Ultraviolet ray irradiation ball aluminum powder surface generates the device of pellumina
Technical field
The utility model is to produce the device that the crystal silicon solar batteries back electrode is used with surface of ball aluminum powder activated alumina film; Solve surface alumina oxide film content and active out of contior problem in the ball aluminum powder production process, belong to the metal-powder technical field of surface.
Background technology
Back electrode of solar cell need generate the pellumina that certain activity is arranged on the surface with ball aluminum powder; Prevent that aluminium and solvent, auxiliary agent from reacting in configuration during electrocondution slurry, the slurry of ball aluminum powder preparation during with the crystal silicon sintering formation vitreum prevent that aluminium and silicon from directly reacting the high-resistance alusil alloy body of formation and silicon is had P type doping function.Now the ball aluminum powder surface generate the method for pellumina be aluminium liquid with in inert gas (as: nitrogen) the pneumatic nebulization globulate aluminium powder process, through the certain content oxygen of increase in inert gas, aluminium liquid pearl and oxygen generation oxidation reaction form during atomizing.The pellumina that produces like this is that high-temperature oxydation generates, and activity is very low, and uncontrollable degree of oxidation.
Summary of the invention
The conveying system that device is made up of blower fan and pipeline, stainless steel ultraviolet ray exposure cell, three parts of stainless steel rewinding jar constitute.The ultraviolet ray exposure cell is the casing of stainless steel; The high-power ultraviolet lamp of wavelength 185nm is housed in the exposure cell; Gas grain conveyance conduit in the exposure cell is high transparent quartz glass tube; Ultraviolet ray sees through quartz glass tube and shines on the gas grain mixture, and ozone and aluminium powder react under nitrogen protection atmosphere, generates pellumina; The two ends, exposure cell have air inlet and air outlet, lower the temperature to room ventilation through the fan of air inlet; The ball aluminum powder that generates pellumina gets into the rewinding jar through exposure cell's output channel, and the rewinding jar is the column type tank body that stainless steel is processed, and the lower end is the back taper body, and the cone bottom is connected to butterfly valve as the discharging valve; Rewinding jar top is connected to discharge duct; Between pipeline and the tank body filter cloth is installed; Gas grain amalgam separates the ball aluminum powder that generates pellumina through filter cloth with gas, gas is discharged from rewinding jar discharge duct; The ball aluminum powder that generates pellumina is stayed in the rewinding jar, has the ball aluminum powder of pellumina to emit through the bleeder valve door knob; The rewinding tank shell is equipped with the earth connection of resistance<3 ohm, and the static that produces ball aluminum powder eliminates.
This device is to be that ball aluminum powder generates pellumina under cryogenic conditions; Active high; And can control the content that ball aluminum powder surface alumina oxide film generates through power, adjustment ozone and the content of aluminium powder of adjustment blower fan wind speed change ultraviolet irradiation time, adjustment ultraviolet lamp.
Description of drawings:
Accompanying drawing is a schematic side view
1, feeding pipe; 2, defeated material blower fan; 3, ultraviolet exposure cell; 4, ultraviolet exposure cell's cooling air import; 5, ultraviolet exposure cell cooling air outlet; 6, high transparent quartz glass tube; 7, ultraviolet lamp; 8, exposure cell's cooling air inlet fan; 9, ultraviolet lamp power line; 10, flange; 11, go out ultraviolet exposure cell feeding pipe; 12, rewinding jar; 13, rewinding jar discharging valve; 14, filter cloth; 15 rewinding jar discharge ducts; 16 earth connections.
The specific embodiment:
1, the ground connection of detecting earth connection (16) is communicated with and resistance<3 ohm; Start ultraviolet exposure cell's cooling air inlet fan (8); Air is after ultraviolet exposure cell's cooling air import (4) gets into ultraviolet exposure cell (3); Flow out by ultraviolet exposure cell cooling air outlet (5), ultraviolet exposure cell (3) are ventilated, start ultraviolet lamp (7) then.
2, start defeated material blower fan (2), contain<nitrogen of 5% ozone and the gas grain mixture of ball aluminum powder, get into ultraviolet exposure cell (3), ball aluminum powder concentration control<15% in the gas grain mixture from feeding pipe (1).
3, the gas grain mixture of ozone, nitrogen and ball aluminum powder, through the irradiation of ultraviolet lamp (7), pellumina takes place to combine rapidly to generate with the ball aluminum powder top layer in ozone during through high transparent quartz glass tube (6).
4, ozone and the content of aluminium powder in the power of the wind speed of adjustment defeated material blower fan (2) change ultraviolet irradiation time, adjustment ultraviolet lamp (7), the adjustment gas can both be adjusted the content that ball aluminum powder surface alumina oxide film generates.
5, the ball aluminum powder that generates pellumina gets into rewinding jar (12) through going out ultraviolet exposure cell feeding pipe (11).
6, gas permeation filter cloth (14) separates the ball aluminum powder that generates pellumina with gas, gas is discharged from rewinding jar discharge duct (15), and the ball aluminum powder that generates pellumina is stayed in the rewinding jar (12).
7, open rewinding jar discharging valve (13), emit the ball aluminum powder that generates pellumina, pack.