CN204874777U - Be used for tombarthite fused salt electrolysis stove to be harmful fume treatment auxiliary - Google Patents
Be used for tombarthite fused salt electrolysis stove to be harmful fume treatment auxiliary Download PDFInfo
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- CN204874777U CN204874777U CN201520452073.4U CN201520452073U CN204874777U CN 204874777 U CN204874777 U CN 204874777U CN 201520452073 U CN201520452073 U CN 201520452073U CN 204874777 U CN204874777 U CN 204874777U
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- China
- Prior art keywords
- gas
- flue
- flue gas
- tube
- heat transfer
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- 238000005868 electrolysis reaction Methods 0.000 title claims abstract description 26
- 150000003839 salts Chemical class 0.000 title abstract description 3
- 239000003517 fume Substances 0.000 title abstract 2
- 239000000428 dust Substances 0.000 claims abstract description 30
- 238000010521 absorption reaction Methods 0.000 claims abstract description 29
- 239000000779 smoke Substances 0.000 claims abstract description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000007921 spray Substances 0.000 claims abstract description 15
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 24
- 150000002910 rare earth metals Chemical class 0.000 claims description 24
- 241000208125 Nicotiana Species 0.000 claims description 6
- 235000002637 Nicotiana tabacum Nutrition 0.000 claims description 6
- 239000003500 flue dust Substances 0.000 claims description 3
- 230000008676 import Effects 0.000 claims description 3
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract description 34
- 239000003546 flue gas Substances 0.000 abstract description 34
- 230000000694 effects Effects 0.000 abstract description 5
- 238000011084 recovery Methods 0.000 abstract description 3
- 239000002351 wastewater Substances 0.000 abstract description 3
- 238000006115 defluorination reaction Methods 0.000 abstract description 2
- 239000002918 waste heat Substances 0.000 abstract description 2
- 238000005507 spraying Methods 0.000 abstract 1
- 239000007789 gas Substances 0.000 description 16
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 3
- 229910052731 fluorine Inorganic materials 0.000 description 3
- 239000011737 fluorine Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000002940 repellent Effects 0.000 description 2
- 239000005871 repellent Substances 0.000 description 2
- 230000003245 working effect Effects 0.000 description 2
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000112 cooling gas Substances 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Landscapes
- Treating Waste Gases (AREA)
Abstract
The utility model discloses a be used for tombarthite fused salt electrolysis stove to be harmful fume treatment auxiliary, including tube replacement, cyclone gentleness bulk absorption tower, the heat exchange tube passes through the air exhauster and absorbs harmful flue gas that the tombarthite electrolysis produced to carry out the heat transfer through the spiral heat exchange tube, cyclone's lower part is equipped with the ash bucket that is used for collecting the smoke and dust, and the inside on gaseous absorption tower has foggy sprinkler head, and the water storage of the inside downside on gaseous absorption tower district connects foggy sprinkler head through the water spray circulating pipe, installs circulating water pump on the circulating pipe of just spraying water. The utility model discloses can retrieve electrolysis flue gas waste heat, reduce the flue -gas temperature, improve the heat energy availability factor, reduce flue gas corrosivity, extension equipment life, the dust collection efficiency is high, can improve the rate of recovery of tombarthite dust, and the defluorination is effectual, has the purifying effect of ideal to can realize that the clean of waste water zero release and flue gas discharges, energy -conserving protection.
Description
Technical field
The utility model relates to a kind of for rare earth molten-salt electrolysis stove harmful smoke treatment facility.
Background technology
Along with improving constantly of Economic development and environmental protection requirement, also increasingly strict to the control of Rare Earth Electrolysis industry flue gas.At present, China's fused salt electrolysis process produces rare earth and rare earth alloy, mostly adopts fluoric-salt system, and major equipment is rare earth electrolysis cell.Can produce a certain amount of fluorine-containing and containing the flue gas of rare earth dust in electrolysis production process, because Oil repellent in electrolysis flue gas is not high, the high-temperature flue gas that most of rare earth metal manufacturing enterprise is produced by absorption tower device processes electrolysis, absorption tower Water spray is introduced by flue gas, directly discharge after simple wet dedusting, this method cannot reach desirable evolution effect, still containing more fluoro-gas and rare earth dust in flue gas after purification, so not only contaminate environment but also cause the wasting of resources of rare earth and heat energy.Energy-saving and cost-reducing, protection of the environment is the target that enterprise is pursued always, finds and exploitation efficient energy-saving Smoke Gas Purity by Electrolysis method and apparatus, has become the urgent task of Rare Earth Electrolysis enterprise.
Utility model content
The utility model, in order to solve the above-mentioned deficiency of prior art, proposes a kind of for rare earth molten-salt electrolysis stove harmful smoke treatment facility.
In order to solve the problems of the technologies described above, the utility model by the following technical solutions: a kind of be used for rare earth molten-salt electrolysis stove harmful smoke treatment facility, comprise heat transfer tube, tornado dust collector and absorption column of gas; The inwall of described heat transfer tube is provided with spiral heat exchange tube along its length, the two ends up and down of described spiral heat exchange tube are respectively equipped with heat transferring medium import and heat transferring medium outlet, the lower end of described heat transfer tube is connected with vacuum fan, the blast inlet of described vacuum fan is provided with smoke absorption cover, the upper end of described heat transfer tube connects the intake interface of described tornado dust collector by tracheae, described tornado dust collector give vent to anger interface connect flue, described flue extend into the bottom of described absorption column of gas, and the bottom of tornado dust collector is provided with the ash bucket for collecting flue dust; Described absorption column of gas interior lower end is provided with circulation storage area, the top of described storage area is fixed wtih a loose tobacco pipe, described loose tobacco pipe smoke outlet upward and lower end is arranged on the smoke place end of described flue, described storage area is connected with water spray circulation tube, water spray circulation tube is provided with recycle pump, and the upper end of described water spray circulation tube is provided with a draining fog spray head of the inner upper end being arranged on absorption column of gas.
The smoke absorption cover of vacuum fan is arranged near rare earth electrolysis cell working face, directly can take the harmful smoke that rare earth electrolysis cell produces away, Rare Earth Electrolysis flue gas enters into heat-exchanger rig, tornado dust collector, absorption column of gas by vacuum fan successively, finally outwardly discharges.
High-temperature electrolysis flue gas corrosion strengthens, and be unfavorable for the work-ing life of flue gas purifying equipment, flue gas carries out heat exchange in heat-exchanger rig, and after heat exchange, flue-gas temperature reduces.Flue gas is dedusting in tornado dust collector, and gained dust Rare-Earth Content, up to more than 70%, has great recovery value.Flue gas after dedusting introduces absorption tower, except clean emission to external world after fluorine and further dedusting in absorption tower.
Compared with prior art, the Rare Earth Electrolysis flue gas processing device that the utility model adopts heat transfer tube, tornado dust collector, absorption column of gas to connect successively, reaches following effect:
1. reclaim electrolysis flue gas waste heat, reduce flue-gas temperature, improve heat energy service efficiency, reduce flue gas corrosion, extension device work-ing life;
2. equipment is simple, and efficiency of dust collection is high, can improve the rate of recovery of rare earth dust;
3. defluorination effect is good, has desirable decontamination effect improving;
4. the clean emission of wastewater zero discharge and flue gas is realized, energy-saving protective.
Accompanying drawing explanation
Fig. 1 is structural representation of the present utility model.
Embodiment
Below in conjunction with drawings and Examples, utility model is described in detail.
As shown in Figure 1, the utility model proposes for rare earth molten-salt electrolysis stove harmful smoke treatment facility, comprise heat transfer tube 1, tornado dust collector 2 and absorption column of gas 3.
The inwall of heat transfer tube 1 is provided with spiral heat exchange tube 4 along its length, the two ends up and down of spiral heat exchange tube 4 are respectively equipped with heat transferring medium import 5 and heat transferring medium outlet 6, the lower end of heat transfer tube 1 is connected with vacuum fan 7, the blast inlet of vacuum fan 7 is provided with smoke absorption cover 8, and the upper end of described heat transfer tube 1 connects the intake interface of described tornado dust collector 2 by tracheae.The harmful smoke be drawn into of vacuum fan upwards flows from the below of heat transfer tube, contrary with the flow direction of the heat transferring medium of spiral heat exchange tube 4, this makes it possible to ensure good heat exchange efficiency.
Tornado dust collector 2 give vent to anger interface connect flue 9, flue 9 extend into the bottom of absorption column of gas 3, and the bottom of tornado dust collector 2 is provided with the ash bucket 10 for collecting flue dust.Absorption column of gas 3 interior lower end is provided with circulation storage area 31, the top of storage area 31 is fixed wtih a loose tobacco pipe 11, loose tobacco pipe 11 smoke outlet upward and lower end is arranged on the smoke place end of flue 9, storage area 31 is connected with water spray circulation tube 12, water spray circulation tube 12 is provided with recycle pump 13, and the upper end of water spray circulation tube 12 is provided with a draining fog spray head 14 of the inner upper end being arranged on absorption column of gas 3.The flue gas that rare earth electrolysis cell produces by vacuum fan of the present utility model is introduced in heat transfer tube and is carried out heat exchange, after flue gas heat exchange, temperature reduces, then flue gas is introduced tornado dust collector, tornado dust collector can remove dedusting larger for particle in flue gas rapidly, efficiency of dust collection can reach 95%, after dedusting, flue gas introduces absorption column of gas through flue again, waterfog head is had in absorption column of gas, waterfog head 11 sprays water smoke and absorbs the fluorine in flue gas and remain dust, and further cooling gas, purify flue gas completely and discharged by the exhanst gas outlet of absorption column of gas.
The flue-gas temperature that rare earth electrolysis cell produces can reach 100 DEG C, after heat transfer tube heat exchange, flue-gas temperature is 40-50 DEG C, heat exchange pipeline is had in heat transfer tube, heat transferring medium is cold water, flow into and flue gas countercurrent flow from entrance, the hot water formed after heat exchange flows out from outlet, and water temperature can reach 60-70 DEG C, directly leads to and uses water mechanism.
Flue gas is dedusting in tornado dust collector, and dust drops in the ash bucket of bottom, and in ash bucket, dust content of rare earth is up to more than 70%, can directly recycle.By recycle pump by the water circulation use in absorption tower, after Oil repellent reaches finite concentration in water, use it for and extract villiaumite product, realize utilization of waste material and wastewater zero discharge.
Above-described embodiment only have expressed several embodiment of the present utility model, and it describes comparatively concrete and detailed, but therefore can not be interpreted as the restriction to the utility model the scope of the claims.It should be pointed out that for the person of ordinary skill of the art, without departing from the concept of the premise utility, can also make some distortion and improvement, these all belong to protection domain of the present utility model.Therefore, the utility model patent and protection domain should be as the criterion with appended claims.
Claims (1)
1. for a rare earth molten-salt electrolysis stove harmful smoke treatment facility, it is characterized in that: comprise heat transfer tube (1), tornado dust collector (2) and absorption column of gas (3), the inwall of described heat transfer tube (1) is provided with spiral heat exchange tube (4) along its length, the two ends up and down of described spiral heat exchange tube (4) are respectively equipped with heat transferring medium import (5) and heat transferring medium outlet (6), the lower end of described heat transfer tube (1) is connected with vacuum fan (7), the blast inlet of described vacuum fan (7) is provided with smoke absorption cover (8), the upper end of described heat transfer tube (1) connects the intake interface of described tornado dust collector (2) by tracheae, described tornado dust collector (2) give vent to anger interface connect flue (9), described flue (9) extend into the bottom of described absorption column of gas (3), and the bottom of tornado dust collector (2) is provided with the ash bucket (10) for collecting flue dust, described absorption column of gas (3) interior lower end is provided with circulation storage area (31), the top of described storage area (31) is fixed wtih a loose tobacco pipe (11), described loose tobacco pipe (11) smoke outlet upward and lower end is arranged on the smoke place end of described flue (9), described storage area (31) is connected with water spray circulation tube (12), water spray circulation tube (12) is provided with recycle pump (13), and the upper end of described water spray circulation tube (12) is provided with a draining fog spray head (14) of the inner upper end being arranged on absorption column of gas (3).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201520452073.4U CN204874777U (en) | 2015-06-29 | 2015-06-29 | Be used for tombarthite fused salt electrolysis stove to be harmful fume treatment auxiliary |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201520452073.4U CN204874777U (en) | 2015-06-29 | 2015-06-29 | Be used for tombarthite fused salt electrolysis stove to be harmful fume treatment auxiliary |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN204874777U true CN204874777U (en) | 2015-12-16 |
Family
ID=54819173
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201520452073.4U Expired - Fee Related CN204874777U (en) | 2015-06-29 | 2015-06-29 | Be used for tombarthite fused salt electrolysis stove to be harmful fume treatment auxiliary |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN204874777U (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105603459A (en) * | 2016-02-03 | 2016-05-25 | 中南大学 | Rare-earth electrolysis fume cleaning system and method |
| CN108057303A (en) * | 2017-12-25 | 2018-05-22 | 刘毅 | A kind of smog dedusting demister and its dedusting defogging method |
| CN108126454A (en) * | 2017-12-18 | 2018-06-08 | 重庆中色新材料有限公司 | A kind of rare earth permanent-magnetic material processing air outlet |
| CN108374184A (en) * | 2017-12-28 | 2018-08-07 | 龙南县中利再生资源开发有限公司 | A kind of high yield and saving energy re metal electrolyzing stove |
| CN116065199A (en) * | 2022-12-27 | 2023-05-05 | 广西国宸稀土金属材料有限公司 | A high-yield and energy-saving rare earth metal electrolytic furnace |
-
2015
- 2015-06-29 CN CN201520452073.4U patent/CN204874777U/en not_active Expired - Fee Related
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105603459A (en) * | 2016-02-03 | 2016-05-25 | 中南大学 | Rare-earth electrolysis fume cleaning system and method |
| CN105603459B (en) * | 2016-02-03 | 2018-05-11 | 中南大学 | Rare Earth Electrolysis flue gas purification system and method |
| CN108126454A (en) * | 2017-12-18 | 2018-06-08 | 重庆中色新材料有限公司 | A kind of rare earth permanent-magnetic material processing air outlet |
| CN108057303A (en) * | 2017-12-25 | 2018-05-22 | 刘毅 | A kind of smog dedusting demister and its dedusting defogging method |
| CN108057303B (en) * | 2017-12-25 | 2020-04-07 | 刘毅 | Smoke dedusting and demisting device and dedusting and demisting method thereof |
| CN108374184A (en) * | 2017-12-28 | 2018-08-07 | 龙南县中利再生资源开发有限公司 | A kind of high yield and saving energy re metal electrolyzing stove |
| CN116065199A (en) * | 2022-12-27 | 2023-05-05 | 广西国宸稀土金属材料有限公司 | A high-yield and energy-saving rare earth metal electrolytic furnace |
| CN116065199B (en) * | 2022-12-27 | 2026-03-24 | 广西国宸稀土金属材料有限公司 | A high-yield and energy-saving rare earth metal electrolytic furnace |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20151216 Termination date: 20160629 |