CN201778205U - Production line of colored triangular acrylic fiber - Google Patents
Production line of colored triangular acrylic fiber Download PDFInfo
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- CN201778205U CN201778205U CN2010202939628U CN201020293962U CN201778205U CN 201778205 U CN201778205 U CN 201778205U CN 2010202939628 U CN2010202939628 U CN 2010202939628U CN 201020293962 U CN201020293962 U CN 201020293962U CN 201778205 U CN201778205 U CN 201778205U
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Abstract
The utility model relates to a production line of colored triangular acrylic fiber, in particular to a production line of colored triangular acrylic fiber with multiple color systems and small color difference, i.e. a production line for producing colored triangular acrylic fiber by using solution polymerization and sodium sulfocyanate wet spinning. The production line uses a strip-shaped arched dyeing solution injector head which comprises an injector head base, an injector head cap and a dyeing solution inlet pipe; the cross section of the strip-shaped arched dyeing solution injector head is in a hollow T shape; the injector head cap is a strip-shaped semi-cylindrical surface; and a plurality of through spray holes are arranged on the injector head cap alternately. The utility model provides a production line of colored triangular acrylic fiber with multiple color systems, fresh color and uniform dyeing, which can be directly used for post-spinning without post-spinning dyeing, thereby overcoming the dyeing quality defects of difficult deep color dying, the occurrence of colored spots and stripes and fiber whitening, simplifying the processing process, reducing the cost and shortening the processing cycle.
Description
Technical field
The utility model relates to a kind of production line that the color triangle acrylic fibers are arranged, particularly relate to the production line that the color triangle acrylic fiber is arranged that a kind of polychrome is, aberration is little, just a kind of polymerisation in solution and sodium sulfocyanate wet spinning of adopting produced the production line that route production has the color triangle acrylic fiber.
Background technology
Adopt the profile spinneret of non-circular pass,, can produce the triangle acrylic fiber of white through spinning technique optimization and improvement, again by after spin and adopt bulk fibre high temperature decatize mode to dye.Have multiple colouring problem thus: the glass transition temperature of acrylic fibers under humid tropical condition is 70~80 ℃, and the intensification when therefore dyeing must strictly be controlled, and needs to add accelerant or retarding agents according to dying shade.And the production technology difference of fiber (dry-spinning, wet spinning, comonomer form), dyestuff kind (performance) difference need be selected different dyeings for use.It is improper to control slightly, and very easily specking appears in the look flower.The aberration desired value (DEcmc) that characterizes colored fibre level-dyeing property and repeatability is usually greater than 1.5.In addition, after spin dyeing and need carry out in batches, unavoidable between each batch product in the difference of aspects such as color and luster, feel or outward appearance.Energy consumption height and coloured sewage quantity are big simultaneously, have also prolonged the process-cycle of product.All factors have all caused the fibre loss rate to improve, and have increased cost of processing.
At present, the method for conventional color acrylic fibre fiber production has endless tow continuous dyeing method, original liquid coloring method, gel staining method.Wherein endless tow continuous dyeing method is consistent with back spinning short fiber dyeing mechanism, and the finished product tow is carried out high temperature pad dyeing, aberration between only having solved batch, and other problems still exists, and only is fit to small lot batch manufacture.The original liquid coloring method is before spinning spinning solution to be mixed with pigment, makes coloured spinning solution, directly carries out spinning production.The original liquid coloring method of CN117004C, CN1523161, CN1465758A explanation exists pigment to grind, and the granules of pigments particle diameter is bigger in coloured stoste, and the spinning difficulty increases, and chromatogram is few.Gel staining method is with liquid dyes the as-spun fibre that is under the gel state to be dyeed in the acrylic fibre wet spinning process.The dyestuff allotment is flexible, so colour system is many, chromatogram is wide.4 kinds of representative in the world acrylic Fibre Gel Dyeing process routes have been introduced in " Kingsoft oiling fibre " the 4th phase of calendar year 2001 " application of gel-colored technology in acrylic fibers NaSCN two-step process ", domestic also have acrylic fibers company to introduce wherein Solutia, Sterling technology to produce conventional color acrylic fibre, as " Kingsoft oiling fibre " the 1st phase in 2004 " gel-colored technical optimization ".But it is solvent that Solutia company, Courtaulds company and Snia company adopt DMAC, NaSCN and DMF respectively, all is in stretching or the stretching poststaining, and dyeing time is short, and difficulty is dyed dark color.And after stretched, the amorphous region degree of orientation of fiber improves, and internal capillary is elongated and attenuates simultaneously, influences the infiltration of dyestuff, level-dyeing property variation, Yi Sehua.Especially DMAC and DMF are organic solvent, the spinning solution concentration of this process route adopts the NaSCN method of inorganic solvent to double above, so fibre structure is finer and close during spinning technique, the fibrous inside voidage is little, the cavity is little, dyestuff penetration is slow during dyeing, and dyeing and ventilative time will be grown, and level-dyeing property is poor than the NaSCN method.Sterling company is solvent with NaSCN, and to spray dyeing before the conventional acrylic fibers employing stretching of circular cross-section, shower is in the relative arranged vertical in tow two sides.Shortcoming is that dyeing time is grown (>30 seconds), and for dye liquor is penetrated in the tow as much as possible, spray pressure is big, has the gel monofilament phenomenon that is thrust.Especially wet spinning triangle acrylic fibers adopt and accelerate the solidification forming mode, and fiber weakness is big relatively, easier thrusting.Road hot-stretch after the gelatine silk that is thrust can't be finished, coloured light is different from the fiber that stretched, and is prone to aberration, and the powder height.In addition, for guaranteeing higher spray pressure, the shower top nozzle distributes less, and spacing is bigger, and owing to constantly circulate through the dye liquor of tow, nozzle is easily stifled, in case relatively the nozzle of arranging can't avoid that plug-hole causes on dye the dead angle.So it is higher dyeing striped probability to occur, even whiting is arranged.The DEcmc fluctuation is bigger, sometimes greater than 1.0, even 1.2.
In sum, wet spinning triangle acrylic fibers are because its each side physical and mechanical properties and dyeability are different from conventional acrylic fibers, so need more the improvement to satisfy its performance requirement on the preparation method, to disclose a kind of be the production line that the wet method of solvent is spun the color triangle acrylic fibers with NaSCN and also still there is not document now.
Summary of the invention
Technical problem to be solved in the utility model is at the above-mentioned state of the art, and a kind of production line that the color triangle acrylic fibers are arranged that spins the polychrome system spun after dyeing can be directly used in, bright-colored and even dyeing after not needing is provided.This production line relates to a kind of special dye liquor injector head, in polymerisation in solution and the production of sodium sulfocyanate wet spinning technology route the color triangle acrylic fiber is arranged, avoided difficult dyeing quality defective of dying dark color, look flower, striped even fiber whiting, and simplified processing process, reduce cost, shorten the process-cycle.
The utility model solves the problems of the technologies described above the technical scheme that is adopted:
A kind of production line that the color triangle acrylic fibers are arranged comprises successively: polymeric kettle, demonomerization tower, deaeration tower, stoste filter press, spinning machine, preliminary draft machine, tow rinsing maching, dyeing machine, hot drawing machine, oiling machine, rotary drum dryer, crimping machine, setting machine, cutting machine, baling press;
Wherein, dyeing machine is provided with some strip arc dye liquor injector heads, described strip arc dye liquor injector head is by nozzle boss, nozzle cap and dye liquor inlet tube constitute, cross section is the "T"-shaped strip of hollow arc shower nozzle, nozzle cap is the semi-cylindrical of strip, the be staggered spray orifice of some perforations of described nozzle cap.
As optimized technical scheme:
Wherein, aforesaid a kind of production line that the color triangle acrylic fibers are arranged, wherein, described spray orifice is the wicker leaf shape spray orifice, also can be ellipse spray orifice, rectangle spray orifice and circular spray orifice; There is the longitudinal fluting of the spray orifice of connection on same straight line on the surface of described nozzle cap.
Aforesaid a kind of production line that the color triangle acrylic fibers are arranged, wherein, described longitudinal fluting is " V " connected in star, " V " shape opening is outside; The angle theta of described " V " shape is 60 °; Also can be " U " shape groove, " U " shape opening be outside; Or dovetail groove, the long limit of trapezoidal parallel edges is a notch; When groove was " U " shape groove, described " U " trench bottom aperture widths was not more than 1/3 of U-lag mouth width; When groove was dovetail groove, the bottom land width of described dovetail groove was 1/3 of a width of rebate.。Described spray orifice is vertically lined up three rows, and every round is equally spaced; Also can arrange the pore size distribution that is staggered front to back arbitrarily according to injector head and spray orifice size.The cylindrical of described dye liquor inlet tube has screw thread; Described nozzle boss connects with welding manner with nozzle cap.
Aforesaid a kind of production line that the color triangle acrylic fibers are arranged, wherein, described nozzle cap is a face of cylinder part, is of a size of: length * arc is wide=100mm * 50mm, face of cylinder diameter is 180mm; The major parameter of spray orifice satisfies following relational expression:
The willow leaf of single wicker leaf shape spray orifice is long to be 2k mm,
Willow leaf is wide to be 2k/3mm,
Total hole count n satisfies: n=23-3k, wherein, k=1~6, preferred k=3 or 4.
The used dye liquor injector head of dyeing machine adopts the semi-cylindrical arc shower nozzle of strip, and arc length * wide is 100 * 50mm, and is distributed on the shower with 100~120mm spacing.Each ejection face is a face of cylinder part, face of cylinder diameter is 180mm, each nozzle surface has 3 60 ° of grooves at length direction, a plurality of wicker leaf shape spray orifices that are staggered front to back arrangement distribute, every round is equally spaced, the length of single hole (2k) mm (k=1~6), wide is (2k/3) mm, hole count is that n (individual) satisfies: n=23-3k.Preferred k=3,4, i.e. single hole hole length=6mm, 8mm, the hole is wide=2mm, 2.7mm, hole count n=14,11.Shower nozzle is apart from tow 20~25mm.Thus, jetting fluid wide coverage and intersection need not bigger spray pressure, and gelatine silk can not thrust, and are particularly useful for adopt accelerating the solidification forming mode, fiber weakness is big relatively, the wet spinning triangle acrylic fibers of not easy-to-use high pressure nozzle spray staining method.
Beneficial effect
A kind of production line that the color triangle acrylic fibers are arranged of the present utility model has adopted the how shower nozzle of the arc arrangement of staggered spray orifice of strip, has simplified dyeing course, improved dyeing efficient, avoided look flower, fringe phenomena, DEcmc is stable less than 0.3, can guarantee fiber quality; And can reduce shower, shorten dyeing time.The dye liquor shower nozzle of a kind of online dyeing apparatus of the present utility model, jetting fluid wide coverage and intersection need not bigger spray pressure, and gelatine silk can not thrust, and is particularly useful for powerful little, not impact-resistant fiber.And interlock because spray nozzle is arranged, stop up the hidden danger that influences local tow colouring because of indivedual spray orifices when having eliminated single tube nozzle spray, the fiber whiting does not take place, fiber colour is even, and aberration is minimum.In addition, easy to operate, single injector head has been realized the effect of many single mouth showers, shortens dyeing time greatly, and color is switched flexibly, and the transitional fibre of generation is few, the quality problems of avoiding fiber, yarn or fabric to bring in road, back dyeing process.
Description of drawings
Fig. 1 is a kind of production line formation schematic diagram that the color triangle acrylic fibers are arranged of the present utility model
Fig. 2 is the vertical view of a kind of dye liquor injector head of the present invention
Fig. 3 is the A-A cross-sectional view of a kind of dye liquor injector head of the present invention
Wherein 1 is nozzle boss; The 2nd, the dye liquor inlet tube; The 3rd, spray orifice; The 4th, groove; The 5th, screw thread; The 6th, nozzle cap
The specific embodiment
Below in conjunction with the specific embodiment, further set forth the utility model.
The present invention also provides a kind of production line that the color triangle acrylic fibers are arranged, as shown in Figure 1, comprise successively: polymeric kettle, demonomerization tower (taking off Dan Ta), deaeration tower, stoste filter press, spinning machine, preliminary draft machine, tow rinsing maching, dyeing machine, hot drawing machine, oiling machine, rotary drum dryer, crimping machine, setting machine, cutting machine, baling press;
Wherein, dyeing machine is provided with some strip arc dye liquor injector heads, shown in Fig. 2 and 3, described strip arc dye liquor injector head is the arc shower nozzle of the "T"-shaped strip of hollow by nozzle boss (1), nozzle cap (6) and dye liquor inlet tube (2) formation, cross section, nozzle cap (6) is the semi-cylindrical of strip, described nozzle cap (6) the some spray orifices (3) that are staggered.
Aforesaid a kind of production line that the color triangle acrylic fibers are arranged, wherein, described spray orifice (3) is the wicker leaf shape spray orifice, also can be ellipse spray orifice, rectangle spray orifice and circular spray orifice; There is the longitudinal fluting (4) of the spray orifice (3) of connection on same straight line on the surface of described nozzle cap (6).
Aforesaid a kind of production line that the color triangle acrylic fibers are arranged, wherein, described longitudinal fluting (4) is " V " connected in star, " V " shape opening is outside; The angle theta of described " V " shape is 60 °; Also can be " U " shape groove, " U " shape opening be outside; Or dovetail groove, the long limit of trapezoidal parallel edges is a notch; When groove was " U " shape groove, described " U " trench bottom aperture widths was not more than 1/3 of U-lag mouth width; When groove was dovetail groove, the bottom land width of described dovetail groove was 1/3 of a width of rebate.Described spray orifice (3) is vertically lined up three rows, and every round is equally spaced; Also can arrange the pore size distribution that is staggered front to back arbitrarily according to injector head and spray orifice size.The cylindrical of described dye liquor inlet tube (2) has screw thread (5), and described screw thread adopts 60 ° of fastening connections of closely-pitched angular thread of common metric system, also the dye liquor injector head can be connected with shower by flange.Described nozzle boss (1) connects with welding manner with nozzle cap (6).
Aforesaid a kind of production line that the color triangle acrylic fibers are arranged, wherein, described nozzle cap (6) is a face of cylinder part, is of a size of: length * arc is wide=100m * 50mm, face of cylinder diameter is 180mm; The major parameter of spray orifice (3) satisfies following relational expression:
The willow leaf of single wicker leaf shape spray orifice is long to be 2k mm,
Willow leaf is wide to be 2k/3mm,
Total hole count n satisfies: n=23-3k, wherein, k=1~6, preferred k=3 or 4.
Aforesaid a kind of dye liquor injector head, described longitudinal fluting (4) degree of depth is k mm.
A kind of dye liquor injector head of the present invention is distributed on the shower with 100~120mm spacing, and the dye liquor injector head is connected on the shower by screw thread (5).Each nozzle cap (6) is a face of cylinder part, face of cylinder diameter is 180mm, each nozzle cap (6) has 3 60 ° grooves (4) at length direction, a plurality of wicker leaf shape spray orifices (3) that are staggered front to back arrangement distribute, every round is equally spaced, willow leaf length=6mm, the 8mm of single spray orifice, willow leaf is wide=2mm, 2.7mm, hole count n=14,11.Dye liquor enters by spray orifice from dye liquor inlet tube (2) and penetrates, and shower nozzle is apart from tow 20~25mm.Thus, jetting fluid wide coverage and intersection need not bigger spray pressure, and gelatine silk can not thrust, and are particularly useful for powerful little, not impact-resistant fiber.And interlock because spray nozzle is arranged, stop up the hidden danger that influences local tow colouring because of indivedual spray orifices when having eliminated single tube nozzle spray, the fiber whiting does not take place, fiber colour is even, and aberration is minimum.In addition, easy to operate, single injector head has been realized the effect of many single mouth showers, shortens dyeing time greatly, and color is switched flexibly, and the transitional fibre of generation is few, the quality problems of avoiding fiber, yarn or fabric to bring in road, back dyeing process.
Through evidence, of the present utility model a kind of the production line of color triangle acrylic fibers is arranged is at the characteristics that the color triangle acrylic fibers are arranged, and a kind of employing novel dye liquor shower nozzle---a kind of production line that the color triangle acrylic fibers are arranged of arc shower nozzle of strip is provided; Described dyeing machine is by circulation and the online dyeing of adding the realization flat acrylic of cation dyes.The utility model adopts novel strip arc injector head, and jetting fluid wide coverage and intersection need not bigger spray pressure, and gelatine silk can not thrust, and is particularly useful for powerful little, not impact-resistant fiber; And interlock because spray nozzle is arranged, stop up the hidden danger that influences local tow colouring because of indivedual spray orifices when having solved the nozzle-type spray, not only eliminated look flower, striped, fiber whiting, and fiber colour is even, aberration is little, and DEcmc stablizes less than 0.3; In addition, easy to operate, single injector head has been realized the effect of many single-nozzle formula showers, shortens dyeing time greatly, simplifies dyeing course, and transitional fibre is few, raises the efficiency, and avoids the quality problems of bringing in road, back dyeing process.
Claims (8)
1. the production line that the color triangle acrylic fibers are arranged is characterized in that comprising successively: polymeric kettle, demonomerization tower, deaeration tower, stoste filter press, spinning machine, preliminary draft machine, tow rinsing maching, dyeing machine, hot drawing machine, oiling machine, rotary drum dryer, crimping machine, setting machine, cutting machine, baling press;
Wherein, dyeing machine is provided with some strip arc dye liquor injector heads, described strip arc dye liquor injector head is the arc shower nozzle of the "T"-shaped strip of hollow by nozzle boss (1), nozzle cap (6) and dye liquor inlet tube (2) formation, cross section, nozzle cap (6) is the semi-cylindrical of strip, the be staggered spray orifice (3) of some perforations of described nozzle cap (6).
2. a kind of production line that the color triangle acrylic fibers are arranged according to claim 1 is characterized in that described spray orifice (3) is the wicker leaf shape spray orifice.
3. a kind of production line that the color triangle acrylic fibers are arranged according to claim 1 is characterized in that, there is the longitudinal fluting (4) of the spray orifice (3) of connection on same straight line on the surface of described nozzle cap (6).
4. a kind of production line that the color triangle acrylic fibers are arranged according to claim 3 is characterized in that, described longitudinal fluting (4) is " V " connected in star, and " V " shape opening is outside.
5. a kind of production line that the color triangle acrylic fibers are arranged according to claim 4 is characterized in that, the angle theta of described " V " shape is 60 °.
6. a kind of production line that the color triangle acrylic fibers are arranged according to claim 1 is characterized in that described spray orifice (3) is vertically lined up three rows, and every round is equally spaced.
7. a kind of production line that the color triangle acrylic fibers are arranged according to claim 1 is characterized in that the cylindrical of described dye liquor inlet tube (2) has screw thread (5); Described nozzle boss (1) connects with welding manner with nozzle cap (6).
8. a kind of production line that the color triangle acrylic fibers are arranged according to claim 1 is characterized in that, described nozzle cap (6) is a face of cylinder part, is of a size of: length * arc is wide=and 100mm * 50mm, face of cylinder diameter is 180mm; The major parameter of spray orifice (3) satisfies following relational expression:
The willow leaf of single wicker leaf shape spray orifice is long to be 2k mm,
Willow leaf is wide to be 2k/3mm,
Total hole count n satisfies: n=23-3k, wherein, k=1~6, preferred k=3 or 4.
Priority Applications (1)
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CN2010202939628U CN201778205U (en) | 2010-08-17 | 2010-08-17 | Production line of colored triangular acrylic fiber |
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CN2010202939628U CN201778205U (en) | 2010-08-17 | 2010-08-17 | Production line of colored triangular acrylic fiber |
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CN201778205U true CN201778205U (en) | 2011-03-30 |
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CN2010202939628U Expired - Fee Related CN201778205U (en) | 2010-08-17 | 2010-08-17 | Production line of colored triangular acrylic fiber |
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2010
- 2010-08-17 CN CN2010202939628U patent/CN201778205U/en not_active Expired - Fee Related
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C17 | Cessation of patent right | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20110330 Termination date: 20130817 |