CN202643621U - Graphite intumescent fire retardant coating - Google Patents

Graphite intumescent fire retardant coating Download PDF

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Publication number
CN202643621U
CN202643621U CN 201220092479 CN201220092479U CN202643621U CN 202643621 U CN202643621 U CN 202643621U CN 201220092479 CN201220092479 CN 201220092479 CN 201220092479 U CN201220092479 U CN 201220092479U CN 202643621 U CN202643621 U CN 202643621U
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CN
China
Prior art keywords
fire
coating
retardant coating
layer
graphite
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Expired - Fee Related
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CN 201220092479
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Chinese (zh)
Inventor
王金平
陈景辉
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BEIJING YOUANSHENG FIREPROOF TECHNOLOGY CO LTD
China Academy of Building Research CABR
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BEIJING YOUANSHENG FIREPROOF TECHNOLOGY CO LTD
China Academy of Building Research CABR
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Priority to CN 201220092479 priority Critical patent/CN202643621U/en
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Publication of CN202643621U publication Critical patent/CN202643621U/en
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Abstract

The utility model relates to a graphite intumescent fire retardant coating. Because a high temperature foamed layer in the coating is uniformly provided with an expanded graphite layer and an aqueous resin film layer, the technology deficiencies that conventional coatings will produce large flue are overcome. The fire retardant coating achieves the rapid expansion to form a lightweight carbon layer to retard flame in the fire, does not release toxic gases, and effectively applies the fire protection on base materials. Taking advantage of the self-expanding property by heating of the graphite, the coating is relatively good in durability, so the trouble of fire retardant coating failure in a long time is improved. By using water-based resin film, the cost of the coating is also greatly reduced.

Description

A kind of graphite mould fire-proof dilatation
Technical field
The utility model relates to the fire-retardant material technical field, particularly relates to a kind of graphite mould fire-proof dilatation.
Background technology
Along with high stratification, clustered, the development of industrial large-sizedization and the expansion utilization of organic synthesis material of building, coating is with its good protectiveness and ornamentally give comfortable enjoyment, but the combustibility of most of coating and inflammableness have also been brought disaster hidden-trouble.Therefore developing frie retardant coating becomes more and more important to adapt to security against fire.
Frie retardant coating is divided into expanded polystyrene veneer and Non-expansive fireproof paint by its fire prevention form and moiety.Expanding fire-proof paint is domestic most popular coating, can be divided into water-based and solvent borne expanding fire-proof paint two classes, and wherein, Water-borne inflation type refractory coating accounts for more than 75% of coating of expanded polystyrene veneer fire.Aqueous fire-proof coating cost on the domestic market is low, toxicity is low, it is little to pollute, but humidity resistance is relatively poor, is only applicable to use under the dry environment.Although aqueous fire-proof coating possesses above performance simultaneously on the world market, price is surprisingly high, is not suitable for the development need of China market.In addition, existing frie retardant coating adopts ammonium polyphosphate-tetramethylolmethane-trimeric cyanamide (PCN) type flame-retardant system mostly, although the frie retardant coating fire resistance of this flame-retardant system is better, but weather resistance and water tolerance are relatively poor, when in the environment that directly contacts with water or wet environment, using, the phenomenons such as the easy generation of its fire retardant is water-soluble, saltout cause frie retardant coating to lose efficacy, thereby make coating lose fire prevention usefulness.
Steel construction is as the principal mode of modern architecture, and quality is light, intensity is high because having, and anti-seismic performance is good, short construction period, and the building industrialization degree is high, and space availability ratio is large, reduces investment outlay and is widely applied.The metallic corrosion meeting brings huge financial loss, 30% steel is wherein arranged owing to corrosion has been wasted, and steel construction must the brushing protective system, and the steel structure fire-proof paint indispensable material of steel construction that to be state compulsion carry out.
Steel structure fire-proof paint is divided into solvent-borne type and aqueous dispersion type.At present, the anticorrosion protection of steel structure surface is take solvent-borne type as main, the solvent-borne type protective system mainly uses Resins, epoxy, urethane resin, chloride platform thing, the resol etc. of birdsing of the same feather flock together to be the film forming base-material, both at home and abroad the research of the resin binder of watery anti-corrosion paint mainly concentrated on aqueous silicon, fluoropolymer, aqueous epoxy resins and the waterborne polyurethane resin etc., although these resins have good fire resistance, but exist following deficiency: (1) is that oleoresin or water-base resin thermotolerance are all poor, and is at high temperature easily softening; Wherein relative higher resin such as the Resins, epoxy of fire performance will soften when temperature reaches 180~200 ℃, thermooxidizing occurs decompose, in the time of more than 290 ℃, curable epoxide product main chain can rupture, and resol can only anti-250 ℃ temperature, will soften, come off in case surpass; When generally running into fire, scene of a fire heat can reach 400~500 ℃ through the temperature that fireproofing passes to steel construction finish paint surface, use the frie retardant coating of these resins all can't bear high temperature like this and soften, cause fireproofing to come off from the interface of fireproofing and fireproofing bonding, cause big fire directly in the face of steel construction, cause fire prevention to lose efficacy serious threat people's the security of the lives and property; (2) the solvent-borne type protective system is because containing a large amount of organic solvents, and solvent mostly evaporates in construction and dry process, this not only severe contamination environment and endangered health of people, the significant wastage that also resource is caused simultaneously; (3) the resin cost is high; The cost price of Resins, epoxy, urethane resin etc. is high, and use is restricted.
Steel structure fire-proof paint is the steel structure surface that is applied over building and structures, can form the refractory heat-insulating protective layer to improve the coating of Steel Fire Resistance Rating.Classify by the thickness of coating according to GB14907-2002 " steel structure fire-proof paint ", be divided into thick type, slim and ultrathin.Wherein, thick formed steel construction frie retardant coating used thickness is greater than 7mm and is less than or equal to 45mm; general for the building of fire endurance greater than 2 hours; main component is inorganic thermal insulation material; meet fire and do not expand, the heat absorptivity when it utilizes the uninflammability, low thermal conductiv-ity of material self and material breakdown delays the rising of steel temperature; avoid the physical and mechanical property of steel construction to be destroyed, thus the protection steel building.At present, domestic and international research for thick formed steel construction frie retardant coating mainly concentrates on following four kinds: alkali metal silicate salt coating, silicon sol class coating, phosphoric acid salt coating, cement class coating.
In the prior art; anticorrosion about thick formed steel construction; the report of frie retardant coating aspect seldom; " non expansion type steel structure fire retarding anticorrosion paint " that publication number provides for CN1948404A is comprised of the component of following weight part: base-material 50~60; expanded vermiculite 4~8; mica powder 8~12; hollow float bead 6~10; pearlstone 10~15; aluminium dihydrogen tripolyphosphate 8~14; SiO2 modified barium metaborate 6~9, water 105~115, this coating are a kind of non-expansion type dual-function paints for the steel structure fireproofing corrosionproof protection; but this coating is anticorrosion; waterproof effect is poor; reason is to have adopted a large amount of expanded vermiculites and hollow float bead, and the hole between coating system is many, and moisture and air easily enter and pass coating; cause the generation of the corrosion of steel construction liberation of hydrogen and oxygen uptake corrosion, can't effectively anticorrosion and waterproof.Because there are many difficult problems in anticorrosion of steel structure fire prevention, mainly is the problem that both can not take into account, prepare have simultaneously superior anticorrosion and anticorrosion frie retardant coating fire-proof function is very difficult.
Along with the development of national economy, the rapid growth of steel construction output.Steel construction have intensity high, from heavy and light, the series of advantages such as anti-seismic performance is good, construction speed is fast, the structure area occupied is few, industrialization degree is high, be described as one of 21 century " green building ".According to statistics at present Beijing steel building near 40% of gross building area; the steel building area in Recent Years in Beijing every year is about more than 700 ten thousand square metres; from the fire prevention angle; although steel structure member is non-combustible component; but its resistivity against fire is relatively poor; in general, do not add the fire endurance 15min only of the steel construction of protection, the fire performance that therefore improves steel construction is an important step during steel building is promoted.
Frie retardant coating is the method that the most often adopts in China's steel construction protection, probably has the steel construction about 80% to adopt the frie retardant coating protection, and annual steel structure fire-proof paint is more than 30,000 tons in the Beijing Market usage quantity.The expanding fire-proof paint coating expands charing under flame or high temperature, form the nonflammable spongy carbonaceous layer of large tens times even hundreds of times of original thickness of ratio, to cut off extraneous flame to the heating of base material, plays fireproofing function.
Because its coating is thin; still can give prominence to the U.S. on the steel building art after the coating; therefore be widely used in the flameproof protection of industry and covil construction steel construction; but the expanding fire-proof paint that is applied at present steel construction is oil paint basically; can discharge a large amount of organic gass when its construction and burning; can discharge toxic gas and smog when especially meeting fire; greatly increased the danger coefficient when fire occurs; therefore people are making great efforts the development environmental protection coating material always; reduce as far as possible or avoid because producing; environmental pollution and hazard to person that construction or burning cause; the oil paint cost is also high simultaneously, the waste resource.
The utility model content
The purpose of this utility model provides a kind of graphite mould fire-proof dilatation; this graphite mould fire-proof dilatation halogen-free flame retardants; the thin section steel structure fire-resisting paint that adopts expanded graphite to participate in; this coating utilizes the adsorption of expanded graphite; overcome the technical deficiency part that coating in the past can produce a large amount of flue gases; in fire, can reach rapid expansion form lightweight charcoal layer fire-retardant in, do not discharge toxic gas, effectively base material is carried out flameproof protection.Owing to the character of having utilized graphite to be heated and self to expand, coating itself also has relatively preferably weather resistance, can improve the puzzlement of frie retardant coating failure in a long time simultaneously.By adopting water-base resin, also greatly reduce the cost of coating.
In order to solve the existing problem of background technology, the utility model is by the following technical solutions:
A kind of graphite mould fire-proof dilatation, comprise the binder for substrates main body, it is characterized in that, the binder for substrates main body is provided with the high temperature foaming layer, described high temperature foaming layer is spongy or the reticulated foams charring layer, evenly is provided with expanded graphite layer and water-base resin rete in the described high temperature foaming layer.
Evenly be provided with the expanded graphite powder layer in the described high temperature foaming layer.
Described binder for substrates main body is the water-base resin rete.
It is peripheral that described graphite mould fire-proof dilatation is located at the steel construction main body.
Described graphite mould fire-proof dilatation integral thickness is 2.81mm.
In addition, the utility model uses expansible black lead therein as expanding fire retardant, and with contain the PCN frie retardant coating and comparing aspect thermal destruction, flame retardant properties and the heat-proof quality.The utility model take expansible black lead as main, is produced a class New-type halide-free and eco-friendly expanding fire-proof paint system on the basis of existing PNC system.
The utility model adopts water-base resin to make frie retardant coating, when realizing its fire resistance, reduced the burst size of VOC, when occuring, construction and fire can realize the environmental protection purpose, the adding of this halogen-free flame retardants of expanded graphite has not only improved its expansion multiple, the gas that discharges in the time of simultaneously also can the burning of absorbed portion coating.Utilize the PCN system to realize expanding, some raw material quality guaranteed period crosses the frie retardant coating expansion character and descends to some extent after several years, self has expansion character expanded graphite, effectively throughout the year, its adding can improve the character that frie retardant coating relies on chemical reaction to expand fully, improve coating durability, can also reduce cost.Expansible black lead uses as expanding fire retardant therein, and with contain the PCN frie retardant coating and comparing aspect thermal destruction, flame retardant properties and the heat-proof quality, on the basis of existing PCN system, adopting expansible black lead and new inorganic material is raw material, and the New-type halide-free of preparing and eco-friendly expanding fire-proof paint system are functional.
Advantage of the present utility model and benefit are:
This coating checks its state, surface drying time, initial dry cracking resistance, water tolerance, freeze-thawing resistant cyclicity, outward appearance and color in container all to meet national standard by GB 14907-2002 " steel structure fire-proof paint general technical specifications ".
Detect fire performance by GBPT 14907-2002 " building slab fire testing method " in addition thick by national building engineering quality supervision central horizontal member fire testing detection 2.81mm, fire endurance is 63min, its cohesive strength is 0.48Mpa, all is up to state standards.
And prolonged product work-ing life, effectively avoided environmental pollution.
Reduce flue gas and toxicity hazard that present frie retardant coating produces in fire, set up the frie retardant coating new system, transform to the non-toxic, environmental friendly direction.
Improve the weather resistance of frie retardant coating.
Reduce the comprehensive cost of frie retardant coating.
Description of drawings
Fig. 1 is the structural representation of a kind of graphite mould fire-proof dilatation of the present utility model.
Wherein: 1 is binder for substrates; 2 is expanded graphite layer.
Embodiment
Below in conjunction with embodiment, further set forth the utility model.
Embodiment 1:
As shown in Figure 1, a kind of graphite mould fire-proof dilatation, comprise the binder for substrates main body, it is characterized in that, the binder for substrates main body is provided with the high temperature foaming layer, described high temperature foaming layer is spongy or the reticulated foams charring layer, evenly is provided with expanded graphite powder layer and water-base resin rete in the described high temperature foaming layer; Described binder for substrates main body is the water-base resin rete.
Embodiment 2:
As shown in Figure 1, a kind of graphite mould fire-proof dilatation, this coating is the waterborne thin fire retardant coating for steel structure that the halogen-free flame retardants expanded graphite participates in, comprise the binder for substrates main body, it is characterized in that, the binder for substrates main body is provided with the high temperature foaming layer, and described high temperature foaming layer is spongy or the reticulated foams carbonaceous layer, evenly is provided with expanded graphite powder layer and water-base resin rete in the described high temperature foaming layer.
Embodiment 3:
As shown in Figure 1, a kind of graphite mould fire-proof dilatation, comprise the binder for substrates main body, it is characterized in that, the binder for substrates main body is provided with the high temperature foaming layer, described high temperature foaming layer is spongy or the reticulated foams charring layer, evenly is provided with expanded graphite powder layer and water-base resin rete in the described high temperature foaming layer, and it is peripheral that described graphite mould fire-proof dilatation is located at the steel construction main body.
Embodiment 4:
As shown in Figure 1; a kind of graphite mould fire-proof dilatation; this frie retardant coating adopts water-based emulsion; choose the novel inorganic fire retardant; overcome in the past that the coating flue gas is large, the bad weak point of weather resistance; when the formation lightweight that expands rapidly charcoal layer is fire-retardant, do not discharge toxic gas in fire, can effectively carry out flameproof protection to base material.
Embodiment 5:
As shown in Figure 1, a kind of graphite mould fire-proof dilatation, comprise the binder for substrates main body, it is characterized in that, the binder for substrates main body is provided with the high temperature foaming layer, described high temperature foaming layer is spongy or the reticulated foams charring layer, evenly is provided with expanded graphite powder layer and water-base resin rete in the described high temperature foaming layer, and described graphite mould fire-proof dilatation integral thickness is 2.81mm.
In addition, the utility model is developed a kind of waterborne thin fire retardant coating for steel structure that is participated in by novel halogen-free flame-retardant agent expanded graphite, and this coating adopts water-based emulsion to make, and improves coating property, has improved the frie retardant coating cost performance.
Steel building is more and more at present; its flameproof protection is by aobvious important; and frie retardant coating is in the majority with oiliness at present, and to environment, the utility model is by selecting novel halogen-free flame retardants; produce aqueous fire-proof coating; its fire performance is good, and environmentally safe, and has changed the poor present situation of the ubiquitous ageing resistance of existing frie retardant coating; because all adopt domestic common raw material of easily buying, cost has also had certain reduction.
The prescription of water-based mono-component is so that production, transportation, storage, easy construction, and cheap, production technique is simple, less investment, and income is large, and especially frie retardant coating manufacturer does not need existing equipment is transformed, and namely can put into production.
The coating of this utility model manufacturing has used Beijing friend's AXA fireproofing technique company limited existing equipment to carry out production, do not need repacking, matching capacity is good, the production line normal operation, utility model achievement production cost is relatively low, but fire performance is more outstanding, is up to state standards, and therefore has very outstanding popularizing application prospect.Good through the engineering effect, for enterprise has created good economic benefit, for the frie retardant coating industry provides a kind of new technology, produce the good frie retardant coating of cost performance, start the new producer of frie retardant coating to, make frie retardant coating to the non-toxic, environmental friendly future development, also improved simultaneously the competitive power of product on market, for enterprise and country bring objective economic benefit, met the trend of society Sustainable development.
Through evidence, the utility model Application Areas is very extensive, and effect is excellent.

Claims (4)

1. graphite mould fire-proof dilatation, comprise the binder for substrates main body, it is characterized in that, the binder for substrates main body is provided with the high temperature foaming layer, described high temperature foaming layer is spongy or the reticulated foams carbonaceous layer, evenly is provided with expanded graphite layer and water-base resin rete in the described high temperature foaming layer.
2. graphite mould fire-proof dilatation according to claim 1, described binder for substrates main body is the water-base resin rete.
3. it is peripheral that graphite mould fire-proof dilatation according to claim 1, described graphite mould fire-proof dilatation are located at the steel construction main body.
4. graphite mould fire-proof dilatation according to claim 1, described graphite mould fire-proof dilatation integral thickness is 2.81mm.
CN 201220092479 2012-03-13 2012-03-13 Graphite intumescent fire retardant coating Expired - Fee Related CN202643621U (en)

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Application Number Priority Date Filing Date Title
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10941566B2 (en) 2016-05-09 2021-03-09 Tremco Illbruck Produktion Gmbh Fireproofing strip

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10941566B2 (en) 2016-05-09 2021-03-09 Tremco Illbruck Produktion Gmbh Fireproofing strip

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GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20130102

Termination date: 20140313