CN202079073U - Real-time treatment system using high-energy oxygen for hydrolyzing and oxidizing organic biomass - Google Patents

Real-time treatment system using high-energy oxygen for hydrolyzing and oxidizing organic biomass Download PDF

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Publication number
CN202079073U
CN202079073U CN2011201488279U CN201120148827U CN202079073U CN 202079073 U CN202079073 U CN 202079073U CN 2011201488279 U CN2011201488279 U CN 2011201488279U CN 201120148827 U CN201120148827 U CN 201120148827U CN 202079073 U CN202079073 U CN 202079073U
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tank
micro
slurry
nano bubble
organic
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杨霆
戴礼潜
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SHENZHEN SHENZHOU CHUANGYU LOW CARBON TECHNOLOGY Co Ltd
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SHENZHEN SHENZHOU CHUANGYU LOW CARBON TECHNOLOGY Co Ltd
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Abstract

The utility model relates to a real-time treatment system using high-energy oxygen for hydrolyzing and oxidizing organic biomass, which comprises an organic biomass crushing slurrying machine, a slurry ozone micro-nano bubble oxidative degradation tank and an aerobic oxidation treatment tank. The organic biomass crushing slurrying machine is connected with a slurry pH (potential of hydrogen) value adjusting tank; the slurry pH value adjusting tank is connected with the slurry ozone micro-nano bubble oxidative degradation tank; one side of the slurry ozone micro-nano bubble oxidative degradation tank is continuously connected with a depth hydrolysis and oxidation tank, a centrifugal dehydrator, a heavy metal filter film, a micro-nano bubble generator, an aeration tank and the aerobic oxidation treatment tank; the aerobic oxidation treatment tank is sequentially connected with a sand filter purifying tank and a purified water collecting tank; and the aeration tank is connected with the micro-nano bubble generator. The real-time treatment system has the advantages that harmless treatment for the organic biomass of domestic garbage and kitchen garbage is completed rapidly, waste is turned into treasure, and a foundation is laid for recycling energy and resources in the organic biomass.

Description

With high energy oxygen hydrolysis oxidation organic-biological matter real time processing system
Technical field
The utility model relates to a kind of with high energy oxygen hydrolysis oxidation organic-biological matter real time processing system.
Background technology
Organic-biological matter is the international difficult problem in the domestic rubbish disposal, also is most important pollution sources in the house refuse, still is the main component of rubbish from cooking simultaneously.It is the key that domestic rubbish disposal, catering trade rubbish from cooking are handled that organic-biological matter fast and harmless is handled, and has only the harm of thorough elimination organic-biological matter, could the calm processing of considering the Other Waste composition, satisfy that garbage disposal is innoxious, the requirement of minimizing.
The organic-biological matter processing mode mainstream technology of present domestic routine is landfill, burning, compost etc., and these processing means all can not be finished the fast and harmless of organic-biological matter and rubbish from cooking and handle, and therefore has great application limitation.For example, the landfill waste floor space is big, and according to incompletely statistics, the land area that China's garbage loading embeading takies has reached 50,000 square kilometres, is equivalent to 1/192 of China's territory gross area.Rubbish organic-biological matter generation anaerobic fermentation is very easily bred pathogenic bacteria, virus and other harmful organisms, especially garbage leachate soil and underground water source is caused severe contamination behind the landfill, and landfill gas is to causing serious air pollution around the refuse landfill.In addition, also there is the danger that sets off an explosion in the methane in the garbage loading embeading gas, and is unfavorable for social stability and community's harmony, and the resource of recyclable utilization is wasted fully in the rubbish.Though incineration treatment of garbage can be generated electricity or heat supply, there is the contradiction that investment is big, operation cost is high; China's house refuse calorific value is low, water content is big, and waste incineration also can produce strong carcinogen dioxin and nitrogen oxide, harm humans life security and health.The organic-biological matter compost treatment cycle long (one month), floor space is bigger, can constantly produce hydrogen sulfide, organic sulfur compound, indoles, aldehyde, the ketone material of the generation of kind more than totally 200 stench in the composting process, the severe contamination atmosphere, wherein kind belongs to carcinogenic substance more than 20.And can add stench and peculiar smell because of the corrupt substance that produces in the composting process, and cause mosquito, fly parasitism, become the epidemic disease carrier, influence environmental sanitation and publilc health.In addition, compost also produces methane, has hidden peril of explosion.In addition, compost fermentation sterilization degree is low, and hypopus of the harmful bacterium in the compost body (gemma) and heat-resisting pathogenic bacteria all grow in a large number, can accumulate a large amount of toxin and can produce secondary pollution to environment.At last, because active organic matter has been consumed by the long-term metabolism decomposition of microorganism, the organic matter that compost obtains is the nonactive organic matter of humic acids.Inorganic content height in the compost can destroy the physical arrangement in the soil.
Therefore above-mentioned various processing modes can not solve the substantive issue of garbage disposal, bigger secondary pollution are arranged, threatening environment safety and human health.
The processing of organic-biological matter is with minimizing and harmlessly turn to basic demand, and realize that minimizing and innoxious effective means are exactly to finish the oxidative degradation of organic-biological matter fast, organic-biological matter all is degraded to the small organic molecule of stablizing the carbon structure, eliminate the constitution water in the organic-biological matter, eliminate organic-biological matter fermentation function.
The utility model content
The purpose of this utility model provides a kind of with high energy oxygen hydrolysis oxidation organic-biological matter real time processing system, and the quick oxidative degradation of realization organic-biological matter reaches organic-biological matter and handles innoxious purpose.
The purpose of this utility model is to be achieved through the following technical solutions:
A kind of with high energy oxygen hydrolysis oxidation organic-biological matter real time processing system, comprise organic living beings pulverizing pulper, the micro-nano bubble oxidative degradation of the slurry ozone jar oxidation processes groove of becoming reconciled, described organic-biological matter is pulverized pulper and is connected with slurry pH value adjustment jar, the slurry pH value is adjusted jar and is connected with the micro-nano bubble oxidative degradation of slurry ozone jar, the micro-nano bubble oxidative degradation of slurry ozone jar is connected with depth hydrolysis's oxidation trough, depth hydrolysis's oxidation trough is connected with centrifugal dehydrator, centrifugal dehydrator is connected with the heavy metal filter membrane, the heavy metal filter membrane is connected with the aeration tank, described aeration tank is connected with the micro-nano bubble generator oxidation processes groove of becoming reconciled respectively again, good oxidation treatment trough is connected with the sand filtration purification tank, and the sand filtration purification tank connects the feeder of purifying waste water again.
The beneficial effects of the utility model are: finish the harmless treatment of house refuse organic-biological matter and rubbish from cooking fast, and turn waste into wealth, for the energy and the resource that reclaim in the organic-biological matter are laid a good foundation.
Description of drawings
With reference to the accompanying drawings the utility model is described in further detail below.
Fig. 1 is the described a kind of syndeton schematic diagram with high energy oxygen hydrolysis oxidation organic-biological matter real time processing system of the utility model embodiment.
Among the figure:
1, organic-biological matter is pulverized pulper; 2, the slurry pH value is adjusted jar; 3, the micro-nano bubble oxidative degradation of slurry ozone jar; 4, depth hydrolysis's oxidation trough; 5, centrifugal dehydrator; 6, heavy metal filter membrane; 7, micro-nano bubble generator; 8, aeration tank; 9, good oxidation treatment trough; 10, sand filtration purification tank; 11, the feeder of purifying waste water.
The specific embodiment
As shown in Figure 1, the utility model embodiment is described a kind of with high energy oxygen hydrolysis oxidation organic-biological matter real time processing system, comprise organic living beings pulverizing pulper 1, the micro-nano bubble oxidative degradation of the slurry ozone jar 3 oxidation processes groove 9 of becoming reconciled, described organic-biological matter is pulverized pulper 1 and is connected with slurry pH value adjustment jar 2, the slurry pH value is adjusted jars 2 and is connected with the micro-nano bubble oxidative degradation of slurry ozone jar 3, the micro-nano bubble oxidative degradation of slurry ozone jar 3 is connected with depth hydrolysis's oxidation trough 4, depth hydrolysis's oxidation trough 4 is connected with centrifugal dehydrator 5, centrifugal dehydrator 5 is connected with heavy metal filter membrane 6, heavy metal filter membrane 6 is connected with aeration tank 8, described aeration tank 8 is connected with the micro-nano bubble generator 7 oxidation processes groove 9 of becoming reconciled respectively again, good oxidation treatment trough 9 is connected with sand filtration purification tank 10, and sand filtration purification tank 10 connects the feeder 11 of purifying waste water again.
With high energy oxygen hydrolysis oxidation organic-biological matter real-time processing method, use micro-nano bubble technology to make high energy ozone and pure oxygen, concrete steps comprise:
1) pulverize pulper 1 by organic-biological matter organic-biological matter is worn into slurry, rubbish organic-biological matter solid pollution is converted into the mud liquid contamination, and pollution abatement in liquid environment;
2) adjust the pH value of regulating organic-biological chylema body in the jar 2 at the slurry pH value, make slurry be in acid condition, be convenient to the best oxidation effectiveness of ozone performance;
3) use micro-nano bubble generator 7 to make the micro-nano bubble aqueous solution of ozone, make the ozone concentration of the aqueous solution reach the over-saturation state, and make pure oxygen concentration reach over-saturation;
4) by the ozone slurry, the micro-nano bubble oxidative degradation of ozone jar 3 mixes back performance oxidative degradation with Ozone Water with organic-biological chylema body, cracks the biological structure (cell) and the organic compound of organic-biological matter, releasing structure water;
5) by the deep oxidation effect of the micro-nano bubble of pure oxygen, the oxidation Decomposition organic compound reaches stablizes the carbon configuration state;
6) deviate from water in the slurry by centrifugal dehydrator 5, obtain dryly stablizing carbon structure organic matter (moisture 20-40%), eliminate organic biologically active;
7) water deviate from of centrifugal dehydrator 5 is through the micro-nano bubble aeration of pure oxygen, and the pollutant in the oxidative degradation water makes water quality obtain preliminary purification;
8) sewage of oxidative degradation pollutant is eliminated heavy metal through equipotential heavy metal ion polymerization filter membrane 6;
9) water of preliminary purification is by the effect of aerobic bacteria, eliminates water pollutant, reaches the purification of water quality purpose, if the residual contamination owner suspended contaminant (MLSS) at this moment in the water;
10) water after the purification filters through sand filtration purification tank 10, eliminates the suspended contaminant (MLSS) in the water at last, gives off clean water.
In above-mentioned process with high energy oxygen hydrolysis oxidation organic-biological matter real-time processing method, in step 1): the preparation method that described organic-biological matter pulverizing pulper 1 is worn into slurry with organic-biological matter can be that the muddy flesh machine is pulverized or pulverized with the water mill rice-flour noodles machine.
In above-mentioned process with high energy oxygen hydrolysis oxidation organic-biological matter real-time processing method, step 2) to regulate the acid that needs to use can be sulfuric acid, hydrochloric acid or nitric acid to pH value in.
In above-mentioned process with high energy oxygen hydrolysis oxidation organic-biological matter real-time processing method, in step 3): the aeration mode that described micro-nano bubble generator 7 adopts when making the micro-nano bubble of ozone can be that straight tube spiral quickens aeration or the right angle vortex quickens aeration, the aerator that adopts can be single straight tube aeration, also can be the parallel connection of a plurality of straight tube aeration.
In above-mentioned process with high energy oxygen hydrolysis oxidation organic-biological matter real-time processing method, the aeration mode that uses in the step 3) can be the vacuum aeration, also can be the supercharging aeration.
In above-mentioned process with high energy oxygen hydrolysis oxidation organic-biological matter real-time processing method, in step 3): described micro-nano bubble generator 7 ozoniferous source of the gas when making the micro-nano bubble of ozone can be an air, also can be the pure oxygen oxygenerator.
In above-mentioned process with high energy oxygen hydrolysis oxidation organic-biological matter real-time processing method, rapid 4) the ozone carrier that uses in can be an Ozone Water, also can be under the higher condition of slurry water content directly with aerator to the micro-nano bubble of slurry input ozone.
In above-mentioned process with high energy oxygen hydrolysis oxidation organic-biological matter real-time processing method, step 6), 7), the bed mud that produces 9), 10) sends back to step 2 through after the backwash) circulate in utilization.
In above-mentioned process with high energy oxygen hydrolysis oxidation organic-biological matter real-time processing method, in the step 8) granularity of heavy metal polymerization greater than 0.5 micron, the equipotential solution pH value place of use between 11-12, the filter membrane metal selective filter membrane of attaching most importance to.
During concrete the use, organic-biological matter enters pulverizes pulper 1, enter pH value adjustment jar 2 after the pulverizing and carry out the pH value adjustment, slurry enters in the micro-nano bubble oxidative degradation of the slurry ozone jar 3 then, carry out ozone hydrolysis oxidation reaction, enter 4 kinds of depth hydrolysis's oxidation troughs then and carry out the deep oxidation degraded, material was poured in the centrifugal dehydrator 5 and is dewatered after oxidative degradation was finished, dehydration back dry material takes out, carry out recycling, behind the sewage process heavy metal filter membrane 6 filtering heavy metals of deviating from, water enters and carries out aerobic aeration in the aeration tank 8, aerobic aeration uses the micro-nano bubble of micro-nano bubble generator 7 input pure oxygens, sewage has entered and has carried out the aerobic microbiological oxidation processes in the oxidation treatment trough 9 behind the aeration, purifying waste water after the processing enters sand filtration purification tank 10 and carries out filtration treatment, and the clear water that obtains at last enters the feeder 11 of purifying waste water, supply production reuse.
Theoretical foundation with high energy oxygen hydrolysis oxidation organic-biological matter real time processing system is specific as follows:
High energy oxygen is meant the micro-bubble that active oxygen (ozone or pure oxygen) ion cluster with higher-energy and micel constitute, and mainly is present in the water environment.
Use micro-nano bubble generator 7 in water, to import ozone or pure oxygen, in gas-liquid mixed, cause the ionization of portion gas molecule because of dissection to gas, so the particle diameter of 90% above bubble is between 5 nanometers to 50 micron in the bubble that produces through the effect of at a high speed rotation and pressurization gradually, characteristic with charged particle, so ozone that obtains or pure oxygen micro-bubble are actual to be ozone or pure oxygen ion group, it is active oxygen radical, this active oxygen radical has very high energy, and the source of energy is as follows:
1, ionization energy:
Ozone or pure oxygen produce mechanical ionization through cutting, and the generating portion oxonium ion forms active oxygen ion group, mainly comprises (the O of ozone ion group 3 2-, O 3 -), (O of ozone molecule group 3), (O of oxonium ion group 2 2-, O 2 -), (O of oxygen molecule group 2) etc., these active oxygen air mass have very high ionization energy, make the bubble particle produce energy level transition, reach the high level that can produce oxidation at any time, can all materials that touch of oxidation.
2, high speed kinetic energy:
The active oxygen micro-bubble produces ozone or the centrifugal cutting suction of pure oxygen effect through water, generate the air water mixing material, bubble is accompanied by the accelerated motion in the vortex accelerating system of the cutting aqueous solution, since the characteristics of vortex accelerating system be into the water total amount with eject water inventory and equate, and the water inlet diameter is 4 times of the delivery port diameter, so the aqueous solution flow velocity of two delivery ports and instantaneous pressure will reach 8 times of water inlet aqueous solution flow velocity and pressure, speed reaches the 160-320 meter per second, instantaneous pressure reaches 3.2-4MPa, the kinetic energy that the active oxygen micro-bubble is had is very high, be enough in effective propagation path, to break any pollutant and be connected with the chemical bond of pollutant inside with covalent bond between the hydrone and be connected, realize the purification of water quality reduction and the oxidative degradation of pollutant.
Micro-bubble and several typical object of which movement speed contrast:
Kind Speed
Hydrogen molecule 1768 meter per seconds
Rifle bullet The 700-1000 meter per second
The active oxygen bubble The 160-320 meter per second
Jet plane 278 meter per seconds
High-speed railway 83 meter per seconds
3, other energy
Other energy comprises the blast energy that intermolecular energy, bubble break etc.
4, the effect of energy
Multiple energy coexists in the active oxygen micro-bubble, makes the active oxygen bubble have the particle energy of superelevation, and the rank of energy is equivalent to the heat motion of gas molecules energy of gas under 6000-8000 ℃ of condition, reach hundreds of thousands in addition million electron volt more than.These energy can directly destroy the chemical constitution of pollutant in sewage, taking place to play a role the process of guiding and accelerating oxidation reaction before the oxidation reaction.
The motion of active oxygen micro-bubble is caused by the bubble self-energy, bubble makes liquid be heated to the critical condition that chemical reaction can take place at any time in high-speed motion, wherein chemical reaction will be unthinkable with us, can not take place from the speed that the angle of physics is inferred, thereby reach the purpose of oxidative degradation organic-biological matter.
After this treatment process process is finished, obtain stablizing the small organic molecule of carbon structure, these small organic molecules can carry out recycling, can produce organic bio-fertilizer, also can be used for the pyrolytic gasification generating recovery energy wherein.Use high energy oxygen technology to finish the oxidative degradation of organic-biological matter, can be applied to the harmless treatment of house refuse organic-biological matter, can also be used for rubbish from cooking processing and sewage bed mud and handle.

Claims (1)

1. one kind with high energy oxygen hydrolysis oxidation organic-biological matter real time processing system, comprise organic living beings pulverizing pulper (1), the micro-nano bubble oxidative degradation of slurry ozone jar (3) the oxidation processes groove (9) of becoming reconciled, it is characterized in that: described organic-biological matter is pulverized pulper (1) and is connected with slurry pH value adjustment jar (2), the slurry pH value is adjusted jar (2) and is connected with the micro-nano bubble oxidative degradation of slurry ozone jar (3), the micro-nano bubble oxidative degradation of slurry ozone jar (3) is connected with depth hydrolysis's oxidation trough (4), depth hydrolysis's oxidation trough (4) is connected with centrifugal dehydrator (5), centrifugal dehydrator (5) is connected with heavy metal filter membrane (6), heavy metal filter membrane (6) is connected with aeration tank (8), described aeration tank (8) is connected with micro-nano bubble generator (7) the oxidation processes groove (9) of becoming reconciled respectively again, good oxidation treatment trough (9) is connected with sand filtration purification tank (10), and sand filtration purification tank (10) connects the feeder (11) of purifying waste water again.
CN2011201488279U 2011-05-11 2011-05-11 Real-time treatment system using high-energy oxygen for hydrolyzing and oxidizing organic biomass Expired - Fee Related CN202079073U (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102746034A (en) * 2012-07-16 2012-10-24 惠州市神州创宇低碳技术发展有限公司 Method for producing microorganism luminous energy organic fertilizer by utilizing table/kitchen wastes
CN104259177A (en) * 2014-09-12 2015-01-07 湖南树林环境科技有限公司 Method for producing soil conditioner raw material by using kitchen garbage and solid agriculture and forestry wastes
CN106277178A (en) * 2016-08-05 2017-01-04 北京未名清源环保科技有限公司 A kind of micro-nano bubble degradation treatment system and method containing organic pollution water body
CN106630096A (en) * 2016-11-09 2017-05-10 江苏宜星星晨环境工程有限公司 High-energy-oxygen water purifier system
CN108911242A (en) * 2018-07-23 2018-11-30 广东上智环保科技有限公司 A kind of super nano bubble circulation ozone sewage water treatment method and device
CN110615550A (en) * 2019-08-12 2019-12-27 中原环资科技有限公司 Water recycling technology for fine garbage sorting process

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102746034A (en) * 2012-07-16 2012-10-24 惠州市神州创宇低碳技术发展有限公司 Method for producing microorganism luminous energy organic fertilizer by utilizing table/kitchen wastes
CN102746034B (en) * 2012-07-16 2014-05-07 惠州市神州创宇低碳技术发展有限公司 Method for producing microorganism luminous energy organic fertilizer by utilizing table/kitchen wastes
CN104259177A (en) * 2014-09-12 2015-01-07 湖南树林环境科技有限公司 Method for producing soil conditioner raw material by using kitchen garbage and solid agriculture and forestry wastes
CN106277178A (en) * 2016-08-05 2017-01-04 北京未名清源环保科技有限公司 A kind of micro-nano bubble degradation treatment system and method containing organic pollution water body
CN106630096A (en) * 2016-11-09 2017-05-10 江苏宜星星晨环境工程有限公司 High-energy-oxygen water purifier system
CN108911242A (en) * 2018-07-23 2018-11-30 广东上智环保科技有限公司 A kind of super nano bubble circulation ozone sewage water treatment method and device
CN110615550A (en) * 2019-08-12 2019-12-27 中原环资科技有限公司 Water recycling technology for fine garbage sorting process

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