CN202594894U - Device for treating methanol wastewater by using ultrasonic wave and ozone - Google Patents
Device for treating methanol wastewater by using ultrasonic wave and ozone Download PDFInfo
- Publication number
- CN202594894U CN202594894U CN 201220243029 CN201220243029U CN202594894U CN 202594894 U CN202594894 U CN 202594894U CN 201220243029 CN201220243029 CN 201220243029 CN 201220243029 U CN201220243029 U CN 201220243029U CN 202594894 U CN202594894 U CN 202594894U
- Authority
- CN
- China
- Prior art keywords
- water
- pipeline
- packed bed
- outlet
- rotary packed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 title claims abstract description 108
- 239000002351 wastewater Substances 0.000 title claims abstract description 34
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 title claims abstract description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 76
- 230000003197 catalytic effect Effects 0.000 claims abstract description 22
- 238000002604 ultrasonography Methods 0.000 claims description 13
- 239000000945 filler Substances 0.000 claims description 4
- 238000007254 oxidation reaction Methods 0.000 abstract description 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract description 3
- 230000003647 oxidation Effects 0.000 abstract description 3
- 230000000694 effects Effects 0.000 abstract description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 abstract 1
- 239000001569 carbon dioxide Substances 0.000 abstract 1
- 230000002195 synergetic effect Effects 0.000 abstract 1
- 239000007789 gas Substances 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000003911 water pollution Methods 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000011089 carbon dioxide Nutrition 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 230000001351 cycling effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
Images
Landscapes
- Treatment Of Water By Oxidation Or Reduction (AREA)
- Physical Water Treatments (AREA)
Abstract
Ultrasonic wave cooperates with ozone treatment methyl alcohol effluent plant, is applied to oil gas field methyl alcohol effluent treatment. The water pipe for methanol wastewater to enter is connected with a centrifugal pump, and the other end of the water pipe for methanol wastewater to enter is connected with the top of the rotary packed bed; the outlet of the ozone generator is connected with the lower part of the rotary packed bed by a pipeline, the water outlet at the bottom of the rotary packed bed is connected with the inlet of the ultrasonic reactor by a pipeline, the water outlet of the ultrasonic reactor is connected with the water inlet at the upper part of the catalytic circulation water tank, the lower part of the catalytic circulation water tank is connected with a circulation pipeline, the circulation pipeline is provided with a circulation valve, and the other end of the circulation pipeline is connected with the inlet end pipeline of the centrifugal pump; the lower part of the catalytic circulation water tank is fixed with a water outlet pipeline, and the water outlet pipeline of the catalytic circulation water tank is connected with a water outlet control valve. The effect is as follows: the wastewater is adsorbed by utilizing the synergistic effect of catalytic oxidation, ultrasonic waves and ozone, so that methanol in the wastewater is oxidized into water and carbon dioxide.
Description
Technical field
The utility model relates to fld production gas technology field, and the treatment unit of the lower concentration methanol waste water in particularly a kind of gas production is the device that a kind of supersonic wave cooperating with ozone is handled methanol waste water.
Background technology
Fast development along with petrochemical enterprise; The present residing environment of people progressively worsens, and the water resources that has cleaning has become the life-and-death big problem of the universe, solves water pollution problem; Will produce far-reaching influence to Human's production and life, benefit the universe.But fld will add methyl alcohol usually and serve as stopping agent in the process of gas production, in order to suppress the generation of hydrate in the Sweet natural gas.Be attended by a large amount of gas field methanol waste waters and produce, demand urgently handling.
The utility model content
The purpose of the utility model is: provide a kind of supersonic wave cooperating with ozone to handle the methanol waste water device, remove methyl alcohol in the methanol waste water of gas field with supersonic wave cooperating with ozone, solve water pollution problems.
The technical scheme that the utility model adopts is: supersonic wave cooperating with ozone is handled the methanol waste water device, comprises catalytic chain water tank, impeller pump, rotary packed bed, ultrasound reactor and ozonizer.It is characterized in that: on the water pipe that methanol waste water gets into, water inlet control valve is housed, is connected with impeller pump on the water pipe that methanol waste water gets into, the water pipe the other end that methanol waste water gets into is connected rotary packed bed top; Filler is arranged tubular in rotary packed bed, the gas outlet is arranged at rotary packed bed top; The outlet of ozonizer connects rotary packed bed bottom by pipeline; The water outlet of rotary packed bed bottom is connected the inlet of ultrasound reactor by pipeline; The water outlet of ultrasound reactor connects the water-in of catalytic chain water tank upper; The bottom of catalytic chain water tank is connected with circulation line, and recycle valve is arranged on the circulation line, and the other end of circulation line is connected with the entrance end pipeline of impeller pump; Be fixed with the water outlet pipeline in the bottom of catalytic chain water tank, be connected with outlet water control valve on the water outlet pipeline of catalytic chain water tank;
What described water inlet control valve, recycle valve and outlet water control valve adopted is solenoid electric valve.
The summary supersonic wave cooperating with ozone is handled the principle of work of methanol waste water device.Consult Fig. 1.Methanol waste water at first gets into impeller pumps 3 through water inlet control valve 2, inject through impeller pump 3 rotary packed bed 4, methanol waste water and ozone counter current contact; Methanol waste water flows out from rotary packed bed 4 bottoms and gets into the ultrasound reactor 5; Well ultrasonic oxidation reaction back gets into the reaction of catalytic chain water tank, and when cistern water level reaches one regularly, water inlet control valve is closed automatically; Recycle valve 9 is opened, and the water behind the catalytic oxidation injects rotary packed bed 4 by impeller pump 3; After the cycling time that reaches setting, (set) by treatment effect, outlet water control valve 10 opening water discharges, after the water tank emptying, outlet water control valve 10 is closed with recycle valve 9, and water inlet control valve 2 is opened, and gets into next handling procedure.
The beneficial effect of the utility model: the utility model supersonic wave cooperating with ozone is handled the methanol waste water device; Utilize catalyzed oxidation, UW and ozone three synergy; Waste water is carried out adsorption treatment; Make the methyl alcohol in the waste water be oxidized to water and carbonic acid gas, it is low to handle the methanol waste water expense, and efficient is high.
Description of drawings
Fig. 1 is that the utility model supersonic wave cooperating with ozone is handled methanol waste water apparatus structure synoptic diagram.
Among the figure, 1-catalytic chain water tank, the 2-water inlet control valve, the 3-impeller pump, 4-is rotary packed bed, 5-ultrasound reactor, the outlet of 6-gas, 7-filler, 8-ozonizer, 9-recycle valve, 10-outlet water control valve.
Embodiment
Embodiment 1: handling the methanol waste water device with a supersonic wave cooperating with ozone is example, and the utility model is done further explain.
Consult Fig. 1.The utility model supersonic wave cooperating with ozone is handled the methanol waste water device, comprises catalytic chain water tank 1, impeller pump 3, rotary packed bed 4, ultrasound reactor 5 and ozonizer 8.Rotary packed bed 4 model: CQCT-100.The model of ultrasound reactor 5: JAC-2500.The model of ozonizer 8: BNP-SOZ-100G.Rotary packed bed 4, ultrasound reactor 5 and ozonizer 8 are currently available productss.
On the water pipe that methanol waste water gets into, water inlet control valve 2 is housed, is connected with an impeller pump 3 on the water pipe that methanol waste water gets into, the water pipe the other end that methanol waste water gets into is connected rotary packed bed 4 top.In tubular rotary packed bed 4, filler 7 is arranged, gas outlet 6 is arranged at rotary packed bed 4 top.The outlet of ozonizer 8 is connected rotary packed bed 4 bottom by pipeline; The water outlet of rotary packed bed 4 bottoms is connected the inlet of ultrasound reactor 5 by pipeline; The water outlet of ultrasound reactor 5 connects the water-in on catalytic chain water tank 1 top; The bottom of catalytic chain water tank 1 is connected with circulation line, and recycle valve 9 is arranged on the circulation line, and the other end of circulation line is connected with the entrance end pipeline of impeller pump 3.Be fixed with the water outlet pipeline in the bottom of catalytic chain water tank 1, be connected with outlet water control valve 10 on the water outlet pipeline of catalytic chain water tank 1.What water inlet control valve 2, recycle valve 9 and outlet water control valve 10 adopted is solenoid electric valve.
Claims (2)
1. a supersonic wave cooperating with ozone is handled the methanol waste water device, comprises catalytic chain water tank (1), impeller pump (3), rotary packed bed (4), ultrasound reactor (5) and ozonizer (8); It is characterized in that: on the water pipe that methanol waste water gets into, water inlet control valve (2) is housed, is connected with impeller pump (3) on the water pipe that methanol waste water gets into, the water pipe the other end that methanol waste water gets into is connected the top of rotary packed bed (4); In tubular rotary packed bed (4), filler (7) is arranged, gas outlet (6) is arranged at the top of rotary packed bed (4); The outlet of ozonizer (8) is connected the bottom of rotary packed bed (4) by pipeline; The water outlet of rotary packed bed (4) bottom is connected the inlet of ultrasound reactor (5) by pipeline; The water outlet of ultrasound reactor (5) connects the water-in on catalytic chain water tank (1) top; The bottom of catalytic chain water tank (1) is connected with circulation line, and recycle valve (9) is arranged on the circulation line, and the other end of circulation line is connected with the entrance end pipeline of impeller pump (3); Bottom at catalytic chain water tank (1) is fixed with the water outlet pipeline, is connected with outlet water control valve (10) on the water outlet pipeline of catalytic chain water tank (1).
2. supersonic wave cooperating with ozone according to claim 1 is handled the methanol waste water device, it is characterized in that: what described water inlet control valve (2), recycle valve (9) and outlet water control valve (10) adopted is solenoid electric valve.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201220243029 CN202594894U (en) | 2012-05-28 | 2012-05-28 | Device for treating methanol wastewater by using ultrasonic wave and ozone |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201220243029 CN202594894U (en) | 2012-05-28 | 2012-05-28 | Device for treating methanol wastewater by using ultrasonic wave and ozone |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN202594894U true CN202594894U (en) | 2012-12-12 |
Family
ID=47312452
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201220243029 Expired - Fee Related CN202594894U (en) | 2012-05-28 | 2012-05-28 | Device for treating methanol wastewater by using ultrasonic wave and ozone |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN202594894U (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103771557A (en) * | 2014-01-24 | 2014-05-07 | 华北水利水电大学 | Method for removing pollutants in water by ultrasonic-absorption synergy |
| CN105130046A (en) * | 2015-08-13 | 2015-12-09 | 南通河海大学海洋与近海工程研究院 | Plasma and ultrasonic and catalysis combined cascading style water treatment device |
-
2012
- 2012-05-28 CN CN 201220243029 patent/CN202594894U/en not_active Expired - Fee Related
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103771557A (en) * | 2014-01-24 | 2014-05-07 | 华北水利水电大学 | Method for removing pollutants in water by ultrasonic-absorption synergy |
| CN105130046A (en) * | 2015-08-13 | 2015-12-09 | 南通河海大学海洋与近海工程研究院 | Plasma and ultrasonic and catalysis combined cascading style water treatment device |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102674528B (en) | Method for treating low-concentration methanol wastewater by using ultrasonic wave and ozone | |
| CN204874211U (en) | A synthesize processing apparatus for high salt industrial waste water that contains | |
| CN204874213U (en) | Petrochemical industry waste water is with synthesizing water treatment facilities | |
| CN204897660U (en) | A dark treatment facility of environment -friendly that is used for high salt industry sewage that contains | |
| CN202594894U (en) | Device for treating methanol wastewater by using ultrasonic wave and ozone | |
| CN203602394U (en) | Jet flow type ozone photocatalysis-membrane treatment organic wastewater device | |
| CN103553270A (en) | Sewage treatment method and sewage treatment device with middle-arranged ozone reinforced bacteria filter | |
| CN204643958U (en) | Modernization pig house wastewater reuse approach anaerobic reaction system | |
| CN105858864A (en) | Operation method of ozonation water treatment system and device | |
| CN203245180U (en) | Integrated secondary fermentation and gas storage device for kitchen waste treatment | |
| CN203559033U (en) | Desulfurizing unit for methane produced from kitchen waste | |
| CN101983936B (en) | High-pressure impulse catalytic ozone strong oxidizing device for sewage treatment | |
| CN110550804A (en) | industrial wastewater circulating treatment and purification device for ozone oxidation and use method | |
| CN217638234U (en) | Chemical reaction device for preparing carbon-14 sample in water | |
| CN204981298U (en) | Chlorine residue of chemical industry waste water reduces discharging device | |
| CN108217903A (en) | A kind of water treatment facilities and method for improving ozone utilization rate | |
| CN208883561U (en) | A kind of multistage cross flow ozone reactor | |
| CN107200393A (en) | A kind of advanced oxidation device for handling high concentration hard-degraded organic waste water | |
| CN202558683U (en) | Iron/manganese removing water treatment device | |
| CN102874913A (en) | Method and device for treating high-concentration acrylonitrile wastewater | |
| CN206783384U (en) | A kind of water process ozone-oxidizing device | |
| CN105800778A (en) | Efficient pulse anaerobic filter | |
| CN206858248U (en) | A kind of fortifying catalytic aoxidizes ozone reactor | |
| CN206069495U (en) | A kind of photocatalysis Biodegradable sewage treating equipment | |
| CN104891706A (en) | Ozone oxidation wastewater treatment device |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20121212 Termination date: 20210528 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |