A kind of ceramic insulation sealing cylinder shape lithium battery
Technical field
The utility model relates to the relevant technical field of chemical power of new forms of energy, in particular for the energy storage of wind energy and solar energy and the ceramic insulation sealing cylinder shape lithium ion battery of power.
Background technology
Along with wind energy, the fast development of solar energy, the electric energy of its generation is because stable inadequately; Be prone to electrical network is produced impact, it is imperative therefore to set up corresponding storage station, therefore needs the high high capacity lithium ion battery of reliability to be used for storage station; With the storage wind energy, the electricity that sun the subject of knowledge and the object of knowledge produces, storage station is very high to the requirement of battery; Such as high reliability and long life (more than 10 years) etc., big capacity column lithium ion battery have high-energy-density (>=130wh/kg), advantage such as manufacturing process is simple; But technically, the sealing means of existing big capacity cylindrical battery and current collection mode lack high reliability, adopt the organic material sealing ring (like polyethylene such as the negative or positive electrode pole of battery and the insulation and the sealing of housing; Polypropylene, organic materials such as rubber-like), there is ageing hardening in such sealing ring long-time use under stress condition; The possibility that becomes fragile, thus its sealing lost, if when using for a long time more than 5 to 10 years; Sealing loses and can cause airborne water and oxygen to get in the battery, and battery can lose efficacy prematurely.In addition; The current collection mode of existing big capacity cylindrical battery all is collector plate and welding of lug position end face of flat shape; For example shown in the patent 201020280024.4 and 201010243100.9, in fact lug position end face is owing to the error in the winding process, and degree of registration has deviation to cause lug position end face and nisi planar shaped; Thus; During the contacting of the collector plate of flat shape and lug position end face, can't guarantee that each the circle lug in the end face of lug position all touches with the collector plate of flat shape, cause the heavy-current discharge weak effect of battery thus.
The utility model content
The utility model contact the solution of bad problem for each circle lug of prior art with plane collector plate technical problem provides a kind of ceramic insulation sealing cylinder shape lithium battery of mechanical seal mode of the alternative existing organic sealing ring of method that adopts the refractory ceramics insulated enclosure.
In order to solve the problems of the technologies described above; The technical scheme that the utility model adopted is: a kind of ceramic insulation sealing cylinder shape lithium battery is provided; Comprise battery container, be arranged on electrical core coiling body in the battery container, the collector plate at gland electrical core coiling body two ends, the pole that links to each other with collector plate through lug and the end cap at battery the two poles of the earth, said pole comprises Positive Poles and negative pole pole, said end cap comprises anode end cap and negative pole end cap; Have hole wall between said negative pole pole and the negative pole end cap; In this hole wall, be provided with ceramic body, negative pole pole and negative pole end cap are through said ceramic body insulated enclosure, and said ceramic body is the high-temperature oxide pottery.
In order to guarantee that collector plate contacts and connection with the good of lug position end face; The utility model is further optimized; Said collector plate diameter is less than or equal to the diameter of electrical core coiling body; Collector plate simultaneously is provided with the raised item more than or two with respect to electrical core coiling body, and said raised item embeds the lug position end face at electrical core coiling body two ends.
Improve collector plate and electrical core coiling body bonding strength, the utility model is further optimized, and the lug position welding at said raised item and electrical core coiling body two ends is fixing.
Wherein, said raised item is the ribbon body of linear or S shape or circular arc.
Wherein, the said raised item height of projection surperficial with respect to collector plate is 0.01mm-1.5mm.
For fear of the sealing problem between Positive Poles and the anode end cap, the utility model is further optimized Positive Poles and anode end cap, said Positive Poles and anode end cap adopt aluminium ingot once to push or forging type one-body molded.
The beneficial effect of the utility model is that the high-temperature oxide pottery has high temperature resistant usually, high strength, high rigidity, good electrical properties, hot property and chemical stability.The utility model cylinder type lithium battery adopts the mode of refractory ceramics insulated enclosure to prolong the useful life of sealing; Long-time use can ageing hardening under stress condition for refractory ceramics insulated enclosure body; Become fragile, can not lose its sealing, make battery can grow useful life and more than 10 years.
Description of drawings
Below in conjunction with accompanying drawing the embodiment of the utility model is done further detailed explanation.
Fig. 1 is the structural representation of the utility model ceramic insulation sealing cylinder shape lithium battery;
Fig. 2 is the structural representation of electrical core coiling body among the utility model embodiment;
Fig. 3 is the structural representation of ceramic insulation sealing among the utility model embodiment;
Fig. 4 is the Front view 1 A of negative or positive electrode collector plate among the utility model embodiment;
Fig. 5 is side-looking Figure 1B of negative or positive electrode collector plate among the utility model embodiment;
Fig. 6 is the Front view 2 A of negative or positive electrode collector plate among the utility model embodiment;
Fig. 7 is the end view 2B of negative or positive electrode collector plate among the utility model embodiment;
Fig. 8 is the front view 3A of negative or positive electrode collector plate among the utility model embodiment;
Fig. 9 is the end view 3B of negative or positive electrode collector plate among the utility model embodiment.
Wherein, 1: battery container;
2: electrical core coiling body; 21: lug position end face; 22: positive plate; 23: negative plate; 24: barrier film;
31: the anode collection plate; 32: the negative pole currect collecting plate; 33: raised item;
41: positive pole ear; 42: negative lug;
51: Positive Poles; 52: the negative pole pole; 53: ceramic body;
61: anode end cap; 62: the negative pole end cap.
Embodiment
By the technology contents, the structural feature that specify the utility model, realized purpose and effect, know clearly below in conjunction with execution mode and conjunction with figs. and give explanation.
As shown in Figure 3; Lug position end face 21: be because positive plate 22, negative plate 23 and barrier film 24 when reeling; Negative plate 23 is Copper Foil or positive plate 22 end face that forms of the limit of the aluminium foil of coating not of coating part not, is equal to electrical core coiling body 2 columniform end face and bottom surfaces in fact.
Please consult Fig. 1, Fig. 2 and Fig. 3 in the lump; As shown in the figure; The embodiment of the utility model ceramic insulation sealing cylinder shape lithium battery comprises battery container 1, electrical core coiling body 2, anode collection plate 31, negative pole currect collecting plate 32, positive pole ear 41, negative lug 42, Positive Poles 51, negative pole pole 52, anode end cap 61 and negative pole end cap 62, and the material of battery container 1 except that the ceramic insulation seal is aluminium alloy or nickel.Battery container 1 and anode end cap 61; Negative pole end cap 62 usefulness laser welding are in one, and Positive Poles 51 materials are aluminium alloy, and negative pole pole 52 materials are copper or copper nickel plating or pure nickel; Anode collection plate 31 materials are aluminium alloy; Negative pole currect collecting plate 32 materials are copper or copper nickel plating or pure nickel, and anode collection plate 31 is provided with 4 holes with negative pole currect collecting plate 32, for the inflow of electrolyte; Anode collection plate 31 and positive pole ear 41 laser welding together; Positive pole ear 41 materials are aluminium alloy, and the other end of this positive pole ear 41 welds with anode end cap 61 mutually, thus with Positive Poles 51 conductings; Negative pole currect collecting plate 32 and negative lug 42 laser welding are together; Negative lug 42 materials are copper or copper nickel plating or pure nickel, the other end of this negative lug 42 and negative pole pole 52 Laser Welding be linked together, the electrical core coiling body 2 in the battery container 1 comprises that the positive plate that is coated with the LiFePO4 active material, the negative plate that is coated with the graphite active material, material are that polyethylene or polyacrylic barrier film and material are the mandrel at the coiling body center of polytetrafluoroethylene or polypropylene or aluminium.The anode post is provided with liquid injection port, and fluid injection seals liquid injection port with steel ball after accomplishing.The utility model adopts the method for refractory ceramics insulated enclosure to substitute the mechanical seal mode of existing organic sealing ring; Have hole wall between said negative pole pole 52 and the negative pole end cap 62; In this hole wall, be provided with ceramic body 53, negative pole pole 52 passes through said ceramic body 53 insulated enclosures with negative pole end cap 62, and the mechanical seal mode of organic sealing ring has been avoided in the sealing of entire cell housing 1; Said ceramic body 53 is the high-temperature oxide pottery, and the high-temperature oxide pottery is (like Al
2O
3, ZrO, MgO, CaO, B
2O
3, ThO
2, Cr
2O
3, SiO
2, BeO, 3Al
2O
32SiO
2Deng), carbide ceramics, boride ceramics, nitride ceramics and silicide ceramics etc.Usually have high temperature resistant, high strength, high rigidity, good electrical properties, hot property and chemical stability.The oxide high-temperature pottery is mostly in oxidizing atmosphere, state sintering such as vacuum, (like argon, nitrogen) sintering under hot pressing commonly used of non-oxidized substance refractory ceramics or the particular atmosphere.The utility model ceramic insulation sealing cylinder shape lithium battery adopts the mode of refractory ceramics insulated enclosure to prolong the useful life of sealing; Long-time use can ageing hardening under stress condition for refractory ceramics insulated enclosure body; Become fragile; Can not lose its sealing, make battery can grow useful life and more than 10 years.
In the present embodiment; Shown in Fig. 4 to 9, anode collection plate 31 or negative pole currect collecting plate 32 are provided with the raised item 33 more than or two with respect to electrical core coiling body 2 one sides, and said raised item 33 can be the ribbon body of linear or similar S shape or circular arc; Raised item 33 height of projection surperficial with respect to collector plate is 0.01mm~1.5mm; Protruding linear ribbon body can be parallel arrangement, or cross arrangement, and said collector plate diameter is less than or equal to the diameter of electrical core coiling body 2.
When actual battery is made; Exert pressure at anode collection plate 31 or negative pole currect collecting plate 32 surfaces; Its surperficial raised item 33 is embedded in the lug position end face 21, owing to aluminium foil, copper thickness very thin (less than 0.03mm), and soft; Therefore be easy to make collector plate raising bar 33 shoestring to be embedded in the lug position end face 21; And guarantee that collector plate raising bar 33 shoestring closely contact with each layer Copper Foil or aluminium foil, weld together with the Copper Foil or the aluminium foil of laser welder then, when anode collection plate 31 or negative pole currect collecting plate 32 raising bars 33 shoestring are embedded in the lug position end face 21 with raised item 33 shoestring and lug position end face 21; Recessed shape in the 21 corresponding appearance of lug position end face; The shape of recessed shape and anode collection plate 31 or negative pole currect collecting plate 32 raising bars 33 shoestring matches, if anode collection plate 31 or negative pole currect collecting plate 32 raising bars 33 shoestring be shaped as the linear parallel arrangement, then recessed shape also is the linear parallel arrangement in the 21 corresponding appearance of lug position end face.
Pass through said structure; The Embedded collector plate that the utility model ceramic insulation sealing cylinder shape lithium battery provides; Collector plate raising bar 33 shoestring are embedded in the lug position end face 21, guarantee that collector plate raising bar 33 shoestring closely contact with each layer Copper Foil or aluminium foil, and realize effectively welding between collector plate and the lug position by laser welder; Thereby the effectively conduction current and the heat of effectively deriving electric in-core portion, electric current 2C or 3C output especially greatly.
In the present embodiment; The Positive Poles 51 of the utility model adopts aluminium ingot once to push with anode end cap 61 or the casting mode processes; Positive Poles 51 becomes one with anode end cap 61; Avoid the sealing problem between Positive Poles 51 and the anode end cap 61, need not between Positive Poles 51 and anode end cap 61, to adopt sealing.Therefore, the utility model ceramic insulation sealing cylinder shape lithium battery can have been avoided the mechanical seal mode of organic sealing ring fully.
The above is merely the embodiment of the utility model; Be not thus the restriction the utility model claim; Every equivalent structure or equivalent flow process conversion that utilizes the utility model specification and accompanying drawing content to be done; Or directly or indirectly be used in other relevant technical fields, all in like manner be included in the scope of patent protection of the utility model.