CN201862409U - Ultrasonic auxiliary electric reactor - Google Patents
Ultrasonic auxiliary electric reactor Download PDFInfo
- Publication number
- CN201862409U CN201862409U CN2010205759171U CN201020575917U CN201862409U CN 201862409 U CN201862409 U CN 201862409U CN 2010205759171 U CN2010205759171 U CN 2010205759171U CN 201020575917 U CN201020575917 U CN 201020575917U CN 201862409 U CN201862409 U CN 201862409U
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- CN
- China
- Prior art keywords
- dividing plate
- electric reactor
- partitions
- exchange membrane
- electrode
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Abstract
An ultrasonic auxiliary electric reactor comprises anion exchange membranes and partitions, cation exchange membranes and partitions, a negative electrode, a positive electrode, ultrasonic vibrators and a shell, and an external direct-current power supply is connected to the reactor. The negative electrode, the positive electrode, the anion exchange membranes and partitions, and the cation exchange membranes and partitions are arranged in parallel according to a specific sequence, the arrangement way is shown in the figure 1, and the ultrasonic vibrators are connected with an external ultrasonic generator. The electric reactor adopting ultrasonic wave as an aid solves the problems of easiness in hole blockage of ion membranes, easiness in electrode pollution and low current effective utilization rate, effectively solves the problem of hole blockage of the ion membranes, reduces electrode pollution as far as possibly, increases current efficiency, is an highly efficient electric reactor which integrates electric oxidation and reduction, and electrodialytic dealkalization and desalination, and is suitable for electrosynthesis.
Description
Technical field
The utility model relates to a kind of electricity that is applicable to and synthesizes current collection oxidation, electroreduction and the electrodialysis dealkalize of use, desalination, the electric reactor that multinomial function can be used simultaneously.
Background technology
All the time, electricity is synthetic generally acknowledges with unrivaled high selectivity of its chemical synthesis and the environment-friendly advantage educational circles that internationalized, but because the synthetic a large amount of electric energy of consumption that needs of electricity, the Reactive Mechanism of Electrode complexity, electrode is contaminated easily in the course of reaction, reasons such as current efficiency is low, its development is restricted always; In recent years, the high speed development of China's nuclear power, water power, wind-powered electricity generation provided sufficient electric power resource for electricity is synthetic, had promoted the development in electric synthetic field greatly.
Summary of the invention
The utility model is primarily aimed at that electrode easily pollutes, the easy plug-hole of ionic membrane and the low problem of electric current effective rate of utilization have designed a kind of by the electric reactor of ultrasonic wave as auxiliary equipment, effectively solve zwitterion film plug-hole problem, at utmost reduce electrode fouling, improve carrying current, the electric current utilization ratio had been turned over one times in theory when electrodialysis was simultaneously carried out simultaneously with electricity is synthetic.
The ultrasonic wave auxiliary electrical reactor that the utility model is related is to be made of external direct current power supply cationic membrane, dividing plate, anionic membrane, dividing plate, anode, negative electrode, supersonic oscillator and shell; Its technical scheme that adopts is that zwitterion film and dividing plate, anodic-cathodic are arranged in parallel in order, electric reactor is divided into a plurality of intervals, anode-side begins to arrange with anion-exchange membrane and dividing plate, it is right that cation-exchange membrane and dividing plate and anion-exchange membrane and dividing plate constitute a film, according to producing needs, film can be less than 1 pair to increasing in pairs or reduce, and the film of cathode side is an anion-exchange membrane.The top of equipment can be added a cover, and also can not add a cover, and from the top drilling charging, from the bottom opening discharging, each input and output material hole all is connected with the pump of outside.In each interval bottom of electric reactor supersonic oscillator is installed simultaneously, anodic-cathodic is connected with anodal with the negative pole of external dc power respectively, supersonic oscillator is connected with the external ultrasound wave producer, ultrasonic unit can start simultaneously when the electricity reaction unit started, because the shock energy that ultrasonic wave produces stops the deposition of viscosity organic matter at film surface and electrode surface, thereby alleviate film plug-hole and electrode fouling, make each indoor liquid keep the prolonged agitation state simultaneously, more help the synthetic and electrodialysis dealkalize of tough organic matter electricity, the current efficiency height.
Description of drawings
Fig. 1 is a structural representation of the present utility model
As shown in Figure 1, this equipment by 1. cationic membrane and dividing plate 2. anionic membrane and dividing plate 3. anode 4. negative electrode 5. supersonic oscillator 6. shell consist of external direct current power supply; Anodic-cathodic, zwitterion film and dividing plate be according to sequence shown in Figure 1, and cationic membrane and an anionic membrane (containing dividing plate) consist of a film pair, and film can increase according to the needs of output or reduce number; The top of this equipment can be to add a cover, and also can be that charging hole is opened in sealing, and discharge opening is opened in the bottom, and feed inlet and outlet all is connected with external pump; Supersonic oscillator connects the external ultrasound wave producer, and anode and cathode connects respectively negative pole and the positive pole of external dc power; The structure of cathodic region and anode region can cooperate the structure of electrode to do corresponding adjustment.
Fig. 2 is that the utility model reclaims the principle schematic of contained NaOH in the feed liquid, is labeled as 1. 2. 3. 4. 5. 6. shell of supersonic oscillator of negative electrode of anode of anionic membrane and dividing plate of cationic membrane and dividing plate among the figure.
The specific embodiment
As shown in Figure 1, the utility model by 1. cationic membrane and dividing plate 2. anionic membrane and dividing plate 3. anode 4. negative electrode 5. supersonic oscillator 6. shell constitute, supersonic oscillator is connected with the external ultrasound wave producer, anodic-cathodic is connected with anodal with the dc power cathode of outside respectively, the cathodic region generates xylitol with the indirect electroreduction of the xylose solution of alkaline activation, by the electrodialysis dealkalize, its dealkalize input and output material as shown in Figure 2 then; Anode region glucose electroxidation generates the last electrodialysis desalination of calcium gluconae with calcium carbonate reaction more simultaneously; The wood sugar activating solution enters the cathodic region and carries out indirect electroreduction from the top, discharge from the bottom, cathodic region, pass back into the dialysing compartment of electric reactor again by mode as shown in Figure 2, obtain the xylitol solution and the sig water of purifying, the alkali lye composition of gained is single, can direct reuse, also can pass back into rare alkali lye the alkali chamber, obtain the alkali lye of enrichment.In electroreduction, the oxidized generation gluconic acid of the glucose in anode pond reacts with calcium carbonate again, generates calcium gluconae and carbon dioxide, the calcium gluconate solution of finishing reaction obtains the calcium gluconate solution and the calcium carbonate weak solution that purify by electrodialysis chamber's desalination.
Its anode reaction formula: H
2O+e-→ H+OH
-
C
5H
10O
5+2H→C
5H
12O
5
Its anode reaction formula: 2H
2O → 4H
+2O+4e-
C
6H
12O
6+2O+CaCO
3→Ca(C
6H
11O
7)
2+CO
2+H
2O
Claims (4)
1. ultrasonic wave auxiliary electrical reactor, it is to be made of anion and cation exchange membrane and dividing plate, anodic-cathodic, supersonic oscillator and shell, it is characterized in that negative electrode is connected with outside dc power cathode, positive electrode is connected with the dc power anode of outside respectively, and supersonic oscillator is connected with the external ultrasound wave producer.
2. electric reactor according to claim 1, it is characterized in that zwitterion film and dividing plate, anodic-cathodic are arranged in parallel in order, anode-side begins to arrange with anion-exchange membrane and dividing plate, it is right that cation-exchange membrane and dividing plate and anion-exchange membrane and dividing plate constitute a film, according to producing needs, film can be less than 1 pair to increasing in pairs or reduce, and the film of cathode side is an anion-exchange membrane.
3. electric reactor according to claim 1 is characterized in that supersonic oscillator is installed in the bottom of each chamber.
4. electric reactor according to claim 1 is characterized in that the top of equipment can be added a cover, and also can not add a cover, and from the top drilling charging, from the bottom opening discharging, each input and output material hole all is connected with the pump of outside.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010205759171U CN201862409U (en) | 2010-10-26 | 2010-10-26 | Ultrasonic auxiliary electric reactor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010205759171U CN201862409U (en) | 2010-10-26 | 2010-10-26 | Ultrasonic auxiliary electric reactor |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN201862409U true CN201862409U (en) | 2011-06-15 |
Family
ID=44133577
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2010205759171U Expired - Fee Related CN201862409U (en) | 2010-10-26 | 2010-10-26 | Ultrasonic auxiliary electric reactor |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN201862409U (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109455797A (en) * | 2018-12-29 | 2019-03-12 | 东莞职业技术学院 | A kind of non-preparation facilities and preparation method thereof for drinking strong basicity electrolytic ionic water |
-
2010
- 2010-10-26 CN CN2010205759171U patent/CN201862409U/en not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109455797A (en) * | 2018-12-29 | 2019-03-12 | 东莞职业技术学院 | A kind of non-preparation facilities and preparation method thereof for drinking strong basicity electrolytic ionic water |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20110615 Termination date: 20151026 |
|
| EXPY | Termination of patent right or utility model |