:
Wherein
be the reflectivity of the second catoptron 8,
be the reflectivity of the 3rd catoptron 10,
be the scattering coefficient of 90 ° of directions,
, r is the distance between testing sample and photodetection and processing unit 5,
the extinction coefficient of the mixed liquor formed for testing sample and described solvent.
For eliminating the extinction coefficient of the mixed liquor that testing sample and described liquid forms
impact, the same mixed liquor that contains testing sample is placed in to reference path, the reference light light intensity that arrives photodetection and processing unit 5 is
, wherein,
transmitance for attenuator 13.?
Step S40, demarcate the reflectivity of the second catoptron 8
, the 3rd catoptron 10 reflectivity
and between testing sample and photodetection and processing unit 5 apart from r, calculate near the scattering spectrum 90 ° of testing samples
.
Testing sample is changed into without the standard model absorbed, repeat the S30 step, described photodetection and processing unit 5 detect measures light light intensity I
s2(λ) and reference light light intensity I
r3(λ), now, measure light light intensity I
s2(λ) and reference light light intensity I
r3(λ) strength ratio is:
Due to
,
Therefore have:
；
That is:
Finally, due to described standard model, without absorption, so its extinction spectra and scattering spectrum overlap fully.Therefore testing sample is changed into without the standard model absorbed, repeat the S20 step, can obtain the extinction spectra of described standard model
thereby, can try to achieve:
Wherein
first element (element of the first row first row) for the Muller matrix (also being the Mueller matrix) of described standard model, can utilize the Mie theory to try to achieve, and is known quantity.Thereby can be in the hope of concentration and the differential scattering of testing sample:
。
By described concentration and differential scattering, can characterize the scattering spectrum of described testing sample.
Spectral measurement system provided by the invention and measuring method, utilize reference light and measure light testing sample is measured, can directly obtain extinction spectra, scattering spectrum, and then can derive absorption spectrum, and light source fluctuation, parasitic light, electronic noise etc. can both be offset the impact of described spectral measurement system and measuring method generation, so the impact of its parasitic light, luminosity noise is all very little, thereby make measuring result error very little.
See also Fig. 2, Fig. 2 provides a kind of spectral measurement system 200, described spectral measurement system 200 is basic identical with described spectral measurement system 100, and its difference is, further comprises one first fibre-optical probe 14, one second fibre-optical probe 15 and a circular slide rail 16.Described the second fibre-optical probe 15 is in order to receive the reference light of 4 outputs from pond, reference sample chamber, and described the second fibre-optical probe 15 is connected to conduct with described photodetection and processing unit 5 reference light detected by optical fiber.Described circular slide rail 16 arranges around described sample cell 3, and further, described sample cell 3 is arranged at the center position of described circular slide rail 16.Described the first fibre-optical probe 14 is arranged on described circular slide rail 16, and can slide along described circular slide rail 16, thereby receives by the measurement light in 360 ° of scopes of testing sample scattering, and imports described photodetection and processing unit 5 by optical fiber transmission.
Further, described polaroid 11 can be arranged on the input path of described measurement light between described the first catoptron 7 and described sample cell 3, and described analyzer 12 can be arranged on the emitting light path of the described measurement light between described sample cell 3 and described the second fibre-optical probe 15.
See also Fig. 3, third embodiment of the invention provides a kind of spectral measurement system 300, the structure of the structure of described spectral measurement system 300 and the described spectral measurement system 300 of the second embodiment is basic identical, and its difference is, described sample cell 3 is arranged in an integrating sphere 17.
Concrete, integrating sphere 17 scribbles the spherical shell of highly reflective coatint for inside surface.Described integrating sphere 17 comprises two the first through hole 171 and the second through holes 173 that relatively run through setting on the incident direction of measuring light, can incide testing sample from described the first through hole 171 so that measure light, and the light transmitted from described sample cell 3 is transmitted from described the second through hole 173, avoid transmitted light to be reflected in integrating sphere 17 and affect the measurement of scattering spectrum.Described the first fibre-optical probe 14 is fixed in any point except described the first through hole 171 and the second through hole 173 on described integrating sphere 17.Further, described integrating sphere 17 comprises a third through-hole 172, and described the first fibre-optical probe 14 is fixed in described third through-hole 172, to receive the measurement light scattered out from testing sample.Described measurement light by described testing sample scattering after, inner through Multi reflections at described integrating sphere 17, enter into described the first fibre-optical probe 14.
Described spectral measurement system 300 can be used for measuring the scattering spectrum in the full solid angle of testing sample.
See also Fig. 4, fourth embodiment of the invention provides a kind of spectral measurement system 400, described spectral measurement system 400 is basic identical with the structure of the spectral measurement system 300 that described the 3rd embodiment provides, and its difference is, described sample cell 3 is arranged on the spherical shell of described integrating sphere 17.
Concrete, described integrating sphere 17 has the first through hole 171 and the second through hole 173 that relatively runs through setting, and described measurement light enters to inject described integrating sphere 17 from the first through hole 171.Described sample cell 3 is arranged in the second through hole 173, from the measurement light of described the first through hole 171 incidents, is directly incident on described sample cell 3.Described measurement light partly transmits described sample cell 3, and another part enters in described integrating sphere 17, after the Multi reflection of integrating sphere 17, enters in described the first fibre-optical probe 14.
Described spectral measurement system 400 can be used for measuring the scattering spectrum in testing sample half solid angle.
In addition, those skilled in the art also can do other and change in spirit of the present invention, and these variations of doing according to spirit of the present invention certainly, all should be included in the present invention's scope required for protection.
Claims (10)
1. a spectral measurement system mainly comprises:
The light source module, in order to produce monochromatic light;
Chopper, be divided into a reference light and in order to the monochromatic light that the light source module is produced and measure light two-way light beam;
The reference sample module, comprise that a reference sample pond and an attenuator are set in turn on the light path of described reference light, and described reference sample pond is in order to carry reference sample, and described attenuator is in order to weaken from the reference light of reference sample pond outgoing;
The reflection module, be arranged on the light path of described measurement light, to change, measures the direction that light incides testing sample, makes incide the measurement light of testing sample and form an angle from the measurement light of testing sample outgoing;
Sample cell, be arranged at the light path of the measurement light of described reflection module outgoing, in order to carry testing sample; And
Photodetection and processing unit, for surveying from the measurement light of sample cell outgoing and from the reference light of attenuator outgoing, and processed two-beam, obtains extinction spectra and scattering spectrum.
2. spectral measurement system as claimed in claim 1, is characterized in that, the reference light that described chopper forms after to described monochromatic light light splitting and to measure the exit direction of light vertical.
3. spectral measurement system as claimed in claim 2, it is characterized in that, described reflection module comprises that one first catoptron, the second catoptron and one the 3rd catoptron set gradually along the emitting light path of described measurement light, from the measurement light of described chopper outgoing after the first catoptron, the second catoptron and the 3rd mirror reflects, along perpendicular to described, with reference to direction of light, inciding described sample cell.
4. spectral measurement system as claimed in claim 3, it is characterized in that, further comprise that a polaroid is arranged on the light path of the measurement light between described the 3rd catoptron and sample cell, one analyzer is arranged at the light path of the measurement light of sample cell outgoing, and is arranged between described sample cell and photodetection and processing unit.
5. spectral measurement system as claimed in claim 3, is characterized in that, described the first catoptron, the second catoptron are level crossing, and described the 3rd catoptron is concave mirror.
6. spectral measurement system as claimed in claim 1, is characterized in that, the reference light that described photodetection and processing unit receive and measurement light are positioned at the same order of magnitude.
7. spectral measurement system as claimed in claim 1, it is characterized in that, further comprise that an absorption layer is arranged at described sample cell surface, to absorb the unnecessary scattered light from the testing sample surface scattering, described absorption layer is arranged at the sample cell surface except the exit direction of the incident direction of measuring light and measurement light.
8. spectral measurement system as claimed in claim 1, it is characterized in that, further comprise one first fibre-optical probe, the second fibre-optical probe and a circular slide rail, described sample cell is arranged at described circular slide rail center position, described the first fibre-optical probe is arranged on described slide rail, and slide along described circular slide rail, acceptance is by the measurement light in 360 ° of scopes of testing sample scattering and pass to into photodetection and processing unit, described the second fibre-optical probe is arranged at the light path of the reference light of reference sample pond outgoing, to receive from the reference light of pond, reference sample chamber output, and export to photodetection and processing unit.
9. spectral measurement system as claimed in claim 1, is characterized in that, described sample cell is arranged in an integrating sphere, and the inside surface of described integrating sphere scribbles the spherical shell of highly reflective coatint; Described integrating sphere comprises the first through hole and the second through hole that relatively runs through setting on the incident direction of measuring light; Described integrating sphere further comprises a third through-hole, one first fibre-optical probe is fixed in the third through-hole of described integrating sphere and receives the measurement light scattered out from testing sample and export to photodetection and processing unit, one second fibre-optical probe is arranged at the light path of the reference light of reference sample pond outgoing, to receive from the reference light of pond, reference sample chamber output, and export to photodetection and processing unit.
10. spectral measurement system as claimed in claim 9, is characterized in that, described sample cell is arranged in the second through hole, and receive the measurement light from the first through hole incident.
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0913171A (en) * | 1994-11-01 | 1997-01-14 | Matsushita Electric Ind Co Ltd | Apparatus for monitoring in-process film thickness therefor |
| CN1338623A (en) * | 2001-10-12 | 2002-03-06 | 周向前 | Miniature biochemical analyzer using dual-spectrum detection |
| CN1542433A (en) * | 2003-08-14 | 2004-11-03 | 中国科学院长春光学精密机械与物理研 | Apparatus for measuring composition and content of solid substance by utilizing near infrared spectra |
| CN1659429A (en) * | 2002-04-09 | 2005-08-24 | 卡斯卡德技术有限公司 | Semiconductor diode laser spectrometer arrangement and method |
| CN1948951A (en) * | 2006-10-13 | 2007-04-18 | 暨南大学 | Apparatus for measuring liquid material component content by near-infrared spectrum |
| CN103063301A (en) * | 2013-01-09 | 2013-04-24 | 浙江大学 | Device and method for detecting plant lamina three-dimensional light distribution |
-
2013
- 2013-09-06 CN CN201310401610.8A patent/CN103499391B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0913171A (en) * | 1994-11-01 | 1997-01-14 | Matsushita Electric Ind Co Ltd | Apparatus for monitoring in-process film thickness therefor |
| CN1338623A (en) * | 2001-10-12 | 2002-03-06 | 周向前 | Miniature biochemical analyzer using dual-spectrum detection |
| CN1659429A (en) * | 2002-04-09 | 2005-08-24 | 卡斯卡德技术有限公司 | Semiconductor diode laser spectrometer arrangement and method |
| CN1542433A (en) * | 2003-08-14 | 2004-11-03 | 中国科学院长春光学精密机械与物理研 | Apparatus for measuring composition and content of solid substance by utilizing near infrared spectra |
| CN1948951A (en) * | 2006-10-13 | 2007-04-18 | 暨南大学 | Apparatus for measuring liquid material component content by near-infrared spectrum |
| CN103063301A (en) * | 2013-01-09 | 2013-04-24 | 浙江大学 | Device and method for detecting plant lamina three-dimensional light distribution |
Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103983434B (en) * | 2014-05-30 | 2016-02-03 | 深圳大学 | Landscape Lighting light source light spectrum reflecting effect appraisal procedure and evaluating system |
| CN103983434A (en) * | 2014-05-30 | 2014-08-13 | 深圳大学 | Method and system for estimating landscape lighting source spectrum reflection luminous efficiency |
| CN104165853A (en) * | 2014-08-29 | 2014-11-26 | 烟台东润仪表有限公司 | Spectroscopy water environment online measuring device |
| CN104833657B (en) * | 2015-01-28 | 2018-03-06 | 水利部交通运输部国家能源局南京水利科学研究院 | With the laser radio sand meter laterally compensated |
| CN104833657A (en) * | 2015-01-28 | 2015-08-12 | 水利部交通运输部国家能源局南京水利科学研究院 | Laser wireless sand meter having side-direction compensation |
| CN104597020A (en) * | 2015-02-02 | 2015-05-06 | 中国科学院光电研究院 | Multifunctional optical material testing device |
| CN104597020B (en) * | 2015-02-02 | 2018-04-27 | 中国科学院光电研究院 | A kind of multifunctional optical material test device |
| CN105158179A (en) * | 2015-06-08 | 2015-12-16 | 苏州谱道光电科技有限公司 | Light source module of analyzer |
| CN105424634A (en) * | 2015-10-29 | 2016-03-23 | 中国计量学院 | Water quality COD detector based on optical fiber coupling ultraviolet light source and prediction model optimization system of water quality COD detector |
| US10983045B2 (en) | 2016-10-11 | 2021-04-20 | Victoria Link Limited | Spectrometer apparatus for measuring spectra of a liquid sample using an integrating cavity |
| CN106841065A (en) * | 2017-01-03 | 2017-06-13 | 中国科学院上海光学精密机械研究所 | Ultraviolet-visible near-infrared transflector spectral measurement device and measuring method |
| CN106841065B (en) * | 2017-01-03 | 2020-09-15 | 中国科学院上海光学精密机械研究所 | Ultraviolet-visible light-near infrared transmission and reflection spectrum measuring device and measuring method |
| US11703388B2 (en) | 2017-01-19 | 2023-07-18 | Agilent Technologies, Inc. | Optical spectrometer modules, systems and methods for optical analysis with multiple light beams |
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| CN109342368A (en) * | 2018-10-24 | 2019-02-15 | 吉林大学 | A kind of two-way measurement of comparison spectrometer and measurement method based on reference optical signal |
| CN109342368B (en) * | 2018-10-24 | 2023-10-20 | 吉林大学 | Dual-path contrast measurement spectrometer based on reference light signals and measurement method |
| CN109444082A (en) * | 2018-12-21 | 2019-03-08 | 天津九光科技发展有限责任公司 | diffuse reflection spectrum measuring device and measuring method |
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