CN202201767U - Comprehensive electroplating wastewater treatment equipment - Google Patents
Comprehensive electroplating wastewater treatment equipment Download PDFInfo
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- CN202201767U CN202201767U CN201120315447XU CN201120315447U CN202201767U CN 202201767 U CN202201767 U CN 202201767U CN 201120315447X U CN201120315447X U CN 201120315447XU CN 201120315447 U CN201120315447 U CN 201120315447U CN 202201767 U CN202201767 U CN 202201767U
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- basin
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- 238000009713 electroplating Methods 0.000 title claims abstract description 42
- 238000004065 wastewater treatment Methods 0.000 title 1
- 239000002351 wastewater Substances 0.000 claims abstract description 29
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 23
- 238000005189 flocculation Methods 0.000 claims abstract description 15
- 230000016615 flocculation Effects 0.000 claims abstract description 15
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 42
- 229910052742 iron Inorganic materials 0.000 claims description 21
- 238000012856 packing Methods 0.000 claims description 20
- 239000002699 waste material Substances 0.000 claims description 19
- 230000015271 coagulation Effects 0.000 claims description 14
- 238000005345 coagulation Methods 0.000 claims description 14
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims description 10
- 235000011941 Tilia x europaea Nutrition 0.000 claims description 10
- 239000004571 lime Substances 0.000 claims description 10
- 238000006243 chemical reaction Methods 0.000 abstract description 7
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract description 6
- 229910001385 heavy metal Inorganic materials 0.000 abstract description 5
- 235000003891 ferrous sulphate Nutrition 0.000 abstract description 4
- 239000011790 ferrous sulphate Substances 0.000 abstract description 4
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 abstract description 4
- 229910000359 iron(II) sulfate Inorganic materials 0.000 abstract description 4
- 229910052804 chromium Inorganic materials 0.000 abstract description 3
- 239000011651 chromium Substances 0.000 abstract description 3
- 230000001112 coagulating effect Effects 0.000 abstract description 3
- 239000013049 sediment Substances 0.000 abstract description 3
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 abstract description 2
- 239000000945 filler Substances 0.000 abstract description 2
- 238000004062 sedimentation Methods 0.000 abstract description 2
- MBMLMWLHJBBADN-UHFFFAOYSA-N Ferrous sulfide Chemical compound [Fe]=S MBMLMWLHJBBADN-UHFFFAOYSA-N 0.000 abstract 5
- JOPOVCBBYLSVDA-UHFFFAOYSA-N chromium(6+) Chemical compound [Cr+6] JOPOVCBBYLSVDA-UHFFFAOYSA-N 0.000 abstract 2
- 239000002994 raw material Substances 0.000 abstract 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 8
- 238000007747 plating Methods 0.000 description 6
- 239000002253 acid Substances 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 239000000701 coagulant Substances 0.000 description 3
- 238000009833 condensation Methods 0.000 description 3
- 230000005494 condensation Effects 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000013019 agitation Methods 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 1
- 230000003044 adaptive effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
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- Removal Of Specific Substances (AREA)
- Separation Of Suspended Particles By Flocculating Agents (AREA)
Abstract
The utility model discloses a synthesize electroplating effluent treatment facility, including consecutive comprehensive electroplating effluent disposal basin, broken net pond, coagulating basin, flocculation basin, sedimentation tank, clean water basin, its characterized in that: the device is characterized in that a ferrous sulfide packed bed is further arranged between the decomplexing tank and the coagulating tank, a water inlet of the ferrous sulfide packed bed is positioned below the ferrous sulfide packed bed, and a water outlet of the ferrous sulfide packed bed is positioned above the ferrous sulfide packed bed. The utility model discloses regard as the slowly-releasing filler with ferrous sulfate, the electroplating effluent after will breaking the complex fully contacts reaction with ferrous sulfate, reduces hexavalent chromium into trivalent chromium and forms stable sulphide sediment with the heavy metal beyond hexavalent chromium. The utility model is used for synthesize electroplating effluent treatment and have: convenient operation, easy control, low operation cost, easy obtaining of raw materials, no need of continuous dosing, strong adaptability to waste water components, concentration and water quantity and the like.
Description
Technical field
The utility model relates to the electroplating wastewater processing field, particularly relates to a kind of integrative electroplating waste treatment facility.
Background technology
In the electroplating industry, that plating commonly used has is zinc-plated, copper facing, chromium plating, zinc-plated, cadmium plating etc.The source of its waste water is more extensive, is generally: (1) plating piece Cleaning Wastewater, (2) electroplating wastewater, (3) other waste water: comprise and wash away mill floor, scrub floor and ventilation installation water of condensation and because the various tank liquors and the draining of coating bath seepage or the improper run, drip, leak that cause of operational administrative; (4) equipment water of condensation: the equipment water of condensation in use except that cooling, does not generally receive the pollution of heavy metal.Wherein the plating piece Cleaning Wastewater is the main source of electroplating wastewater, almost accounts for more than 80% of workshop wastewater discharge.Contain high pollution materials such as a large amount of heavy metal ion and prussiate in the electroplating wastewater, toxicity is bigger.
The best treatment process of electroplating wastewater is the shunting of branch matter, handles respectively according to the situation of waste water.Yet at present, most of Electroplate Factory has a plurality of plating kinds simultaneously, and electroplating wastewater is not carried out the shunting of branch matter, causes various electroplating wastewater dual disposals, has brought certain difficulty for the processing of waste water.And also bigger for its water quality daily variation of same Electroplate Factory, add the bad control of dose, the dosing quantity not sufficient is then handled not up to standard, adds too much then processing cost increase of dose.
Summary of the invention
To the problems referred to above, the purpose of the utility model is providing a kind of integrative electroplating waste treatment facility of realizing the electroplating wastewater qualified discharge.
For achieving the above object; The technical scheme that the utility model proposed is: a kind of integrative electroplating waste treatment facility; Comprise the integrative electroplating waste pond, contact break pond, coagulation basin, flocculation basin, settling tank, the clean water basin that link to each other successively; It is characterized in that: also comprise an Iron sulfuret bed of packings between described contact break pond and coagulation basin; Described Iron sulfuret bed of packings water-in is positioned at Iron sulfuret bed of packings below, and water outlet is positioned at Iron sulfuret bed of packings top, and electroplating wastewater is from passing through the Iron sulfuret bed of packings down.
Further, be equipped with on the described contact break pond and add sour device and chlorinated lime adding set.
Further, describedly add in the sour device acid and be hydrochloric acid.
Further, adder-subtractor and PAC adding set are installed on the described coagulation basin.
Further, on the described flocculation basin PAM adding set is installed.
Further, adopt the integrative electroplating waste treatment process of aforesaid device: comprise the steps:
Step 1: with acid the pH in the contact break pond is transferred to acidity, and under agitation condition, add chlorinated lime, reaction 20-40min, added chlorinated lime is by 0.7-1.5kg/ ton electroplating wastewater;
Step 2: the waste water after the chlorinated lime contact break flows into the reaction of Iron sulfuret bed of packings;
Step 3: water outlet gets into coagulation basin in the Iron sulfuret bed of packings, in coagulation basin, adds alkali and regulates pH for alkaline, and add the PAC coagulating agent, and stirring reaction 5-10min gets into flocculation basin behind the coagulating sedimentation, and added PAC coagulating agent is by 50-500g/ ton electroplating wastewater;
Step 4: in flocculation basin, adding massfraction is the PAM flocculation agent of 0.5-1.0%, and added PAM is by 100-500ml/ ton electroplating wastewater; Slowly stir 1-2min, get into settling tank, behind the flocculation sediment, produce water and get into clean water basin.
Further, the added acid in the step 1 is hydrochloric acid.
Further, pH transfers to below 3.5 in the step 1.
Further, pH transfers to 7.5-8.5 in the step 3.
In sum, the utility model,, becomes hexavalent chrome reduction trivalent chromium and forms stable sulfide precipitation with sexavalent chrome heavy metal in addition abolishing complex compound electroplating wastewater and the abundant contact reacts of ferrous sulfate afterwards as the slowly-releasing filler with ferrous sulfate.The utility model is used for integrative electroplating waste to be handled, and has following advantage:
1) present method is easy to operate, and is easy to control, and working cost is low, and starting material obtain easily;
2) need not continuous dosing, waste water component, concentration, the water yield are all had stronger adaptive faculty;
3) all can effectively remove the heavy metal ion in the waste water, particularly therefore sexavalent chrome is applicable to the processing integrative electroplating waste.
Description of drawings
Fig. 1 is the described integrative electroplating waste treatment facility of a utility model substruction;
Fig. 2 is described another structure iron of integrative electroplating waste treatment facility of the utility model;
Wherein: 10. integrative electroplating waste pond, 11. contact break ponds, 110. add sour device, 111. chlorinated lime adding sets, 12. Iron sulfuret bed of packings, 13. coagulation basins, 130. adder-subtractors, 131.PAC adding set, 14. flocculation basins, 140.PAM adding set, 15. settling tanks, 16. clean water basin.
Embodiment
Below in conjunction with accompanying drawing and specific embodiment, the utility model is further specified.
As shown in Figure 1; A kind of integrative electroplating waste treatment facility; Comprise the integrative electroplating waste pond 10, contact break pond 11, Iron sulfuret bed of packings 12, coagulation basin 13, flocculation basin 14, settling tank 15, the clean water basin 16 that link to each other successively; Iron sulfuret bed of packings 12 water-ins are positioned at Iron sulfuret bed of packings 12 belows, and water outlet is positioned at Iron sulfuret bed of packings 12 tops, and the integrative electroplating waste that comes out in contact break pond 11 is from passing through Iron sulfuret bed of packings 12 down; Water outlet from the top comes out again, gets into coagulation basin 13.As shown in Figure 2; Compared to Figure 1, be equipped with on the contact break pond 11 and add sour device 110 and chlorinated lime adding set 111, the acid that adds in the sour device 110 is hydrochloric acid; Adder-subtractor 130 and PAC adding set 131 are installed on the coagulation basin 13, PAM adding set 140 is installed on the flocculation basin 14.
Embodiment 1:
1) with hydrochloric acid the pH in the contact break pond is transferred to 3.0, and under agitation condition, add chlorinated lime, reaction 30min, added chlorinated lime is by 0.7kg/ ton electroplating wastewater;
2) waste water after the chlorinated lime contact break flows into the reaction of Iron sulfuret bed of packings;
3) water outlet gets into coagulation basin in the Iron sulfuret bed of packings, in coagulation basin, adds adjusting PH with base=8.0, and adds 200g/ ton electroplating wastewater PAC coagulating agent, stirring reaction 7min;
4) in flocculation basin, add 200ml/ ton electroplating wastewater, massfraction is 0.5% PAM flocculation agent.Slowly stir 2min, get into settling tank, behind the flocculation sediment, produce water and get into clean water basin, experimental result is seen table one.
Table one: experimental result
Although specifically show and introduced the utility model in conjunction with preferred embodiment; But the those skilled in the art should be understood that; In the spirit and scope of the utility model that does not break away from appended claims and limited; In form with on the details the utility model is made various variations, be the protection domain of the utility model.
Claims (4)
1. integrative electroplating waste treatment facility; Comprise the integrative electroplating waste pond, contact break pond, coagulation basin, flocculation basin, settling tank, the clean water basin that link to each other successively; It is characterized in that: also comprise an Iron sulfuret bed of packings between described contact break pond and coagulation basin; Described Iron sulfuret bed of packings water-in is positioned at Iron sulfuret bed of packings below, and water outlet is positioned at Iron sulfuret bed of packings top, and electroplating wastewater is from passing through the Iron sulfuret bed of packings down.
2. a kind of integrative electroplating waste treatment facility according to claim 1 is characterized in that: be equipped with on the described contact break pond and add sour device and chlorinated lime adding set.
3. a kind of integrative electroplating waste treatment facility according to claim 1 is characterized in that: adder-subtractor and PAC adding set are installed on the described coagulation basin.
4. a kind of integrative electroplating waste treatment facility according to claim 1 is characterized in that: the PAM adding set is installed on the described flocculation basin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201120315447XU CN202201767U (en) | 2011-08-25 | 2011-08-25 | Comprehensive electroplating wastewater treatment equipment |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201120315447XU CN202201767U (en) | 2011-08-25 | 2011-08-25 | Comprehensive electroplating wastewater treatment equipment |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN202201767U true CN202201767U (en) | 2012-04-25 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201120315447XU Expired - Fee Related CN202201767U (en) | 2011-08-25 | 2011-08-25 | Comprehensive electroplating wastewater treatment equipment |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN202201767U (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102336486A (en) * | 2011-08-25 | 2012-02-01 | 厦门市威士邦膜科技有限公司 | Integral electroplating waste water treatment equipment and process |
| CN104058520A (en) * | 2014-07-09 | 2014-09-24 | 奥加诺(苏州)水处理有限公司 | Process method for deeply treating low-concentration chelated heavy metal wastewater |
| CN105280261A (en) * | 2015-10-01 | 2016-01-27 | 南华大学 | Uranium electroreduction and precipitation method used in uranium-containing wastewater treatment |
-
2011
- 2011-08-25 CN CN201120315447XU patent/CN202201767U/en not_active Expired - Fee Related
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102336486A (en) * | 2011-08-25 | 2012-02-01 | 厦门市威士邦膜科技有限公司 | Integral electroplating waste water treatment equipment and process |
| CN104058520A (en) * | 2014-07-09 | 2014-09-24 | 奥加诺(苏州)水处理有限公司 | Process method for deeply treating low-concentration chelated heavy metal wastewater |
| CN105280261A (en) * | 2015-10-01 | 2016-01-27 | 南华大学 | Uranium electroreduction and precipitation method used in uranium-containing wastewater treatment |
| CN105280261B (en) * | 2015-10-01 | 2017-06-09 | 南华大学 | A kind of method that electroreduction for uranium-containing waste water treatment precipitates uranium |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C56 | Change in the name or address of the patentee |
Owner name: VISBE (XIAMEN) ENVIRONMENTAL TECHONLOGY CO., LTD. Free format text: FORMER NAME: XIAMEN VISBE FILM TECHNOLOGY CO., LTD. |
|
| CP01 | Change in the name or title of a patent holder |
Address after: 101, 17, 102, Xiang Yue Road, 361000 torch hi tech Zone (Xiangan) Industrial Zone, Fujian, Xiamen Patentee after: XIAMEN VISBE MEMBRANE TECHNOLOGY CO., LTD. Address before: 101, 17, 102, Xiang Yue Road, 361000 torch hi tech Zone (Xiangan) Industrial Zone, Fujian, Xiamen Patentee before: Xiamen Visbe Membrane Technology Co., Ltd. |
|
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20120425 Termination date: 20140825 |
|
| EXPY | Termination of patent right or utility model |