CN202601618U - Integral solar power generation and luminescence template - Google Patents
Integral solar power generation and luminescence template Download PDFInfo
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- CN202601618U CN202601618U CN 201220221951 CN201220221951U CN202601618U CN 202601618 U CN202601618 U CN 202601618U CN 201220221951 CN201220221951 CN 201220221951 CN 201220221951 U CN201220221951 U CN 201220221951U CN 202601618 U CN202601618 U CN 202601618U
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Abstract
The utility model relates to an integral solar power generation and luminescence template and belongs to the technical field of solar photovoltaic. The integral solar power generation and luminescence template is mainly technically characterized in that a transparent anode layer I, a hole transport layer I, a functional layer I, an electronic transmission layer I, a cathode layer I, an electronic transmission layer II, a functional layer II, a hole transport layer II and a transparent anode layer II are sequentially laminated on a substrate to form an integral power generation and luminescence template, the power generation element and the luminescence element of the template share one cathode layer, the shared cathode and the anode of the power generation element are connected with the input end of a controller, and the output end of the controller is connected with the shared cathode and the anode of the luminescence element. The integral solar power generation and luminescence template provided by the utility model is only packed on single surface, thereby reducing the packing material, the packing process and the weight of the whole assembly, and the cost is low as a result.
Description
Technical field
The utility model relates to the integrated template of a kind of solar electricity-generating and light-emitting; Integrated template and manufacturing approach thereof with electricity-generating and light-emitting function that particularly a kind of organic solar batteries (OPVC) combines with Organic Light Emitting Diode (OLED) belong to the solar-photovoltaic technology field.
Background technology
Along with the development of solar-photovoltaic technology and the expansion of application; Make people also increasingly high to the solar cell application requirement of products; Originally adopting mostly divides the photovoltaic application product of body structure also more and more to trend towards integrated; The integrated mould plate technique of the electricity-generating and light-emitting that solar cell combines with illumination component is also more and more, and Chinese patent 201110119329.6 " photovoltaic light-emitting integrated apparatus and application process thereof " discloses the integrated mould plate technique scheme of electricity-generating and light-emitting of a kind of inorganic solar cell and light-emitting diode (LED), LED is arranged on the edge of solar panel; Realized that generating combines with the effective of lighting function; Chinese patent 200920256347.7 " solar plane light-emitting device " discloses the integrated mould plate technique scheme of electricity-generating and light-emitting of a kind of inorganic thin film solar cell and Organic Light Emitting Diode (OLED), with the two sides that inorganic thin film solar cell and OLED are deposited on glass substrate respectively, has realized that equally generating combines with the effective of lighting function; But present two kinds of technical schemes are all because processing technology is comparatively complicated; Make manufacturing cost higher, hindered the application of its industrialization, along with the technical research of organic solar batteries; It can be through printing or the processing technology that applies; Making manufacturing cost reduce becomes possibility, and the structural similarity of organic solar batteries and OLED makes it combine to use the prospect that has more simultaneously.
Summary of the invention
Deficiency to above prior art; The purpose of the utility model is luminous template of integrated power generation and the manufacturing approach thereof that a kind of organic solar batteries of design (OPVC) combines with Organic Light Emitting Diode (OLED); Solve the technical problem that how OPVC is combined with OLED, with simplified manufacturing technique, reduce production costs.
The technical scheme that the utility model adopts: OPVC and OLED are printed successively or be coated on the same one side of glass substrate, because the structure of OPVC and OLED all comprises negative electrode and anode, so can common cathode in the junction; When common cathode during as the negative electrode of OPVC; OLED is an off-state, and the power supply of OPVC generating accumulators is when common cathode during as the negative electrode of OLED; OLED is an on-state; Storage battery is given the OLED power supply light emitting, can make OPVC earlier in glass substrate and make OLED again, also can make OLED earlier and make OPVC again.
The integrated template of the described solar electricity-generating and light-emitting of the utility model; Be on substrate, to stack gradually transparent anode layer I, hole transmission layer I, functional layer I, electron transfer layer I, cathode layer, electron transfer layer II, functional layer II, hole transmission layer II and transparent anode layer II; Forming the collection electricity-generating and light-emitting is the template of one; The shared cathode layer of the generating element of this template and light-emitting component; The anode of this common cathode and generating element is connected the input of controller, the output termination common cathode of controller and the anode of light-emitting component.
Generating element is an organic solar batteries, and light-emitting component is an Organic Light Emitting Diode.
When functional layer I was the luminescent layer of Organic Light Emitting Diode, functional layer II was the photoactive layer of organic solar batteries.
When functional layer I was the photoactive layer of organic solar batteries, functional layer II was the luminescent layer of Organic Light Emitting Diode.
The thickness of common cathode layer, transparent anode layer I and transparent anode layer II is 100 ~ 500nm.
Hole transmission layer I and hole transmission layer II are processed by identical or different material, and its thickness is 40 ~ 80 nm.
Electron transfer layer I and electron transfer layer II are processed by identical or different material, and its thickness is 40 ~ 80 nm.
The gross thickness of the photoactive layer of generating element is 100 ~ 200 nm.
The gross thickness of the luminescent layer of light-emitting component is 100 ~ 200 nm.
Template is encapsulated by back-panel glass, and the anode of generating element and light-emitting component leads to the outside of back-panel glass by conductive strips.
Transparent anode layer I and transparent anode layer II can be processed by identical or different material, and material is preferably ITO, AZO, FTO etc.
Cathode layer can be the metallic diaphragm of low work function, like Al, Ca, Ba etc.
Hole transmission layer I and hole transmission layer II can be by NPB, TPD, TCTA, PEDOT:PSS, Cu
2O, NiO, MoO
3, V
2O
5And WO
3Deng in a kind of material process.
Electron transfer layer I and electron transfer layer II can be by Alq
3, PBD, TAZ, OXD-7, DPVBi, Beq
2, LiF, TiOx, ZnO and SnO
2Deng in a kind of material process.
The photoactive layer of generating element is the mixture of organic donor material and acceptor material, and organic donor material is polythiophene and derivative thereof as gathering one or more the mixture in (3-hexyl) thiophene, phthalocyanine dye, the inferior ethene of polyparaphenylene and derivative thereof, pentacene, the porphyrin compound cyanine dyes; The organic electronic acceptor material is the fullerene or derivatives thereof.
The luminescent layer of light-emitting component is different according to application requirements, can realize emitting red light, green emitting, blue-light-emitting, white luminous; Luminescent layer is monochromatic luminous can be that luminous, the dye adulterated main body luminescent material of main body luminescent material is luminous, and wherein white luminous can be the mixed luminescence of several kinds of luminescent materials of red, green, blue, or single kind white light material is luminous;
The luminescent layer main body luminescent material of light-emitting component can be the derivative of classes such as aromatic amine, diazole, thiazole, cumarin, pyrazine, 1,3-butadiene etc.; Dyestuff can be fluorescent dye, phosphorescent coloring, organometallic complex class etc.; Fluorescent dye can be coumarin 6, rhodamine class dyestuff, rubrene class, N-aromatic radical benzimidazole, 1, the derivative of 3-4-oxadiazole, two stilbene classes etc.; Phosphorescent coloring can be the organic coordination compound of heavy metals such as iridium, platinum etc.; Organometallic complex can be quinolines complex compound, Schiff bases complex compound, rare-earth chelates etc.
Single to plant white light emitting material be the polymeric material that contains three kinds of luminophores of red, green, blue, can be poly (phenylenevinylene) (PPV) class, polythiophene class, gathers oh diazoles, poly-triphenylamine class, poly alkyl fluorene class, gathers benzene (PPP) type, the inferior acetylene of polyparaphenylene (PPE) type, polypyrrole (PPY) type, gather pyridine vinylene (PPYV) type, polyvinylcarbazole (PVK) class etc.
Each rete of the integrated template of the described solar electricity-generating and light-emitting of the utility model can adopt printing, coating or sputter to form.
When functional layer I was the luminescent layer of Organic Light Emitting Diode, cathode layer, electron transfer layer II, functional layer II, hole transmission layer II, transparent anode layer II all need carry out the processing of rete merogenesis intraconnected.
When functional layer I was the photoactive layer of organic solar batteries, transparent anode layer I, hole transmission layer I, functional layer I, electron transfer layer I, cathode layer all need adopt laser grooving and scribing or mask processing method to carry out the processing of rete merogenesis intraconnected.
The good effect that the utility model produces: the integrated template of solar electricity-generating and light-emitting is processing organic solar batteries and an Organic Light Emitting Diode on the same one side of glass substrate; Only need carry out the single face encapsulation; Can reduce the weight of encapsulating material, packaging technology and whole assembly, cost is low.Generating element and light-emitting component common cathode can reduce rete quantity, simplify processing step.
Description of drawings
Fig. 1: the cross-sectional view of the utility model.
Fig. 2: the cross-sectional view of the embodiment one of the utility model.
Fig. 3: the cross-sectional view of the embodiment two of the utility model.
Among the figure: 1, glass substrate, 201, transparent anode layer I, 202, hole transmission layer I; 203, functional layer I, 204, electron transfer layer I, 205, cathode layer; 206, electron transfer layer II, 207, functional layer II, 208, hole transmission layer II; 209 transparent anode layer II, 3, transparent adhesive film, 4, glass back plate.
Embodiment
Embodiment one:
After making OPVC earlier on the glass substrate 1, make OLED.
As shown in Figure 2, transparent anode layer I201 is the anode of OPVC, and material is ITO, and hole transmission layer I202 is the hole transmission layer of OPVC; Material is PEDOT:PSS, and functional layer I203 is the photoactive layer of OPVC, and material is the mixture of P3HT:PCBM, and electron transfer layer I204 is the electron transfer layer of OPVC; Material is ZnO, and cathode layer 205 is the common cathode of OPVC and OLED, and material is Al, and electron transfer layer II206 is the electron transfer layer of OLED; Material is PBD, and functional layer II207 is the luminescent layer of OLED, and material is the PPV class; Hole transmission layer II208 is the hole transmission layer of OLED, and material is TPD, and transparent anode layer II209 is the anode of OLED; Material is ITO, and the cathode layer 205 of common cathode is guided to the transparent anode layer II209 of OLED, respectively at the transparent anode layer I201 of OPVC and the transparent anode layer II209 layer welding extraction electrode band of OLED; And be drawn out to back-panel glass 4 outsides, by transparent adhesive film 3 sealed package, the transparent anode layer I201 of OPVC and common cathode layer 205 are received the input of controller; The accumulators power supply, the output that the transparent anode layer II209 layer of OLED and common cathode layer 205 are received controller is by storage battery power supply.
Embodiment two:
After making OLED earlier on the glass substrate 1, make OPVC.
As shown in Figure 3, transparent anode layer I201 is the anode of OLED, and material is AZO; Hole transmission layer I202 is the hole transmission layer of OLED, and material is NPB, and functional layer I203 is the luminescent layer of OLED; Material is the PVK class, and electron transfer layer I204 is the electron transfer layer of OLED, and material is Alq
3, cathode layer 205 is the common cathode of OPVC and OLED, material is Al; Electron transfer layer II206 is the electron transfer layer of OPVC; Material is TiOx, and functional layer II207 is the photoactive layer of OPVC, and material is the mixture of P3HT:PCBM; Hole transmission layer II208 is the hole transmission layer of OPVC, and material is WO
3, transparent anode layer II209 is the anode of OPVC, material is FTO; The cathode layer 205 of common cathode is guided to the transparent anode layer II209 of OPVC; Weld the extraction electrode band at the transparent anode layer I201 of OLED and the transparent anode layer II209 layer of OPVC respectively, and be drawn out to back-panel glass 4 outsides, by transparent adhesive film 3 sealed package; The transparent anode layer I201 of OPVC and common cathode layer 205 are received the input of controller; The accumulators power supply, the output that the transparent anode layer II209 layer of OLED and common cathode layer 205 are received controller is by storage battery power supply.
The solar energy luminous generating integrated template of the utility model design can be used as construction material, supplies uses such as indoor or garden lamp illumination.
Claims (10)
1. integrated template of solar electricity-generating and light-emitting; It is characterized in that: on substrate, stack gradually transparent anode layer I, hole transmission layer I, functional layer I, electron transfer layer I, cathode layer, electron transfer layer II, functional layer II, hole transmission layer II and transparent anode layer II; Forming the collection electricity-generating and light-emitting is the template of one; The shared cathode layer of the generating element of this template and light-emitting component; The anode of this common cathode and generating element is connected the input of controller, the output termination common cathode of controller and the anode of light-emitting component.
2. the integrated template of solar electricity-generating and light-emitting according to claim 1 is characterized in that said generating element is an organic solar batteries, and light-emitting component is an Organic Light Emitting Diode.
3. the integrated template of solar electricity-generating and light-emitting according to claim 1 is characterized in that said functional layer I is the luminescent layer of Organic Light Emitting Diode, and functional layer II is the photoactive layer of organic solar batteries.
4. the integrated template of solar electricity-generating and light-emitting according to claim 1 is characterized in that said functional layer I is the photoactive layer of organic solar batteries, and functional layer II is the luminescent layer of Organic Light Emitting Diode.
5. the integrated template of solar electricity-generating and light-emitting according to claim 1 is characterized in that the thickness of said common cathode layer, transparent anode layer I and transparent anode layer II is 100 ~ 500nm.
6. the integrated template of solar electricity-generating and light-emitting according to claim 1 is characterized in that said hole transmission layer I and hole transmission layer II are processed by identical or different material, and its thickness is 40 ~ 80 nm.
7. the integrated template of solar electricity-generating and light-emitting according to claim 1 is characterized in that said electron transfer layer I and electron transfer layer II are processed by identical or different material, and its thickness is 40 ~ 80 nm.
8. the integrated template of solar electricity-generating and light-emitting according to claim 2, the gross thickness that it is characterized in that the photoactive layer of said generating element is 100 ~ 200 nm.
9. the integrated template of solar electricity-generating and light-emitting according to claim 2, the gross thickness that it is characterized in that the luminescent layer of said light-emitting component is 100 ~ 200 nm.
10. the integrated template of solar electricity-generating and light-emitting according to claim 1 is characterized in that said template is encapsulated by back-panel glass, and the anode of generating element and light-emitting component leads to the outside of back-panel glass by conductive strips.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201220221951 CN202601618U (en) | 2012-05-17 | 2012-05-17 | Integral solar power generation and luminescence template |
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|---|---|---|---|
| CN 201220221951 CN202601618U (en) | 2012-05-17 | 2012-05-17 | Integral solar power generation and luminescence template |
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| CN 201220221951 Expired - Lifetime CN202601618U (en) | 2012-05-17 | 2012-05-17 | Integral solar power generation and luminescence template |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105042390A (en) * | 2015-06-24 | 2015-11-11 | 苏州佳亿达电器有限公司 | Foldable LED lamp band based on solar cell panel |
| CN105156933A (en) * | 2015-06-24 | 2015-12-16 | 苏州佳亿达电器有限公司 | LED strip based on solar cell panels and capable of changing color at different temperatures |
-
2012
- 2012-05-17 CN CN 201220221951 patent/CN202601618U/en not_active Expired - Lifetime
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105042390A (en) * | 2015-06-24 | 2015-11-11 | 苏州佳亿达电器有限公司 | Foldable LED lamp band based on solar cell panel |
| CN105156933A (en) * | 2015-06-24 | 2015-12-16 | 苏州佳亿达电器有限公司 | LED strip based on solar cell panels and capable of changing color at different temperatures |
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| Date | Code | Title | Description |
|---|---|---|---|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CX01 | Expiry of patent term | ||
| CX01 | Expiry of patent term |
Granted publication date: 20121212 |