CN202279859U - Acid vaporizing gas intensified cleaning device in silver electrolytic process - Google Patents

Acid vaporizing gas intensified cleaning device in silver electrolytic process Download PDF

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Publication number
CN202279859U
CN202279859U CN 201120368460 CN201120368460U CN202279859U CN 202279859 U CN202279859 U CN 202279859U CN 201120368460 CN201120368460 CN 201120368460 CN 201120368460 U CN201120368460 U CN 201120368460U CN 202279859 U CN202279859 U CN 202279859U
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China
Prior art keywords
class
electrolyzer
box
hollow shelf
cleaning device
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Expired - Lifetime
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CN 201120368460
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Chinese (zh)
Inventor
李卫锋
王文胜
赵洪浩
夏胜文
徐诗燕
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Henan Yuguang Gold and Lead Co Ltd
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Henan Yuguang Gold and Lead Co Ltd
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Priority to CN 201120368460 priority Critical patent/CN202279859U/en
Application granted granted Critical
Publication of CN202279859U publication Critical patent/CN202279859U/en
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Abstract

The utility model relates to an acid vaporizing gas intensified cleaning device in a silver electrolytic process. An electrolytic cell is provided with an A-type hollow clapboard box and a B-type hollow clapboard box. Clapboard air vents arranged at the upper parts of the A-type hollow clapboard box and the B-type hollow clapboard box and are vertical to a left ventilating channel and a right ventilating channel. The A-type hollow clapboard box is connected with the left ventilating channel, and the B-type hollow clapboard box is connected with the right ventilating channel. The left ventilating channel and the right ventilating channel are connected with a left-right air channel gathering box at the front end part of the electrolytic cell. The left-right air channel gathering box is connected with a ventilating pipeline. In the front of the connection part of a stainless steel air blower and the ventilating pipeline, a condensing box is arranged at the lowermost position of the ventilating pipeline. A condensed liquid discharge valve is arranged at the bottom of the condensing box, and the tail end of the ventilating pipeline is connected with a purifying and absorbing tower. According to the acid vaporizing gas intensified cleaning device disclosed by the utility model, not only can the defects in the prior art of electrolyte waste and bad conditions of a work environment be overcome, but also the device has the advantages that resources are saved, the environmental conservation effect is good, the operation is simple and convenient, the operation environment conditions are improved and the like.

Description

Sour Volatile Gas intensification cleaning device in the silver electrolytic process
Technical field
The utility model belongs to the non-ferrous metal metallurgy industry, relates in particular to a kind of sour Volatile Gas intensification cleaning device that is used for the sour Volatile Gas intensification of silver-colored electrolytic process clean.
Background technology
The equipment that at present domestic silver-colored electrolytic process adopts is a kind of open electrolyzer; This electrolyzer is to be made by non-metallic material; And electrolytic solution is that processed and had by easy evaporable nitric acid must temperature requirement; In electrolytic process, a part of nitric acid can be waved in the surrounding space, directly is discharged in the outer atmosphere of factory building by exhaust fan.
Present stage is domestic also do not have a tame enterprise in the electrolytic process in the electrolytic solution evaporable nitric acid acid mist clean that intensifies, and this acid mist can cause very big harm to aspects such as environment, equipment, safety, mainly shows following several respects:
1, the acid mist 100% that produces in the silver-colored electrolytic process evaporate into production plant, contacts with peripheral equipment to be agglomerated to rapidly on the equipment, makes the equipment heavy corrosion.
2, the acid mist of production plant is big, is prone to cause operator's respiratory disease, and now the employing increases the method solution operating environment environment problem that the smell is awful that exhaust fan adds high ventilating rate more.The ventilation volume of silver potroom is 3-5 a times of common workshop.
3, both contaminate environment is wasted resource again.The nitric acid acid mist that in electrolytic process, volatilizes directly is discharged to by exhaust fan and has not only polluted environment in the atmosphere, but also the consumption that has strengthened nitric acid.
Summary of the invention
The purpose of the utility model is to overcome the waste of nitric acid in the existing technology and the situation of working environment difference; Sour Volatile Gas intensification cleaning device in a kind of silver-colored electrolytic process is provided; On the electrolyzer cell body, increase ventilation system; Electrolyte surface forms negative pressure under the effect of blower fan; Reclaim the nitric acid acid mist that volatilizes in the electrolytic solution through ventilation system and reach the purpose that reclaims electrolytic solution and optimization work environment, this device has not only been filled up the blank of the acid mist collection and treatment of volatilizing in the domestic electrolytic process, also have economize on resources, advantages such as environment protecting is good, simple to operation, raising operating environmental condition.
The technical scheme of the utility model is achieved in that
Sour Volatile Gas intensification cleaning device in a kind of silver-colored electrolytic process; Comprise electrolyzer; It is characterized in that: on the cell body of electrolyzer, be provided with Class A hollow shelf case, Class B hollow shelf case, left side ventilation duct, left and right sides air channel collector, right air path, dividing plate ventilation opening, electrolytic solution riser; Wherein Class A hollow shelf case and Class B hollow shelf case are the mechanism of electrolyzer own; The dividing plate ventilation opening is hollow shelf and Class B hollow shelf top and perpendicular to left side ventilation duct and right side ventilation duct in the Class A, and on the both sides of dividing plate length direction the dividing plate ventilation opening is arranged all; Class A hollow shelf case passes on left electrolyzer left side cell wall and links to each other with the left side ventilation duct, and Class B hollow shelf case right side links to each other with the right side ventilation duct through electrolyzer right side cell wall; The left side ventilation duct links to each other with the left and right sides air channel collector that is arranged on the electrolyzer leading section with the right side ventilation duct, and left and right sides air channel collector is connected with ventilator trunk; At stainless steel blower fan and ventilator trunk junction leading portion, the lowest part of ventilator trunk is provided with cooling cylinder, and the cooling cylinder bottom is provided with the condensate discharge valve, and terminal connection of ventilator trunk purifies the absorption tower.
In order to guarantee that the electrolytic solution Volatile Gas gets into ventilation system, install the high 10mm of median septum ventilation opening, wide 835mm, and the present position is than the high 10cm of liquid level of electrolyte.
In order to guarantee electrolysis liquid surface at settling position, on electrolyzer, establish the electrolytic solution riser, when electrolyte content was big, electrolytic solution can go out electrolyzer from the overflow of electrolytic solution riser, is recycled again.
In order to have guaranteed that airshed is basic identical between each dividing plate, the suction opening of every adjacent two Class A hollow shelf casees and Class B hollow shelf case is on relative position.
Sour Volatile Gas intensification cleaning device in the described silver-colored electrolytic process, the manufacturing materials system of electrolyzer and ventilation system all adopt not can be by acid electrolyte corrosive material, thereby can not cause electrolytic solution and finished product silver powder contaminated.
The advantage of the utility model is:
1, to adopt electrolyzer and ventilation system be the mechanism of one to the utility model, take up space little, do not influence tankage, look into necessary work in electrolytic process such as groove.
2, behind the described device of use the utility model, reduced evaporable acid mist in 90% electrolytic process, operating environment improves greatly.
3, behind the described electrolyzer of use the utility model, original ventilation system is that the factory building exhaust fan will be cancelled, and has avoided noise pollution.
4, can utilize through handling after the electrolytic solution Volatile Gas is recovered, 330 days=13200 kilograms of annual recyclable approximately nitric acid 40 kg/day * reduce the wasting of resources again.
5, after uncooled electrolytic solution Volatile Gas was handled through scavenging tower in the air channel, sour gas was neutralized the back discharging, has alleviated N0x gas to atmospheric pollution.
6, all adopt not can be by acid electrolyte corrosive material for electrolyzer and ventilation system, thereby can not cause electrolytic solution and finished product silver powder contaminated.
7, equipment making, easy to maintenance.
Description of drawings
Fig. 1 is the vertical view of the utility model electrolyzer.
Fig. 2 is the sectional view of the utility model electrolyzer.
Fig. 3 is the front view of the utility model electrolyzer.
Fig. 4 is that the major equipment of sour Volatile Gas intensification cleaning device in the utility model silver electrolytic process connects synoptic diagram.
Embodiment
Like Fig. 1, Fig. 2, Fig. 3, shown in Figure 4; Sour Volatile Gas intensification cleaning device in a kind of silver-colored electrolytic process; Comprise electrolyzer; It is characterized in that: on the cell body of electrolyzer 1, be provided with Class A hollow shelf case 2, Class B hollow shelf case 3, left side ventilation duct 4, left and right sides air channel collector 5, right air path 6, dividing plate ventilation opening 7, electrolytic solution riser 8; Wherein Class A hollow shelf case 2 is the mechanism of electrolyzer own with Class B hollow shelf case 3; Hollow shelf case 2 and all has dividing plate ventilation opening 7 on the both sides of dividing plate length direction with Class B hollow shelf case 3 tops and perpendicular to left side ventilation duct 4 and right side ventilation duct 6 to dividing plate ventilation opening 7 in the Class A; The electrolyzer left side cell wall that passes on left of Class A hollow shelf case 2 links to each other with left side ventilation duct 4, and Class B hollow shelf case 3 right sides link to each other with right side ventilation duct 6 through electrolyzer right side cell wall; Left side ventilation duct 4 links to each other with the left and right sides air channel collector 5 that is arranged on the electrolyzer leading section with right side ventilation duct 6, and left and right sides air channel collector 5 is connected with ventilator trunk 9; At stainless steel blower fan 12 and ventilator trunk 9 junction leading portions, the lowest part of ventilator trunk 9 is provided with cooling cylinder 10, and cooling cylinder 10 bottoms are provided with condensate discharge valve 11, and 9 terminal connections of ventilator trunk purify absorption tower 13.
In order to guarantee that the electrolytic solution Volatile Gas gets into ventilation system, install median septum ventilation opening 7 high 10mm, wide 835mm, and the present position is than the high 10cm of liquid level of electrolyte.
In order to guarantee electrolysis liquid surface at settling position, on electrolyzer, establish electrolytic solution riser 8, can be when electrolyte content is big from 8 overflows of electrolytic solution riser from newly being recycled.
In order to have guaranteed that airshed is basic identical between each dividing plate, the suction opening of every adjacent two Class A hollow shelf casees 2 and Class B hollow shelf case 3 is on relative position.
In the described silver-colored electrolytic process in the sour Volatile Gas intensification cleaning device, the manufacturing materials system of electrolyzer and ventage all adopts not can be by acid electrolyte corrosive material, thereby can not cause electrolytic solution and finished product silver powder contaminated.

Claims (5)

1. sour Volatile Gas intensification cleaning device in the silver-colored electrolytic process; Comprise electrolyzer (1); It is characterized in that: on the cell body of electrolyzer (1), be provided with Class A hollow shelf case (2), Class B hollow shelf case (3), left side ventilation duct (4), left and right sides air channel collector (5), right air path (6), dividing plate ventilation opening (7), electrolytic solution riser (8); Wherein Class A hollow shelf case (2) and Class B hollow shelf case (3) are the mechanism of electrolyzer own; Dividing plate ventilation opening (7) is hollow shelf case (2) and Class B hollow shelf case (3) top and perpendicular to left side ventilation duct (4) and right side ventilation duct (6) in the Class A, and on the both sides of dividing plate length direction dividing plate ventilation opening (7) is arranged all; The electrolyzer left side cell wall that passes on left of Class A hollow shelf case (2) links to each other with left side ventilation duct (4), and Class B hollow shelf case (3) right side links to each other with right side ventilation duct (6) through electrolyzer right side cell wall; Left side ventilation duct (4) links to each other with the left and right sides air channel collector (5) that is arranged on the electrolyzer leading section with right side ventilation duct (6), and left and right sides air channel collector (5) is connected with ventilator trunk (9); At stainless steel blower fan (12) and ventilator trunk (9) junction leading portion; The lowest part of ventilator trunk (9) is provided with cooling cylinder (10); Cooling cylinder (10) bottom is provided with condensate discharge valve (11), and terminal connection of ventilator trunk (9) purifies absorption tower (13).
2. sour Volatile Gas intensification cleaning device in the silver-colored electrolytic process according to claim 1, it is characterized in that: the suction opening of per two adjacent Class A hollow shelf casees (2) and Class B hollow shelf case (3) is on relative position.
3. sour Volatile Gas intensification cleaning device in the silver-colored electrolytic process according to claim 1 is characterized in that: the high 10mm of device median septum ventilation opening (7), and wide 835mm, and the present position is than the high 10cm of liquid level of electrolyte.
4. sour Volatile Gas intensification cleaning device in the silver-colored electrolytic process according to claim 1, it is characterized in that: the rearward end at electrolyzer (1) cell body is provided with electrolytic solution riser (8).
5. sour Volatile Gas intensification cleaning device in the silver-colored electrolytic process according to claim 1, it is characterized in that: said device is selected for use can be by acid electrolyte corrosive material as manufacturing materials.
CN 201120368460 2011-09-30 2011-09-30 Acid vaporizing gas intensified cleaning device in silver electrolytic process Expired - Lifetime CN202279859U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 201120368460 CN202279859U (en) 2011-09-30 2011-09-30 Acid vaporizing gas intensified cleaning device in silver electrolytic process

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 201120368460 CN202279859U (en) 2011-09-30 2011-09-30 Acid vaporizing gas intensified cleaning device in silver electrolytic process

Publications (1)

Publication Number Publication Date
CN202279859U true CN202279859U (en) 2012-06-20

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102304729A (en) * 2011-09-30 2012-01-04 河南豫光金铅股份有限公司 Intensive cleaning treatment device for acidic volatile gas of silver electrolysis process and use method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102304729A (en) * 2011-09-30 2012-01-04 河南豫光金铅股份有限公司 Intensive cleaning treatment device for acidic volatile gas of silver electrolysis process and use method thereof

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AV01 Patent right actively abandoned

Granted publication date: 20120620

Effective date of abandoning: 20130807

RGAV Abandon patent right to avoid regrant