CN202454682U - Valve-control type sealed lead-acid battery - Google Patents

Valve-control type sealed lead-acid battery Download PDF

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Publication number
CN202454682U
CN202454682U CN2011204538227U CN201120453822U CN202454682U CN 202454682 U CN202454682 U CN 202454682U CN 2011204538227 U CN2011204538227 U CN 2011204538227U CN 201120453822 U CN201120453822 U CN 201120453822U CN 202454682 U CN202454682 U CN 202454682U
Authority
CN
China
Prior art keywords
sealed lead
acid accumulator
valve controlled
lead
plate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
CN2011204538227U
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Chinese (zh)
Inventor
陈杰
刘翀
胡水华
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
WUHAN CHANGGUANG BATTERY CO Ltd
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WUHAN CHANGGUANG BATTERY CO Ltd
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Publication date
Application filed by WUHAN CHANGGUANG BATTERY CO Ltd filed Critical WUHAN CHANGGUANG BATTERY CO Ltd
Priority to CN2011204538227U priority Critical patent/CN202454682U/en
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Publication of CN202454682U publication Critical patent/CN202454682U/en
Anticipated expiration legal-status Critical
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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Abstract

The utility model provides a valve-control type sealed lead-acid battery and belongs to the technical field of lead-acid batteries. The valve-control type sealed lead-acid battery comprises a plate group composed of a positive electrode plate and a negative electrode plate, a partition plate, a casing group and electrolyte, wherein the positive electrode plate is of a tubular structure, and sulfuric acid electrolyte is filled in micropores of the electrode plates and the partition plate in adsorption mode. Colloid electrolyte formed by mixing dilute sulphuric acid and nano-silicon sol is filled in gaps on the portion lower than a busbar of the electrode plate group and between the surrounding of the electrode plates and the casing group. The valve-control type sealed lead-acid battery is capable of well achieving deep circulation and strong in charging recovering capability after deep discharging.

Description

A kind of valve controlled sealed lead-acid accumulator
Technical field
The utility model relates to the lead acid accumulator technical field, relates in particular to a kind of valve controlled sealed lead-acid accumulator.
Background technology
21st century, battery industry was the important component part of new energy field, was the new focus of global economy development.Lead acid accumulator accounts for 1/3rd of battery industry gross sales amount, and is closely bound up with industries such as electric power, traffic, information.Have a wide range of applications at emergency power supply, uninterruptible power system, new green power aspects such as (wind energy, solar energy).
Common valve controlled sealed lead-acid accumulator by: positive plate (paste spread type), negative plate (paste spread type), dividing plate (AGM), electrolyte (dilute sulfuric acid), shell group are formed.As in the lead acid accumulator industry important one used in a large number and widely because of its in use non-maintaining, no acid solution leaks outside to pollute.But its positive plate of common valve controlled sealed lead-acid accumulator be the paste spread type structure in use positive active material constantly expand along with the carrying out that discharges and recharges and contraction is destroyed its inherent structure to cause the active material softening and shedding to make battery failure.Common analysing valve control type lead-acid accumulator battery electrolyte is to satisfy the compound needs of oxygen to adopt the design of lean solution amount.The battery of lean solution amount design is high to the requirement of environment for use, charging/discharging apparatus, receives above-mentioned factor affecting in use to be prone to cause the battery thermal runaway and causes losing efficacy.
Therefore, need a urgent technical problem that solves to be exactly instantly: how can propose a kind of effective measures, to solve the problem that exists in the prior art.
The utility model content
The utility model technical problem to be solved provides a kind of valve controlled sealed lead-acid accumulator, can be good at realizing dark circulation, and the charging recovery capability is strong behind deep discharge.
In order to solve the problems of the technologies described above, the utility model provides a kind of valve controlled sealed lead-acid accumulator, comprises utmost point crowd, dividing plate, shell group and electrolyte that positive/negative plate is formed; Positive plate adopts tubular structure, adsorbs sulfuric acid electrolyte abrim in the micropore of pole plate and dividing plate.
Further, said positive plate is a flat pipe type or box-section tubular.
Further, said positive plate comprises the bone core of being processed by lead-calcium alloy or low-antimony-lead alloy, and is centered around the outer comb of being processed by terylene or glass fiber of bone core.
Further, said dividing plate is PVC micropore SiO2 composite diaphragm or AGM dividing plate.
Further, said cap group comprises common valve controlled sealed lead-acid accumulator cap group and preposition terminal valve controlled sealed lead-acid accumulator cap group.
To sum up; The utility model provides a kind of valve controlled sealed lead-acid accumulator; Thereby its positive plate adopts tubular structure to avoid battery active material loose or dislocation in use to cause cycle performance of battery poor; The deficiency that useful life is short, thus the design of flat tube, rectangular tube makes itself and dividing plate contact-making surface greatly the high-rate battery discharge characteristic not had obvious influence again simultaneously.
Simultaneously; Electrolyte adopts the mixture of dilute sulfuric acid and Nano silica sol; To increase the electrolyte liquid measure, wherein dilute sulfuric acid electrolyte is full of battery pole plates inner active material micropore and dividing plate micropore to colloidal electrolyte after solidifying by the design of rich solution amount, is used to satisfy battery charging and discharging and uses.Colloidal electrolyte is distributed in and removes active material and dividing plate micropore in the battery with exterior domain, and battery can not dried up, and the thermal runaway risk is little during use, and the acceptance of charging is good, and battery life is also longer.
Description of drawings
Fig. 1 is the structural representation of a kind of medium-sized valve controlled sealed lead-acid accumulator of the utility model.
Embodiment
Below in conjunction with accompanying drawing and embodiment the utility model is done further detailed explanation.
Reference is shown in Figure 1 to be the described a kind of medium-sized valve controlled sealed lead-acid accumulator of the utility model embodiment, comprises by positive plate 2 and negative plate 3 mutual group poling crowds, dividing plate 4, shell group 1 and electrolyte; Sulfuric acid electrolyte 8 is abrim adsorbed in pole plate and dividing plate 4 inside; Colloidal electrolyte 9 abrim around the pole plate and between the shell group 1 and in the slit, the following position of bus-bar of pole plate.
Said positive plate is a flat pipe type or box-section tubular; Comprise the bone core of processing by lead-calcium alloy or low-antimony-lead alloy 5; And be centered around the bone core 5 outer combs of processing by terylene or glass fiber 6, and be filled with the active material brown lead oxide 7 that interpolation contains short fiber, carbon materials and pore forming agent at bone core 5 and 6 of combs.
Concrete, the sulfuric acid electrolyte 8 of pole plate and dividing plate 4 inner absorption is dilute sulfuric acid electrolyte (its concentration is 38%-42%).
Dividing plate 4 can be PVC micropore SiO2 composite diaphragm or AGM dividing plate.
Bone core 5 is to be formed by casting of NEW Pb calcium tin aluminium quaternary alloy or low-antimony-lead alloy or die casting, adopts twin-core structure.
Comb 6 can be terylen comb or glass fiber comb, and its structure is made up of the multi-filament tube side-by-side and its cross section is oval structure or rectangular configuration.
Colloidal electrolyte 9 is mixtures of dilute sulfuric acid and Nano silica sol.
Said cap group comprises common valve controlled sealed lead-acid accumulator cap group and preposition terminal valve controlled sealed lead-acid accumulator cap group.
More than a kind of valve controlled sealed lead-acid accumulator that the utility model provided has been carried out detailed introduction; Used concrete example among this paper the principle and the execution mode of the utility model are set forth, the explanation of above embodiment just is used to help to understand the method and the core concept thereof of the utility model; Simultaneously, for one of ordinary skill in the art, according to the thought of the utility model, the part that on embodiment and range of application, all can change, in sum, this description should not be construed as the restriction to the utility model.

Claims (5)

1. a valve controlled sealed lead-acid accumulator comprises utmost point crowd, dividing plate, shell group and electrolyte that positive/negative plate is formed; It is characterized in that: positive plate adopts tubular structure, adsorbs sulfuric acid electrolyte abrim in the micropore of pole plate and dividing plate.
2. valve controlled sealed lead-acid accumulator according to claim 1 is characterized in that: said positive plate is a flat pipe type or box-section tubular.
3. valve controlled sealed lead-acid accumulator according to claim 2 is characterized in that: said positive plate comprises the bone core of being processed by lead-calcium alloy or low-antimony-lead alloy, and is centered around the outer comb of being processed by terylene or glass fiber of bone core.
4. valve controlled sealed lead-acid accumulator according to claim 1 is characterized in that: said dividing plate is PVC micropore SiO2 composite diaphragm or AGM dividing plate.
5. valve controlled sealed lead-acid accumulator according to claim 1 is characterized in that: said cap group comprises common valve controlled sealed lead-acid accumulator cap group and preposition terminal valve controlled sealed lead-acid accumulator cap group.
CN2011204538227U 2011-11-16 2011-11-16 Valve-control type sealed lead-acid battery Expired - Lifetime CN202454682U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2011204538227U CN202454682U (en) 2011-11-16 2011-11-16 Valve-control type sealed lead-acid battery

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2011204538227U CN202454682U (en) 2011-11-16 2011-11-16 Valve-control type sealed lead-acid battery

Publications (1)

Publication Number Publication Date
CN202454682U true CN202454682U (en) 2012-09-26

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN2011204538227U Expired - Lifetime CN202454682U (en) 2011-11-16 2011-11-16 Valve-control type sealed lead-acid battery

Country Status (1)

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CN (1) CN202454682U (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102903880A (en) * 2012-10-26 2013-01-30 夏伟绩 Method for manufacturing superfine glass fiber colloidal composite baffle plate for valve regulated lead storage battery
CN109546232A (en) * 2018-11-02 2019-03-29 小洋电源股份有限公司 A kind of Solid silica gel traction accumulator

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102903880A (en) * 2012-10-26 2013-01-30 夏伟绩 Method for manufacturing superfine glass fiber colloidal composite baffle plate for valve regulated lead storage battery
CN109546232A (en) * 2018-11-02 2019-03-29 小洋电源股份有限公司 A kind of Solid silica gel traction accumulator
CN109546232B (en) * 2018-11-02 2021-11-05 小洋电源股份有限公司 Solid-state silica gel traction storage battery

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CX01 Expiry of patent term

Granted publication date: 20120926

CX01 Expiry of patent term